城市路面降雨径流污染特征及源解析的研究进展

城市路面径流是城市地表径流的重要组成部分,因其污染强度大、对地表水体的影响严重而被予以格外的关注。通过对国内外关于路面径流水质的研究进行总结发现：我国城市道路径流中COD、TP、TN和Pb的平均质量浓度分别为239.59、0.46、6.29和0.14 mg·L-1,超过了国家地表水环境质量Ⅴ类标准,TSS的质量浓度高达552.86 mg·L-1。因此,COD、TP、TN、Pb和TSS是我国路面径流的主要污染物。高速路径流污染物Pb、Cu和Zn的浓度明显高于普通道路,而普通道路径流污染物中COD和TSS要高于高速路。与其他国家相比,我国城市道路雨水径流污染物浓度偏高。多数研究表明：污染物的质量浓度与降雨量呈负相关关系,路面坡度增加了车辆与路面的摩擦力和燃料的消耗,进而导致路面径流污染物的浓度较高,路面清扫或许对污染物的浓度有不利的影响,主要由于道路清扫将路面中部分大颗粒破碎,释放出了细小的颗粒物（粒径〈43μm）并且不能将其清除的缘故。但是,降雨强度、干期、降雨历时和车流量对径流水质的影响存在一定的争议。通过对现有的研究总结发现：车流量≥30000的路面径流中COD、TSS、Pb和Cu的浓度是车流量〈30000的路面径流中的2.5、4.3、1.4和5.1倍;路面径流中的重金属主要来源于车辆的交通损耗,有机污染物来源于车辆的交通活动和路面材质,营养污染物来源于大气干湿沉降。今后应从以下几方面开展研究：将多环芳烃、大肠杆菌等水质指标列入研究计划;深入分析影响降雨径流水质的因素及各影响因子间的交互作用;运用同位素溯源技术识别道路径流污染物来源。     

Modeling ecosystem responses to prescribed fires in a phosphorus-enriched Everglades wetland: I. Phosphorus dynamics and cattail recovery

We have developed and applied a process-based model, the Wetland Ecosystem Model (WEM), to evaluate the effects of a prescribed fire on the phosphorus (P) dynamics and cattail (Typha domingensis) growth in a P-enriched area in the Florida Everglades. The WEM couples major ecosystem processes including carbon (C), nitrogen (N) and P biogeochemical cycles, plant growth, hydrology, and fire disturbance. The model is used to assess the effects of a prescribed fire on P dynamics and cattail growth through dynamic interaction among four modules: fire, water chemistry, soil, and vegetation. The simulation results are in agreement with observed data including cattail above- and belowground biomass and dead mass, P concentration in surface-water, pore-water, and soil, and soil and water temperature. Cattail aboveground biomass reached the unburned level one year after burn; belowground biomass recovered to unburned level one and half years after the fire, however, dead mass did not completely reach unburned level two years after fires. The fire increased water and soil temperatures in the short term, while indirectly increasing the sensitivity of water and soil temperature post-fire response to air temperature by altering the energy exchange between air and water through a canopy gap created by fire. The fire also altered the P dynamics in surface-water and pore-water. A post-fire P pulse that lasted for less than one month was observed in surface-water. A similar P pulse, but in a small magnitude and a longer duration, was also observed in the pore-water total phosphorus (TP), and then came back to normal level after approximately three months. No significant changes in soil TP was observed during the study period. Meanwhile, no significant changes in water nutrients were observed downstream of the study plot. This finding indicated that the P-enriched wetlands in Everglades act as a buffer in regulating the P concentration in surface-water. Our study showed that the distance of fire effects on a 300 m × 300 m plot was less than 300 m downstream. Sensitivity analysis identified that the air temperature and hydrological conditions are two important driving factors which may alter the cattail community dynamics in response to prescribed fires. Similar to the filed studies, this study provided evidences that fire played an important role in managing plant growth and P dynamics in the Florida Everglades.     

再生水用于景观水体的氮磷水质标准确定

污水再生利用是解决水资源短缺问题的重要措施,其中再生水回用于景观水体是主要途径之一.而防止水华爆发则是再生水景观利用的首要任务,控制再生水中的氮磷是防止水华爆发的根本措施.目前已有的景观水体水质标准中,氮磷浓度限值要求不统一,缺乏科学依据.因此再生水处理过程中氮磷控制标准执行易出现矛盾,不利于保障再生水景观利用的水质安全.再生水景观利用的氮磷控制标准,应在藻类最大生长潜力研究的基础上,通过藻类生长的Logistic模型和Monod模型、景观水体氮磷浓度模型按拟合,并结合水体自净能力和水质保障措施等综合因素加以确定.以栅藻(Scenedesmus sp)为例,通过Logistic模型和Monod模型拟合景观水体水华控制氮磷浓度限值的确定方法.     

Bioavailability of trace metals in brownfield soils in an urban area in the UK

Thirty-two brownfield sites from the city of Wolverhampton were selected from those with a former industrial use, wasteland or areas adjacent to industrial processes. Samples (<2 mm powdered soil fraction) were analysed, using inductively coupled plasma–atomic emission spectrometry (ICP–AES) for 20 elements. Loss on ignition and pH were also determined. A five-step chemical sequential extraction technique was carried out. Single leach extraction with 0.12 M hydrochloric acid of Pb, Cu and Zn in soil was determined as a first approximation of the bioavailability in the human stomach. Some of the sites were found to have high concentrations of the potentially toxic elements Pb, Zn, Cu and Ni. The partitioning of metals showed a high variability, however a number of trends were determined. The majority of Zn was partitioned into the least chemically stable phases (steps 1, 2 and 3). The majority of Cu was associated with the organic phase (step 4) and the majority of Ni was fractionated into the residue phase (step 5). The majority of Pb was associated with the residue fraction (step 5) followed by Fe–Mn oxide fraction (step 3). The variability reflects the heterogeneous and complex nature of metal speciation in urban soils with varied historic histories. There was a strong inverse linear relationship between the metals Ni, Zn and Pb in the readily exchangeable phase (step 1) and soil pH, significant at P < 0.01 level. There was a significant increase (P < 0.05) in the partitioning of Cu, Ni and Zn into step 4 (the organic phase) in soils with a higher organic carbon content (estimated by loss on ignition). Copper was highly partitioned into step 4 as it has a strong association with organics in soil but this phase was not important for the partitioning of Ni or Zn. The fractionation of Ni, Cu and Zn increased significantly in step 3 when the total metal concentration increases (P < 0.01). The Fe–Mn oxide fraction becomes more important in soils elevated in these metals, possibly due to the scavenging of metals by oxides. Cu and Pb extracted by HCl was statistically similar to the sum of the metals in steps 1 to 4 (P < 0.01) and HCl available Zn was statistically similar to the sum of Zn in steps 1 to 3 (P < 0.01). Step 4 (the organic phase) was not an important phase for Zn, so it was concluded that any Cu, Zn and Pb present in soil in a nonresidue phase would be potentially available for uptake into the human system once soil has been ingested.     

Estimating an homogeneous series of a population abundance indicator despite changes in data collection procedure: A hierarchical Bayesian modelling approach

Abundance indicators are required both to assess and to manage wild populations. As new techniques are developed and teams in charge of gathering the data change, data collection procedures (DCPs) can evolve in space and time. How to estimate an homogeneous series of abundance indicator despite changes in DCP? To tackle this question a hierarchical Bayesian modelling (HBM) approach is proposed. It integrates multiple DCPs in order to derive a single abundance indicator that can be compared over space and time irrespective of the DCP used. Compared to single DCP models, it takes further advantage for abundance estimation of the joint treatment of a larger set of spatio-temporal units. After presenting the general formulation of our HBM approach, it is applied to the juvenile Atlantic salmon (Salmo salar L.) population of the River Nivelle (France). Posterior model checking, using χ² discrepancy measure, do not reveal any inadequacy between the model and the data. Despite a change in the DCP used (successive removals to catch-per-unit of effort), a unique abundance indicator for the 425 spatio-temporal units (site × year) sampled over twenty-four years (1985-2008) is estimated. The HBM approach allows the assessment of precision of the abundance estimates and shows variation between DCPs: a reduction in precision is observed during the most recent years (2005-2008) when only the catch-per-unit of effort DCP was used. The merits and generality of our HBM approach are discussed. We contend it extends previous single DCP models or inter-calibration of two DCPs, and it could be applied to a wide range of specific situations (taxon and DCPs).     

广州城郊菜地土壤磷素特征及流失风险分析

通过化学分析和土壤淋洗试验对广州城郊菜地土壤磷素特征和流失风险进行了研究和分析。结果表明.广州城郊菜地土壤全磷含量极高;与自然土壤相比较,菜园土壤无机磷比例增大、有机磷比例降低;无机磷中的AI-P、Fe-P比例增加.O-P比例降低,Ca-P比例基本一致;土壤Olsen P、Bray-1 P、Mehlich-1 P、0.01mol/L CaCl_2和H_2O提取的磷含量相当高;土壤淋洗液中溶解态磷和总磷持续保持很高的浓度,土壤磷供应强度大。菜园土壤中磷进入水体引起水体磷浓度增加,导致水体富营养化风险大;土壤磷的测定值可作为土壤磷流失风险和对水环境影响程度的评估依据。菜地应作为农业非点源磷污染的优先控制区、应通过严格控制磷肥的投入和合理施肥等控制磷的流失。     

Source identification and groundwater health risk assessment of PTEs in the stormwater runoff in an abandoned mining area

Environmental Geochemistry and Health - Xikuangshan antimony mine in Lengshuijiang, China, has been developed for many years, and stormwater runoff contains high levels of potentially toxic...     

皖南低山丘陵地区流域氮磷径流输出特征

通过对安徽南部宣城地区梅村小流域的定位监测,研究了该小流域地表径流中氮磷输出特征。结果表明:氮输出以NO-3N为主,占氮素输出总量的60%,磷输出以悬浮颗粒结合态磷(PAP)为主,占磷输出总量的92%;各类形态氮素输出量间存在极显著线性正相关关系;PAP随悬浮颗粒输出量的增加而增加,PAP与水溶性磷(DP)输出量间存在着极显著的对数关系;氮磷输出具有明显的季节性变化规律,夏季输出量最大,其次是春季,再次是秋季,冬季最少,这是由降雨量的季节性变化所引起的。而且暴雨对氮磷输出的贡献率极大,因此控制雨季土壤侵蚀是有效控制氮磷通过径流输出的最重要方式。     

Cycling of metals in desert soils: effects of Tamarix nilotica and inundation by lake water

Concentrations of Ca, Mg, K, Na, Cu, Zn, Al, Fe and Mn were measured in soils and in Tamarix nilotica from Wadi Allaqi on the shore of Lake Nasser in the Eastern Desert of Egypt. All of the elements were concentrated in the leaves of Tamarix relative to the stems and roots. Leaf:soil concentration ratios, used as an indicator of metal accumulation in the plant, showed high enrichment factors for Na (67.5), K (63.0) and Mg (35.0); of the trace elements measured, Zn had the highest enrichment factor (7.64). Comparison with other desert species suggested that Tamarix was exceptional only in the accumulation of sodium. Periodic inundation of the soil by Lake Nasser caused dilution and dispersion of the accumulated salts.     

氮肥运筹和少免耕对麦田氮素径流流失的影响

采用田间小区定位试验研究了自然降雨条件下氮肥运筹和少免耕措施对稻麦两熟农田麦季氮素径流流失特征的影响。结果表明：自然降雨后麦田耕层土壤平均水分质量分数26.34%为径流事件发生的临界土壤水分质量分数。常规施肥（T0）条件下,麦季径流水量达2185.05 m3·hm-2,径流侵蚀泥沙量达716.08 kg.hm-2,少免耕（T2）处理增加麦田径流水量达29.67%,减少径流侵蚀泥沙量达13.96%,而肥料运筹（T1）与T0处理差异不显著;就整个麦季而言,T0处理条件下,径流水全氮（TN）平均质量浓度和径流侵蚀泥沙TN平均质量分数分别为10.51 mg·L-1和1.19 g·kg-1,T1处理显著降低径流水TN质量浓度和侵蚀泥沙TN质量分数分别达11.63%和5.93%,T2处理显著降低径流侵蚀泥沙TN质量分数达7.95%;麦季氮素径流流失主要集中在小麦生育前期,包括径流水氮素流失量和径流侵蚀过程中由泥沙流失的氮素量。T0处理条件下,氮素流失总量达31.76 kg·hm-2,其中,径流水氮素流失量占麦季氮素总流失量95%以上,T1处理减少麦季氮素总流失量达9.25%,而T2处理则增加麦季氮素总流失量达16.75%。     

Bayesian predictive inference for the proportion of eroded land in a small area in Iowa

There is an increasing interest in the quality of soil, especially for small geographical areas. We present a method to estimate the percent of the area in a county or hydrological basin that is eroded. There are sample data (for several counties in eastern Iowa) from the National Resources Inventory and population data on land use, land capability class, rainfall and slope length and steepness. Using the Gibbs sampler we perform Bayesian predictive inference to obtain estimates for the non-sampled units. These estimates, together with the sample data, provide an estimate of the proportion of the total area that is eroded. We assess the quality of fit of our model using two cross-validation exercises and graphical methods.     

氮肥运筹和少免耕对麦田氮素径流流失的影响

采用田间小区定位试验研究了自然降雨条件下氮肥运筹和少免耕措施对稻麦两熟农田麦季氮素径流流失特征的影响。结果表明:自然降雨后麦田耕层土壤平均水分质量分数26.34%为径流事件发生的临界土壤水分质量分数。常规施肥(T0)条件下,麦季径流水量达2185.05 m3·hm-2,径流侵蚀泥沙量达716.08 kg.hm-2,少免耕(T2)处理增加麦田径流水量达29.67%,减少径流侵蚀泥沙量达13.96%,而肥料运筹(T1)与T0处理差异不显著;就整个麦季而言,T0处理条件下,径流水全氮(TN)平均质量浓度和径流侵蚀泥沙TN平均质量分数分别为10.51 mg·L-1和1.19 g·kg-1,T1处理显著降低径流水TN质量浓度和侵蚀泥沙TN质量分数分别达11.63%和5.93%,T2处理显著降低径流侵蚀泥沙TN质量分数达7.95%;麦季氮素径流流失主要集中在小麦生育前期,包括径流水氮素流失量和径流侵蚀过程中由泥沙流失的氮素量。T0处理条件下,氮素流失总量达31.76 kg·hm-2,其中,径流水氮素流失量占麦季氮素总流失量95%以上,T1处理减少麦季氮素总流失量达9.25%,而T2处理则增加麦季氮素总流失量达16.75%...     

Estimating preferences for outdoor recreation:: a comparison of continuous and count data demand system frameworks

Continuous and count data demand system models have emerged as attractive alternatives to the discrete choice random utility maximization models (RUMs) that currently dominate the seasonal, multi-site recreation demand literature. This paper compares the frameworks conceptually and investigates their empirical performance with a common data set. Although the two modeling approaches employ substantially different behavioral and econometric assumptions, results from a recreation application based on the 1997 Iowa Wetlands Survey suggest that qualitatively similar policy inferences arise from the competing structures.     

牧草轮作对奶牛场污水氮、磷的净化效果研究

以土壤为基质,选择象草（Pennisetum purpureum）和黑麦草（Lolium perenne）两种牧草作为植被模拟人工湿地净化系统,研究牧草全年轮作在间歇流人工湿地中对奶牛场高质量浓度污水的适应性及对污水氮、磷的净化效果。结果表明：象草、黑麦草在间歇性高质量浓度污水中生长良好,可作为畜牧场高质量浓度污水修复植物进行全年轮作,并适时的收割,去除污水中的氮、磷。在不同污水质量浓度处理的牧草净化系统中,水力停留时间为8 d的条件下,铵氮的去除率为75.9%~94.9%;硝态氮的去除率为65.4%~90.9%;总氮的去除率64.2%~90.1%;总磷的去除率在90%以上;象草和黑麦草对污水中氮、磷的吸收转化在系统对氮磷净化中的贡献率平均分别为氮25.12%和20.03%、磷31.20%和20.42%;各处理氮、磷的去除效果与污水的质量浓度呈负相关。     

Phosphorus in Phoenix: a budget and spatial representation of phosphorus in an urban ecosystem

As urban environments dominate the landscape, we need to examine how limiting nutrients such as phosphorus (P) cycle in these novel ecosystems. Sustainable management of P resources is necessary to ensure global food security and to minimize freshwater pollution. We used a spatially explicit budget to quantify the pools and fluxes of P in the Greater Phoenix Area in Arizona, USA, using the boundaries of the Central Arizona-Phoenix Long-Term Ecological Research site. Inputs were dominated by direct imports of food and fertilizer for local agriculture, while most outputs were small, including water, crops, and material destined for recycling. Internally, fluxes were dominated by transfers of food and feed from local agriculture and the recycling of human and animal excretion. Spatial correction of P dynamics across the city showed that human density and associated infrastructure, especially asphalt, dominated the distribution of P pools across the landscape. Phosphorus fluxes were dominated by agricultural production, with agricultural soils accumulating P. Human features (infrastructure, technology, and waste management decisions) and biophysical characteristics (soil properties, water fluxes, and storage) mediated P dynamics in Phoenix. P cycling was most notably affected by water management practices that conserve and recycle water, preventing the loss of waterborne P from the ecosystem. P is not intentionally managed, and as a result, changes in land use and demographics, particularly increased urbanization and declining agriculture, may lead to increased losses of P from this system. We suggest that city managers should minimize cross-boundary fluxes of P to the city. Reduced P fluxes may be accomplished through more efficient recycling of waste, therefore decreasing dependence on external nonrenewable P resources and minimizing aquatic pollution. Our spatial approach and consideration of both pools and fluxes across a heterogeneous urban ecosystem increases the utility of nutrient budgets for city managers. Our budget explicitly links processes that affect P cycling across space with the management of other resources (e.g., water). A holistic management strategy that deliberately couples the management of P and other resources should be a priority for cities in achieving urban sustainability.     

Estimating the critical phosphorus loading of shallow lakes with the ecosystem model PCLake: Sensitivity, calibration and uncertainty

There is a vast body of knowledge that eutrophication of lakes may cause algal blooms. Among lakes, shallow lakes are peculiar systems in that they typically can be in one of two contrasting (equilibrium) states that are self-stabilizing: a ‘clear’ state with submerged macrophytes or a ‘turbid’ state dominated by phytoplankton. Eutrophication may cause a switch from the clear to the turbid state, if the P loading exceeds a critical value. The ecological processes governing this switch are covered by the ecosystem model PCLake, a dynamic model of nutrient cycling and the biota in shallow lakes. Here we present an extensive analysis of the model, using a three-step procedure. (1) A sensitivity analysis revealed the key parameters for the model output. (2) These parameters were calibrated on the combined data on total phosphorus, chlorophyll-a, macrophytes cover and Secchi depth in over 40 lakes. This was done by a Bayesian procedure, giving a weight to each parameter setting based on its likelihood. (3) These weights were used for an uncertainty analysis, applied to the switchpoints (critical phosphorus loading levels) calculated by the model. The model was most sensitive to changes in water depth, P and N loading, retention time and lake size as external input factors, and to zooplankton growth rate, settling rates and maximum growth rates of phytoplankton and macrophytes as process parameters. The results for the ‘best run’ showed an acceptable agreement between model and data and classified nearly all lakes to which the model was applied correctly as either ‘clear’ (macrophyte-dominated) or ‘turbid’ (phytoplankton-dominated). The critical loading levels for a standard lake showed about a factor two uncertainty due to the variation in the posterior parameter distribution. This study calculates in one coherent analysis uncertainties in critical phosphorus loading, a parameter that is of great importance to water quality managers.     

湿地服务价值评估的复杂性及研究进展

湿地服务价值评估具有重要的理论意义和应用价值。由于湿地具有类型多样、分布广泛和过程复杂等特点,湿地服务价值评估极具复杂性。主要表现为:湿地科学是一门年轻的科学,其过程与功能研究有待深入;对生态系统服务及其价值认识上还存在分歧;湿地服务价值研究具有多学科交叉的特点等。近年来,国内外湿地服务价值评估发展很快,取得了丰硕的研究成果,但也存在着一些问题与不足,如对湿地研究成果的利用不够充分;评估理论和方法有待完善;评估标准和评估结果差异较大等。因此,今后湿地服务价值评估研究应该将重点放在理论探索和方法完善方面,对应用研究加强引导和规范。从湿地生态系统过程与功能的机理入手,认真研究和改进湿地服务价值评估的手段、方法和技术,使湿地服务价值评估结果更具说服力、可比性和实用性,为湿地的科学管理,生态补偿机制的制定以及社会经济可持续发展提供有力支持。     

洞庭湖湿地水环境变化趋势及成因分析

采用经典的Mann-Kendall非参数统计检测方法对洞庭湖湿地1991—2009年的水环境重要参数进行了变化趋势分析。结果表明,电导率、COD、BOD5、总氮、总磷、悬浮物呈显著上升趋势,色度、大肠杆菌、硝态氮、铵态氮呈不显著上升趋势,溶解氧呈显著降低趋势,pH、透明度呈不显著降低趋势。可见,洞庭湖湿地水质在逐步下降。突变趋势中,各参数突变时期及次数存在明显差别。除色度有1突变点位于显著信度线（p=0.05）与极显著信度线（p=0.01）之间,其余参数突变点均位于显著信度线之间。以色度和悬浮物突变最频繁,总氮和硝态氮变化最为平缓,其余参数居中。从各参数突变发生的时间可知,水质突变主要发生在1992—1998年。其次,对影响洞庭湖湿地水环境变化的因素进行了分析,得出＂四水＂流域及洞庭湖区工业污染、农业污染（化肥污染、农药污染、水产养殖、畜禽粪便）、生活污染等是导致水环境逐步恶化的主要原因。     

洞庭湖湿地水环境变化趋势及成因分析

采用经典的Mann-Kendall非参数统计检测方法对洞庭湖湿地1991—2009年的水环境重要参数进行了变化趋势分析。结果表明,电导率、COD、BOD5、总氮、总磷、悬浮物呈显著上升趋势,色度、大肠杆菌、硝态氮、铵态氮呈不显著上升趋势,溶解氧呈显著降低趋势,pH、透明度呈不显著降低趋势。可见,洞庭湖湿地水质在逐步下降。突变趋势中,各参数突变时期及次数存在明显差别。除色度有1突变点位于显著信度线(p=0.05)与极显著信度线(p=0.01)之间,其余参数突变点均位于显著信度线之间。以色度和悬浮物突变最频繁,总氮和硝态氮变化最为平缓,其余参数居中。从各参数突变发生的时间可知,水质突变主要发生在1992—1998年。其次,对影响洞庭湖湿地水环境变化的因素进行了分析,得出四水流域及洞庭湖区工业污染、农业污染(化肥污染、农药污染、水产养殖、畜禽粪便)、生活污染等是导致水环境逐步恶化的主要原因。