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1.
2.
We sketch four possible pathways how carbon dioxide capture and storage (CCS) (r)evolution may occur in the Netherlands, after which the implications in terms of CO2 stored and avoided, costs and infrastructural requirements are quantified. CCS may play a significant role in decarbonising the Dutch energy and industrial sector, which currently emits nearly 100 Mt CO2/year. We found that 15 Mt CO2 could be avoided annually by 2020, provided some of the larger gas fields that become available the coming decade could be used for CO2 storage. Halfway this century, the mitigation potential of CCS in the power sector, industry and transport fuel production is estimated at maximally 80–110 Mt CO2/year, of which 60–80 Mt CO2/year may be avoided at costs between 15 and 40 €/t CO2, including transport and storage. Avoiding 30–60 Mt CO2/year by means of CCS is considered realistic given the storage potential represented by Dutch gas fields, although it requires planning to assure that domestic storage capacity could be used for CO2 storage. In an aggressive climate policy, avoiding another 50 Mt CO2/year may be possible provided that nearly all capture opportunities that occur are taken. Storing such large amounts of CO2 would only be possible if the Groningen gas field or large reservoirs in the British or Norwegian part of the North Sea will become available.  相似文献   

3.
By analyzing how the largest CO2 emitting electricity-generating region in the United States, the East Central Area Reliability Coordination Agreement (ECAR), responds to hypothetical constraints on greenhouse gas emissions, the authors demonstrate that there is an enduring role for post-combustion CO2 capture technologies. The utilization of pulverized coal generation with carbon dioxide capture and storage (PC + CCS) technologies is particularly significant in a world where there is uncertainty about the future evolution of climate policy and in particular uncertainty about the rate at which the climate policy will become more stringent. The paper's analysis shows that within this one large, heavily coal-dominated electricity-generating region, as much as 20–40 GW of PC + CCS could be operating before the middle of this century. Depending upon the state of PC + CCS technology development and the evolution of future climate policy, the analysis shows that these CCS systems could be mated to either pre-existing PC units or PC units that are currently under construction, announced and planned units, as well as PC units that could continue to be built for a number of decades even in the face of a climate policy. In nearly all the cases analyzed here, these PC + CCS generation units are in addition to a much larger deployment of CCS-enabled coal-fueled integrated gasification combined cycle (IGCC) power plants. The analysis presented here shows that the combined deployment of PC + CCS and IGCC + CCS units within this one region of the U.S. could result in the potential capture and storage of between 3.2 and 4.9 Gt of CO2 before the middle of this century in the region's deep geologic storage formations.  相似文献   

4.
Industrial Combined Heat and Power plants (CHPs) are often operated at partial load conditions. If CO2 is captured from a CHP, additional energy requirements can be fully or partly met by increasing the load. Load increase improves plant efficiency and, consequently, part of the additional energy consumption would be offset. If this advantage is large enough, industrial CHPs may become an attractive option for CO2 capture and storage CCS. We therefore investigated the techno-economic performance of post-combustion CO2 capture from small-to-medium-scale (50–200 MWe maximum electrical capacity) industrial Natural Gas Combined Cycle- (NGCC-) CHPs in comparison with large-scale (400 MWe) NGCCs in the short term (2010) and the mid-term future (2020–2025). The analyzed system encompasses NGCC, CO2 capture, compression, and branch CO2 pipeline.The technical results showed that CO2 capture energy requirement for industrial NGCC-CHPs is significantly lower than that for 400 MWe NGCCs: up to 16% in the short term and up to 12% in the mid-term future. The economic results showed that at low heat-to-power ratio operations, CO2 capture from industrial NGCC-CHPs at 100 MWe in the short term (41–44 €/tCO2 avoided) and 200 MWe in the mid-term future (33–36 €/tCO2 avoided) may compete with 400 MWe NGCCs (46–50 €/tCO2 avoided short term, 30–35 €/tCO2 avoided mid-term).  相似文献   

5.
This paper summarizes the results of a first-of-its-kind holistic, integrated economic analysis of the potential role of carbon dioxide (CO2) capture and storage (CCS) technologies across the regional segments of the United States (U.S.) electric power sector, over the time frame 2005–2045, in response to two hypothetical emissions control policies analyzed against two potential energy supply futures that include updated and substantially higher projected prices for natural gas. This paper's detailed analysis is made possible by combining two specialized models developed at Battelle: the Battelle CO2-GIS to determine the regional capacity and cost of CO2 transport and geologic storage; and the Battelle Carbon Management Electricity Model, an electric system optimal capacity expansion and dispatch model, to examine the investment and operation of electric power technologies with CCS against the background of other options. A key feature of this paper's analysis is an attempt to explicitly model the inherent heterogeneities that exist in both the nation's current and future electricity generation infrastructure and in its candidate deep geologic CO2 storage formations. Overall, between 180 and 580 gigawatts (GW) of coal-fired integrated gasification combined cycle with CCS (IGCC + CCS) capacity is built by 2045 in these four scenarios, requiring between 12 and 41 gigatonnes of CO2 (GtCO2) storage in regional deep geologic reservoirs across the U.S. Nearly all of this CO2 is from new IGCC + CCS systems, which start to deploy after 2025. Relatively little IGCC + CCS capacity is built before that time, primarily under unique niche opportunities. For the most part, CO2 emissions prices will likely need to be sustained at over $20/tonne CO2 before CCS begins to deploy on a large scale within the electric power sector. Within these broad national trends, a highly nuanced picture of CCS deployment across the U.S. emerges. Across the four scenarios studied here, power plant builders and operators within some North American Electric Reliability Council (NERC) regions do not employ any CCS while other regions build more than 100 GW of CCS-enabled generation capacity. One region sees as much as 50% of its geologic CO2 storage reservoirs’ total theoretical capacity consumed by 2045, while most of the regions still have more than 90% of their potential storage capacity available to meet storage needs in the second half of the century and beyond. A detailed presentation of the results for power plant builds and operation in two key regions: ECAR in the Midwest and ERCOT in Texas, provides further insight into the diverse set of economic decisions that generate the national and aggregate regional results.  相似文献   

6.
This paper explores the integration and evaluation of a power plant with a CaO-based CO2 capture system. There is a great amount of recoverable heat in the CaO-based CO2 capture process. Five cases for the possible integration of a 600 MW power plant with CaO-based CO2 capture process are considered in this paper. When the system is configured so that recovered heat is used to replace part of the boiler heat load (Case 2), modelling not only shows that this is the system recovering the most heat of 1008.8 MW but also results in the system with the lowest net power output of 446 MW and the second lowest of efficiency of 34.1%. It is indicated that system performance depends both on the amount of heat recovery and the type of heat utilization. When the system is configured so that a 400 MW power plant is built using the recovered heat (Case 4), modelling shows that this is the system with the most net power output of 846 MW, the highest efficiency of 36.8%, the lowest cost of electricity of 54.3 €/MWh and the lowest cost of CO2 avoided of 28.9 €/tCO2. This new built steam cycle will not affect the operation of the reference plant which vents its CO2 to the atmosphere, highly reducing the connection between the CO2 capture process and the reference plant which vents its CO2 to the atmosphere. The average cost of electricity and the cost of CO2 avoided of the five cases are about 58.9 €/kWh and 35.9 €/tCO2, respectively.  相似文献   

7.
Methodology is presented for a first-order regional-scale estimation of CO2 storage capacity in coals under sub-critical conditions, which is subsequently applied to Cretaceous-Tertiary coal beds in Alberta, Canada. Regions suitable for CO2 storage have been defined on the basis of groundwater depth and CO2 phase at in situ conditions. The theoretical CO2 storage capacity was estimated on the basis of CO2 adsorption isotherms measured on coal samples, and it varies between ∼20 kt CO2/km2 and 1260 kt CO2/km2, for a total of approximately 20 Gt CO2. This represents the theoretical storage capacity limit that would be attained if there would be no other gases present in the coals or they would be 100% replaced by CO2, and if all the coals will be accessed by CO2. A recovery factor of less than 100% and a completion factor less than 50% reduce the theoretical storage capacity to an effective storage capacity of only 6.4 Gt CO2. Not all the effective CO2 storage capacity will be utilized because it is uneconomic to build the necessary infrastructure for areas with low storage capacity per unit surface. Assuming that the economic threshold to develop the necessary infrastructure is 200 kt CO2/km2, then the CO2 storage capacity in coal beds in Alberta is greatly reduced further to a practical capacity of only ∼800 Mt CO2.  相似文献   

8.
Desires to enhance the energy security of the United States have spurred renewed interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3 MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000 and 7000 MtCO2, in addition to storing potentially 900–5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000–5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000–22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result in an accelerated rate of utilization of the nation's CO2 storage resource, leaving less high-quality storage capacity for other carbon-producing industries including electric power generation.  相似文献   

9.
While the demand for reduction in CO2 emission is increasing, the cost of the CO2 capture processes remains a limiting factor for large-scale application. Reducing the cost of the capture system by improving the process and the solvent used must have a priority in order to apply this technology in the future. In this paper, a definition of the economic baseline for post-combustion CO2 capture from 600 MWe bituminous coal-fired power plant is described. The baseline capture process is based on 30% (by weight) aqueous solution of monoethanolamine (MEA). A process model has been developed previously using the Aspen Plus simulation programme where the baseline CO2-removal has been chosen to be 90%. The results from the process modelling have provided the required input data to the economic modelling. Depending on the baseline technical and economical results, an economical parameter study for a CO2 capture process based on absorption/desorption with MEA solutions was performed.Major capture cost reductions can be realized by optimizing the lean solvent loading, the amine solvent concentration, as well as the stripper operating pressure. A minimum CO2 avoided cost of € 33 tonne−1 CO2 was found for a lean solvent loading of 0.3 mol CO2/mol MEA, using a 40 wt.% MEA solution and a stripper operating pressure of 210 kPa. At these conditions 3.0 GJ/tonne CO2 of thermal energy was used for the solvent regeneration. This translates to a € 22 MWh−1 increase in the cost of electricity, compared to € 31.4 MWh−1 for the power plant without capture.  相似文献   

10.
Hybrid life cycle assessment has been used to assess the environmental impacts of natural gas combined cycle (NGCC) electricity generation with carbon dioxide capture and storage (CCS). The CCS chain modeled in this study consists of carbon dioxide (CO2) capture from flue gas using monoethanolamine (MEA), pipeline transport and storage in a saline aquifer.Results show that the sequestration of 90% CO2 from the flue gas results in avoiding 70% of CO2 emissions to the atmosphere per kWh and reduces global warming potential (GWP) by 64%. Calculation of other environmental impacts shows the trade-offs: an increase of 43% in acidification, 35% in eutrophication, and 120–170% in various toxicity impacts. Given the assumptions employed in this analysis, emissions of MEA and formaldehyde during capture process and generation of reclaimer wastes contributes to various toxicity potentials and cause many-fold increase in the on-site direct freshwater ecotoxicity and terrestrial ecotoxicity impacts. NOx from fuel combustion is still the dominant contributor to most direct impacts, other than toxicity potentials and GWP. It is found that the direct emission of MEA contribute little to human toxicity (HT < 1%), however it makes 16% of terrestrial ecotoxicity impact. Hazardous reclaimer waste causes significant freshwater and marine ecotoxicity impacts. Most increases in impact are due to increased fuel requirements or increased investments and operating inputs.The reductions in GWP range from 58% to 68% for the worst-case to best-case CCS system. Acidification, eutrophication and toxicity potentials show an even large range of variation in the sensitivity analysis. Decreases in energy use and solvent degradation will significantly reduce the impact in all categories.  相似文献   

11.
The experience from CO2 injection at pilot projects (Frio, Ketzin, Nagaoka, US Regional Partnerships) and existing commercial operations (Sleipner, Snøhvit, In Salah, acid-gas injection) demonstrates that CO2 geological storage in saline aquifers is technologically feasible. Monitoring and verification technologies have been tested and demonstrated to detect and track the CO2 plume in different subsurface geological environments. By the end of 2008, approximately 20 Mt of CO2 had been successfully injected into saline aquifers by existing operations. Currently, the highest injection rate and total storage volume for a single storage operation are approximately 1 Mt CO2/year and 25 Mt, respectively. If carbon capture and storage (CCS) is to be an effective option for decreasing greenhouse gas emissions, commercial-scale storage operations will require orders of magnitude larger storage capacity than accessed by the existing sites. As a result, new demonstration projects will need to develop and test injection strategies that consider multiple injection wells and the optimisation of the usage of storage space. To accelerate large-scale CCS deployment, demonstration projects should be selected that can be readily employed for commercial use; i.e. projects that fully integrate the capture, transport and storage processes at an industrial emissions source.  相似文献   

12.
Qualitative proposals to control atmospheric CO2 concentrations by spreading crushed olivine rock along the Earth's coastlines, thereby accelerating weathering reactions, are presently attracting considerable attention. This paper provides a critical evaluation of the concept, demonstrating quantitatively whether or not it can contribute significantly to CO2 sequestration. The feasibility of the concept depends on the rate of olivine dissolution, the sequestration capacity of the dominant reaction, and its CO2 footprint. Kinetics calculations show that offsetting 30% of worldwide 1990 CO2 emissions by beach weathering means distributing of 5.0 Gt of olivine per year. For mean seawater temperatures of 15–25 °C, olivine sand (300 μm grain size) takes 700–2100 years to reach the necessary steady state sequestration rate and is therefore of little practical value. To obtain useful, steady state CO2 uptake rates within 15–20 years requires grain sizes <10 μm. However, the preparation and movement of the required material poses major economic, infrastructural and public health questions. We conclude that coastal spreading of olivine is not a viable method of CO2 sequestration on the scale needed. The method certainly cannot replace CCS technologies as a means of controlling atmospheric CO2 concentrations.  相似文献   

13.
Plug-in hybrid electric vehicles (PHEVs) have the potential to be an economic means of reducing direct (or tailpipe) carbon dioxide (CO2) emissions from the transportation sector. However, without a climate policy that places a limit on CO2 emissions from the electric generation sector, the net impact of widespread deployment of PHEVs on overall U.S. CO2 emissions is not as clear. A comprehensive analysis must consider jointly the transportation and electricity sectors, along with feedbacks to the rest of the energy system. In this paper, we use the Pacific Northwest National Laboratory's MiniCAM model to perform an integrated economic analysis of the penetration of PHEVs and the resulting impact on total U.S. CO2 emissions. In MiniCAM, the deployment of PHEVs (or any technology) is determined based on its relative economics compared to all other methods of providing fuels and energy carriers to serve passenger transportation demands. Under the assumptions used in this analysis where PHEVs obtain 50–60% of the market for passenger automobiles and light-duty trucks, the ability to deploy PHEVs under the two climate policies modelled here results in over 400 million tons (MT) CO2 per year of additional cost-effective emissions reductions from the U.S. economy by 2050. In addition to investments in nuclear and renewables, one of the key technology options for mitigating emissions in the electric sector is CO2 capture and storage (CCS). The additional demand for geologic CO2 storage created by the introduction of the PHEVs is relatively modest: approximately equal to the cumulative geologic CO2 storage demanded by two to three large 1000 megawatt (MW) coal-fired power plants using CCS over a 50-year period. The introduction of PHEVs into the U.S. transportation sector, coupled with climate policies such as those examined here, could also reduce U.S. demand for oil by 20–30% by 2050 compared to today's levels.  相似文献   

14.
15.
The purpose of this article is to study the energy and carbon dioxide intensities of Thailand's steel industry and to propose greenhouse gas emission trends from the year 2011 to 2050 under plausible scenarios. The amount of CO2 emission from iron and steel production was calculated using the 2006 Intergovernmental Panel on Climate Change (IPCC) guidelines in the boundary of production process (gate to gate). The results showed that energy intensity of semi-finished steel product was 2.84 GJ/t semi-finished steel and CO2 intensity was 0.37 tCO2eq/t semi-finished steel. Energy intensity of steel finishing process was 1.86 GJ/t finished steel and CO2 intensity was 0.16 tCO2eq/t finished steel. Using three plausible scenarios from Thailand's steel industry, S1: without integrated steel plant (baseline scenario), S2: with a traditional integrated BF–BOF route and S3: with an alternative integrated DR-EAF route; the Greenhouse Gas emissions from the year 2011 to 2050 were projected. In 2050, the CO2 emission from S1 (baseline scenario) was 4.84 million tonnes, S2 was 21.96 million tonnes increasing 4.54 times from baseline scenario. The CO2 emission from S3 was 7.12 million tonnes increasing 1.47 times from baseline scenario.  相似文献   

16.
Basic research on the corrosive effect of flue gases has been performed at the BAM Federal Institute for Materials Research and Testing (Germany). Conditions at both high and low temperatures were simulated in specially designed experiments. Carburization occured in flue gases with high CO2 content and temperatures higher than 500 °C. In SO2 containing flue gases sulphur was detected in the oxide scale. At lower temperatures no corrosion was observed when gases with low humidity were investigated. Humidity higher than 1500 ppm was corrosive and all steels with Cr contents lower than 12% revealed corroded surfaces. At low temperatures below 10 °C a mixture of sulphuric and nitric acid condensed on metal surfaces. Acid condensation caused severe corrosion. Humidity, CO2, O2, and SO2 contents are the important factors determining corrosion. Below 300 °C acid condensation is the primary reason for corrosion. Low humidity and low temperatures are conditions which can be expected in the CO2 separation and treatment process. This work includes major conditions of the flue gas and CO2 stream in CCS plants and CCS technology.  相似文献   

17.
Capture and storage of CO2 from fossil fuel fired power plants is drawing increasing interest as a potential method for the control of greenhouse gas emissions. An optimization and technical parameter study for a CO2 capture process from flue gas of a 600 MWe bituminous coal fired power plant, based on absorption/desorption process with MEA solutions, using ASPEN Plus with the RADFRAC subroutine, was performed. This optimization aimed to reduce the energy requirement for solvent regeneration, by investigating the effects of CO2 removal percentage, MEA concentration, lean solvent loading, stripper operating pressure and lean solvent temperature.Major energy savings can be realized by optimizing the lean solvent loading, the amine solvent concentration as well as the stripper operating pressure. A minimum thermal energy requirement was found at a lean MEA loading of 0.3, using a 40 wt.% MEA solution and a stripper operating pressure of 210 kPa, resulting in a thermal energy requirement of 3.0 GJ/ton CO2, which is 23% lower than the base case of 3.9 GJ/ton CO2. Although the solvent process conditions might not be realisable for MEA due to constraints imposed by corrosion and solvent degradation, the results show that a parametric study will point towards possibilities for process optimisation.  相似文献   

18.
Large-scale, dedicated commercial biomass energy systems are a potentially large contributor to meeting global climate policy targets by the end of the century. We use an integrated assessment model of energy and agriculture systems to show that, given a climate policy in which terrestrial carbon is appropriately valued equally with carbon emitted from the energy system, biomass energy has the potential to be a major component of achieving these low concentration targets. A key aspect of the research presented here is that the costs of processing and transporting biomass energy at much larger scales than current experience are explicitly incorporated into the modeling. From the scenario results, 120–160 EJ/year of biomass energy is produced globally by midcentury and 200–250 EJ/year by the end of this century. In the first half of the century, much of this biomass is from agricultural and forest residues, but after 2050 dedicated cellulosic biomass crops become the majority source, along with growing utilization of waste-to-energy. The ability to draw on a diverse set of biomass-based feedstocks helps to reduce the pressure for drastic large-scale changes in land use and the attendant environmental, ecological, and economic consequences those changes would unleash. In terms of the conversion of bioenergy feedstocks into value added energy, this paper demonstrates that biomass is and will continue to be used to generate electricity as well as liquid transportation fuels. A particular focus of this paper is to show how climate policies and technology assumptions – especially the availability of carbon dioxide capture and storage (CCS) technologies – affect the decisions made about where the biomass is used in the energy system. The potential for net-negative electric sector emissions through the use of CCS with biomass feedstocks provides an attractive part of the solution for meeting stringent emissions constraints; we find that at carbon prices above $150/tCO2, over 90% of biomass in the energy system is used in combination with CCS. Despite the higher technology costs of CCS, it is a very important tool in controlling the cost of meeting a target, offsetting the venting of CO2 from sectors of the energy system that may be more expensive to mitigate, such as oil use in transportation. CCS is also used heavily with other fuels such as coal and natural gas, and by 2095 a total of 1530 GtCO2 has been stored in deep geologic reservoirs. The paper also discusses the role of cellulosic ethanol and Fischer–Tropsch biomass derived transportation fuels as two representative conversion processes and shows that both technologies may be important contributors to liquid fuels production, with unique costs and emissions characteristics.  相似文献   

19.
A laboratory-scale reactor system was built and operated to demonstrate the feasibility of catalytically reacting carbon dioxide (CO2) with renewably-generated hydrogen (H2) to produce methane (CH4) according to the Sabatier reaction: CO2 + 4H2  CH4 + 2H2O. A cylindrical reaction vessel packed with a commercial methanation catalyst (Haldor Topsøe PK-7R) was used. Renewable H2 produced by electrolysis of water (from solar- and wind-generated electricity) was fed into the reactor along with a custom blend of 2% CO2 in N2, meant to represent a synthetic exhaust mixture. Reaction conditions of temperature, flow rates, and gas mixing ratios were varied to determine optimum performance. The extent of reaction was monitored by real-time measurement of CO2 and CH4. Maximum conversion of CO2 occurred at 300–350 °C. Approximately 60% conversion of CO2 was realized at a space velocity of about 10,000 h?1 with a molar ratio of H2/CO2 of 4/1. Somewhat higher total CO2 conversion was possible by increasing the H2/CO2 ratio, but the most efficient use of available H2 occurs at a lower H2/CO2 ratio.  相似文献   

20.
The inclusion of CO2 capture and storage (CCS) in the Kyoto Protocol's Clean Development Mechanism (CDM) is still subject to controversy and discussion. A myriad of barriers prevents CCS in the CDM. Apart from political barriers, economic, social and procedural barriers play a role. This paper discusses relevant new results on the human capacity, procedural feasibility and economic potential of CCS in the CDM. The conclusions of a capacity building effort in Africa show that awareness and knowledge are low but that capacity building efforts are well received. A reality check on methodologies for hypothetical CCS projects shows that most of the issues can be resolved, and the CDM institutional arrangements can accommodate CCS. A bottom-up estimate of the potential of natural gas processing CCS in the CDM, based on a previously proprietary database from the oil and gas industry, suggests that there is an annual potential of about 174 MtCO2 in 2020 in that sector. Most of that potential can be realized at CER prices between $20 and $30/tCO2 but there is no sign of flooding the CDM market with cheap credits from CCS projects. Despite these results and more open information, the CCS and CDM debate, progress in the negotiations on CCS in the CDM is slow and there is no clear view on a solution.  相似文献   

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