我国大陆地区电器电子产品报废量预测研究

随着我国电器电子产品的报废量不断增长,准确预测报废量及其分布对回收网络体系规划研究十分关键.本文利用Gompertz模型及保有量系数法对我国电器电子产品报废量进行建模,在验证预测模型及结果准确性的前提下,对全国31个省2003—2020年电视机、电冰箱、洗衣机、空调及电脑的报废量进行预测,并对5种家用电器报废总量构成、时间序列及空间分布进行分析.结果表明,到2020年,我国5种家用电器报废量将达到20.3亿台,广东省以1794万台报废量列居全国首位,上海市以1083台·km~(-2)的报废密度列居首位;按现有回收处理规模,2014年全国仍存在103万t待处理缺口.最后对废旧电器电子产品拆解处理产能布局提出了合理化建议,为我国的家用电器回收网络规划提供参考.     

欧盟《指令》羁绊下的后中国电子电气时代

8月13日,欧盟委员会宣布《关于报废电子电气设备指令》（WEEE指令）正式实施。这标志着从即日起,欧盟成员国所有的生产商、进口商、经销商要切实担负起回收、处理进入欧盟市场的废弃电器和电子产品的义务,并对此后投放市场的电器和电子产品加贴回收标志。《关于在电子电气设备中禁止使用某些有害物质指令）》（RoSH指令）则预计于明年7月1日起执行。     

天津市规划筹建废旧电子电器产品回收处理厂

记者日前从天津市环保局有关部门获悉,《天津市固体废物污染防治规划》中拟筹建天津市废旧电子电器产品回收处理厂。五大废旧电器即电视机、电冰箱、电脑、洗衣机和空调以及手机等电子产品,最终将有归处。据了解,天津市2 0 0 2年五大电器报废量约为1 2 3.2万台,约2 .4万t,今后每年将有1 0 %的增长率。至2 0 1 0年,天津市五大电器的淘汰量近4万t。这座拟建在天津市滨海新区海洋高科技开发区的处理厂占地1 0hm2 。2 0 0 4年开始建设,2 0 0 6年可达到年回收和处理废家电1 2万t,力争在2 0 1 0～2 0 1 5年达到年60万t的回收处理能力。天津市规划…     

商务部:再生资源回收试点达90个 回收总值近6000亿元

正2014年4月25日,商务部新闻发言人姚坚就加快再生资源回收体系建设有关问题回答了记者提问。姚坚介绍,截至2013年底,全社会再生资源回收企业达10多万家,80%以上为中小企业。据初步统计,2013年废钢铁、废塑料、废有色金属、废纸、废轮胎、报废汽车、废弃电器电子产品7大品种回收量接近1.6亿t,比2000年增长3倍多;回收总值接近6 000亿元,比2000年增长12倍;废钢铁、废有色金属、     

中国废弃电器电子产品回收体系发展现状及建议研究

随着中国电子产业的飞速发展和人们消费水平的提高,电器电子产品的拥有量和报废量都持续攀升,废弃电器电子产品(以下简称“废电器”)已成为中国增长速度最快的固体废弃物之一。如何规范有效的回收废电器,建立正规回收渠道,完善回收管理体系是中国废电器管理面临的难题之一。通过对中国废电器的定义、特点以及回收链特征进行概述,结合中国废电器回收体系的发展现状,综合分析回收体系建立的必要性,对中国废电器回收体系管理提出对策和建议。     

德国报废汽车拆解的环境无害化管理及对我国的启示

报废汽车的拆解是汽车生命周期管理过程中的重要环节，是实现报废汽车的资源回收和循环利用的必然途径，拆解过程的环境无害化管理对于提高回收率、合理处置废物和防治污染非常重要。欧盟、美国、日本等发达国家早就对报废汽车进行了环境无害化管理。我国正面临大量报废汽车对环境带来的压力。介绍了德国报废汽车拆解环境无害化管理要求和经验，希望能为我国报废汽车拆解的环境管理提供参考，并提出了建议。     

关于对报废汽车造成的环境污染问题及回收管理的对策

本文论述了报废汽车可回收利用的结构材料的资源化价值,提出了汽车报废时或非法拆解拼装后带来的一系列环境污染问题;得出了解决报废汽车环境污染问题的建议以及报废汽车回收管理的具体对策.     

电子产品常用有机涂层防霉特性研究

对于电子产品中不防霉的材料和零部件,为防止其长霉影响整个产品,采用防霉涂层和喷涂保护剂是最经济有效的措施.通过对1280件电子产品(或主要组成材料和工艺试片)霉菌试验结果的统计分析,总结出各种电子产品常用材料,特别是几种常用有机涂层的防霉特性.     

重庆市报废汽车拆解企业固体废物管理现状分析

通过调查研究,对重庆市报废汽车拆解企业的固体废物管理现状进行了分析,对重庆市报废汽车的回收、拆解情况有详细研究并对结果原因进行了分析,为报废汽车ODS的污染防治提出了针对性的建议。     

中国报废飞机的资源回收潜力评估

为厘清飞机的报废代谢机制及我国报废飞机的回收潜力,本研究考虑了五类典型飞机,首先利用保有量系数法,对飞机的报废量进行评估,然后估算了报废飞机中有价值资源(如黑色金属、有色金属和稀有金属)的产量.主要研究结果如下:报废飞机的潜在重量从2015年的472t迅速增长到2020年的1034t;报废飞机的回收经济潜力从2015年的约630万元增长到2020年的约1500万元,到2040年预计约1.3亿元;在所有机型中,波音737和空客A320报废量最大,且有色金属在飞机中占比最高.因此,相关回收企业在规划产能分配时,可重点关注这两种机型,并提高有色金属的回收技术.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Removal of heavy metals from sewage sludge by low costing chemical method and recycling in agriculture

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Isolation and preliminary characterization of a 3-chlorobenzoate degrading bacteria

A study was conducted to compare the diversity of 2-, 3-, and 4-chlorobenzoate degraders in two pristine soils and one contaminated sewage sludge. These samples contained strikingly different populations of mono-chlorobenzoate degraders. Although fewer cultures were isolated in the uncontaminated soils than contaminated one, the ability of microbial populations to mineralize chlorobenzoate was widespread. The 3- and 4-chlorobenzoate degraders were more diverse than the 2-chlorobenzoate degraders. One of the strains isolated from the sewage sludge was obtained. Based on its phenotype, chemotaxonomic properties and 16S rRNA gene, the organism S-7 was classified as Rhodococcus erythropolis. The strain can grow at temperature from 4 to 37℃. It can utilize several （halo）aromatic compounds. Moreover, strain S-7 can grow and use 3-chlorobenzoate as sole carbon source in a temperatures range of 10-30℃ with stoichiometric release of chloride ions. The psychrotolerant ability was significant for bioremediation in low temperature regions. Catechol and chlorocatechol 1,2-dioxygenase activities were present in cell free extracts of the strain, but no （chloro）catechol 2,3- dioxygenase activities was detected. Spectral conversion assays with extracts from R. erythropolis S-7 showed accumulation of a compound with a similar UV spectrum as chloro-cis,cis-muconate from 3-chlorobenzoate. On the basis of these results, we proposed that S-7 degraded 3-chlorobenzoate through the modified ortho-cleave pathway.     

Single and joint effects of pesticides and mercury on soil urease

The influence of two pesticides including chlorimuron-ethyl and furadan and mercury （Hg） on urease activity in 4 soils （meadow burozem and phaeozem） was investigated. The soils were exposed to various concentrations of the two pesticides and Hg individually and simultaneously. Results showed that there was a close relationship between urease activity and organic matter content in soil. Chlorimuron-ethyl and furadan could both activate urease in the 4 soils. The maximum increment of urease activity by chlorimuronethyl was up to 14%-18%. There was almost an equal increase （up to 13%-21%） in the urease activity by furadan. On the contrary, Hg markedly inhibited soil urease activity. A logarithmic equation was used to describe the relationship （P〈0.05） between the concentration of Hg and the activity of soil urease in the 4 tested soils. Semi-effect dose （ED50） values by the stress of Hg based on the inhibition of soil urease in the 4 soils were 88, 5.5, 24 and 20 mg/kg, respectively, according to the calculation of the corresponding equations. The interactive effect of chlorimuron-ethyl or furadan with metal Hg on soil urease was mainly synergic at the highest tested concentrations.     

Organochlorine pesticides in soils under different land usage in the Taihu Lake region, China

A field study was conducted in the Taihu Lake region, China in 2004 to reveal the organochlorine pesticide concentrations in soils after the ban of these substances in the year 1983. Thirteen organochlorine pesticides (OCPs) were analyzed in soils from paddy field, tree land and fallow land. Total organochlorine pesticide residues were higher in agricultural soils than in uncultivated fallow land soils. Among all the pesticides, ΣDDX (DDD, DDE and DDT) had the highest concentration for all the soil samples, ranging from 3.10 ng/g to 166.55 ng/g with a mean value of 57.04 ng/g and followed by ΣHCH, ranging from 0.73 ng/g to 60.97 ng/g with a mean value of 24.06 ng/g. Dieldrin, endrin, HCB and α-endosulfan were also found in soils with less than 15 ng/g. Ratios of p,p'-(DDD DDE)/DDT in soils under three land usages were: paddy field ＞ tree land ＞ fallow land, indicating that land usage inlfuenced the degradation of DDT in soils. Ratios of p,p'-(DDD DDE)/DDT ＞1, showing aged residues of DDTs in soils of the Taihu Lake region. The results were discussed with data from a former study that showed very low actual concentrations of HCH and DDT in soils in the Taihu Lake region, but according to the chemical half-lives and their concentrations in soils in 1980s, the concentration of DDT in soils seemed to be underestimated. In any case our data show that the ban on the use of HCH and DDT resulted in a tremendous reduction of these pesticide residues in soils, but there are still high amounts of pesticide residues in soils, which need more remediation processes.     

Alterations of organ histopathology and metallolhionein mRNA expression in silver barb, Puntius gonionotus during subchronic cadmium exposure

Common silver barb,Puntius gonionotus,exposed to the nominal concentration of 0.06 mg/L Cd for 60 d,were assessed for histopathological alterations(gills,liver and kidney),metal accumulation,and metallothionein(MT)mRNA expression.Fish exhibited pathological symptoms such as hypertrophy and hyperplasia of primary and secondary gill lamellae,vacuolization in hepatocytes,and prominent tubular and glomerular damage in the kidney.In addition,kidney accumulated the highest content of cadmium,more than gills and liver.Expression of MT mRNA was increased in both liver and kidney of treated fish.Hepatic MT levels remained high after fish were removed to Cd-free water.In contrast,MT expression in kidney was peaked after 28 d of treatment and drastically dropped when fish were removed to Cd-free water.The high concentrations of Cd in hepatic tissues indicated an accumulation site or permanent damage on this tissue.