Environmental and human exposure assessment monitoring of communities near an abandoned mercury mine in the Philippines: a toxic legacy

Abandoned mines are an important global concern and continue to pose real or potential threats to human safety and health including environmental damage/s. Very few countries had government mine regulation and reclamation policies until the latter part of the century where legal, financial and technical procedures were required for existing mining operations. Major reasons for mine closure may be mainly due to poor economies of the commodity making mining unprofitable, technical difficulties and national security. If the mine is abandoned, more often than not it is the government that shoulders the burden of clean-up, monitoring and remediation. The topic of abandoned mines is complex because of the associated financial and legal liability implications. Abandoned mercury mines have been identified as one of the major concerns because of their significant long-term environmental problems. Primary mercury production is still ongoing in Spain, Kyrgzystan, China, Algeria, Russia and Slovakia while world production declined substantially in the late 1980s. In the Philippines, the mercury mine located southeast of Manila was in operation from 1955 to 1976, before ceasing operation because of the decline in world market price for the commodity. During this time, annual production of mercury was estimated to be about 140,000 kg of mercury yearly. Approximately 2,000,000 t of mine-waste calcines (retorted ore) were produced during mining and roughly 1,000,000 t of these calcines were dumped into nearby Honda Bay to construct a jetty to facilitate mine operations where about 2000 people reside in the nearby three barangays. In October, 1994 the Department of Health received a request from the Provincial Health Office for technical assistance relative to the investigation of increasing complaints of unusual symptoms (e.g. miscarriages, tooth loss, muscle weakness, paralysis, anemia, tremors, etc.) among residents of three barangays. Initial health reports revealed significant elevation of blood mercury levels exceeding the then recommended exposure level of 20ppb in 12 out of the 43 (27.9%) residents examined. The majority of the volunteers were former mine workers. In this study the abnormal findings included gingivitis, mercury lines, gum bleeding and pterydium. The most common neurologic complaints were numbness, weakness, tremors and incoordination. Anemia and elevated liver function tests were also seen in a majority of those examined. The assessment also revealed a probable association between blood mercury level and eosinophilia. The same association was also seen between high mercury levels and the presence of tremors and working in the mercury mine. To date, there are very limited environmental and health studies on the impact of both total and methylmercury that have been undertaken in the Philippines. Thus, this area of study was selected primarily because of its importance as an emerging issue in the country, especially regarding the combined effects of total and methylmercury low-dose and continuous uptake from environmental sources. At present the effects of total mercury exposure combined with MeHg consumption remain an important issue, especially those of low-dose and continuous uptake. Results of the study showed that four (4) species of fish, namely ibis, tabas, lapu-lapu and torsillo, had exceeded the recommended total mercury and methylmercury levels in fish (NV>0.5 microg/gf.w., NV>0.3 microg/gf.w., respectively). Saging and kanuping also exceeded the permissible levels for methylmercury. Total and methylmercury in canned fish, and total mercury in rice, ambient air and drinking water were within the recommended levels, however, additional mercury load from these sources may contribute to the over-all body burden of mercury among residents in the area. Surface water quality at the mining area, Honda Bay and during some monitoring periods at Palawan Bay exceeded total mercury standards (NV>0.002 ng/mL). Soil samples in two sites, namely Tagburos and Honda Bay, exceeded the EPA Region 9 Primary Remediation Goal recommended values for total mercury for residential purposes (NV>23 mg/kg). The hand to mouth activity among infants and children is another significant route for mercury exposure. Statistically significant results were obtained for infants when comparing the results after one year of monitoring for methylmercury levels in hair for both exposed and control sub-groups. Likewise, comparing the initial and final hair methylmercury levels among pregnant women/mothers in the exposed group showed statistically significant (p<0.05) results. Comparing the exposed and control sub-groups' mercury hair levels per sub-group showed statistically significant results among the following: (a) initial and final total mercury hair levels among children, (b) initial and final methylmercury hair levels among children, (c) final total mercury hair levels among pregnant women, (d) initial and final total mercury hair levels among mothers, and (e) initial and final methyl hair levels among mothers.     

Health and environmental assessment of mercury exposure in a gold mining community in Western Mindanao, Philippines

The small-scale gold mining activities using mercury began in the late 1980s in Sibutad, Western Mindanao. It is located very near the Murcielagos Bay with tailing ponds directly discharging into bodies of water. This cross-sectional study aimed to determine the health and environmental effects of gold mining activities on the community. Residents were randomly selected and classified into two groups, namely, the directly exposed and indirectly exposed populations using a set inclusion criteria. Complete medical and laboratory examinations were performed. Environmental and biologic samples were collected for total mercury and methylmercury determinations. The results showed that the directly exposed group had significantly higher mean blood total mercury and methylmercury levels in comparison with the indirectly exposed population. Although there were no significant differences between hair total mercury and methylmercury levels, there was a trend for higher levels of these biomarkers among the directly exposed residents as compared with the unexposed group. The absence of statistically significant differences may be attributable to the small sample size. Ambient air quality monitoring for mercury exceeded the allowable levels. However, levels of mercury in drinking water and sediments were within allowable limits. Frequency of gastrointestinal complaints was significantly associated with elevated hair methylmercury levels (p=0.02). Also, there appears to be a trend towards higher blood total mercury levels and frequency of gastrointestinal complaints (p=0.09). An interesting finding in this study was the increasing incidence of elevated diastolic blood pressure with elevated hair total mercury levels (p=0.07). Mercury storage at home is a risk factor.     

正交试验-硝酸微波消解-冷原子吸收法测定土壤中汞

应用硝酸微波消解土壤样品-冷原子吸收法测定土壤中的汞。通过正交试验,优化了土壤中汞的微波消解条件。并对干扰消除、方法精密度、加标回收、检出限进行了试验研究。在0～10μg／L范围内线性关系良好,方法测定下限为0．20μg／L,土壤中汞的检出限为0．005μg／g。该优化条件对汞含量为0．02—0．46μg／g的土壤样品,汞提取完全。建立了一种简便、成本低、干扰少、灵敏度高的方法。     

南极内陆科考站的环境影响评价及减缓措施

南极内陆地区以其特殊的地理位置和特有的生态环境在研究全球变化尤其是气候变化中发挥不可替代的作用.随着越来越多的科考站在南极内陆地区建立,人类活动对南极环境的不利影响的程度和性质正在发生范围的扩散和层次的转移.本研究以中国昆仑站为例,依据不同类型活动的发生概率、范围、持续时间,严重程度的不同,对在南极内陆地区建立科考站所产生的环境影响进行了综合分析,结果表明,科考站的建设和运行对南极内陆环境及其附属的生态系统带来了不可避免的负效应,提出相关减缓措施以期尽可能减缓不良的环境影响,这不仅为日后南极科考活动提供规范化指导,还为南极内陆地区环境污染的控制及管理和可持续发展提供参考.     

Resource scarcity,energy use and environmental impact: A case study of the New Bedford,Massachusetts, USA,fisheries

The commercial fishing fleet in New Bedford, Massachusetts, USA, harvests seafood on George’s Bank, home of one of the nation’s most productive fisheries. We calculated the energy return on investment (EROI) and carbon intensity of protein harvest in the New Bedford fisheries from 1968 to 1988. EROI is the ratio of the energy content of the edible fish protein harvested to the quantity of fossil fuel energy used directly in the harvesting process. Carbon intensity is the quantity of carbon dioxide (CO₂) released (from the burning of fossil fuels) per calorie of edible fish protein harvested. The results show that the EROI of protein harvest declined from 0.18 to 0.028 from 1968 to 1988, indicating that the energy used to harvest seafood increased from about 6 to 36 kcal of fuel for each kilocalorie of protein harvested. The quantity of CO₂ released per calorie of edible fish protein is a linear function of energy use and therefore increased in a similar manner. During this period there was a large increase in fishing effort (caused by the increase in the real price of seafood products, favorable tax treatment for new vessel construction, and low interest loans from the government), and a decline in several important species of fish. The results suggest that fishing pressure could be managed effectively by the regulation of fuel use by the fleet. Despite the increase in the price of many seafood products, fishermen absorbed many of the costs of increasing scarcity in the form of longer working hours and fewer men per vessel.     

The littoral zone of lake okeechobee as a source of phosphorus after drawdown

Following a period of prolonged drought or intentional lake level drawdown, large littoral areas that once contained submersed aquatic vegetation (SAV) are reinundated when lake levels rise. A complete assessment of the contribution made by decomposing SAV to the in-lake phosphorus (P) concentration is important in both the management of Lake Okeechobee and understanding basic P processes. The P contribution to the open waters of Lake Okeechobee from a rapid inundation of exposed SAV was calculated by four methods: cores of field-desiccated SAV, cores of lab-desiccated SAV in the presence and absence of sediments, in situ decomposition, and sequential macrophyte harvesting. P releases, given such an episodic event, were similar among the four methods, ranging from 116±48 to 384±528 mg/m² in the absence of sediment. When SAV is in contact with sediment, which is the realistic field situation, the amount of P released was four times less (30±14 mg/m²) than in the absence of sediment. The calculated P releases would result in total P concentration increases in the lake from 2 to 15 μg/liter (upper 95% CI=2–25 μg/liter) in the absence of sediment; only 1 μg/liter increase was predicted when SAV released P in contact with sediment. Thus it is unlikely that a significant rise in total P concentrations in the limnetic zone of the lake would occur from the export of P released during the desiccation of SAV in the littoral-marsh zone during a drawdown.     

Model Calculations of Total Maximum Daily Loads of Mercury for Drainage Lakes1

Abstract: The Watershed Analysis Risk Management Framework watershed model was enhanced to simulate the transport and fate of mercury and to calculate the fish mercury concentrations (FMC) attained by fish through the food web. The model was applied to Western Lake Superior Basin of Minnesota, which has many peat lands and lakes. Topographic, land use, and soil data were used to set up the model. Meteorology and precipitation chemistry data from nearby monitoring stations were compiled to drive the model. Simulated flow and mercury concentrations for several stream stations were comparable to available data. The model was used to perform mercury total maximum daily load calculations for two contrasting drainage lakes (Wild Rice Lake and Whiteface Reservoir). The model results for wet deposition, dry deposition, evasion, watershed yield, and soil sequestration of mercury were comparable with available actual data. The model predicted lake ice cover from November to April and weak stratification in summer, typical of shallow lakes in cold regions. The simulated sulfate decrease and methylmercury increase near the lake bottom in late summer are caused by sulfate reduction and mercury methylation that occur in the surficial sediment. Simulated FMC were within the range of observed values and the R² of correlation between the simulated and observed FMC was 0.77. Under the 1989‐2004 base condition, the average simulated FMC of four‐year‐old walleye was 0.31 μg/g for Whiteface Reservoir and 0.15 μg/g for Wild Rice Lake. The FMC criterion in Minnesota is 0.2 μg/g. Wild Rice Lake already meets this criterion without any load reduction. The model showed that a 65% reduction in atmospheric mercury deposition will not, by itself, allow Whiteface Reservoir to meet the criterion in 15 years. Additional best management practices will be needed to reduce 50% of the watershed input.     

MERCURY IN WATER AND SEDIMENT OF STEAMBOAT CREEK,NEVADA: IMPLICATIONS FOR STREAM RESTORATION1

ABSTRACT: The objective of this study was to characterize the sources, concentrations, and distribution of total and methylmer‐cury in water, and channel and bank sediments of Steamboat Creek, Nevada. This information was needed to begin to assess the potential impacts of stream restoration on mercury pollution in this tributary to the Truckee River. The Truckee River flows into Pyramid Lake, a terminal water body home to one endangered and one threatened fish species, where stable pollutants will accumulate over time. Mercury in Steamboat Creek was originally derived from its headwaters, Washoe Lake, where several gold and silver mills that utilized mercury were located. In the 100 plus years since ore processing occurred, mercury‐laden alluvium has been deposited in the stream channel and on streambanks where it is available for remobilization. Total mercury concentrations measured in unfiltered water from the creek ranged from 82 to 419 ng/L, with greater than 90 percent of this mercury being particle‐bound (> 0.45 (m). Mercury in sediments ranged from 0.26 to 10.2 μg/g. Methylmercury concentrations in sediments of Steamboat Creek were highest in wetlands, lower in the stream channel, and still lower in streambank settings. Methylmercury concentrations in water were 0.63 to 1.4 ng/L. A streambank restoration plan, which includes alterations to channel geometry and wetland creation or expansion, has been initiated for the creek. Data developed indicate that streambank stabilization could reduce the mercury loading to the Creek and that wetland construction could exacerbate methylmercury production.     

The impact of ISO 14001 on corporate environmental performance: a study of Swedish manufacturing firms

The debate concerning the environmental effectiveness of environmental management systems (EMS) based on ISO 14001 is still open and scholars have called for further studies that can explain the contrasting evidence in previous research. As a response, this study aims to contribute knowledge about the effects of ISO 14001-based EMS by presenting fact-based environmental data. The study focuses on changes in performance over a period of 12 years and includes both firms with an EMS (66 firms) and firms without one (50 firms). Consideration is given to the improvement efforts in the firms before EMS adoption making it possible to neutralize any selection effects where better environmental performance precedes ISO 14001 adoption. Analysis has been carried out using statistical methods for six different environmental areas. No statistically significant differences between certified and non-certified firms concerning the change in the rate of improvement could be found in any of the six areas. However, it can be suspected that EMS adoption has positive effects on energy use and waste production whereas the non-adopting firms seem to perform better concerning air emissions. These mixed results mirrors previous research, which is rather worrying considering the worldwide popularity of EMS based on ISO 14001 in industry.     

Evaluation of wetland methyl mercury export as a function of experimental manipulations

Mercury associated with natural enrichment, historic mining, and ore processing is a contaminant of concern in watersheds of the western USA. In this region, water is a highly managed resource and wetlands, known to be important sites of methyl mercury production, are often an integral component of watersheds. This study applied controlled manipulations of four replicated experimental wetland designs with different water and soil mercury concentrations to determine the potential impacts on methyl mercury export. Wetlands were manipulated by drying and wetting, changing hydraulic retention time, and adding sulfate and nitrate to influent waters. In a summer drying and wetting manipulation, an immediate increase in total methyl mercury release was observed with rewetting, however, concentrations decreased quickly. Drying all wetlands over the winter and rewetting in the spring resulted in high net methyl mercury output relative to that observed before drying. Net methyl mercury output was not influenced by changes in hydraulic retention time from 4 to 8 h or to 30 min, or by increasing the nitrate concentration from 0.1 to 10 mg L(-1). The addition of sulfate to the inlet waters of two mesocosms to increase concentrations from approximately 100 to 250 mg L(-1) did not result in a clear effect on methyl mercury output, most likely due to sulfate concentrations being higher than optimal for methyl mercury production. Despite the lack of response to sulfate amendments, the change in sulfate concentration between the inlet and outlet of the mesocosms and temperature were the parameters best correlated with methyl mercury outputs.     

Assessment of spatial-temporal patterns of surface and ground water qualities and factors influencing management strategy of groundwater system in an urban river corridor of Nepal

This study examined the spatial-temporal variations and factors influencing the management of groundwater along a section of the Bagmati river corridor in the Kathmandu valley (Nepal). The results showed that rural areas were less polluted than urban areas. In urban areas, the biochemical oxygen demand (BOD), total nitrogen (TN) and total phosphorus (TP) concentrations ranged from 8.41 to 29.74 mg/L, 6.7 to 128.96 mg/L and 0.06 to 1.5 mg/L, respectively. In rural areas, the BOD, TN and TP concentrations ranged from 0.78 to 18.25 mg/L, 4.8 to 11.56 mg/L and 0.07 to 0.65 mg/L, respectively. The level of organics was higher in the pre-monsoon season, while the level of nutrients was higher in post-monsoon season. A comparison of the groundwater and surface water in the upstream rural areas revealed that the TP concentration was higher in the groundwater than in the surface water, which was attributed to the sorption of phosphorus on iron, aluminum or calcium compounds contained in the surface water, which depends upon the temperature, pH and dissolved oxygen. In urban areas, a few wells were found at groundwater levels lower than the corresponding surface water levels and were subjected to a high risk of pollution. Overall, these findings reinforce the notion that the management of surface and ground waters in an integrated approach is essential for attaining sustainable development of groundwater systems.     

Analysis of heavy metals and aromatics compounds in soil layers of a sanitary landfill

Solid waste presents the potential for contamination of the soil when it is improperly managed. One of the great challenges of today's society is to promote the proper disposal of municipal solid waste in order to guarantee the safety of public health and to avoid risks to the environment. In this context, the objective of this study is to analyze the concentration profiles of heavy metals and aromatic hydrocarbons of risk that human health in landfill soil. Such works provides an important tool to evaluate the possible presence of contaminants from inappropriate waste disposal, as well as to assist in the management of waste and to prevent environmental contamination. In order to analyze cadmium (Cd), lead (Pb), nickel (Ni), arsenic (As), and mercury (Hg), which are toxic elements, and aromatic hydrocarbons, including benzene, toluene, ethylbenzene, o‐xylene, m‐xylene, and p‐xylene, soil samples were collected at different sites and depths. Neither Cd nor As was detected in any of the samples that were analyzed. Pb levels ranged from 5.34 milligrams per kilograms (mg/kg) to 7.40 mg/kg, Ni levels ranged from 2.17 mg/kg to 3.00 mg/kg, and Hg levels ranged from 75.4 micrograms per kilograms (μg/kg) to 88.3 μg/kg. The aromatic hydrocarbon compounds of benzene, toluene, ethylbenzene, and o‐xylene were below 5.5 μg/kg, and m‐, p‐xylene was below 11 μg/kg. The analysis of heavy metals and aromatic hydrocarbons present in the landfill soil showed concentrations below the soil quality guideline values of the Brazilian National Environment Council (CONAMA) Resolution 420, which has criteria for the presence of chemical substances in soil for Brazil. Therefore, the low levels of chemicals may be related to the operational time of the landfill or to the population profile of the municipality, which is predominantly composed of persons involved in family‐based agriculture.     

Predicting estuarine sediment metal concentrations and inferred ecological conditions: an information theoretic approach

Empirically derived relationships associating sediment metal concentrations with degraded ecological conditions provide important information to assess estuarine condition. Resources limit the number, magnitude, and frequency of monitoring activities to acquire these data. Models that use available information and simple statistical relationships to predict sediment metal concentrations could provide an important tool for environmental assessment. We developed 45 predictive models for the total concentrations of copper, lead, mercury, and cadmium in estuarine sediments along the Southern New England and Mid-Atlantic regions of the United States. Using information theoretic model-averaging approaches, we found total developed land and percent silt/clay of estuarine sediment were the most important variables for predicting the presence of all four metals. Estuary area, river flow, tidal range, and total agricultural land varied in their importance. The model-averaged predictions explained 78.4, 70.5, 56.4, and 50.3% of the variation for copper, lead, mercury, and cadmium, respectively. Overall prediction accuracies of selected sediment benchmark values (i.e., effects ranges) were 83.9, 84.8, 78.6, and 92.0% for copper, lead, mercury, and cadmium, respectively. Our results further support the generally accepted conclusion that sediment metal concentrations are best described by the physical characteristics of the estuarine sediment and the total amount of urban land in the contributing watershed. We demonstrated that broad-scale predictive models built from existing monitoring data with information theoretic model-averaging approaches provide valuable predictions of estuarine sediment metal concentrations and show promise for future environmental modeling efforts in other regions.     

The environmental impact of a chloro-alkali factory in a river basin in Eastern India

Summary It has been established that the electrodes of the dialyser in a chloro-alkali plant in Eastern India release mercury beyond the permissible limits into the River Koel. Mercury in elemental form, as well as certain organo-mercury compounds, including methyl mercury, have been detected at a distance of 25 km from the discharge point. Even at a distance of 5–10 km, the mercury content of the sediment may be as high as 0.6–3.2 mg kg^–1 above the value of sediment upstream of the plant. This sediment itself is contaminated, probably by battery and paint factories, etc., still further upstream. Thus, the chloro-alkali factory has contributed 60–320 times above the permissible limit (0.01 mg kg^–1) of mercury release, at a distance of 5–10 km from the point of release. Furthermore, various phytoplankton and zooplankton have been contaminated, leading to very high mercury contents in certain fish. This food chain, therefore, threatens man himself.Dr Sajalendu Nanda is currently a Research Associate at Bangur Institute of Neurology in Calcutta. He possesses an MSc in Environmental Biology and a PhD in Ecology. His address for correspondence is c/o Dr P.K. Tapaswi, Professor-in-Charge at the Biological Sciences Division of the Indian Statistical Institute.     

OCCURRENCE OF TOTAL DISSOLVED PHOSPHORUS IN UNCONSOLIDATED AQUIFERS AND AQUITARDS IN IOWA1

ABSTRACT: Seven sets of ground water samples from 103 observation wells were analyzed for total dissolved phosphorus (TDP) in four areas and five materials including loess and loess derived alluvium in the Deep Loess Hills of western Iowa, outwash and fractured till adjacent to Clear Lake in north central Iowa, fractured till in central Iowa, and a sand and gravel aquifer in northwest Iowa. Land use in ground water recharge zones in all four areas is dominated by crop or animal production or both. Concentrations of TDP exceeding the minimum laboratory detection limit of 20 μg/l as P were found in all areas and in all materials sampled. Samples from the outwash deposits associated with Clear Lake contained significantly larger concentrations than all other areas and materials with a median of 160 μg/l. Water from fractured till in three areas produced the smallest range of concentrations with a median of 40 μg/l. The mean value of TDP in all sample sets exceeded 50 μg/l, an important ecological threshold that causes increased productivity in lakes and perennial streams and one being considered as a surface water nutrient standard by regulatory agencies. These results clearly show that ground water in essentially all near‐surface aquifers and aquitards discharging to Iowa's streams and lakes is capable of sustaining P concentrations of 50 to 100 μg/l in streams, lakes, and reservoirs. Consequently, even if point discharges and sediment sources of P are substantially reduced, ground‐water discharge to surface water may exceed critical thresholds under most conditions.     

Trace metal contents of the pacific oyster (Crassostrea gigas) purchased from markets in Hong Kong

Arsenic, cadmium, chromium, and copper concentrations of the Pacific oyster,Crassostrea gigas, purchased from four different markets were determined in this project. In general, gill tissue had the highest proportion of metal contents (34%–67%) when compared with other tissue parts (mantle, viscera, and adductor muscle), except for arsenic, which showed the highest level in adductor muscle (44%). Smaller oysters (longitudinal length of soft body part less than 6 cm) had higher metal levels than larger ones (longitudinal length of soft body part more than 6 cm), except copper. None of the four metals examined showed an obvious seasonal trend, although cadmium levels seemed to be higher in autumn and winter months. Arsenic, cadmium, and copper levels in oysters purchased from different markets and different months obtained in the present study were higher when compared with past reports. Cadmium levels, as high as 10.98 mg/kg (dry weight basis) have been obtained. This approaches the safety limit that may be hazardous to human health. Continual monitoring of cadmium and other trace metals of toxicological significance to man in Hong Kong seafood is recommended.     

Distribution and mobility of mercury in soils of a gold mining region, Cuyuni river basin, Venezuela

An extensive and remote gold mining region located in the East of Venezuela has been studied with the aim of assessing the distribution and mobility of mercury in soil and the level of Hg pollution at artisanal gold mining sites. To do so, soils and pond sediments were sampled at sites not subject to anthropological influence, as well as in areas affected by gold mining activities. Total Hg in regionally distributed soils ranged between 0.02 mg kg(-1) and 0.40 mg kg(-1), with a median value of 0.11 mg kg(-1), which is slightly higher than soil Hg worldwide, possibly indicating long-term atmospheric input or more recent local atmospheric input, in addition to minor lithogenic sources. A reference Hg concentration of 0.33 mg kg(-1) is proposed for the detection of mining affected soils in this region. Critical total Hg concentrations were found in the surrounding soils of pollutant sources, such as milling-amalgamation sites, where soil Hg contents ranged from 0.16 mg kg(-1) to 542 mg kg(-1) with an average of 26.89 mg kg(-1), which also showed high levels of elemental Hg, but quite low soluble+exchangeable Hg fraction (0.02-4.90 mg kg(-1)), suggesting low Hg soil mobility and bioavailability, as confirmed by soil column leaching tests. The vertical distribution of Hg through the soil profiles, as well as variations in soil Hg contents with distance from the pollution source, and Hg in pond mining sediments were also analysed.     

Point- and nonpoint-source pesticide contamination in the Zwester Ohm catchment, Germany

Reducing pesticide loads in surface waters implies identifying the pathways responsible for the pollution. The current study documents the pesticide contamination of the river Zwester Ohm, a 4917-ha catchment in Germany with 41% of the land used for crop production. Discharges and concentrations of 19 pesticides were measured continuously at three locations for 15 mo. The load detected at the outlet of the catchment amounted to 9048 g a.i. The losses represent 0.22% of the pesticides applied by the farmers. The contamination showed a seasonal pattern following the pesticide application times. The wastewater treatment plant system (WWTPS) in the catchment (two wastewater treatment plants [WWTP], 14 combined sewer overflows (CSO), four CSO tanks) emits during dry weather periods purified sewage and during storm events sewage mixed with stormwater runoff into the river. The contribution by the WWTPS to the pesticide load was defined as point-source pollution (PSP). The load was dominated by PSP with at least 77% of the total pollution. No significant interdependencies between intrinsic properties of the pesticides, hydrometeorological factors, and the loads occurring in the stream could be found. Therefore, it is not possible to predict PSP for other catchments based on the results from this study. Whereas 65% of the total load entered the river via the WWTP, a portion of 12% was attributed to the CSO. The study points out that the influence of CSO on PSP should be taken into account in future catchment studies in areas with comparable agricultural structure.     

洪水灾害风险评价研究综述

洪水灾害是当今世界最严重的自然灾害之一,带来了巨大的人员伤亡和经济损失。洪水灾害风险评价是科学有效地防洪减灾的前提和基础。文章对洪水灾害风险相关概念进行了界定,从气象、水文水力、社会经济、遥感与GIS和土地利用5个方面对洪水灾害风险评价的常用方法进行了评述,并列出了常用的评价因子。最后指出了未来研究的可能发展方向。     

Fish Mercury and Surface Water Sulfate Relationships in the Everglades Protection Area

Few published studies present data on relationships between fish mercury and surface or pore water sulfate concentrations, particularly on an ecosystem-wide basis. Resource managers can use these relationships to identify the sulfate conditions that contain fish with health-concerning total mercury (THg) levels and to evaluate the role of sulfate in methyl-mercury (MeHg) production. In this study, we derived relationships between THg in three fish trophic levels (mosquitofish, sunfish, and age-1 largemouth bass) and surface water sulfate from 1998 to 2009 for multiple stations across the Everglades Protection Area (EPA). Results show the relationship between sulfate and fish THg in each fish type is nonlinear and largely skewed, similar to the relationship between MeHg production and sulfate concentration in peatland sediment pore water identified by other researchers. Peak fish THg levels occurred in ~1 to 12 mg/L sulfate conditions. There was significant variability in the fish THg data, and there were several instances of high-fish THg levels in high-sulfate conditions (>30 mg/L). Health-concerning fish THg levels were present in all surface water sulfate conditions; however, most of these levels occurred in 1–20 mg/L sulfate. The data in this study, including recent studies, show consistent and identifiable areas of high- and low-fish THg across the spectrum of surface water sulfate concentration, therefore, applying an ecosystem-wide sulfur strategy may be an effective management approach as it would significantly reduce MeHg risk in the EPA.