考虑参数不确定性的框剪结构敏感性分析

建筑结构的地震需求受诸多不确定性参数的影响,为研究这些参数对地震响应的影响,以13层钢筋混凝土框架-剪力墙结构为例,基于结构非线性时程分析的结果,得到了选择不确定性参数的Tornado图形敏感程度排序,排序结果表明:对于无控和有控结构,地震动强度和地震动特征对地震需求的影响均较显著;增设阻尼器后,阻尼系数和阻尼指数也会...     

Importance and uncertainty analysis of flue gas scrubber systems with extreme reliability parameter values

Although reliability analyses have been used to improve the reliability of industrial systems, generic reliability data from publications, such as component failure intensities and repair times, are used to calculate reliability measures instead of the real reliability data collected from the plant. One reason is that the repair history of the components is not well managed in the plant. In this work, the effect of extreme reliability parameter values on system reliability and unavailability is studied. To do this, importance and uncertainty analysis of the components of flue gas scrubber systems is carried out, and results calculated with the extreme reliability parameter values are compared with those with the mean reliability values of the systems. The different reliability parameter values can give us totally different ranks of the components critical to the reliability of the representative scrubber system. Consequently, the effort to establish a reliable database is emphasized to perform accurate reliability analysis of the system.     

An economic evaluation framework for membrane reactor modules in the presence of uncertainty: The case for process safety investment and risk reduction

A comprehensive Net Present Value (NPV) model has been developed to demonstrate the economic advantages of process safety and risk reduction investments on Pd/Au-based membrane reactors. In particular, the economic viability of Pd/Au-based membrane reactor modules incorporated into Integrated Gasification Combined Cycle (IGCC) plants is evaluated within the aforementioned framework by pro-actively following sound process safety design principles. Sources of irreducible uncertainty (market, technological, operational) as well as safety risk are explicitly recognized, such as the Pd/Au prices, membrane life-time and loss in the power plant capacity factor due to possible accidents. The effect of the above uncertainty drivers on the membrane module cost along with production disruption and associated revenue losses is elucidated using Monte-Carlo simulation techniques that enable the propagation of the above uncertain inputs through the NPV-model, and therefore, generate a more realistic distribution of the process system's value rather than a single-point/estimate that overlooks these uncertainties. Pre-investment on risk reducing measures, such as spare safety relief systems (cautionary redundancy) for membrane reactor modules operating at high pressures (e.g. 50 atm), is shown to be economically more attractive than cases where analogous safety measures are not implemented. Since accidents and possibly catastrophic events do happen in an uncertain world, additional investment on safety measures could ensure a safer and more profitable operation of the process system under consideration giving credence to the thesis that process safety investments may result in enhanced techno-economic performance in the presence of irreducible uncertainties.     

Use of bifurcation analysis for identification of a safe CSTR operability

Exothermic reactions are the most interesting systems for safety analysis because of their potential safety problems and the possibility of exotic behavior like multiple steady states. An operability and safety analysis of an exothermic reaction (hydrolysis of propylene oxide to tri-propylene glycol with consecutive reactions in a CSTR) with cooling is reported in this work. The information obtained from the bifurcation diagram is used to identify a set of unsafe operation points, which have been chosen on the base of requirement of maximal production of the process. An important information of safe reactor operation is the time in which the operator must handle a critical situation. For this reason, dynamics simulation of a failure in the cooling medium flow rate has been done and discussed for each of the selected operation points.     

化工园区安全规划方法与应用研究

如何进行科学合理的园区安全规划,整体上提高化工园区的安全水平,是当前化工园区发展过程中的一个关键问题。中国安全生产科学研究院研发的化工园区定量风险评价(QRA)技术及其软件通过化工园区各类事故后果计算、事故概率分析获得园区个人风险、社会风险和安全容量等园区整体性风险评价结果,可用于园区选址规划、园区布局规划、园区企业准入规划和园区安全生产一体化规划等,为化工园区土地使用安全规划提供了实用技术方法,在国内几十个化工园区推广应用,取得了良好实际应用效果。     

化工园区安全容量计算模型研究

本文探讨了化工园区安全容量的含义。选择了适当的基础安全容量计算模型及事故统计指标,建立了安全容量影响因素体系,在此基础上,运用改进G1法和模糊综合评价法确定各因素的权重和隶属度,进而提出化工园区安全容量的计算模型。     

工业产品安全相关性评价研究

根据事故发生机理和系统相关性,给出了产品安全相关性的概念,并由此建立了定量评价模型.提出了主动安全相关性系数和被动安全相关性系数,并用其来表示产品安全相关性的大小.     

基于安全规划要素表的化工园区安全规划研究

化工园区的蓬勃发展为我国经济发展做出了重要贡献,与此同时,近年来化工园区的安全状况不容乐观,事故时有发生,缺乏有效的安全规划是事故发生的原因之一,而安全规划依据不完善、操作性不强是化工园区安全规划难以有效落实的重要原因。针对此问题,笔者依据《中华人民共和国安全生产法》等相关法律法规、标准规范,并借鉴国内外化工园区安全规划的先进经验,提炼出化工园区安全规划核心要素,将安全规划要素表作为化工园区安全规划的直接依据,该依据内容具体、较为完整。同时,基于安全规划要素表,本文重点研究了在化工园区生命周期内各阶段应重点规划的内容,指导化工园区各阶段的安全建设以及应重点注意的问题,以期加强化工园区的整体安全。     

岗位安全评价在化工企业安全管理中的运用

近几年,作为安全职能管理部门,将传统安全管理和现代安全管理有机结合,运用岗位安全评价技术,贯穿到化工企业安全管理全过程,以达到安全生产的目的,对此,谈一谈岗位安全评价在化工企业安全管理中应如何运用.     

Robotic testing of radio frequency devices designed for industrial safety

An experimental setup is proposed to test the performance of safety devices based on radio frequency technology. The setup specifically tests devices designed for improving safety in dangerous areas of small size, such as those surrounding power press brakes. Tested here is a radio frequency identification (RFID) prototype, whose main objective is to prevent accidents by sending a stop signal to a machine when a worker’s wrist, bearing an RFID tag, gets too close to the dangerous area. An ABB IRB 2400L robot is used as a reference system; this system is capable of providing millimeter accuracy. A plastic hand and a wristband with at least one passive RFID tag are attached to the end of the robot arm, which emulates the behavior of a human arm. With this robotic approach, it is possible to test trajectories with different velocities and orientations and to simulate several risky situations associated with machine use. Several experiments are presented that were conducted with the RFID prototype, and statistics are reported on the distance detection capability of this safety system with respect to the plane that defines the dangerous area. A matrix approach is proposed for analyzing the robustness of safety devices that are designed to automatically prevent a worker entering in dangerous areas. The results show the benefits that development of a radio frequency device of this class could confer towards increasing worker safety.     

汽车色彩设计对交通安全的影响研究

人的因素对道路交通安全的影响最大,色彩作用于人的生理与心理,能给人不同的心理感受.介绍了色彩的属性和几种常见颜色的色彩心理;根据色彩的生理心理特性,从车身和驾驶室配色等方面,采用安全心理学和色彩心理学以及定性分析的方法,分析了汽车色彩对交通安全和驾驶员反应的重要影响;最后提出了对汽车进行安全色彩设计的构想,并给出汽车安全色彩设计的原则、体系和步骤;对车身和驾驶室进行安全色彩设计,其中合理的色彩模拟系统的开发是关键.与其他有效的交通管理措施相结合,从而达到交通系统和谐的效果.     

Kinetic and 2D reactor modeling for simulation of the catalytic reduction of NOx in the monolith honeycomb reactor

Emission of NO_x is of primary environmental concern in the oil sands industry. Selective catalytic reduction (SCR) is one of the best NO_x reduction technologies. The present study discusses the testing of a mechanistic kinetic model for the SCR of NO_x to describe the kinetics of V₂O₅/TiO₂ catalysis at atmospheric pressure and a temperature of 623 K in a monolith honeycomb reactor. The modeling results impart insight into the significance of the diffusion with reaction steps and guidance for optimal monolith design for SCR. The validated expression would predict the conversion performance of the catalysts for different values of temperature inlet and ammonia concentration. A good agreement between experimental and model results has been obtained. A heterogeneous numerical model consisting of coupled mass and momentum balance equations was solved using the finite elements method without neglecting the axial dispersion term. The operating range for the catalyst relies on the NO conversion and emission. The optimum operating range for the best performance of the reactor is discussed.     

液氨储罐事故性泄漏扩散过程模拟分析

液氨是化工企业常用的原料，而每年因为液氨储罐的泄漏造成的事故也十分频繁，液氨属于高度危险性物质，一旦泄漏极可能造成灾难性后果。本文探讨了描述液氨储罐事故性泄漏及扩散过程的数学模型，并用所建模型针对某市化学园区某化工公司液氨储罐工程建设项目进行模拟分析。从模拟结果来看，采用数学模型的方法对事故后果进行预测和分析具有一定程度的可靠性，对于救灾、重大危险源编制应急事故预案以及对新建项目进行危险性预评价都具有一定程度的指导意义。     

反应器热爆炸风险分析模型的构建

从风险的角度开展化工安全管理与决策。基于能量转移论,综合运用化工工艺的热风险评估和保护层分析(LOPA)方法,在对各类典型事故预防控制措施的有效性分析基础上,选择化工工艺过程中的绝热温升(ΔTad)表征反应器热爆炸的严重度,采用保护层分析得到的事故发生频率表征反应器热爆炸的发生可能性,构建了适用于反应器热爆炸的风险分析模型。在运用该模型对甲苯一段硝化间歇反应器的热爆炸风险进行分析的过程中,给出了相应的风险决策方案,验证了模型的可行性。     

旧工业建筑再生利用项目施工安全的评价及改进

针对旧工业建筑再生利用项目施工过程中存在诸多安全隐患的问题,首先,结合此类项目遗留工业垃圾冗杂、施工场地狭窄、部分构件拆换、大型机械使用受限的施工特点从4MTE角度构建施工安全评价指标体系。然后,在考虑指标赋权的主客观综合性与评价工作的未确知性后,建立了基于结构熵权法与未确知测度理论的旧工业建筑再生利用项目施工安全评价模型,并通过工程实例验证该模型,得出的评价结果与实际情况相符。最后,结合未确知测度单因素指标测度函数的特点,提出了施工安全管理改进策略的制定方法。     

有机过氧化物在生产、储运过程中的危险与可操作性分析

有机过氧化物的易燃、受热分解等特殊性质和生产、储运过程要求严格的低温条件与操作程序,使得有机过氧化物潜在的危险性很高。通过基于有机过氧化物危险特性及其在生产、储运过程中物质、能量与信息的分析,依据物-能量-信息的安全要素体系,应用危险与可操作分析方法,研究了有机过氧化物的安全理论,在某种程度上是延伸了HAZOP分析的内容。     

转锥式闪速热解反应器结构安全性设计理论研究

本文对转锥式热解反应器结构安全性设计理论进行了初步的探讨 ,主要是对热解装置工作影响较大的两个问题 :高热负荷条件下转锥强度的计算和转轴的临界转速问题进行了研究。     

安全认知观念的研究与决策分析

通过分析当前石油石化企业发生的事故数据,发现由于人为因素造成的事故时有发生,给企业安全生产造成重大影响。为了深入了解造成事故发生的人为因素产生根源,笔者通过多种方式获取资料,利用系统论研究方法,得出了企业员工和管理者普遍存在的安全认知观念。在此基础上,提出员工和管理者之间推荐的共同安全认知观念,从观念上让员工和管理者对不安全行为形成一致的认知,并在减少员工不安全行为、规范员工的安全行为方面给出了行之有效的解决方法,即在企业推行行为安全管理工具-HSE观察卡。应用结果表明,通过推行HSE观察卡,可有效提高企业员工在现场作业活动中的安全作业意识,从而避免或减少由于人的不安全行为造成事故发生率,提升了企业安全生产水平。     

建立工伤保险与安全生产相结合的管理体制

工伤保险与安全生产相结合是人们的共识。而如何结合,才能发挥工伤保险在事故预防中的作用哪?分析国内外工伤保险的管理体制、运行模式和工作特点,人们不难从中得出结论。     

Exploratory analysis of the safety climate and safety behavior relationship

Problem: Safety climate refers to the degree to which employees believe true priority is given to organizational safety performance, and its measurement is thought to provide an “early warning” of potential safety system failure(s). However, researchers have struggled over the last 25 years to find empirical evidence to demonstrate actual links between safety climate and safety performance.Method: A safety climate measure was distributed to manufacturing employees at the beginning of a behavioral safety initiative and redistributed one year later.Results: Multiple regression analysis demonstrated that perceptions of the importance of safety training were predictive of actual levels of safety behavior. The results also demonstrate that the magnitude of change in perceptual safety climate scores will not necessarily match actual changes (r=0.56, n.s.) in employee's safety behavior.Discussion: This study obtained empirical links between safety climate scores and actual safety behavior. Confirming and contradicting findings within the extant safety climate literature, the results strongly suggest that the hypothesized climate-behavior-accident path is not as clear cut as commonly assumed.Summary: A statistical link between safety climate perceptions and safety behavior will be obtained when sufficient behavioral data is collected.Impact on Industry: The study further supports the use of safety climate measures as useful diagnostic tools in ascertaining employee's perceptions of the way that safety is being operationalized.