Stormwater Control Measures for Runoff and Water Quality Management in Urban Landscapes

This study develops and tests a novel optimization method for optimally selecting and sizing stormwater control measures (SCMs) in urban landscapes for selected design storms. The developed methodology yields SCMs that capture and retain stormwater via onsite percolation, remove stormwater pollutants, and minimize stormwater control expenditures. The resulting environmental optimization problem involves integer and real variables imbedded in an objective function that is subjected to multiple constraints. This study's methodology aims at practicality and ease of implementation in the solution of the SCM sizing and selection optimization problem while taking into account the main factors that govern stormwater management in urban landscapes. The near‐optimal global solution of the SCM selection and design problem is obtained with nonlinear programming and verified with the average of multiple solutions calculated with multiple runs of an optimization evolutionary algorithm. The developed methodology is illustrated with one stormwater project in the City of Los Angeles, California.     

THE DETERMINATION OF PRIMARY PRODUCTION IN A STREAM USING AN EXACT SOLUTION TO THE OXYGEN BALANCE EQUATION1

ABSTRACT. A promising technique for recognition of early stages of cultural eutrophication relies on determining production and respiration in streams. The most successful and most widely used method of estimating production of a segment of a stream is the upstream-downstream, diurnal curve method introduced by Odum [1956]. This technique is equivalent to obtaining an approximate solution to the oxygen balance equation. We report here an exact solution of the balance equation as a method for calculating primary production. Data presented by Owens [1966] are analyzed; effects of depth and oxygen saturation are studied. A major advantage of the method described here is that continuous temporal variation of net production may be rigorously handled. The method is shown to be well suited to our ultimate goal of studying energy budgets of streams, and thereby the eutrophication process.     

Aluminum effect on dissolution and precipitation under hyperalkaline conditions: I. Liquid phase transformations

Substantial amounts of self-boiling, Al-rich, hyperalkaline, and saline high-level waste fluids (HLWF) were deposited to the vadose zone at the Hanford Site, in Washington State. The objective of this study was to investigate the effects of similar fluids on the extent of dissolution and precipitation in the sediments. Metal- and glass-free systems were used to conduct batch experiments at 323 K under CO2 and O2 free conditions. Base-induced dissolution of the soil minerals was rapid in the first 48 h as indicated by immediate releases of Si and Fe into the soil solution. Potassium release lagged behind and dissolution of K-bearing minerals (mica and K-feldspar) proceeded faster only after 2 to 3 d of the experiment. Silicon and Fe release exhibited high dependence on aqueous [Al] (rate orders <-1), because Al decreased free OH concentration in the contact solution and probably inhibited soil mineral dissolution. Initial K release exhibited low dependence on [Al] (fractional rate orders). Initial dissolution rates calculated based on Si release varied with aqueous [Al] from 29.47 to 4.35 x 10(-12) mol m(-2) s(-1). Aluminum participated in the formation of the secondary phases (precipitation rates of 10(-8) mol s(-1)) but the overall precipitation rate of alumino-silicate secondary phases was probably controlled by aqueous [Si] (rates of 10(-9), and rate constants between 0.0054 and 0.0084 h(-1)). The changes in the soil solution chemistry (release of K, Si, Fe, and other elements) may play a significant role in the fate of radionuclides and contaminants like Cs, Sr, Cr, and U in the Hanford sediments.     

Measuring sorption of hydrophilic organic compounds in soils by an unsaturated transient flow method

Determination of sorption of hydrophilic, weakly sorbing organic compounds in soil by conventional batch methods using a slurried suspension is often prone to considerable errors because small changes in the solution concentration on equilibration must be accurately determined. This difficulty is exacerbated for compounds susceptible to degradation, which also decreases the solution concentration. The objective of this study was to determine sorption of hydrophilic pesticides by applying an unsaturated transient flow method, which enables determination of sorption at sufficiently small solution to soil ratios. The method makes use of piston-like displacement of the antecedent solution in equilibrium with sorbed phase when pesticide-free water is infiltrated into a soil column spiked with a pesticide. Pesticide sorption and the solution concentration are inferred from a plot of total pesticide content per unit mass of soil vs. water content in a region where the antecedent solution is accumulated. Thus, extraction of solution from relative dry soil is unnecessary. We tested this method for two hydrophilic pesticides, monocrotophos [dimethyl (E)-1-methyl-2-(methyl-carbamoyl) vinyl phosphate] and dichlorvos (2,2-dichlorovinyl dimethyl phosphate). The sorption coefficient, K(d), obtained for monocrotophos was slightly lower than that by batch method (K(d) = 0.10 vs. 0.19 L kg(-1)), whereas for dichlorvos, a compound highly susceptible to degradation, the unsaturated flow method yielded a much smaller K(d) (0.19 vs. 3.22 L kg(-1)). The K(d) values for both compounds were consistent with the observed retardation in the pesticide displacement in the columns. The proposed method is more representative of field conditions and particularly suitable for weakly sorbing organic compounds in soils.     

Application of a new leaf area index algorithm to China's landmass using MODIS data for carbon cycle research

An operational system was developed for mapping the leaf area index (LAI) for carbon cycle models from the moderate resolution imaging spectroradiometer (MODIS) data. The LAI retrieval algorithm is based on Deng et al. [2006. Algorithm for global leaf area index retrieval using satellite imagery. IEEE Transactions on Geoscience and Remote Sensing, 44, 2219-2229], which uses the 4-scale radiative transfer model [Chen, J.M., Leblancs, 1997. A 4-scale bidirectional reflection model based on canopy architecture. IEEE Transactions on Geoscience and Remote Sensing, 35, 1316-1337] to simulate the relationship of LAI with vegetated surface reflectance measured from space for various spectral bands and solar and view angles. This algorithm has been integrated to the MODISoft platform, a software system designed for processing MODIS data, to generate 250 m, 500 m and 1 km resolution LAI products covering all of China from MODIS MOD02 or MOD09 products. The multi-temporal interpolation method was implemented to remove the residual cloud and other noise in the final LAI product so that it can be directly used in carbon models without further processing. The retrieval uncertainties from land cover data were evaluated using five different data sets available in China. The results showed that mean LAI discrepancies can reach 27%. The current product was also compared with the NASA MODIS MOD15 LAI product to determine the agreement and disagreement of two different product series. LAI values in the MODIS product were found to be 21% larger than those in the new product. These LAI products were compared against ground TRAC measurements in forests in Qilian Mountain and Changbaishan. On average, the new LAI product agrees with the field measurement in Changbaishan within 2%, but the MODIS product is positively biased by about 20%. In Qilian Mountain, where forests are sparse, the new product is lower than field measurements by about 38%, while the MODIS product is larger by about 65%.     

In situ bioremediation through mulching of soil polluted by a copper-nickel smelter

Bioremediation of a heavy metal-polluted soil was investigated in a 3-yr field experiment by adding mulch to a polluted forest floor. The mulch consisted of a mixture of compost and woodchips. The remediation treatment decreased the toxicity of the soil solution to bacteria as determined by the [3H]-thymidine incorporation technique, that is, by measuring the growth rate of soil bacteria extracted from unpolluted humus after exposing them to soil solution containing heavy metals from the experimental plots. Canonical correlation analysis was performed in order to identify the chemical and microbiological changes in the soil. The pH of the mulched organic layer increased by one unit. The concentration of complexed Cu increased and that of free Cu2+ decreased in the soil solution from the mulch treatment. According to basal respiration and litter decomposition, microbial activity increased during the 3 yr following the remediation treatment. The [3H]-thymidine incorporation technique was also used to study the growth rate and tolerance of bacteria to Cu. The bacterial growth rate increased and the Cu tolerance decreased on the treated plots. The structure of the microbial community, as determined by phospholipid fatty acid (PLFA) analysis, remained unchanged. The results indicate that remediation of the polluted soil had occurred, and that adding a mulch to the forest floor is a suitable method for remediating heavy metal-polluted soil.     

搅拌棒吸附萃取气相色谱法测定地表水中多环芳烃

建立了新型的搅拌棒吸附萃取（SBSE）和热脱附系统（TDU）结合的气相色谱（GC）测定地表水中多环芳烃的方法。考察了萃取时间、搅拌条件及萃取温度对实验的影响,对7种多环芳烃（萘、荧蒽、苯并[b]荧蒽、苯并[k]荧蒽、苯并[ghi]苝、茚并[1,2,3-cd]芘和苯并[a]芘）的加标回收率为89.17%～99.38%,相对标准偏差（RSD）为1.6%～5.6%（n=3）。通过实际样品中PAHs的分析表明,该法快速、灵敏、简单,能满足痕量分析的需求。     

Guided group discussion and the reported use of toxic products: The persuasiveness of hearing others’ views

Guided group discussion ( [Lewin et?al., 1952] , [Werner, 2003] and [Werner and Adams, 2001] ) was used to persuade groups to replace their toxic home and garden chemicals with nontoxic alternatives. We hypothesized that discussion would allow participants to hear others endorse the new information, and this normative information would facilitate persuasion. Approximately two months after the group discussion, we obtained questionnaires from the organizer of the meeting and a member of the group who had missed the meeting because of another obligation (i.e., not because of disinterest in the topic). Most organizers were female and analyses were limited to females. This quasi-experimental matched control group design indicated that those who attended the meeting were more favorable towards using nontoxics and more interested in sharing leftover toxic products with friends (instead of discarding them). Path and mediation analyses showed that the organizer’s evaluation of the meeting predicted her final attitude, and perceptions that the group endorsed the material (perceived group norm) partially mediated this relationship. A second mediation analysis showed that evaluation of the meeting predicted intention to share leftover toxics and this relationship was fully mediated by the organizer’s impression that the group would also share leftovers. The results support the idea that persuasion is based both on individual evaluation and normative influence, especially when people are not confident others will accept the behavior, such as sharing leftover toxic products.     

OPTIMAL MANAGEMENT AND DESIGN OF HYDRAULIC SYSTEMS1

ABSTRACT: A possible methodology is developed to deal with the problem of designing complex pipeline systems, when they are subject to different rates of demand, and when a hypothesis of the flow distribution in different branches is not allowed. The mathematical algorithm used in linear programming. The problem, which is not linear, is dealt with by means of an iterative method; that is, by starting with a possible solution and inserting at each iteration the solution found in the preceding iteration. By taking as variables of the problem the piezometric heads of the ends for each branch of the network, the piezometric gradients and flows, and by thus considering the diameter as a derived variable, it is possible to isolate the nonlinearity in the cost function of the network. The latter is linearized each time close to the solution found in the preceding iteration.     

Infiltration and adsorption of dissolved atrazine and atrazine metabolites in buffalograss filter strips

Vegetated filter strips (VFS) potentially reduce the off-site movement of herbicides from adjacent agricultural fields by increasing herbicide mass infiltrated (Minf) and mass adsorbed (Mas) compared with bare field soil. However, there are conflicting reports in the literature concerning the contribution of Mas to the VFS herbicide trapping efficiency (TE). Moreover, no study has evaluated TE among atrazine (6-chloro-N-ethyl-N'-isopropyl-[1,3,5]triazine-2,4-diamine) and atrazine metabolites. This study was conducted to compare TE, Minf, and Mas among atrazine, diaminoatrazine (DA, 6-chloro[1,3,5]triazine-2,4-diamine), deisopropylatrazine (DIA, 6-chloro-N-ethyl-[1,3,5]triazine-2,4-diamine), desethylatrazine (DEA, 6-chloro-N-isopropyl-[1,3,5]triazine-2,4-diamine), and hydroxyatrazine (HA, 6-hydroxy-N-ethyl-N'-isopropyl-[1,3,5]triazine-2,4-diamine) in a buffalograss VFS. Runoff was applied as a point source upslope of a 1- x 3-m microwatershed plot at a rate of 750 L h(-1). The point source was fortified at 0.1 microg mL(-1) atrazine, DA, DIA, DEA, and HA. After crossing the length of the plot, water samples were collected at 5-min intervals. Water samples were extracted by solid phase extraction and analyzed by high performance liquid chromatography (HPLC) photodiode array detection. During the 60-min simulation, TE was significantly greater for atrazine (22.2%) compared with atrazine metabolites (19.0%). Approximately 67 and 33% of the TE was attributed to Minf and Mas, respectively. These results demonstrate that herbicide adsorption to the VFS grass, grass thatch, and/or soil surface is an important retention mechanism, especially under saturated conditions. Values for Mas were significantly higher for atrazine compared with atrazine's metabolites. The Mas data indicate that atrazine was preferentially retained by the VFS grass, grass thatch, and/or soil surface compared with atrazine's metabolites.     

Major herbicides in ground water: results from the National Water-Quality Assessment

To improve understanding of the factors affecting pesticide occurrence in ground water, patterns of detection were examined for selected herbicides, based primarily on results from the National Water-Quality Assessment (NAWQA) program. The NAWQA data were derived from 2,227 sites (wells and springs) sampled in 20 major hydrologic basins across the USA from 1993 to 1995. Results are presented for six high-use herbicides--atrazine (2-chloro-4-ethylamino-6-isopropylamino-s-triazine), cyanazine (2-[4-chloro-6-ethylamino-1,3,5triazin-2-yl]amino]-2-methylpropionitrile), simazine (2-chloro-4,6-bis-[ethylamino]-s-triazine), alachlor (2-chloro-N-[2,6-diethylphenyl]-N-[methoxymethyl]acetamide), acetochlor (2-chloro-N-[ethoxymethyl]-N-[2-ethyl-6-methylphenyl]acetamide), and metolachlor (2-chloro-N-[2-ethyl-6-methylphenyl]-N-[2-methoxylethyl]acetamide)--as well as for prometon (2,4-bis[isopropylamino]-6-methoxy-s-triazine), a nonagricultural herbicide detected frequently during the study. Concentrations were <1 microg L(-1) at 98% of the sites with detections, but exceeded drinking-water criteria (for atrazine) at two sites. In urban areas, frequencies of detection (at or above 0.01 microg L(-1)) of atrazine, cyanazine, simazine, alachlor, and metolachlor in shallow ground water were positively correlated with their nonagricultural use nationwide (P < 0.05). Among different agricultural areas, frequencies of detection were positively correlated with nearby agricultural use for atrazine, cyanazine, alachlor, and metolachlor, but not simazine. Multivariate analysis demonstrated that for these five herbicides, frequencies of detection beneath agricultural areas were positively correlated with their agricultural use and persistence in aerobic soil. Acetochlor, an agricultural herbicide first registered in 1994 for use in the USA, was detected in shallow ground water by 1995, consistent with previous field-scale studies indicating that some pesticides may be detected in ground water within 1 yr following application. The NAWQA results agreed closely with those from other multistate studies with similar designs.     

Phosphorus retention mechanisms of a water treatment residual

Water treatment residuals (WTRs) are a by-product of municipal drinking water treatment plants and can have the capacity to adsorb tremendous amounts of P. Understanding the WTR phosphorus adsorption process is important for discerning the mechanism and tenacity of P retention. We studied P adsorbing mechanism(s) of an aluminum-based [Al2(SO4)3 x 14H2O] WTR from Englewood, CO. In a laboratory study, we shook mixtures of P-loaded WTR for 1 to 211 d followed by solution pH analysis, and solution Ca, Al, and P analysis via inductively coupled plasma atomic emission spectroscopy. After shaking periods, we also examined the solids fraction by X-ray diffraction (XRD) and electron microprobe analysis using wavelength dispersive spectroscopy (EMPA-WDS). The shaking results indicated an increase in pH from 7.2 to 8.2, an increase in desorbed Ca and Al concentrations, and a decrease in desorbed P concentration. The pH and desorbed Ca concentration increases suggested that CaCO3 controlled Ca solubility. Increased desorbed Al concentration may have been due to Al(OH)4 formation. Decreased P content, in conjunction with the pH increase, was consistent with calcium phosphate formation or precipitation. The system appeared to be undersaturated with respect to dicalcium phosphate (DCP; CaHPO4) and supersaturated with respect to octacalcium phosphate [OCP; Ca4H(PO4)3 x 2.5H2O]. The Ca and Al increases, as well as OCP formation, were supported by MINTEQA2 modeling. The XRD and EMPA-WDS results for all shaking times, however, suggested surface P chemisorption as an amorphous Al-P mineral phase.     

Environmentally conscious manufacturing and product recovery (ECMPRO): A review of the state of the art

Gungor and Gupta [1999, Issues in environmentally conscious manufacturing and product recovery: a survey. Computers and Industrial Engineering, 36(4), 811–853] presented an important review of the development of research in Environmentally Conscious Manufacturing and Product Recovery (ECMPRO) and provided a state of the art survey of published work. However, that survey covered most papers published through 1998. Since then, a lot of activity has taken place in EMCPRO and several areas have become richer. Many new areas also have emerged. In this paper we primarily discuss the evolution of ECMPRO that has taken place in the last decade and discuss the new areas that have come into focus during this time. After presenting some background information, the paper systematically investigates the literature by classifying over 540 published references into four major categories, viz., environmentally conscious product design, reverse and closed-loop supply chains, remanufacturing, and disassembly. Finally, we conclude by summarizing the evolution of ECMPRO over the past decade together with the avenues for future research.     

THE CHANCE A FLOOD WILL BE EXCEEDED IN A PERIOD OF YEARS1

ABSTRACT. Much has been written about the chance that a hydrologic event, such as a flood peak of a given size or greater, will occur during a given period of years. Four variables are involved, and any one of the four can be the dependent variable: (1) the probability of encountering such an event in a single year, (2) the probability of encountering one or several of these events in a period of years, (3) the least number of times of encountering the event in that period of years, and (4) the number of years in the period involved. Most of these problems are not difficult to solve, but they are tedious to calculate, not well understood, and consequently seldom used in water resources planning and development. The most popular approach is based on the binomial distribution. Graphical procedures similar to those developed by Riggs [1961] were further elaborated and are presented here with illustrative examples to facilitate their use in solving the many related problems. The confidence that one can place in these probability estimates is also explained and illustrated by tables and further examples. To help assure proper use of these methods, commonly used terms such as “recurrence interval” and “partial duration series” are discussed. No new theory is developed: at issue is a deeper understanding of the significance of design levels and their ease of computation.     

基于1NM1模型的环保信息系统模式构建及其技术实现

环保信息化建设是一项复杂的系统工程,它需要充分考虑地域差异、业务差异、标准差异以及各层级数据之间的互联互通等问题。本文从顶层设计角度提出了1NM1信息化理论模型及其系统架构,并提出一个熵值公式来表示整个系统信息化的复杂程度。1NM1模型用来描述并指导在一个具有M个层级,每个层级又有N个部门,且层级和部门之间各具特色的组织中如何建设遵循统一平台、统一标准的统一化信息系统。该系统按照"云"加"端"的总分架构进行设计,并将整个系统分为云平台(Joint Cloud)和端平台(Joint OS)两个部分。通过云平台来对本级节点各类应用的数据和业务进行整合,然后利用端平台对本级节点新应用系统进行构建。1NM1模型的提出,不仅可为环保信息化的顶层设计、系统各层级之间的业务协同以及信息资源的整合提供一种新的解决思路,也可为其他行业的信息化建设提供理论指导与借鉴。     

A CODED ALGORITHM FOR CAPACITY EXPANSION OF A WATER QUALITY MANAGEMENT SYSTEM1

ABSTRACT: This paper describes a mathematical model, an algorithm and a computer program that were specially developed to study the problem of a water quality management system undergoing a rapidly increasing environmental stress. The model output will determine the locations, sizes and the timing of construction of new treatment plants plus an overall treatment plant operating policy so that environmental standards are maintained at a minimum cost. The model, as formulated, is a 0-1 mixed integer programming problem which is solved by decomposing it into a capital budgeting problem (solved by Little's branch and bound algorithm) and an operational policy problem (solved by linear programming). The coded algorithm (in FORTRAN 10) has been tested with a semi-realistic example.     

村镇供水管网优化设计探讨

如何合理确定村镇供水管网敷设方案,关系到整个供水系统的安全性和可靠性。通过生成树变化法,将环状管网转化成树状管网,确定供水管网中最短供水路线,再计算最短供水路线下的最低综合费用、供水系统的经济管径,以确定最优管道敷设方案。根据该方法对四川省某镇供水系统进行了设计。     

Contrasting physiological responses of dwarf sea-lavender and marguerite to simulated sea aerosol deposition

Plants of two wild native species from littoral areas, marguerite [Argyranthemum coronopifolium (Willd.) C.J. Humphries] and dwarf sea-lavender [Limonium pectinatum (Aiton) O. Kuntze], grown in an unheated plastic greenhouse, were sprayed 2 to 3 min per day over a 7-d period with different aqueous solutions containing (i) an anionic surfactant (S1); (ii) a solution simulating the composition of sea aerosol (S2); (iii) a solution simulating sea aerosol with anionic surfactant (S3), and (iv) deionized water alone (control). The plant resistance to sea aerosol and the ability to recover from treatments were studied. By the end of the spraying period, marguerite showed a significant reduction in growth compared with control. However, most of the growth parameters were significantly unaffected in dwarf sea-lavender when plants were treated with sea aerosol containing surfactant. Measurements of water relations variables in marguerite showed a slight decrease in leaf turgor potential after spraying with sea aerosol containing surfactant. The surfactant enhanced the foliar absorption of salt in marguerite plants, inducing reductions in leaf stomatal conductance and causing such damage in the photosynthetic apparatus that the level of net photosynthesis decreased and had not recovered by the end of the experiment. The treatments had no effect on leaf stomatal conductance and photosynthesis rate in dwarf sea-lavender plants. The response of the species studied to sea aerosol was related to the degree of salinity tolerance. Although both species are wild native plants from littoral areas, marguerite is not salt tolerant and was the most sensitive to the sea aerosol treatments, while dwarf sea-lavender, a halophyte species, was more efficient at decreasing the toxic salt content of the tissues as its growth and ornamental characteristics were not affected.     

Urban water resources planning by using a modified particle swarm optimization algorithm

A new optimization algorithm by coupling the mutation process to the particle swarm optimization (PSO) is developed in this paper. This algorithm, entitled particle swarm optimization with mutation similarity (PSOMS), is successfully applied to an urban water resources management problem for the large city of Tabriz, Iran. The objective functions of the optimization problem are to minimize the cost, maximize water supply and minimize the environmental hazards. The constraints are physical limits such as pipelines capacity, ground water, the demand and the impact of conservation tools. Due to the parameters uncertainty, the water supply objective is modeled with fuzzy set theory and the objectives are then combined with compromise programming. The resulted single objective is solved using PSOMS, and its efficiency is then compared with the basic PSO and two kinds of genetic algorithms. Among them, PSOMS shows rapid convergence and suitable results compared to other methods. PSOMS is also improved to provide the Pareto frontier, which is needed to proper selecting of the optimal solutions in the uncertain conditions. Finally, the diversity of solutions is checked based on an indicator of the distances between different solutions, which show the efficiency of the PSOMS algorithm with respect to the genetic algorithm. Then by using the non-symmetric Kalai–Smorodinsky method a guideline is provided for comfort selection of the most preferred solution in the Pareto frontier. Based on these outcomes, the multi-objective PSOMS provides more appropriate results needed for urban systems management.     

Application of Tabu Search Algorithm With a Coupled AnnAGNPS‐CCHE1D Model to Optimize Agricultural Land Use1

Abstract: A principal contributor to soil erosion and nonpoint source pollution, agricultural activities have a major influence on the environmental quality of a watershed. Impact of agricultural activities on the quality of water resources can be minimized by implementing suitable agriculture land‐use types. Currently, land uses are designed (location, type, and operational schedule) based on field study results, and do not involve a science‐based approach to ensure their efficiency under particular regional, climatic, geological, and economical conditions. At present, there is a real need for new methodologies that can optimize the selection, design, and operation of agricultural land uses at the watershed scale by taking into account environmental, technical, and economical considerations, based on realistic simulations of watershed response. In this respect, the present study proposes a new approach, which integrates computational modeling of watershed processes, fluvial processes in the drainage network, and modern heuristic optimization techniques to design cost effective land‐use plans. The watershed model AnnAGNPS and the channel network model CCHE1D are linked together to simulate the sediment and pollutant transport processes. Based on the computational results, a multi‐objective function is set up to minimize soil losses, nutrient yields, and total associated costs, while the production profits from agriculture are maximized. The selected iterative optimization algorithm uses adaptive Tabu Search heuristic to flip (switching from one alternative to another) land‐change variables. USDA’s Goodwin Creek experimental watershed, located in Northern Mississippi, is used to demonstrate the capabilities of the proposed approach. The results show that the optimized land‐use design with BMPs using an integrated approach at the watershed level can provide efficient and cost‐effective conservation of the environmental quality by taking into account both productivity and profitability.