Environmental hazard — Assessment of chemicals and products

Part III: The Limits to Single Compound Assessment The principles and basic assumptions of single compound assessment are briefly reviewed. Limitations to this approach are shown, especially with regard to complex mixtures of similar substances, substitution products, and complicated (final) products containing chemicals and materials produced by the chemical industry. A new thinking in product lines and life cycles is emerging, leading to new assessment methods. In some cases, substitution has not improved the environmental performance of products, since very similar chemicals were used as substitutes.     

Environmental Auditing—A Timely and Effective Tool

The requirements of environmental regulations imposed on industry are complex and expensive. As these regulations have developed, corporate compliance programs have had to become more sophisticated. For many, this means that an environmental auditing program is now timely (or overdue) for organizing their approach to meeting the constraints of these regulations. Contributing to this timeliness is a renewed emphasis by regulators on enforcement activities. This paper discusses what environmental auditing is and what it consists of, gives examples from a few approaches which are currently being used, and reviews some of its benefits and liabilities.     

The Petroleum Refining Industry—Air Pollution Problems and Control Methods

Polyurethane foam was incorporated as a prefilter on standard hi-volume samplers of the National Air Sampling Network (NASN) in an exploratory study. The foam selectively filtered particles of various sizes. The characteristics of the particles passing through the foam approached the respirable size fraction as defined by reports of the Atomic Energy Commission. The respirable fraction was then collected on a glass-fiber filter. Parameters such as pore size and thickness of the foam, air flow rates, and loadings were studied to determine their effects on the filtration of “respirable” dust. Ambient air was the particulate source, and sizing was accomplished by an Andersen sampler coupled with nephelometric analyses. Some sizing was also done microscopically. The foam was evaluated at several locations to account for possible variations in ambient air over areas of different industrial complexity.     

Environmental Monitoring and Research in the Abisko Area—An Overview

This article gives an overview of the studies on the environment surrounding the Abisko Scientific Research Station in Swedish Lapland. The long-term monitoring of the Station on processes related to the climate, and to the physical, biotic, and chemical environmental conditions is particularly addressed. Some variables are recorded since more than 100 years. The obtained data in combination with results from short-term studies and manipulation experiments are important to understand past and future conditions of the ecosystems. This has practical applications for the planning of tourism, transports, reindeer herding, and for societal purposes.     

ESTROM,Environmental Science and Technology in Romania—programme overview

Environmental Science and Pollution Research -     

Environmental factors and unhealthy lifestyle influence oxidative stress in humans—an overview

Oxygen is the most essential molecule for life; since it is a strong oxidizing agent, it can aggravate the damage within the cell by a series of oxidative events including the generation of free radicals. Antioxidative agents are the only defense mechanism to neutralize these free radicals. Free radicals are not only generated internally in our body system but also trough external sources like environmental pollution, toxic metals, cigarette smoke, pesticides, etc., which add damage to our body system. Inhaling these toxic chemicals in the environment has become unavoidable in modern civilization. Antioxidants of plant origin with free radical scavenging properties could have great importance as therapeutic agents in several diseases caused by environmental pollution. This review summarizes the generation of reactive oxygen species and damage to cells by exposure to external factors, unhealthy lifestyle, and role of herbal plants in scavenging these reactive oxygen species.     

1990 Update of the U.S. Environmental Protection Agency’s SITE Emerging Technology Program

The Superfund Amendments and Reauthorization Act of 1986 (SARA) directed the U.S. Environmental Protection Agency (EPA) to establish an Alternative/Innovative Treatment Technology Research and Demonstration Program. The EPA’s Office of Solid Waste and Emergency Response and the Office of Research and Development established a program called the Superfund Innovative Technology Evaluation (SITE) Program to accelerate the development and use of innovative cleanup technologies at hazardous waste sites. The SITE Program comprises of five areas: the Demonstration Program, the Emerging Technology Program, the Measurement and Monitoring Technologies Development Program, the Innovative Technologies Program, and the Technology Transfer Program.

This paper discusses the Emerging Technology Program (ETP) that supports the development of technologies that have been successfully tested at bench-scale level. Before a technology can be accepted into the Emerging Technology Program, sufficient data must be available to validate its basic concepts. The ETP enters into a co-funding effort with developers for a one- or two-year effort. Developers are responsible for contributing financial support and conducting the developmental research. After development and data collection, the technology’s performance is documented and a report is prepared, which may include recommendations for further developing the technology. If test results are encouraging, a technology may proceed with approval to a field demonstration.

The purpose of this article is to provide the reader with (1) an introduction to the Emerging Technology Program (2) an understanding of how the program operates (3) a summary of those technologies currently being tested and evaluated under the program and (4) information on how to apply to the program.     

CEPA—The Canadian. Environmental Protection Act

CEPA, the Canadian Environmental Protection Act, is a law of the Parliament of Canada that provides a framework for protecting Canadians from all forms of pollution caused by toxic substances. CEPA improves the federal government’s ability to manage chemical substances. The approach is comprehensive. It encompasses the entire life cycle of toxic substances— from their development and manufacture, through the stages of transport, distribution, use, and storage, to their ultimate disposal. CEPA not only guarantees a safer environment for all Canadians, it also provides for better enforcement and tougher punishment of polluters than ever before.     

Resilience and Challenges of Marine Social–Ecological Systems Under Complex and Interconnected Drivers

In this paper, we summarize the contributions made by an interdisciplinary group of researchers from different disciplines (biology, ecology, economics, and law) that deal with key dimensions of marine social–ecological systems. Particularly, the local and global seafood provision; the feasibility and management of marine protected areas; the use of marine ecosystem services; the institutional dimension in European fisheries, and the affordable models for providing scientific advice to small-scale fisheries. This Special Issue presents key findings from selected case studies around the world available to educators, policy makers, and the technical community. Together, these papers show that a range of diverse ecological, economic, social, and institutional components often mutually interact at spatial and temporal scales, which evidence that managing marine social–ecological systems needs a continuous adaptability to navigate into new governance systems.     

Environmental prevalence,fate, impacts,and mitigation of microplastics—a critical review on present understanding and future research scope

Environmental Science and Pollution Research - Microplastics are considered to be ubiquitous and widespread emerging contaminants. They are persistent in the nature and pose considerable harm to...     

Environmental analysis of Turkey’s aggregated and sector-level CO2 emissions

Environmental Science and Pollution Research - Turkey’s ecological footprint has recently been increasing, while its biocapacity has been decreasing. Furthermore, the country’s CO2...     

Combining Environmental Factors and Agriculturalists’ Observations of Environmental Changes in the Traditional Terrace System of the Amalfi Coast (Southern Italy)

Terraces are traditional engineered ecosystems that affect the hydro-geological equilibrium, slope stability, and local communities. The aims of this paper are (i) identifying environmental factors that affect terrace stability in the Amalfi Coast, (ii) defining agriculturalists’ observations on environmental changes within that system and (iii) exploring potentiality of these observations to better define conservation strategies. All available data on physical and ecological factors recognized to affect the terrace system were collected and analyzed. Interviews were conducted with agriculturalists to obtain long-term observations on environmental factors that interact with this system. Landslides are more frequent where rainfall is high and during winter. Fires have an uneven annual distribution, with higher frequency during summers. Agriculturalists detailed complex interactions among environmental factors, economic elements, and terraces. These observations represent a valuable resource for defining causes and effects of abandonment and for better addressing conservation strategies.

Electronic supplementary material

The online version of this article (doi:10.1007/s13280-013-0433-3) contains supplementary material, which is available to authorized users.     

Environmental change and fishermen’s income: is there a poverty trap

Environmental Science and Pollution Research - The unequal cost and benefit led by environmental changes may potentially set China’s rural areas a “Poverty Trap.” Therefore,...     

Remote Sensing Tools Assist in Environmental Forensics:Part II—Digital Tools

This is the second part of a two-part discussion, in which we will provide an overview of the use of GIS and GPS in environmental analysis and enforcement. Geographic Information Systems (GIS) describes a system which manages, analyses and displays geographic information. Environmental applications include analysis of source, extent and transport of contaminants, nonpoint runoff modeling, flood control, and emergency response support. The ability to examine spatial relationships between environmental observations and other mapped and historical information, and to communicate these relationships to others, makes GIS valuable in environmental forensics. The US Environmental Protection Agency currently requires the inclusion of locational information with all other environmental data that is collected. Geographic Information Systems is a complex tool that requires careful planning and design to be successfully implemented. Choices in hardware, software and data development must be based on evaluation of project objectives, analytical requirements, data availability and data development considerations. Data sets must be evaluated and documented with metadata. The Global Positioning System (GPS) is a satellite-based system which provides highly accurate, three-dimensional position information anywhere on the earth’s surface. Using portable radio receivers, field analysts can easily record the positions of spill sites, sampling locations and other environmental features. Spatial accuracy of GPS ranges from 20–30 m (single receiver) to 1–5 m (differential GPS) for navigation-grade instruments, and down to millimeter level accuracy for geodetic units. Global Position Systems can be used not only to capture spatial information into a GIS system, but also to evaluate and quantify the spatial accuracy of existing digital map data, and to provide control points for existing aerial photographs and other remotely-sensed data.     

GC × GC—A New Analytical Tool For Environmental Forensics

Comprehensive two-dimensional gas chromatography, GC × GC, is a new analytical tool with a tremendous capability to separate and identify organic compounds in complex environmental samples. GC × GC uses two different chromatography columns coupled serially by a modulator to produce a volatility by polarity separation and distribute compound peaks across a two-dimensional retention time plane. The two-dimensional separation produces an order of magnitude more resolved peaks than traditional GC methods. The grouping or ordering of the peaks in the GC × GC chromatogram facilitates the identification of unknown compounds and the comparison of complex environmental samples. When a mass spectrometer detector is used, each resolved GC × GC peak yields a single-component, interference-free mass spectrum that leads to accurate matching with mass spectral libraries. GC × GC examination of marine sediment extracts identified a wide variety of chemical contaminants including polychlorinated biphenyls, p -nonylphenol isomers, polycyclic aromatic hydrocarbons, benzotriazoles, and the alkane, cycloalkane, alkylbenzene, alkylnaphthalene, and biomarker fractions of petroleum. The two-dimensional GC × GC chromatogram image permits rapid screening of the sediment extracts for these and other unknown contaminants.     

Environmental and social impacts of the increasing number of geothermal power plants (Büyük Menderes Graben—Turkey)

Environmental Science and Pollution Research - The use of renewable energy is critical to the long-term development of global energy. Geothermal power plants (GPPs) differ in the technology they...     

Environmental and socioeconomic assessment of impacts by mining activities—a case study in the Certej River catchment,Western Carpathians,Romania

Background, aim and scope

In the region of the Apuseni Mountains, part of the Western Carpathians in Romania, metal mining activities have a long-standing tradition. These mining industries created a clearly beneficial economic development in the region. But their activities also caused impairments to the environment, such as acid mine drainage (AMD) resulting in long-lasting heavy metal pollution of waters and sediments. The study, established in the context of the ESTROM programme, investigated the impact of metal mining activities both from environmental and socioeconomic perspectives and tried to incorporate the results of the two approaches into an integrated proposition for mitigation of mining-related issues.

Study site

The small Certej catchment, situated in the Southern Apuseni Mountains, covers an area of 78 km². About 4,500 inhabitants are living in the basin, in which metal mining was the main economic sector. An open pit and several abandoned underground mines are producing heavy metal-loaded acidic water that is discharged untreated into the main river. The solid wastes of mineral processing plants were deposited in several dumps and tailings impoundment embodying the acidic water-producing mineral pyrite.

Methods

The natural science team collected samples from surface waters, drinking water from dug wells and from groundwater. Filtered and total heavy metals, both after enrichment, and major cations were analysed by inductively coupled plasma optical emission spectroscopy (ICP-OES). Major anions in waters, measured by ion chromatography, alkalinity and acidity were determined by titration. Solid samples were taken from river sediments and from the largest tailings dam. The latter were characterised by X-ray fluorescence and X-ray diffraction. Heavy metals in sediments were analysed after digestion. Simultaneously, the socioeconomic team performed a household survey to evaluate the perception of people related to the river and drinking water pollution by way of a logistic regression analysis.

Results and discussion

The inputs of acid mine waters drastically increased filtered heavy metal concentrations in the Certej River, e.g. Zn up to 130 mg L⁻¹, Fe 100 mg L⁻¹, Cu 2.9 mg L⁻¹, Cd 1.4 mgL⁻¹ as well as those of SO₄ up to 2.2 g L⁻¹. In addition, river water became acidic with pH values of pH 3. Concentrations of pollutant decreased slightly downstream due to dilution by waters from tributaries. Metal concentrations measured at headwater stations reflect background values. They fell in the range of the environmental quality standards proposed in the EU Water Framework Directive for dissolved heavy metals. The outflow of the large tailing impoundment and the groundwater downstream from two tailings dams exhibited the first sign of AMD, but they still had alkalinity.

Most dug wells analysed delivered a drinking water that exhibited no sign of AMD pollution, although these wells were a distance of 7 to 25 m from the contaminated river. It seems that the Certej River does not infiltrate significantly into the groundwater.

Pyrite was identified as the main sulphide mineral in the tailings dam that produces acidity and with calcite representing the AMD-neutralising mineral. The acid–base accounting proved that the potential acid-neutralising capacity in the solid phases would not be sufficient to prevent the production of acidic water in the future. Therefore, the open pits and mine waste deposits have to be seen as the sources for AMD at the present time, with a high long-term potential to produce even more AMD in the future.

The socioeconomic study showed that mining provided the major source of income. Over 45% of the households were partly or completely reliant on financial compensations as a result of mine closure. Unemployment was considered by the majority of the interviewed persons as the main cause of social problems in the area. The estimation of the explanatory factors by the logistic regression analysis revealed that education, household income, pollution conditions during the last years and familiarity with environmental problems were the main predictors influencing peoples’ opinion concerning whether the main river is strongly polluted. This model enabled one to predict correctly 77% of the observations reported. For the drinking water quality model, three predictors were relevant and they explained 66% of the observations.

Conclusions

Coupling the findings from the natural science and socioeconomic approaches, we may conclude that the impact of mining on the Certej River water is high, while drinking water in wells is not significantly affected. The perceptions of the respondents to pollution were to a large extent consistent with the measured results.

Recommendations and perspectives

The results of the study can be used by various stakeholders, mainly the mining company and local municipalities, in order to integrate them in their post-mining measures, thereby making them aware of the potential long-term impact of mining on the environment and on human health as well as on the local economy.

     

Environmental cost of sustainable development and climate change: can SAARC shift some liability with renewable energy and efficiency?

Environmental Science and Pollution Research - Sustainable development holds the key not to resolve the problems every nation is facing these days but also for long-lasting effects. In the current...