长江危险品运输风险下的分类管理方法研究

分析了危险品分类管理的现状及不足。在此基础上,研究了长江危险品运输的分类方法,并提出危险品分类管理的步骤,针对该方法在长江危险品运输的分类管理进行了实践。在危险品运输分类管理的基础上,提出了分类风险管理措施,以提高危险品运输的安全监管能力,改善长江危险品运输的安全监管结构,实现长江危险品运输的安全。     

建筑安全风险因素分级排序的风险矩阵法

为减少风险分级排序时产生的风险结,在引入施工安全事故频率的基础上,采用单元格细化和Borda序值法改进原有的风险矩阵法。改进后的方法使得风险等级数量增加,风险结数量减少。将该方法应用于脚手架工程的风险因素的分级与排序,风险等级分为6级,且实现了12个因素的明确排序。     

基于风险管理方法的危险源评价分级研究

以化工企业内涉及危险物质的装置、设施而构成的危险源为研究对象,在简要分析重大危险源评价分级的作用与方法的基础上,针对中小型化工企业,提出基于风险管理方法的危险源评价分级概念。通过计算危险源引发事故的概率和事故后果来确定危险源的风险值,并将其分为4个等级,指导企业制定合适的安全管理制度、使用恰当的安全技术措施,以最小化的代价确保危险源安全运行,从而提高中小型化工企业的危险源管理水平。     

基于事故发展与控制的隐患分级方法

为使隐患管理工作更加科学,对隐患与事故的关系进行研讨,提出隐患的根本属性是能够促使事故发生或发展。通过预估促使和控制(阻碍)事故发展的因素,来揭示隐患在事故过程中的作用机制。根据发生作用的时间将隐患分为第1类隐患和第2类隐患。在风险评估过程中,解决了具体隐患风险分级的问题,提出隐患暴露频率、其他条件的可能性、隐患纠正系数、事故后果初始分值、人员防护修正系数、人员暴露修正系数、应急处理与事故控制修正系数和财产损失修正系数等评价指标。通过隐患致因事故风险的计算,评估隐患的最终风险。     

Absorption kinetics of NO from simulated flue gas using Fe(II)EDTA solutions

The absorption of NO encountering flue gases in aqueous solutions of Fe(II)EDTA was determined using a semi-batch stirred tank with a plane gas–liquid interface at 50 °C. The concentrations of NO, SO₂ and O₂ in the feeding stream were 300–800 ppm, 500–2200 ppm and 0–20%, respectively. The pH value of the Fe(II)EDTA solutions varied from 3 to 11. The concentrations of Fe(II)EDTA were maintained between 0.01 and 0.05 M. Experiments were performed to evaluate the effect of operating parameters on the NO absorption rate, the reaction kinetics of the reactants in gas and liquid phases, and the effect of competition between various reactants on the mass transfer rate in the NO removal system. Results indicate that the average reaction rate constant is 3.70 × 10⁷ M⁻¹ s⁻¹. Adding NaOH does not increase the absorption capability of Fe(II)EDTA. The presence of O₂ decreases the NO absorption rate with Fe(II)EDTA. The absorption rate of NO with Fe(II)EDTA decreases at low concentrations of SO₂, but increases at high concentrations.     

The BG Measurement System for Hazardous Substances (BGMG) and the Exposure Database of Hazardous Substances (MEGA)

German employers ‘ liability insurance associations or Berufsgenossenschaften (BGs)—institutions for statutoryaccident insurance—maintain a measurement system for hazardous substances, the so-called BGMG. The aimof the BGMG is to determine and document valid results of measurements of exposure primarily for preventionpurposes. The data are collected systematically, in parallel to the sampling in a company. Parameters which aresupposed to have a visible effect on exposure levels are documented. The MEGA database (documentation ofmeasurement data relating to workplace exposure to hazardous substances) holds 1,629 million measurementvalues, which have been compiled in since 1972. The database offers a host of selection possibilities forassessments depending on the evaluation strategy.     

基于多层次灰色评价理论的海洋输油管道安全评估方法

针对海上输油管道在多层次、多变量、多种非定量因素的影响下缺乏有效定量评估手段的情况,建立输油管道体系的多层次安全评估指标,结合层次分析法,确定各层指标对应的权重,提出采用多层次灰色理论,对输油管道体系进行安全评估,将风险影响程度进行定量化处理,给出了在役输油管道的可靠性量化结果。多层次灰色评估方法针对少数据、小样本、信息不完全和经验缺乏的不确定性问题有着计算简便、直接、科学和实用的特点,可为海上输油管道的在役安全评估提供一种有效手段。     

Kinetic and 2D reactor modeling for simulation of the catalytic reduction of NOx in the monolith honeycomb reactor

Emission of NO_x is of primary environmental concern in the oil sands industry. Selective catalytic reduction (SCR) is one of the best NO_x reduction technologies. The present study discusses the testing of a mechanistic kinetic model for the SCR of NO_x to describe the kinetics of V₂O₅/TiO₂ catalysis at atmospheric pressure and a temperature of 623 K in a monolith honeycomb reactor. The modeling results impart insight into the significance of the diffusion with reaction steps and guidance for optimal monolith design for SCR. The validated expression would predict the conversion performance of the catalysts for different values of temperature inlet and ammonia concentration. A good agreement between experimental and model results has been obtained. A heterogeneous numerical model consisting of coupled mass and momentum balance equations was solved using the finite elements method without neglecting the axial dispersion term. The operating range for the catalyst relies on the NO conversion and emission. The optimum operating range for the best performance of the reactor is discussed.     

基于文本挖掘的管制运行风险主题分析*

为充分挖掘管制运行风险信息和隐藏规律,实现数据驱动的风险管理。以某管制单位2004—2019年共269条管制原因不安全事件数据为挖掘语料,在考虑上下文语义的基础上,运用潜在狄利克雷分配（LDA）主题模型挖掘管制运行风险主题及关键词,使用Word2Vec挖掘主题之间、关键词之间的关联关系,运用社会网络分析软件UCINET、可视化工具NETDRAW构建语义网络将关联关系进行可视化并进行网络分析。结果表明:LDA主题模型可以通过运行数据实现对管制运行风险的高效提取和深层挖掘,挖掘到管制人为因素、特情处置、地空配合、班组资源管理、组织管理、运行环境、管制指挥共7个主题,其中管制人为因素主题是核心主题,与其他主题都具有较强的相互关联;Word2Vec和语义网络相结合能够更准确地挖掘风险之间的关系,确定主题的重要度排序,识别关键风险。     

General Evaluation of Risk Associated With the Use of Pesticides and Other Chemical Substances on Animal Breeding and Plant Production Farms

Abstract

A general characteristic of chemical risk on plant production farms in Poland is presented. The paper describes risk associated with the natural occurrence of chemical substances (such as ammonium and hydrogen sulfide) in the process of animai breeding and risk connected with the use of artificial fertilizers and pesticides. Pesticides are briefly described taking into consideration toxicity classes and the toxic effect of individual compounds. Exposure to pesticides is presented for individual methods and related activities. Finally, the author discusses pesticide risk on fruit-growing farms and in greenhouses.     

A method for simulation of vapour cloud explosions based on computational fluid dynamics (CFD)

The effectiveness of the application of CFD to vapour cloud explosion (VCE) modelling depends on the accuracy with which geometrical details of the obstacles likely to be encountered by the vapour cloud are represented and the correctness with which turbulence is predicted. This is because the severity of a VCE strongly depends on the types of obstacles encountered by the cloud undergoing combustion; the turbulence generated by the obstacles influences flame speed and feeds the process of explosion through enhanced mixing of fuel and oxidant. In this paper a CFD-based method is proposed on the basis of the author’s finding that among the various models available for assessing turbulence, the realizable k-? model yields results closer to experimental findings than the other, more frequently used, turbulence models if used in conjunction with the eddy-dissipation model. The applicability of the method has been demonstrated in simulating the dispersion and ignition of a typical vapour cloud formed as a result of a spill from a liquid petroleum gas (LPG) tank situated in a refinery. The simulation made it possible to assess the overpressures resulting from the combustion of the flammable vapour cloud. The phenomenon of flame acceleration, which is a characteristic of combustion enhanced in the presence of obstacles, was clearly observed. Comparison of the results with an oft-used commercial software reveals that the present CFD-based method achieves a more realistic simulation of the VCE phenomena.     

趋势面拟合法在煤矿瓦斯地质变量预测中的应用研究

从瓦斯地质学的观点出发,将反映煤层瓦斯基本参数的空间变化规律看做是与其赋存地质条件密切相关的连续函数。结合趋势面拟合及其模型优化的原理和方法分析得出了淮北矿业集团公司芦岭煤矿井田范围内瓦斯含量的变化及分布与其位置坐标的对应数值关系,依据该数值关系可对矿井深部采场和未开采区域实施比较准确、可靠的定量瓦斯预测。该方法也适用于其他具有相似特征的瓦斯地质变量分析。     

脱硫脱硝用煤质颗粒活性炭及试验方法国家标准解读

本文介绍了GB/T 30201-2013《脱硫脱硝用煤质颗粒活性炭》及GB/T 30202.1--5-2013《脱硫脱硝用煤质颗粒活性炭试验方法》的编制背景、主要内容、试验验证情况等,本系列标准于2014年发布实施,它对规范我国脱硫脱硝用煤质颗粒活性炭的科研、生产、应用以及推动干法脱硫脱硝减少二氧化硫、氮氧化物的排放将起到重要作用。     

纺织品隔声性能的测试研究

本文提出了纺织品隔声性能的测试方法和评价指标,探讨了织物结构参数对隔声性能的影响。织物平方米重对声波衰减率的影响大于覆盖系数和厚度。织物对声波的衰减作用具有频率选择性。     

饮用水中卤乙腈(HANs)类消毒副产物研究现状与进展

对国内外饮用水中HANs类消毒副产物检测方法、生成的影响因素及毒理学试验的研究进展与现状进行了调查和分析,探讨了其存在于饮用水中可能导致的人体健康危害。结果表明,饮用水中HANs类消毒副产物普遍存在,而且HANs消毒副产物比常规消毒副产物(三卤甲烷、卤乙酸等)具有更强的三致效应、生殖发育毒性、基因和细胞毒性,通过饮水摄入人体,对健康造成潜在危害。HANs的检测、人体健康风险评价和控制是今后的研究重点。     

空中交通管制雷达管制训练分类考核方法研究

分析当前我国管制员雷达培训考核环节中存在的问题,提出一种新的雷达管制培训的考核方法——检查单式考核,根据管制过程所涉及的各个环节以及航空器在空中的运行状态,对雷达管制培训实施分类考核。并结合一个进近雷达管制考核表的实例,分析其检查单式考核表的设计思想,详细说明其考核表记录和考核结果量化的步骤和方法。     

安全帽阻燃性能测试方法研究与探讨

本文采用GB/T2812-2006《安全帽测试方法》提供的方法对安全帽的阻燃性能进行了测试,测试结果表明,采用该方法,同一顶安全帽得到了两种不同的实验结果:一种实验结果为"合格",另一种实验结果为"不合格"。进而研究发现,标准仅对火焰的长度和颜色作了简单的要求,并未对燃气压力、火焰温度等作出明确的要求,从而导致同一顶安全帽有两种不同的实验结果。建议在以后的标准修订中,对试验用气体的纯度和实验时气体的压力有所要求,从而确保测试结果的唯一性和可重复性。     

The method for leakage detection of urban natural gas pipeline based on the improved ITA and ALO

To solve the problems of the difficulty in early leakage monitoring and larger positioning error for urban hazardous chemicals pipelines, the optimized method based on the improved Inverse Transient Analysis (ITA) and Ant Lion Optimizer (ALO) was proposed. Firstly, based on the obtained experiment's results of leakage of natural gas in the non-metallic pipeline, the segment classification method was incorporated into the pressure gradient calculation. The modified method can adapt to the multi-node characteristics of urban pipe networks and help to obtain the preliminary positioning calculation results after optimization. Then the calculation results were embedded in the ITA calculation model. The input parameters of the gas pipeline such as boundary conditions, leakage rate and friction coefficient were used to establish the characteristic linear equations. Then the objective function of the least-squares criterion was defined, and the improved ITA model suitable for leakage detection of urban natural gas pipeline networks was constructed. Finally, the ALO was used to optimize the calculation process of the improved ITA model, and iteratively optimize the optimal friction coefficient and its corresponding minimum objective function (OF) value. As a result, a more precise location of the leakage source was calculated. The validation of the modified method is conducted by comparing the calculated values with the experiment's results. The results show that the method can accurately predict the location where the pipeline leakage occurs. The minimum error is 3.17%. Compared with the traditional ITA, this method not only accelerates the convergence speed of the objective function, but also improves the accuracy of location calculation.     

制冷剂二氟甲烷热解生成氟化氢的实验研究

空调制冷剂二氟甲烷(R32)是R22的替代制冷剂之一,其分子中含有氟元素,受热可产生剧毒物质氟化氢(HF),一旦泄漏分解,将会对人员造成极大危害.首次通过实验研究了R32泄漏后的受热分解情况,利用激光气体分析仪,测量了不同工况下HF的实时浓度,分析了R32受热分解的影响因素.结果表明R32泄漏后,在受热状态下很容易产生HF,HF浓度随着泄漏量和受热状态的变化而异,浓度可达1000ppm以上;研究结果可为含氟制冷剂的应用提供技术支持.