WATER QUALITY AND SOURCE OF FRESHWATER DISCHARGE TO THE CALOOSAHATCHEE ESTUARY,FLORIDA1

ABSTRACT: The Caloosahatchee River has two major sources of freshwater one from its watershed and the other via an artificial connection to Lake Okeechobee. The contribution of each source to the freshwater discharge reaching the downstream estuary varies and either may dominate. Routine monitoring data were analyzed to determine the effects of total river discharge and source of discharge (river basin, lake) on water quality in the downstream estuary. Parameters examined were: color, total suspended solids, light attenuation, chlorophyll a, and total and dissolved inorganic nitrogen and phosphorus. In general, the concentrations of color, and total and dissolved inorganic nitrogen increased, and total suspended solids decreased, as total discharge increased. When the river basin was the major source, the concentrations of nutrients (excepting ammonia) and color in the estuary were relatively higher than when the lake was the major source. Light attenuation was greater when the river basin dominated freshwater discharge to the estuary. The analysis indicates that water quality in the downstream estuary changes as a function of both total discharge and source of discharge. Relative to discharge from the river basin, releases from Lake Okeechobee do not detectably increase concentrations of nutrients, color, or TSS in the estuary.     

EVALUATING THE INFLUENCE OF SOURCE BASINS ON DOWNSTREAM WATER QUALITY IN THE MISSISSIPPI RIVER1

ABSTRACT: Chemical variability in the Mississippi River during water years 1989 to 1998 was evaluated using stream discharge and water‐quality data in conjunction with the DAFLOW/BLTM hydraulic model. Model simulations were used to identify subbasin contributions of water and chemical constituents to the Mississippi River upstream from its confluence with the Ohio and the Mississippi River and at the Atchafalaya Diversion in Louisiana. Concentrations of dissolved solids, sodium, and sulfate at the Thebes site showed a general decreasing trend, and concentrations of silica and nitrate showed a general increasing trend as the percentage of discharge from the Mississippi River upstream from Grafton increased. Concentrations of most chemical constituents in the Mississippi River at the Atchafalaya Diversion exhibited a decreasing trend as the percentage of water from the Ohio River increased. Regression models were used to evaluate the importance of the source of water to the water chemistry in the Mississippi River at Thebes and the Atchafalaya Diversion. The addition of terms in regression equations to account for the percent of water from sub‐basins improved coefficients of determination for predicting chemical concentrations by as much as nine percent at the Thebes site and by as much as 48 percent at the Atchafalaya Diversion site. The addition of source‐water terms to regression equations increased the estimated annual loads of nitrate and silica delivered from the Mississippi River Basin to the Gulf of Mexico by as much as 14 and 13 percent, respectively.     

CONTROL OF NATURAL BRINE SPRINGS IN BRAZOS RIVER BASIN PART II: BRINE DISPOSAL1

ABSTRACT: Water quality in the Brazos River of Texas is seriously degraded by natural salt pollution. Two thousand tons/day of total dissolved solids emanate from brine springs and seeps in the Upper Brazos River drainage. Approximately 45 percent of the total salt load comes from a relatively small flow in the Dove Creek area. The companion paper demonstrates that a system of wells pumping brine at a constant rate of about 2 cfs from the near surface aquifer should eliminate the brine springs in this area. In this paper, injection into deep brine aquifers is shown to be a feasible brine disposal alternative. Four brine aquifers were determined from the literature to be possible injection zones. Accurate net aquifer thickness maps were generated in a 23 by 14 mile area centered on the Dove Creek area for three of the aquifers from an interpretation of 41 well logs. Constant injection for a project life of 100 years was simulated using the SWIFT/486 software. Modeling suggests that one well would be sufficient to inject the entire disposal volume into either the Strawn or Ellenburger Formation.     

SOLIDS DISTRIBUTION IN LAKE CHAPALA,MEXICO1

ABSTRACT: Lake Chapala is the largest natural water body in Mexico and also one of the most important shallow lakes in Latin America. For the past several years it has suffered various environmental problems such as the upstream overuse of water, contamination, and sedimentation. For the past 10 years the lake has had less than 50 percent of its historical water level over the past century. No criteria are reported in the literature that establish a water storage volume that will guarantee water quality conditions necessary for the survival of the lake. After determining the behavior of total solids concentrations in relation to the variations in the lake's depth, we proposed a minimum water column height of 5.0 m, representing a storage volume of about 5,000 Mm³. This volume would result in the recommended water quality standards for total dissolved solids. Calculated distribution maps show that the total solids concentration in the lake has increased since the end of the 1970s. The solids are primarily concentrated in the eastern part of the lake, as a consequence of the high solids discharged from the Lerma River, its main tributary.     

Salt Flushing,Salt Storage,and Controls on Selenium and Uranium: A 31‐Year Mass‐Balance Analysis of an Irrigated,Semiarid Valley

Salinity, selenium, and uranium pose water‐quality challenges for the Arkansas River in southeastern Colorado and other rivers that support irrigation in semiarid regions. This study used 31 years of continuous discharge and specific conductance (SC) monitoring data to assess interannual patterns in water quality using mass balance on a 120‐km reach of river. Discrete sampling data were used to link the SC records to salinity, selenium, and uranium. Several important patterns emerged. Consumptive use reduced discharge by a median value of 33% and drove corresponding increases in salinity and uranium concentrations. Increased water availability for irrigation from rainfall and upstream snowpack in 1995–1999 flushed additional salinity and uranium into the river in 1996–2000; average annual total dissolved solids (salinity) concentrations increased 25%, and loads increased 131%. Smaller flushing events have occurred, sometimes lagging an increase in water availability by about one year. The pattern indicates flushing of salts temporarily stored, evaporatively concentrated, or of geologic origin. Mobilization of selenium from the reach was minor compared to salinity and uranium, and net selenium removal from the river was suggested in some years. Several processes related to irrigation could be removing selenium. The results provide context for efforts to improve water quality in the Arkansas River and rivers in other semiarid regions.     

TEMPORAL VARIABILITY OF WATER QUALITY IN THE ST. LUCIE ESTUARY,SOUTH FLORIDA1

ABSTRACT: Four years of monthly freshwater discharge and constituent concentration data from three tributaries were related to a concurrent series of data for three segments of the St. Lucie Estuary in South Florida using multiple regression and time-series analysis techniques. Water quality parameters examined were dissolved inorganic and total nitrogen and phosphorus, chlorophyll a, total suspended solids, turbidity, and color. On monthly time scales, a multiple regression, which included freshwater discharge, freshwater constituent concentration, and dilution with ocean water (salinity) as independent variables, explained 50 percent or less of the variability in estuarine constituents. No single independent variable explained more variation than another. By contrast, on seasonal (wet, dry) time scales, freshwater discharge explained the bulk of variation in estuarine water quality (up to 93 percent). On monthly time scales, variability in concentrations of nutrients and other constituents may be largely controlled by processes internal to the system. At seasonal time scales, freshwater discharge appears to drive variability in most estuarine water quality parameters examined. Results indicate that management of tributary input on a seasonal basis, with the expectation of achieving seasonal concentration goals in the estuary, would have a higher probability of success than managing on a monthly basis.     

GENERALIZED WATERSHED LOADING FUNCTIONS FOR STREAM FLOW NUTRIENTS1

ABSTRACT: Loading functions are proposed as a general model for estimating monthly nitrogen and phosphorus fluxes in stream flow. The functions have a simple mathematical structure, describe a wide range of rural and urban nonpoint sources, and couple surface runoff and ground water discharge. Rural runoff loads are computed from daily runoff and erosion and monthly sediment yield calculations. Urban runoff loads are based on daily nutrient accumulation rates and exponential wash off functions. Ground water discharge is determined by lumped parameter unsaturated and saturated zone soil moisture balances. Default values for model chemical parameters were estimated from literature values. Validation studies over a three-year period for an 850 km² watershed showed that the loading functions explained at least 90 percent of the observed monthly variation in dissolved and total nitrogen and phosphorus fluxes in stream flow. Errors in model predictions of mean monthly fluxes were: dissolved phosphorus - 4 percent; total phosphorus - 2 percent; dissolved nitrogen - 18 percent; and total nitrogen - 28 percent. These results were obtained without model calibration.     

INTERACTIONS BETWEEN GROUND WATER AND SURFACE WATER IN THE SUWANNEE RIVER BASIN,FLORIDA1

ABSTRACT: Ground water and surface water constitute a single dynamic system in most parts of the Suwannee River basin due to the presence of karst features that facilitate the interaction between the surface and subsurface. Low radon-222 concentrations (below background levels) and enriched amounts of oxygen-18 and deuterium in ground water indicate mixing with surface water in parts of the basin. Comparison of surface water and regional ground water flow patterns indicate that boundaries for ground water basins typically do not coincide with surface water drainage subbasins. There are several areas in the basin where ground water flow that originates outside of the Suwannee River basin crosses surface water basin boundaries during both low-flow and high-flow conditions. In a study area adjacent to the Suwannee River that consists predominantly of agricultural land use, 18 wells tapping the Upper Floridan aquifer and 7 springs were sampled three times during 1990 through 1994 for major dissolved inorganic constituents, trace elements, and nutrients. During a period of above normal rainfall that resulted in high river stage and high ground water levels in 1991, the combination of increased amounts of dissolved organic carbon and decreased levels of dissolved oxygen in ground water created conditions favorable for the natural reduction of nitrate by denitrification reactions in the aquifer. As a result, less nitrate was discharged by ground water to the Suwannee River.     

LOADING FUNCTIONS FOR PREDICTING NUTRIENT LOSSES FROM COMPLEX WATERSHEDS1

ABSTRACT: A loading function methodology is presented for predicting runoff, sediment, and nutrient losses from complex watersheds. Separate models are defined for cropland, forest, urban and barnyard sources, and procedures for estimating baseflow nutrients are provided. The loading functions are designed for use as a preliminary screening tool to isolate the major contributors in a watershed. Input data sources are readily available and the functions do not require costly calibrations. Data requirements include watershed land use and soil information, daily precipitation and temperature records and rainfall erosivities. Comparison of predicted and measured water, sediment, and nutrient runoff fluxes for the West Branch Deleware River in New York, indicated that runoff was underpredicted by about 14 percent while dissolved nutrients were within 30 percent of observed values. Sediment and solid-phase nutrients were overpredicted by about 50 percent. An annual nutrient budget for the West Branch Delaware River showed that cornland was the major source of sediment, solid phase nutrients, and total phosphorus. Waste water treatment plants and ground water discharge contributed the most dissolved phosphorus and dissolved nitrogen, respectively.     

REGIONAL SCALE MODELING OF SURFACE AND GROUND WATER INTERACTION IN THE SNAKE RIVER BASIN1

ABSTRACT: Changes in irrigation and land use may impact discharge of the Snake River Plain aquifer, which is a major contributor to flow of the Snake River in southern Idaho. The Snake River Basin planning and management model (SRBM) has been expanded to include the spatial distribution and temporal attenuation that occurs as aquifer stresses propagate through the aquifer to the river. The SRBM is a network flow model in which aquifer characteristics have been introduced through a matrix of response functions. The response functions were determined by independently simulating the effect of a unit stress in each cell of a finite difference groundwater flow model on six reaches of the Snake River. Cells were aggregated into 20 aquifer zones and average response functions for each river reach were included in the SRBM. This approach links many of the capabilities of surface and ground water flow models. Evaluation of an artificial recharge scenario approximately reproduced estimates made by direct simulation in a ground water flow model. The example demonstrated that the method can produce reasonable results but interpretation of the results can be biased if the simulation period is not of adequate duration.     

POLLUTANT LOADING CAPACITY FOR THE BLACK RWER,CHEHALIS RWER SYSTEM,WASHINGTON1

ABSTRACT: The Black River, a tributary of the Chehalis River in western Washington State, has a history of widespread low dissolved oxygen (DO), anoxia in some locations, and fish kills. As part of a Total Maximum Daily Load (TMDL) study, environmental data were collected during two summer dry seasons and simulations were conducted with the WASP5 model to assess the effect of biochemical oxygen demand ( BOD ), ammonia, and nutrient loads on DO in the Black River. DO levels were below the State water quality regulatory criterion of 8.0 mg/L in almost all locations during the study. The slow middle reach of the river showed stratified conditions, with anoxia in some of the deepest pools. Based on model simulations, DO was found to still fall below the 8.0 mg/L criterion in the entire mainstem under “natural” conditions, and eutrophication was identified as a potential problem in the middle reach. A TMDL was proposed for BOD and ammonia that would prevent significant degradation of DO in the Black River. To prevent eutrophic conditions in the Black River, a TMDL for total phosphorus was proposed that establishes a protective criterion of 0.05 mg/L for the middle river during the dry low-flow season.     

福州城市排污规划布局的水环境影响研究

以闽江下游福州城区段为研究区间,分析了闽江下游福州段的水环境质量现状,采用二维水动力-水质耦合模型研究了枯水期城市排污口布局和排污强度规划对水环境质量的影响。研究结果表明,感潮河段排污存在明显的污染物上溯现象,在东南区水厂至马尾水厂备用水源地之间形成高浓度污染团,洋里和连坂排污口对东南区水厂水源地水质影响最为显著,高潮时刻的高锰酸盐指数增量将达1.0mg/L,氨氮增量将达约0.15mg/L,叠加本底值后水质已接近Ⅲ类标准限值。建议逐步将取水口向城市上游淮安段转移,更换取消东南区水厂的取水口。     

IMPACT OF DROUGHT ON QUALITY IN A NEW JERSEY WATER SUPPLY SYSTEM1

ABSTRACT. New Jersey, together with other states in the northeast, was stricken with drought during 1961-66. The effect of this drought was most severe in the northern part of the State. The water quality of the Passaic River, which drains the urban, industrialized northeast, perhaps deteriorated the most among the major drainage systems. This river system is used as a raw-water source by 10 water suppliers. The impact of the drought upon the water supply of the Passaic Valley Water Commission, the most downstream of the basin's suppliers, which supplies an average of about 90 million gallons a day to more than 650,000 persons, is evaluated herein. The drought's impact on the raw-water quality is appraised by the comparison of before-and-after qualities of dissolved solids, dissolved oxygen, biochemical-oxygen demand, turbidity, and hardness. For example, at the worst point during the drought, monthly average dissolved-solids content in the raw water were about 210 percent, hardness, about 167 percent, and biochemical-oxygen demand about 270 percent higher than antecedent values. In general, the study concludes that the drought produced a deterioration in both raw and finished water quality, and is estimated to have increased chemical-treatment costs during the drought by about $650,000.     

MODELING THE IMPACT OF SUBSURFACE NUTRIENT FLUX ON WATER QUALITY IN THE LOWER TRUCKEE RWER,NEVADA1

ABSTRACT: The impacts of regional groundwater quality and local agricultural activities on in-stream water quality in the Lower Truckee River, Nevada, were assessed through a detailed program of monitoring and computer simulation. An agricultural diversion and return-flow were monitored in great detail to determine mass loading rates of nutrients from agriculture in the area. Once characterized, the cumulative impacts of agricultural diversions and return-flows were evaluated using the Water Quality Assessment Program (WASP) to model nitrogen, phosphorus, periphyton, and dissolved oxygen. Monitoring showed that a significant proportion of the water diverted for agricultural purposes returned to the river as surface point return-flow (estimated at 13.9 percent $ 0.1 percent), and as groundwater diffuse return-flow (estimated at 27 percent $ 6 percent). Modeling efforts demonstrated the significant effect of assumed regional groundwater quality (nitrate) upon predicted periphyton growth and associated diel fluctuations of dissolved oxygen.     

Water Quality and Land Use Changes in the Alafia and Hillsborough River Watersheds,Florida, USA1

Abstract: Spatial distribution of land use can have a substantial effect on surface and groundwater quality. Our objective was to test for trends in flow components and water quality related to changes in land use in the Alafia and Hillsborough River watersheds in Florida, USA, over the period 1974‐2007. In addition, water quality statistics were evaluated in the perspective of numeric water quality criteria and proposed reclassification of segments of the Alafia River. Trends in 10 water quality parameters and three discharge variables were evaluated using a nonparametric trend detection test. Results of land use analysis indicated substantial urbanization and loss of agricultural land in the study area. Discharge variables did not exhibit significant trends, whereas trends in the majority of water quality concentrations were negative or nonsignificant with total nitrogen and total Kjeldahl nitrogen as exceptions showing positive trends. Changes in nutrient pathways could not be clearly identified. Considering recently promulgated numeric nutrient criteria and standards for dissolved fluoride, much of the Alafia River was found to be out of compliance. While there were land use changes and changes in water quality over the study period, it was difficult to identify a direct cause‐effect relationship. Responses to regulatory efforts, such as the Clean Water Act and improvements in phosphate mining practices, may have had greater impacts on water quality than changes in land use.     

Water quality assessment and meta model development in Melen watershed – Turkey

Istanbul, being one of the highly populated metropolitan areas of the world, has been facing water scarcity since the past decade. Water transfer from Melen Watershed was considered as the most feasible option to supply water to Istanbul due to its high water potential and relatively less degraded water quality. This study consists of two parts. In the first part, water quality data covering 26 parameters from 5 monitoring stations were analyzed and assessed due to the requirements of the “Quality Required of Surface Water Intended for the Abstraction of Drinking Water” regulation. In the second part, a one-dimensional stream water quality model with simple water quality kinetics was developed. It formed a basic design for more advanced water quality models for the watershed. The reason for assessing the water quality data and developing a model was to provide information for decision making on preliminary actions to prevent any further deterioration of existing water quality. According to the water quality assessment at the water abstraction point, Melen River has relatively poor water quality with regard to NH₄⁺, BOD₅, faecal streptococcus, manganese and phenol parameters, and is unsuitable for drinking water abstraction in terms of COD, PO₄^3?, total coliform, total suspended solids, mercury and total chromium parameters. The results derived from the model were found to be consistent with the water quality assessment. It also showed that relatively high inorganic nitrogen and phosphorus concentrations along the streams are related to diffuse nutrient loads that should be managed together with municipal and industrial wastewaters.     

基于模糊数学的矿业城市地表水污染风险评价

根据模糊数学方法,建立了水污染风险模糊综合评价数学模型,以煤炭资源型城市阜新为研究对象,选取辽河流域阜新段1996～2005年枯水期和丰水期水质状况平均值进行水污染风险评价。旨在定量分析评价阜新地区地表水环境质量现状和存在的问题。结果表明：辽河阜新段水质在1996～2005年间波动较大,呈水质日益恶化的状态。水体主要污染物为有机物、氨氮和溶解性铁,总体来说各污染物变化规律各不相同,总磷、BOD5、溶解性铁呈递增趋势,其他污染物质都呈波动性变化。     

QUALITY OF 1995 SPRING TOTAL DISSOLVED GAS DATA: COLUMBIA AND SNAKE RWERS1

ABSTRACT: The quality of the U.S. Army Corps of Engineers' (Corps) total dissolved gas (TDG) data base for the 1995 spring spill season was reviewed to determine the value of this information in real-time management decisions regarding river operations. We concluded that problems in transmitting, archiving, correcting and interpreting the records constitute significant sources of data anomalies that affect the accuracy and reliability of information necessary to manage spill and TDG in the Columbia and Snake rivers. The data base that was reviewed covers 25 selected Columbia and Snake river stations, and includes real-time TDG data needed to regulate spill operations to maintain gas levels within state water quality standards and to monitor effects on fish and aquatic life during the salmon migration season. A wide range of anomalies (daily averages missing or in error or based on incomplete records) was detected in more than one-third (37 percent) of the Corps' gas data base. Extreme anomalies (daily averages including errors and discontinuities for more than eight hours in a day) were found in 16 percent of the data base. The Fish Passage Center, also reviewed the Corps' data and reported an overall 33 percent incidence of anomalous days. Despite arriving at similar findings about the Corps' data base, we detected a 28 percent discrepancy in the type of data anomalies between our analyses. Real. time improvements in the quality of the dissolved gas data base are necessary to provide managers with a reliable product from this monitoring effort.     

Long-term field-scale experiment on using lime filters in an agricultural catchment

The River Yl?neenjoki catchment in southwest Finland is an area with a high agricultural nutrient load. We report here on the nutrient removal performance of three on-site lime-sand filters (F1, F2, and F3), established within or on the edge of the buffer zones. The filters contain burnt lime (CaO) or spent lime [CaO, Ca(OH), and CaCO]. Easily soluble lime results in a high pH level (>11) and leads to an efficient precipitation of soluble phosphorus (P) from the runoff. Water samples were taken from the inflow and outflow of each site in different hydrological situations. The length of the monitoring period was 4 yr for F1, 6 yr for F2, and 1.5 yr for F3. F1 and F2 significantly reduced the suspended solids (SS), total P (PTOT), and dissolved reactive P (DRP) in the treated water. The proportional reduction (%) varied but was usually clearly positive. Filter F3 was divided into two equal parts, one containing burnt lime and the other spent lime. Both filter parts removed PTOT and SS efficiently from the water; the burnt-lime part also removed DRP. The mixed-lime part removed DRP for a year, but then the efficiency decreased. The effect of filters on nitrogen compounds varied. We conclude that sand filters incorporating lime can be used together with buffer zones to reduce both P and SS load to watercourses.     

NATIONWIDE REGRESSION MODELS FOR PREDICTING URBAN RUNOFF WATER QUALITY AT UNMONITORED SITES1

ABSTRACT: Regression models are presented that can be used to estimate mean loads for chemical oxygen demand, suspended solids, dissolved solids, total nitrogen, total ammonia plus nitrogen, total phosphorous, dissolved phosphorous, total copper, total lead, and total zinc at unmonitored sites in urban areas. Explanatory variables include drainage area, imperviousness of drainage basin to infiltration, mean annual rainfall, a land-use indicator variable, and mean minimum January temperature. Model parameters are estimated by a generalized-least-squares regression method that accounts for cross correlation and differences in reliability of sample estimates between sites. The regression models account for 20 to 65 percent of the total variation in observed loads.