Emissions from US waste collection vehicles

This research is an in-depth environmental analysis of potential alternative fuel technologies for waste collection vehicles. Life-cycle emissions, cost, fuel and energy consumption were evaluated for a wide range of fossil and bio-fuel technologies. Emission factors were calculated for a typical waste collection driving cycle as well as constant speed. In brief, natural gas waste collection vehicles (compressed and liquid) fueled with North-American natural gas had 6–10% higher well-to-wheel (WTW) greenhouse gas (GHG) emissions relative to diesel-fueled vehicles; however the pump-to-wheel (PTW) GHG emissions of natural gas waste collection vehicles averaged 6% less than diesel-fueled vehicles. Landfill gas had about 80% lower WTW GHG emissions relative to diesel. Biodiesel waste collection vehicles had between 12% and 75% lower WTW GHG emissions relative to diesel depending on the fuel source and the blend. In 2011, natural gas waste collection vehicles had the lowest fuel cost per collection vehicle kilometer travel. Finally, the actual driving cycle of waste collection vehicles consists of repetitive stops and starts during waste collection; this generates more emissions than constant speed driving.     

A comparative assessment of waste incinerators in the UK

The uptake in Europe of Energy from Waste (EfW) incinerator plants has increased rapidly in recent years. In the UK, 25 municipal waste incinerators with energy recovery are now in operation; however, their waste supply chains and business practices vary significantly. With over a hundred more plant developments being considered it is important to establish best business practices for ensuring efficient environmental and operational performance. By reviewing the 25 plants we identify four suitable case study plants to compare technologies (moving grate, fluidised bed and rotary kiln), plant economics and operations. Using data collected from annual reports and through interviews and site visits we provide recommendations for improving the supply chain for waste incinerators and highlight the current issues and challenges faced by the industry. We find that plants using moving grate have a high availability of 87–92%. However, compared to the fluidised bed and rotary kiln, quantities of bottom ash and emissions of hydrogen chloride and carbon monoxide are high. The uptake of integrated recycling practices, combined heat and power, and post incineration non-ferrous metal collections needs to be increased among EfW incinerators in the UK. We conclude that one of the major difficulties encountered by waste facilities is the appropriate selection of technology, capacity, site, waste suppliers and heat consumers. This study will be of particular value to EfW plant developers, government authorities and researchers working within the sector of waste management.     

Greenhouse gas emissions from MSW incineration in China: Impacts of waste characteristics and energy recovery

Determination of the amount of greenhouse gas (GHG) emitted during municipal solid waste incineration (MSWI) is complex because both contributions and savings of GHGs exist in the process. To identify the critical factors influencing GHG emissions from MSWI in China, a GHG accounting model was established and applied to six Chinese cities located in different regions. The results showed that MSWI in most of the cities was the source of GHGs, with emissions of 25–207 kg CO₂-eq t^?1 rw. Within all process stages, the emission of fossil CO₂ from the combustion of MSW was the main contributor (111–254 kg CO₂-eq t^?1 rw), while the substitution of electricity reduced the GHG emissions by 150–247 kg CO₂-eq t^?1 rw. By affecting the fossil carbon content and the lower heating value of the waste, the contents of plastic and food waste in the MSW were the critical factors influencing GHG emissions of MSWI. Decreasing food waste content in MSW by half will significantly reduce the GHG emissions from MSWI, and such a reduction will convert MSWI in Urumqi and Tianjin from GHG sources to GHG sinks. Comparison of the GHG emissions in the six Chinese cities with those in European countries revealed that higher energy recovery efficiency in Europe induced much greater reductions in GHG emissions. Recovering the excess heat after generation of electricity would be a good measure to convert MSWI in all the six cities evaluated herein into sinks of GHGs.     

Climate balance of biogas upgrading systems

One of the numerous applications of renewable energy is represented by the use of upgraded biogas where needed by feeding into the gas grid. The aim of the present study was to identify an upgrading scenario featuring minimum overall GHG emissions. The study was based on a life-cycle approach taking into account also GHG emissions resulting from plant cultivation to the process of energy conversion. For anaerobic digestion two substrates have been taken into account: (1) agricultural resources and (2) municipal organic waste. The study provides results for four different upgrading technologies including the BABIU (Bottom Ash for Biogas Upgrading) method. As the transport of bottom ash is a critical factor implicated in the BABIU-method, different transport distances and means of conveyance (lorry, train) have been considered. Furthermore, aspects including biogas compression and energy conversion in a combined heat and power plant were assessed. GHG emissions from a conventional energy supply system (natural gas) have been estimated as reference scenario. The main findings obtained underlined how the overall reduction of GHG emissions may be rather limited, for example for an agricultural context in which PSA-scenarios emit only 10% less greenhouse gases than the reference scenario. The BABIU-method constitutes an efficient upgrading method capable of attaining a high reduction of GHG emission by sequestration of CO₂.     

An integrated analytical framework for quantifying the LCOE of waste-to-energy facilities for a range of greenhouse gas emissions policy and technical factors

This study presents a novel integrated method for considering the economics of waste-to-energy (WTE) facilities with priced greenhouse gas (GHG) emissions based upon technical and economic characteristics of the WTE facility, MSW stream, landfill alternative, and GHG emissions policy. The study demonstrates use of the formulation for six different policy scenarios and explores sensitivity of the results to ranges of certain technical parameters as found in existing literature. The study shows that details of the GHG emissions regulations have large impact on the levelized cost of energy (LCOE) of WTE and that GHG regulations can either increase or decrease the LCOE of WTE depending on policy choices regarding biogenic fractions from combusted waste and emissions from landfills. Important policy considerations are the fraction of the carbon emissions that are priced (i.e. all emissions versus only non-biogenic emissions), whether emissions credits are allowed due to reducing fugitive landfill gas emissions, whether biogenic carbon sequestration in landfills is credited against landfill emissions, and the effectiveness of the landfill gas recovery system where waste would otherwise have been buried. The default landfill gas recovery system effectiveness assumed by much of the industry yields GHG offsets that are very close to the direct non-biogenic GHG emissions from a WTE facility, meaning that small changes in the recovery effectiveness cause relatively larger changes in the emissions factor of the WTE facility. Finally, the economics of WTE are dependent on the MSW stream composition, with paper and wood being advantageous, metal and glass being disadvantageous, and plastics, food, and yard waste being either advantageous or disadvantageous depending upon the avoided tipping fee and the GHG emissions price.     

An integrated appraisal of energy recovery options in the United Kingdom using solid recovered fuel derived from municipal solid waste

This paper reports an integrated appraisal of options for utilising solid recovered fuels (SRF) (derived from municipal solid waste, MSW) in energy intensive industries within the United Kingdom (UK). Four potential co-combustion scenarios have been identified following discussions with industry stakeholders. These scenarios have been evaluated using (a) an existing energy and mass flow framework model, (b) a semi-quantitative risk analysis, (c) an environmental assessment and (d) a financial assessment. A summary of results from these evaluations for the four different scenarios is presented. For the given ranges of assumptions; SRF co-combustion with coal in cement kilns was found to be the optimal scenario followed by co-combustion of SRF in coal-fired power plants. The biogenic fraction in SRF (ca. 70%) reduces greenhouse gas (GHG) emissions significantly (～2500 g CO₂ eqvt./kg DS SRF in co-fired cement kilns and ～1500 g CO₂ eqvt./kg DS SRF in co-fired power plants). Potential reductions in electricity or heat production occurred through using a lower calorific value (CV) fuel. This could be compensated for by savings in fuel costs (from SRF having a gate fee) and grants aimed at reducing GHG emission to encourage the use of fuels with high biomass fractions. Total revenues generated from coal-fired power plants appear to be the highest (£95/t SRF) from the four scenarios. However overall, cement kilns appear to be the best option due to the low technological risks, environmental emissions and fuel cost. Additionally, cement kiln operators have good experience of handling waste derived fuels. The scenarios involving co-combustion of SRF with MSW and biomass were less favourable due to higher environmental risks and technical issues.     

Japan’s greenhouse gas reduction scenarios toward net zero by 2050 in the material cycles and waste management sector

The first draft scenario toward net zero greenhouse gas (GHG) emissions by 2050 for the material cycles and waste management sector was presented by the Ministry of the Environment, Japan in August 2021. The details of the future GHG emission estimation used to create the draft scenario are described in this document. For multiple scenarios where more aggressive measures, such as carbon capture, utilization, and storage (CCUS), were included in addition to business-as-usual and the current policy continuity scenario, future GHG emissions were estimated as the sum of the products of activities and emission factors indicating changes in measures between scenarios. The estimation outcomes demonstrated that future GHG emissions from the solid waste management sector could be anticipated to be zero or even negative when material conversion to biomass, primarily for plastics, recycling to raw materials, and installation of CCUS at incineration facilities are assumed. Extensions of prior plans are not enough to reach the goal of net zero emissions, according to the measures necessary and the volume and pace of their implementation suggested in this study. Stakeholders should collaborate with great ambition.

     

International comparative study of 3R and waste management policy developments

Reduce, reuse, and recycle (3R) policies form the basis of waste management and global warming countermeasures globally, so we conducted a comparative study of 3R and waste management policies in the European Union (EU), USA, Korea, Japan, China, and Vietnam. An international workshop for 3R and waste management policymakers was held in Kyoto, Japan, and a bibliographic survey was also conducted to collect data. 3R policies are clearly given priority in the hierarchy of waste management in every country studied. Thermal recovery, which includes power generation from waste heat and methane gas collected from organic waste, is also a priority; this is consistent with the increased use of countermeasures to reduce greenhouse gas (GHG) emissions. In the EU, waste management is characterized by practical and effective 3R policies through the development of realistic regulations and by the policymakers??desire to simplify management systems. The policy ideal in China, however, is the development of a circular economy that targets reductions in the amount and hazardousness of waste. Limits on the number of final disposal sites, strategies for procuring resources, and GHG emission countermeasures are closely linked with 3R policies, and further development of 3R policies in parallel with such issues is expected.     

Energy from Waste – Clean,efficient, renewable: Transitions in combustion efficiency and NOx control

Traditionally EfW (Energy from Waste) plants apply a reciprocating grate to combust waste fuel. An integrated steam generator recovers the heat of combustion and converts it to steam for use in a steam turbine/generator set. This is followed by an array of flue gas cleaning technologies to meet regulatory limitations.Modern combustion applies a two-step method using primary air to fuel the combustion process on the grate. This generates a complex mixture of pyrolysis gases, combustion gases and unused combustion air. The post-combustion step in the first pass of the boiler above the grate is intended to “clean up” this mixture by oxidizing unburned gases with secondary air.This paper describes modifications to the combustion process to minimize exhaust gas volumes and the generation of noxious gases and thus improving the overall thermal efficiency of the EfW plant. The resulting process can be coupled with an innovative SNCR (Selective Non-Catalytic Reduction) technology to form a clean and efficient solid waste combustion system.Measurements immediately above the grate show that gas compositions along the grate vary from 10% CO, 5% H₂ and 0% O₂ to essentially unused “pure” air, in good agreement with results from a mathematical model. Introducing these diverse gas compositions to the post combustion process will overwhelm its ability to process all these gas fractions in an optimal manner. Inserting an intermediate step aimed at homogenizing the mixture above the grate has shown to significantly improve the quality of combustion, allowing for optimized process parameters. These measures also resulted in reduced formation of NO_x (nitrogenous oxides) due to a lower oxygen level at which the combustion process was run (2.6 vol% O_2, wet instead of 6.0 vol% O_2, wet).This reduction establishes optimal conditions for the DyNOR? (Dynamic NO_x Reduction) NO_x reduction process. This innovative SNCR technology is adapted to situations typically encountered in solid fuel combustion. DyNOR? measures temperature in small furnace segments and delivers the reducing reagent to the exact location where it is most effective. The DyNOR? distributor reacts precisely and dynamically to rapid changes in combustion conditions, resulting in very low NO_x emissions from the stack.     

Mitigation of global greenhouse gas emissions from waste: conclusions and strategies from the Intergovernmental Panel on Climate Change (IPCC) Fourth Assessment Report. Working Group III (Mitigation).

Greenhouse gas (GHG) emissions from post-consumer waste and wastewater are a small contributor (about 3%) to total global anthropogenic GHG emissions. Emissions for 2004-2005 totalled 1.4 Gt CO2-eq year(-1) relative to total emissions from all sectors of 49 Gt CO2-eq year(-1) [including carbon dioxide (CO2), methane (CH4), nitrous oxide (N2O), and F-gases normalized according to their 100-year global warming potentials (GWP)]. The CH4 from landfills and wastewater collectively accounted for about 90% of waste sector emissions, or about 18% of global anthropogenic methane emissions (which were about 14% of the global total in 2004). Wastewater N2O and CO2 from the incineration of waste containing fossil carbon (plastics; synthetic textiles) are minor sources. Due to the wide range of mature technologies that can mitigate GHG emissions from waste and provide public health, environmental protection, and sustainable development co-benefits, existing waste management practices can provide effective mitigation of GHG emissions from this sector. Current mitigation technologies include landfill gas recovery, improved landfill practices, and engineered wastewater management. In addition, significant GHG generation is avoided through controlled composting, state-of-the-art incineration, and expanded sanitation coverage. Reduced waste generation and the exploitation of energy from waste (landfill gas, incineration, anaerobic digester biogas) produce an indirect reduction of GHG emissions through the conservation of raw materials, improved energy and resource efficiency, and fossil fuel avoidance. Flexible strategies and financial incentives can expand waste management options to achieve GHG mitigation goals; local technology decisions are influenced by a variety of factors such as waste quantity and characteristics, cost and financing issues, infrastructure requirements including available land area, collection and transport considerations, and regulatory constraints. Existing studies on mitigation potentials and costs for the waste sector tend to focus on landfill CH4 as the baseline. The commercial recovery of landfill CH4 as a source of renewable energy has been practised at full scale since 1975 and currently exceeds 105 Mt CO2-eq year(-1). Although landfill CH4 emissions from developed countries have been largely stabilized, emissions from developing countries are increasing as more controlled (anaerobic) landfilling practices are implemented; these emissions could be reduced by accelerating the introduction of engineered gas recovery, increasing rates of waste minimization and recycling, and implementing alternative waste management strategies provided they are affordable, effective, and sustainable. Aided by Kyoto mechanisms such as the Clean Development Mechanism (CDM) and Joint Implementation (JI), the total global economic mitigation potential for reducing waste sector emissions in 2030 is estimated to be > 1000 Mt CO2-eq (or 70% of estimated emissions) at costs below 100 US$ t(-1) CO2-eq year(-1). An estimated 20-30% of projected emissions for 2030 can be reduced at negative cost and 30-50% at costs < 20 US$ t(-) CO2-eq year(-1). As landfills produce CH4 for several decades, incineration and composting are complementary mitigation measures to landfill gas recovery in the short- to medium-term--at the present time, there are > 130 Mt waste year(-1) incinerated at more than 600 plants. Current uncertainties with respect to emissions and mitigation potentials could be reduced by more consistent national definitions, coordinated international data collection, standardized data analysis, field validation of models, and consistent application of life-cycle assessment tools inclusive of fossil fuel offsets.     

Mathematical modeling of MSW combustion and SNCR in a full-scale municipal incinerator and effects of grate speed and oxygen-enriched atmospheres on operating conditions

The rising popularity of incineration of municipal solid waste (MSW) calls for detailed mathematical modeling and accurate prediction of pollutant emissions. In this paper, mathematical modeling methods for both solid and gaseous phases were employed to simulate the operation of a 450 t/d MSW-burning incinerator to obtain detailed information on the flow and combustion characteristics in the furnace and to predict the amount of pollutant emissions. The predicted data were compared to on-site measurements of gas temperature, gas composition and SNCR de-NO_X system. The major operating conditions considered in this paper were grate speed and oxygen concentration. A suitable grate speed ensures complete waste combustion. The predictions are as follows: volatile release increases with increasing grate speed, and the maximal value is within the range of 700–800 kg/m² h; slow grate speeds result in incomplete combustion of fixed carbon; the gas temperature at slow grate speeds is higher due to adequate oxygenation for fixed carbon combustion, and the deviation reaches 200 K; NO_X emission decreases, but CO emission and O₂ concentrations increase, and the deviation is 63%, 34% and 35%, respectively. Oxygen-enriched atmospheres promote the destruction of most pollutants due to the high oxygen partial pressure and temperature. The furnace temperature, NO production and CO emission increase as the oxygen concentration increases, and the deviation of furnace exit temperature, NO and CO concentration is 38.26%, 58.43% and 86.67%, respectively. Finally, oxygen concentration is limited to below 35% to prevent excessive CO and NO_X emission without compromising plant performance. The current work greatly helps to understand the operating characteristics of large-scale MSW-burning plants.     

Energy implications of mechanical and mechanical–biological treatment compared to direct waste-to-energy

Primary energy savings potential is used to compare five residual municipal solid waste treatment systems, including configurations with mechanical (MT) and mechanical–biological (MBT) pre-treatment, which produce waste-derived fuels (RDF and SRF), biogas and/or recover additional materials for recycling, alongside a system based on conventional mass burn waste-to-energy and ash treatment. To examine the magnitude of potential savings we consider two energy efficiency levels (state-of-the-art and best available technology), the inclusion/exclusion of heat recovery (CHP vs. PP) and three different background end-use energy production systems (coal condensing electricity and natural gas heat, Nordic electricity mix and natural gas heat, and coal CHP energy quality allocation).The systems achieved net primary energy savings in a range between 34 and 140 MJ_primary/100 MJ_{input waste}, in the different scenario settings. The energy footprint of transportation needs, pre-treatment and reprocessing of recyclable materials was 3–9.5%, 1–18% and 1–8% respectively, relative to total energy savings. Mass combustion WtE achieved the highest savings in scenarios with CHP production, nonetheless, MBT-based systems had similarly high performance if SRF streams were co-combusted with coal. When RDF and SRF was only used in dedicated WtE plants, MBT-based systems totalled lower savings due to inherent system losses and additional energy costs. In scenarios without heat recovery, the biodrying MBS-based system achieved the highest savings, on the condition of SRF co-combustion. As a sensitivity scenario, alternative utilisation of SRF in cement kilns was modelled. It supported similar or higher net savings for all pre-treatment systems compared to mass combustion WtE, except when WtE CHP was possible in the first two background energy scenarios. Recovery of plastics for recycling before energy recovery increased net energy savings in most scenario variations, over those of full stream combustion. Sensitivity to assumptions regarding virgin plastic substitution was tested and was found to mostly favour plastic recovery.     

Possibilities and limitations of life cycle assessment (LCA) in the development of waste utilization systems – Applied examples for a region in Northern Germany

Against the background of increasing concerns about climate change, the reduction of greenhouse gas emissions has become an integral part of processes in both the waste management and the energy industries. This is reflected in the development of new waste treatment concepts, in which domestic and commercial waste is treated with the aim of utilizing its energy content, while at the same time recycling as much of its material content as possible. Life cycle assessment (LCA) represents a method of assessing the environmental relevance of a waste management system, the basis of which is a material flow analysis of the system in question. GHG emissions from different options for thermal treatment and energy recovery from waste as applied to a region in Northern Germany have been analyzed by the LCA approach and an indicative LCA, which only considers those emissions resulting from operating stages of the system. Operating stages have the main share of emissions compared to pre-processing stages. Results show that through specific separation of waste material flows and highly efficient energy recovery, thermal treatment and energy generation from waste can be optimized resulting in reduction of emissions of greenhouse gases. There are also other areas of waste utilization, currently given little attention, such as the solar drying of sewage sludge, which can considerably contribute to the reduction of greenhouse gas emissions.     

Assessment of solid waste generation and greenhouse gas emission potential in Yangon city,Myanmar

Due to booming economy, growing population and rapid urbanization, solid waste generation in the cities of developing countries has significantly increased. Yangon is the largest and most densely populated city, with over five million residents in Myanmar. Open dumping is the major waste disposal method and recycling sector remains at an early development stage. With increasing waste generation, current waste management activities in Yangon have significant environmental impacts. Therefore, the study developed two linear models to predict annual solid waste generation, regarding per capita waste generation, population growth scenarios, literacy rates and gross domestic products. The Intergovernmental Panel on Climate Change and Institute for Global Environmental Strategies calculation methods were used for greenhouse gas (GHG) emission prediction from recycling, waste transportation and final disposal sites (FDSs). As a result, the total annual waste generation and GHG emission in 2015 may double over the next decade. Two major FDSs, Htawe Chaung and Hteinpin, may contribute waste disposal of 272–797 kilotons per year and emit 177–518 Gg of CO₂-eq per year by 2025. The assessment of annual solid waste generation and GHG emission potential may offer advantages in assisting development of waste management plans in Yangon.     

Greenhouse gas emissions from biogenic waste treatment: options and uncertainty

A simplified life cycle assessment was conducted to estimate greenhouse gas (GHG) emissions and energy production from each component of biogenic waste treated in an open dumping site, and by composting, anaerobic digestion, and incineration employed with additional options. The impact of uncertainties and sensitivities of the parameters in the treatment methods were investigated. We conducted a sensitivity analysis to identify the most sensitive parameters, and we discussed the relationship between uncertainty and sensitivity. Our results revealed that the moisture content of food waste and the biomass-derived carbon and methane concentration of the landfill gas of biogenic waste subjected to open dumping are the most sensitive parameters across all the treatment methods. The net GHG emissions from food waste treated in an open dumping site ranged over ten times (0.30 ? 3.67 Gg CO₂ eq/Gg). In addition, by employing additional options for the open dumping site, including soil cover, a landfill gas collection system, shifting to a semi-aerobic condition, and energy conservation by using a gas engine, we found that the net GHG emissions could be reduced by 10, 27.9, 37.4 %, and up to 56.7 %, respectively. Shifting to a semi-aerobic system is the most effective method for reducing GHG emissions, followed by landfill gas collection.     

Role of waste management with regard to climate protection: a case study.

According to the Kyoto Protocol and the burden-sharing agreement of the European Union, Austria is required to cut greenhouse gas (GHG) emissions during the years 2008 to 2012 in order to achieve an average reduction of 13%, based on the level of emissions for the year 1990. The present contribution gives an overview of the history of GHG emission regulation in Austria and identifies the progress made towards the realization of the national climate strategy to attain the GHG emission targets. The contribution uses Austria as an example of the way in which proper waste management can help to reduce GHG emissions. The GHG inventories show that everything must be done to minimize the carbon input due to waste deposition at landfill sites. The incineration of waste is particularly helpful in reducing GHG emissions. The waste-to-energy by incineration plants and recovery of energy yield an ecologically proper treatment of waste using state-of-the-art techniques of a very high standard. The potential for GHG reduction of conventional waste treatment technologies has been estimated by the authors. A growing number of waste incinerators and intensified co-incineration of waste in Austrian industry will both help to reduce national GHG emissions substantially. By increasing the number and capacity of plants for thermal treatment of waste the contribution of proper waste management to the national target for reduction of GHG emissions will be in the range of 8 to 14%. The GHG inventories also indicate that a potential CO2 reduction of about 500 000 t year(-1) is achievable by co-incineration of waste in Austrian industry.     

Home composting as an alternative treatment option for organic household waste in Denmark: An environmental assessment using life cycle assessment-modelling

An environmental assessment of the management of organic household waste (OHW) was performed from a life cycle perspective by means of the waste-life cycle assessment (LCA) model EASEWASTE. The focus was on home composting of OHW in Denmark and six different home composting units (with different input and different mixing frequencies) were modelled. In addition, incineration and landfilling was modelled as alternatives to home composting. The most important processes contributing to the environmental impact of home composting were identified as greenhouse gas (GHG) emissions (load) and the avoided emissions in relation to the substitution of fertiliser and peat when compost was used in hobby gardening (saving). The replacement of fertiliser and peat was also identified as one of the most sensible parameters, which could potentially have a significant environmental benefit. Many of the impact categories (especially human toxicity via water (HTw) and soil (HTs)) were affected by the heavy metal contents of the incoming OHW. The concentrations of heavy metals in the compost were below the threshold values for compost used on land and were thus not considered to constitute a problem. The GHG emissions were, on the other hand, dependent on the management of the composting units. The frequently mixed composting units had the highest GHG emissions. The environmental profiles of the home composting scenarios were in the order of −2 to 16 milli person equivalents (mPE) Mg⁻¹ wet waste (ww) for the non-toxic categories and −0.9 to 28 mPE Mg⁻¹ ww for the toxic categories. Home composting performed better than or as good as incineration and landfilling in several of the potential impact categories. One exception was the global warming (GW) category, in which incineration performed better due to the substitution of heat and electricity based on fossil fuels.     

Analysis of potential for reducing emissions of greenhouse gases in municipal solid waste in Brazil,in the state and city of Rio de Janeiro

This paper examines potential changes in solid waste policies for the reduction in GHG for the country of Brazil and one of its major states and cities, Rio de Janeiro, from 2005 to 2030. To examine these policy options, trends in solid waste quantities and associated GHG emissions are derived. Three alternative policy scenarios are evaluated in terms of effectiveness, technology, and economics and conclusions posited regarding optimal strategies for Brazil to implement. These scenarios are been building on the guidelines for national inventories of GHG emissions (IPCC, 2006) and adapted to Brazilian states and municipalities’ boundaries. Based on the results, it is possible to say that the potential revenue from products of solid waste management is more than sufficient to transform the current scenario in this country into one of financial and environmental gains, where the negative impacts of climate change have created a huge opportunity to expand infrastructure for waste management.     

Quantification of greenhouse gas emissions from waste management processes for municipalities--a comparative review focusing on Africa

The amount of greenhouse gases (GHG) emitted due to waste management in the cities of developing countries is predicted to rise considerably in the near future; however, these countries have a series of problems in accounting and reporting these gases. Some of these problems are related to the status quo of waste management in the developing world and some to the lack of a coherent framework for accounting and reporting of greenhouse gases from waste at municipal level. This review summarizes and compares GHG emissions from individual waste management processes which make up a municipal waste management system, with an emphasis on developing countries and, in particular, Africa. It should be seen as a first step towards developing a more holistic GHG accounting model for municipalities. The comparison between these emissions from developed and developing countries at process level, reveals that there is agreement on the magnitude of the emissions expected from each process (generation of waste, collection and transport, disposal and recycling). The highest GHG savings are achieved through recycling, and these savings would be even higher in developing countries which rely on coal for energy production (e.g. South Africa, India and China) and where non-motorized collection and transport is used. The highest emissions are due to the methane released by dumpsites and landfills, and these emissions are predicted to increase significantly, unless more of the methane is captured and either flared or used for energy generation. The clean development mechanism (CDM) projects implemented in the developing world have made some progress in this field; however, African countries lag behind.     

Decreased PCDD/F formation when co-firing a waste fuel and biomass in a CFB boiler by addition of sulphates or municipal sewage sludge

Polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) are formed during waste incineration and in waste-to-energy boilers. Incomplete combustion, too short residence times at low combustion temperatures (<700 °C), incineration of electronic waste and plastic waste containing chlorine are all factors influencing the formation of PCDD/Fs in boilers. The impact of chlorine and catalysing metals (such as copper and iron) in the fuel on PCDD/F formation was studied in a 12 MW_th circulating fluidised bed (CFB) boiler. The PCDD/F concentrations in the raw gas after the convection pass of the boiler and in the fly ashes were compared. The fuel types were a so-called clean biomass with low content of chlorine, biomass with enhanced content of chlorine from supply of PVC, and solid recovered fuel (SRF) which is a waste fuel containing higher concentrations of both chlorine, and catalysing metals. The PCDD/F formation increased for the biomass with enhanced chlorine content and it was significantly reduced in the raw gas as well as in the fly ashes by injection of ammonium sulphate. A link, the alkali chloride track, is demonstrated between the level of alkali chlorides in the gas phase, the chlorine content in the deposits in the convection pass and finally the PCDD/F formation. The formation of PCDD/Fs was also significantly reduced during co-combustion of SRF with municipal sewage sludge (MSS) compared to when SRF was fired without MSS as additional fuel.