Analysis of an intermediate-temperature proton-conducting SOFC hybrid system

The performance of an intermediate-temperature proton-conducting solid oxide fuel cell (pSOFC) hybrid system is investigated in this work. The hybrid system consists of a 20-kW pSOFC, a micro gas turbine (MGT), and heat exchangers. Heat exchangers are used to recover waste heat from pSOFC and MGT. The performance of the system is analyzed by using Matlab/Simulink/Thermolib. Flow rates of air and hydrogen are controlled by assigning different stoichiometric ratio (St). St considered in this study is between 2 and 3.5 for air, and between 1.25 and 1.45 for hydrogen. Results show that the combined heat and power (CHP) efficiency increases as the fuel St decreases or air St increases. This is because lowering fuel St means fewer fuel will be wasted from the fuel cell stack, so the CHP efficiency increases. On the other hand, as air St increases, the amount of recovered waste heat increases, so does the CHP efficiency.     

Evaluation of different CHP options for refinery integration in the context of a low carbon future

This study presents a comparison of different concepts for delivering combined heat and power (CHP) to a refinery in Norway. A reference case of producing high pressure steam from natural gas in boilers and electricity in a combined cycle power plant, is compared to a: (1) natural gas fueled CHP without any CO₂ capture; (2) hydrogen fueled CHP with hydrogen produced from steam methane reforming (SMR); (3) hydrogen fueled CHP with hydrogen produced from autothermal reforming (ATR); and finally (4) natural gas fueled CHP with postcombustion CO₂ removal. The options are compared on the basis of first law efficiency, emissions of CO₂ and a simplified cash flow evaluation. Results show that in terms of efficiency the standard natural gas fueled CHP performs better than the reference case as well as the options with carbon capture. The low carbon options in turn offer lower emissions of greenhouse gases while maintaining the same efficiency as the reference case. The cash flow analysis shows that for any option, a certain mix of prices is required to produce a positive cash flow. As expected, the relationship between natural gas price and electricity price affects all options. Also the value of heat and CO₂ emissions plays an important role.     

中外沼气发展史略

产甲烷菌是一种古细菌(Archebacteria),有机物在厌氧条件下的产甲烷现象早在远古便有。而有文字记载的人类发现、认识以及研究开发并利用厌氧消化产生沼气的历史还是近两千年内的事情。本文通过大量史料、史实,从化学、生物、地质和比较历史学的角度,论证了西汉四川“火井”浅层生物生成气与沼气在形成机理上的相同性,从而提出了中国是世事上最早发现并利用沼气的国家(年代可追朔到公元前一世纪)的新观点,这一研究结果比以往中国沼气史的计算方法提早了约2000年。本文还用详尽的文字论述了中外沼气的发现、沼气实验,厌氧消化工艺研究及人工制取沼气技术的发展史。     

Global Warming Impact of Electricity Generation from Beef Cattle Manure: A Life Cycle Assessment Study

We compare calculated greenhouse gas emissions for a North American beef feedlot operation, which includes biogas production by anaerobic digestion with subsequent electricity generation (the AD case), to the emissions for a “business as usual” case, which includes both a feedlot and an equivalent amount of grid-generated electricity. Anaerobic digestion, biogas production and electricity production are the major sources of differences in emissions. Fertilizer production, crop production, manure collection and spreading, as well as the associated transport stages are also considered within the LCA system boundaries; impacts on life cycle emissions from these sources are lower. Running a feedlot and producing electricity using typical grid power plants produces 3,845 kg CO_2?eq/MWh while running a feedlot, which generates biogas to produce electricity, produces 2,965 kg CO_2?eq/MWh. This savings of 880 kg CO_2?eq/MWh arises because the net power generation in the AD case emits about 90% less life cycle GHG emissions compared to grid-average electricity. The high overall emission levels arise due to emissions associated with enteric fermentation in beef cattle as the main source of GHG emissions in both the “business as usual” and the AD cases. It contributed 57% of total emissions for the feedlot /biogas /electricity system and 44% of total emissions for the feedlot /grid electricity system.     

Lagoon-biogas emissions and carbon balance estimates of a swine production facility

Gaseous emissions from animal manure storage facilities can contribute to global greenhouse gas inventories. Biogas fluxes were measured for one year from a 2-ha anaerobic lagoon that received waste from a 10500-head swine (Sus scrofa) finishing operation in southwestern Kansas. During 2001, ebullition of biogas was measured continuously by using floating platforms equipped with gas-collection domes. Periodically, the composition of the biogas was determined by using gas chromatography. Detailed records of feed quality and quantity and animal weights and gains also were obtained to determine the carbon budget of the facility (barns and lagoon). Flux of biogas was very seasonal, with peak emission (18.7 mol m(-2) d(-1)) occurring in early June. Nearly 50% of the annual biogas losses occurred during a 30-d period beginning on day of year (DOY) 146. Flux patterns suggest that the start of the high biogas production period was governed by temperature, while the decline in production in mid-June was caused by substrate limitations. Average biogas composition was 0.71 L CH4 L(-1). The quantity of CH4 released from the lagoon was 86.3 Mg yr(-1), which represents about 38 g of CH4 per kg of animal weight gain. The average flux density of biogas from the lagoon was 382 mol m(-2) yr(-1) or 728 mol yr(-1) per resident animal where the resident animal population was 10500. Flux rates of CH4 were 1.7 to 3.4 times less than predictions made with Intergovernmental Panel on Climate Change (IPCC) models. Additional research is needed on the carbon budgets of other animal feeding operations so that better estimates of greenhouse gas emissions can be determined.     

Indicators for sustainable energy development: Brazil's case study

This article summarizes the results of the project on indicators for sustainable energy development (ISED) in Brazil. The project's aim was to present energy related economic, social and environmental data to policy makers in a coherent and consistent form, showing interlinkages, time‐series and cross‐sectoral analyses and assess energy policy. Two priority areas assessed by these indicators, regarding the country's energy supply and demand, helped in the identification of a number of energy policy options that focused on specific aspects of the country's energy sector. On the supply side, these options include the development and stimulation of renewable energy, such as small‐scale hydroelectric, wind, solar photovoltaic power and bagasse cogeneration; stimulation of programmes for ethanol use as automotive fuel and sugarcane bagasse cogeneration; and implementation of natural gas‐fired, combined heat and power (CHP) plants. On the demand side, policy options include: the full implementation of the law on efficiency standards for appliances; expansion of utility investment in end‐use energy efficiency; adoption of targets and protocols to reduce energy intensity in the industrial sector; improvement of passenger transport efficiency; and the creation of a fund to improve energy affordability for the poor.     

Development of a PEMFC-based heat and power cogeneration system

Hydrogen-fed proton exchange membrane fuel cell (PEMFC) has to overcome high installation and operation cost before being adopted as a distributed power candidate. Cogeneration of power and heat is a good approach to increase hydrogen energy utilization rate. A PEMFC-based power and heat cogeneration system is proposed and established in the current study to investigate system’s technological and economical feasibility. This cogeneration of heat and power (CHP) system composes of a 2.5-kW fuel cell stack, hydrogen supply system, air supply system, water and heat management system, and heat recovery system. The control strategies to automate the system operation are realized by a programmable automation controller (PAC) system. Detailed measurement of the system is also constructed along with a web-based human–machine interface (HMI) platform to facilitate experiments and demonstration. Preliminary testing of the CHP system shows good performance of heat and power outputs. System’s electrical power conversion efficiency and thermal efficiency of the CHP system are measured at 38% and 35%, respectively. System combined efficiency therefore reached about 73%.     

Biogas production from olive pomace

Biogas production from a slurry obtained by mixing finely ground olive pomace in water was investigated using anaerobic digesters of 1-l working volume at 37°C. A start-up culture was obtained from a local landfill area and was adopted to the slurry within 10 days at this temperature. The biogas generation rates were determined by varying the total solids (TS) concentration in the slurry and the hydraulic retention time (HRT) during semi-continuous digestion. The maximum rate was found to be 0.70 l of biogas per l of digester volume per day, corresponding to a HRT of 20 days and 10% TS with a yield of 0.08 l biogas per g chemical oxygen demand (COD) added to the digester. The methane content of the biogas was in the range of 75–80% for both batch and semi-continuous runs, the remainder being principally carbon dioxide.     

Biomass for Fuel Cells: A Technical and Economic Assessment

Fuel cells can be highly efficient energy conversion devices. However, the environmental benefit of utilising fuel cells for energy conversion is completely dependent on the source of the fuel. Hydrogen is the ideal fuel for fuel cells but the current most economical methods of producing hydrogen also result in the production of significant amounts of carbon dioxide. Utilising biomass to produce the fuel for fuel cell systems offers an option that is technically feasible, potentially economically attractive and greenhouse gas neutral. High-temperature fuel cells that are able to operate with carbon monoxide in the feed are well suited to these applications. Furthermore, because they do not require noble metal catalysts, the cost of high-temperature fuel cells has the greatest potential to become competitive in the near future compared to other types of fuel cells. It is, however, extremely difficult to assess the economic feasibility of biomass-fuelled fuel cell systems because of a lack of published cost information and uncertainty in the predicted cost per kW of the various types of fuel cells for large volume production methods. From the scant information available it appears that the current cost for fuel-cell systems operating on anaerobic digester gas is about US$2,500 per kW compared to a target price of US$1,200 required to compete with conventional technologies.     

Performance of sequential anaerobic/aerobic digestion applied to municipal sewage sludge

A promising alternative to conventional single phase processing, the use of sequential anaerobic-aerobic digestion, was extensively investigated on municipal sewage sludge from a full scale wastewater treatment plant. The objective of the work was to evaluate sequential digestion performance by testing the characteristics of the digested sludge in terms of volatile solids (VS), Chemical Oxygen Demand (COD) and nitrogen reduction, biogas production, dewaterability and the content of proteins and polysaccharides. VS removal efficiencies of 32% in the anaerobic phase and 17% in the aerobic one were obtained, and similar COD removal efficiencies (29% anaerobic and 21% aerobic) were also observed. The aerobic stage was also efficient in nitrogen removal providing a decrease of the nitrogen content in the supernatant attributable to nitrification and simultaneous denitrification. Moreover, in the aerobic phase an additional marked removal of proteins and polysaccharides produced in the anaerobic phase was achieved. The sludge dewaterability was evaluated by determining the Optimal Polymer Dose (OPD) and the Capillary Suction Time (CST) and a significant positive effect due to the aerobic stage was observed. Biogas production was close to the upper limit of the range of values reported in the literature in spite of the low anaerobic sludge retention time of 15 days. From a preliminary analysis it was found that the energy demand of the aerobic phase was significantly lower than the recovered energy in the anaerobic phase and the associated additional cost was negligible in comparison to the saving derived from the reduced amount of sludge to be disposed.     

Ignition advancement study for optimized characteristics of a raw biogas operated spark ignition engine

In the current investigation, raw biogas obtained from rural sectors was used as the alternative to gasoline fuel in the spark ignition (SI) engine. The performance and efficiency are mainly dependent on the combustion phasing for which “ignition timing” is an effective tool in a SI engine. Hence, the objective of the present work is to understand the effect of “variable ignition timing” for a biogas-fueled SI engine. For this purpose, a single cylinder, 4-stroke, SI engine of rated power 4.5 kW was operated with raw biogas at a compression ratio (CR) of 10. By maintaining a speed of 1650 rpm, the engine was operated in wide open (WOT) and part throttle (PT) mode with an equivalence ratio of 0.81 and 0.83, respectively. It was observed that the biogas fueled SI engine was found to be operative only within the ignition advance (IA) range of 33–47° CA bTDC both in WOT and PT conditions. The results showed optimal brake power (BP), brake thermal efficiency (BTE) and brake specific fuel consumption (BSFC) are achieved at 45° CA bTDC. The average peak cylinder pressure, neat heat release rate (NHRR) and mean gas temperature (MGT) are also observed to be maximum while CO and HC emission at this point of IA were found to be minimum. Due to controlled and complete combustion, CO₂ and NO_x concentration in the exhaust emission were found to be higher at this point of ignition timing.     

Biogas production from slaughterhouse wastewaters and use of biofertilizer obtained for biodegradation of aromatic hydrocarbons

The anaerobic digestion of industrial wastes produces a biogas that is an alternative to the use of fossil fuels for energy production. At the end of this process, the stabilized biomass presents high levels of nutrients, which can be used both as biofertilizers in agriculture and for the biodegradation of contaminants in the soil through improvement of the microbiota. Thus, this study aimed to evaluate biogas production by industrial wastes and to use the biofertilizer for the bioremediation of soils previously contaminated with gasoline. The biomass (420 mL) generated approximately 10 liters (L) of methane and 3 L of other gases. Anaerobic incubation reduced total and volatile solids, as well as biochemical oxygen demand, chemical oxygen demand, and the carbon and nitrogen contents of the biomass. The bioremediation experiment showed that 15 days after contamination with gasoline, the addition of the biofertilizer improved the degradation efficiency of monoaromatic hydrocarbons; however, the degradation of polyaromatic hydrocarbons was less time efficient. So, we conclude that the anaerobic incubation of industrial wastes generates a high amount of biogas, and that biofertilizer deposition into contaminated soil does not affect the efficiency of the degradation of aromatic hydrocarbons after 30 days. Novelty or significance : Anaerobic incubation of industrial wastes generates a high calorific value gas, which can be used as an alternative source of energy. And, the resulting biomass, called biofertilizer, can be used to remediate soils contaminated with hydrocarbons.     

Techno-economic analysis and environmental impact assessment of energy recovery from Municipal Solid Waste (MSW) in Brazil

Due to the lack of appropriate policies in the last decades, 60% of Brazilian cities still dump their waste in non-regulated landfills (the remaining ones dump their trash in regulated landfills), which represent a serious environmental and social problem. The key objective of this study is to compare, from a techno-economic and environmental point of view, different alternatives to the energy recovery from the Municipal Solid Waste (MSW) generated in Brazilian cities. The environmental analysis was carried out using current data collected in Betim, a 450,000 inhabitants city that currently produces 200 tonnes of MSW/day. Four scenarios were designed, whose environmental behaviour were studied applying the Life Cycle Assessment (LCA) methodology, in accordance with the ISO 14040 and ISO 14044 standards. The results show the landfill systems as the worst waste management option and that a significant environmental savings is achieved when a wasted energy recovery is done. The best option, which presented the best performance based on considered indicators, is the direct combustion of waste as fuel for electricity generation. The study also includes a techno-economical evaluation of the options, using a developed computer simulation tool. The economic indicators of an MSW energy recovery project were calculated. The selected methodology allows to calculate the energy content of the MSW and the CH₄ generated by the landfill, the costs and incomes associated with the energy recovery, the sales of electricity and carbon credits from the Clean Development Mechanism (CDM). The studies were based on urban centres of 100,000, 500,000 and 1,000,000 inhabitants, using the MSW characteristics of the metropolitan region of Belo Horizonte. Two alternatives to recovering waste energy were analyzed: a landfill that used landfill biogas to generate electricity through generator modules and a Waste-to-Energy (WtE) facility also with electricity generation. The results show that power generation projects using landfill biogas in Brazil strongly depend on the existence of a market for emissions reduction credits. The WtE plant projects, due to its high installation, Operation and Maintenance (O&M) costs, are highly dependent on MSW treatment fees. And they still rely on an increase of three times the city taxes to become attractive.     

Bioenergy production from roadside grass: A case study of the feasibility of using roadside grass for biogas production in Denmark

This paper presents a study of the feasibility of utilising roadside vegetation for biogas production in Denmark. The potential biomass yield, methane yields, and the energy balances of using roadside grass for biogas production was investigated based on spatial analysis. The results show that the potential annual yield of biomass obtainable from roadside verges varies widely depending on the local conditions. The net energy gain (NEG) from harvest, collection, transport, storage and digestion of roadside vegetation was estimated to range from 60,126–121,476 GJ, corresponding to 1.5–3.0% of the present national energy production based on biogas. The estimated values for the energy return on invested energy (EROEI) was found to range from 2.17 to 2.88. The measured contents of heavy metals in the roadside vegetation was seen not to exceed the legislative levels for what can be applied as fertilizer on agricultural land, neither does it reach levels considered as inhibitory for the anaerobic fermentation process. From a practical point of view, few challenges were identified related to the acquisition and processing of the roadside vegetation. Considering the positive net energy gains, further energy investments for management of these challenges can be made. Despite the somewhat low EROEI values, the use of this resource could however result in other positive externalities, such as improved biodiversity of the verges and recycling of nutrients.     

Biogas production from pistachio (Pistaciavera L.) de-hulling waste

Pistachio processing wastes create significant waste management problems unless properly managed. However, there are not well-established methods to manage the waste generated during the processing of pistachios. Anaerobic digestion can be an attractive option not only for the management of pistachio processing wastes but also producing renewable energy in the form of biogas. This study investigated anaerobic digestibility and biogas production potential of pistachio de-hulling waste from wet de-hulling process. Best to our knowledge, this is the first report on biogas production from pistachio de-hulling waste. The results indicated that (1) anaerobic digestion of pistachio de-hulling wastewater, solid waste, and their mixtures in different ratios is possible with varying levels of performance; (2) 1 L of de-hulling wastewater (chemical oxygen demand concentration of 30 g/L) produced 0.7 L of methane; (3) 1 L of de-hulling wastewater and 20 g of pistachio de-hulling solid waste produced 1.25 L of methane; and (4) 1 g of de-hulling solid waste produced 62.6 mL of methane (or 134 mL of biogas).     

CO2 capture from combined cycles integrated with Molten Carbonate Fuel Cells

In this paper Molten Carbonate Fuel Cells (MCFCs) are considered for their potential application in carbon dioxide separation when integrated into natural gas fired combined cycles. The MCFC performs on the anode side an electrochemical oxidation of natural gas by means of CO₃^2? ions which, as far as carbon capture is concerned, results in a twofold advantage: the cell removes CO₂ fed at the cathode to promote carbonate ion transport across the electrolyte and any dilution of the oxidized products is avoided.The MCFC can be “retrofitted” into a combined cycle, giving the opportunity to remove most of the CO₂ contained in the gas turbine exhaust gases before they enter the heat recovery steam generator (HRSG), and allowing to exploit the heat recovery steam cycle in an efficient “hybrid” fuel cell + steam turbine configuration. The carbon dioxide can be easily recovered from the cell anode exhaust after combustion with pure oxygen (supplied by an air separation unit) of the residual fuel, cooling of the combustion products in the HRSG and water separation. The resulting power cycle has the potential to keep the overall cycle electrical efficiency approximately unchanged with respect to the original combined cycle, while separating 80% of the CO₂ otherwise vented and limiting the size of the fuel cell, which contributes to about 17% of the total power output so that most of the power capacity relies on conventional low cost turbo-machinery. The calculated specific energy for CO₂ avoided is about 4 times lower than average values for conventional post-combustion capture technology. A sensitivity analysis shows that positive results hold also changing significantly a number of MCFC and plant design parameters.     

Exergy and economic analysis of organic Rankine cycle hybrid system utilizing biogas and solar energy in rural area of China

Due to the existing huge biogas resource in the rural area of China, biogas is widely used for production and living. Cogeneration system provides an opportunity to realize the balanced utilization of the renewable energy such as biogas and solar energy. This article presented a numerical investigation of a hybrid energy-driven organic Rankine cycle (ORC) cogeneration system, involving a solar ORC and a biogas boiler. The biogas boiler with a module of solar parabolic trough collectors (PTCs) is employed to provide heat source to the ORC via two distinct intermediate pressurized circuits. The cogeneration supplied the power to the air-condition in summer condition and hot water, which is heated in the condenser, in winter condition. The system performance under the subcritical pressures has been assessed according to the energy–exergy and economic analysis with the organic working fluid R123. The effects of various parameters such as the evaporation and condensation temperatures on system performance were investigated. The net power generation efficiency of the cogeneration system is 11.17%, which is 25.8% higher than that of the base system at an evaporation temperature 110°C. The exergy efficiency of ORC system increases from 35.2% to 38.2%. Moreover, an economic analysis of the system is carried out. The results demonstrate that the profits generated from the reduction of biogas fuel and electricity consumption can lead to a significant saving, resulting in an approximate annual saving from $1,700 to $3,000. Finally, a case study based on the consideration of typical rural residence was performed, which needs a payback period of 7.8 years under the best case.     

Performance of a combined anaerobic reactor for municipal wastewater treatment at ambient temperature

A bench-scale experimental study was carried out to investigate the overall performance of a combined anaerobic reactor for treating pre-settled municipal wastewater at ambient temperature (18–28°C) in terms of substrate removal efficiencies, biogas, methane production, volatile fatty acid (VFA) profiles and effluent suspended solids (SS) concentration, etc. The tested reactor was a modified anaerobic baffled reactor (ABR). The second and third compartments were partly packed with supporting media. The experimental results were similar to, or compared favourably with, other anaerobic reactor systems for municipal wastewater treatment at ambient temperature and proved the technical feasibility of this compartmentalised reactor. Considering its simple structure and operation, it could be considered a potential reactor system for treating municipal and domestic wastewaters in tropical and sub-tropical areas of developing countries.     

Electric power and the environment: an analysis of pollutant emissions at Argentine state-owned electric power stations

This paper describes the impact on particulate and 'greenhouse gases' emissions of substitution policies implemented by Argentine state-owned electric power stations. Those policies involve the substitution, on the one hand, of hydroelectric and nuclear energy for conventional thermal energy and, on the other hand, of natural gas for fuel oil, diesel oil and coal. As additional investments are required in conventional thermal power stations to prevent environmental pollution, the investment savings generated by substitution policies have been calculated. While the environmental impact of hydroelectric, nuclear and natural gas facilities is locally significant and is experienced in geographical areas away from cities, there can be no doubt that the substitution policies implemented in the Argentine electricity sector have overall both ecological and economic benefits.     

Energy,exergy analysis,and sustainability assessment of different engine powers for helicopter engines

The rapid decrease of energy resources has accelerated studies on energy efficiency. Energy efficiency refers to the effective use of energy, in other words, completing a specific task to the required standard by using less energy. Exergy is an effective instrument to indicate the effective and sustainable use of energy in systems and processes. Transportation is an important part of human life. The studies on energy saving and the effective use of energy in different areas around the world have also increased for transportation systems and vehicles. With the more effective use of fuel, there will be potential benefits for the environment as well as a reduction in operating costs. This study includes energy and exergy analyses as well as a sustainability assessment by using C₈H₁₆ as a fuel at different engine powers (150–600 SHP (shaft horse power)), for the piston-prop helicopter engine. The maximum exergetic sustainability index was found at the power that provided the maximum energy and exergy efficiency. As a result of this index, the lowest waste exergy ratio, the lowest exergy destruction factor, and the lowest environmental impact factor were obtained. The highest exergy destruction and the highest exergy loss value were obtained at maximum power (600 SHP).