中国污染场地分类管理程序与方法研究

借鉴发达国家对污染物场地的管理方法,探索了我国污染场地分类管理的程序:从疑似污染场地的申报建档、疑似污染场地的初步调查、场地的危害分级、污染场地的详细调查、污染场地风险评估,到污染场地的治理修复,以及贯穿场地管理始终的环境监测.在上述管理程序中还缺失危害分级的方法,其他步骤已有相关技术文件支持.本文进一步构建了其中场地危害分级的方法:即根据污染源是否存在,污染物的性质、赋存状态、迁移性、含量水平,周围是否有敏感目标及其类型,分成不同的危害级别和管理级别,并实施不同的管理措施.以江苏省八家氯丹、灭蚁灵生产企业场地为例,经初步调查和危害分级,将8个场地分为3类:B类场地(有1个场地)环境介质中无超标污染物检出,但场地上的有害废弃物需要处置;C类场地(包括3个场地)局部有超标污染物检出,但场地不具备详细调查采样和修复的条件,需要对污染区进行隔离处置,以降低人体健康风险;还有D类场地(包括4个场地)需要详细采样以确定污染范围并进行风险评估.根据最后一类4个场地进一步调查评估的结果,并考虑到场地实施修复的经费、技术可行性及场地相关利益方的意见,决定优先对其中1个场地实施修复治理.     

南京市经济增长与工业“三废”污染水平计量模型研究

根据环境库兹涅茨曲线原理，选取南京市1985～2004年的经济与环境数据，运用SPSS和EXCEL软件，分析了经济因子与环境因子的相关关系，并建立了模拟经济因子与环境因子之间动态回归模型。研究结果表明，南京市工业废水排放量和人均GDP具有一般相关性，并不呈现库兹涅茨曲线倒“U”模型，而是呈三次曲线的“N”型，两个拐点分别在9 000元和29 000元，这可能与产业结构转变较快有关。工业废气排放量和固体废物产量与人均GDP存在显著相关性， 符合环境库兹涅茨曲线的倒“U”模型，拐点分别在30 000元和38 000元,均提前实现拐点。此外环境政策与科技对工业废水排放量影响也较大。经济结构是影响工业废气排放量和固体废物产量的主要因素，同时，南京市有利的环保科技政策使这两个环境指标提前实现拐点。     

乌江流域石灰土中铀等元素形态与铀活性

以中国西南乌江流域石灰土为例，运用逐级提取(Sequential Extraction，SEE)技术，并结合化学成分和相关参数数据，研究了石灰土中铀(U)等元素的形态，并在此基础上探讨了石灰土中U的活动性及释放潜力，旨在增进对U等元素生物地球化学循环的了解，同时也为流域U污染防治提供科学依据。研究结果表明：①石灰土中Mn主要存在于锰(氢)氧化物中，Ca主要存在于碳酸盐和硅酸盐矿物中，P主要存在于硅酸盐矿物和有机质中，U主要赋存于硅酸盐等残留部分中，其次赋存于有机质结合部分和碳酸盐矿物中；②石灰土剖面中活动态U所占的比例为10%~30%，平均17%，说明石灰土中的部分U在酸性和氧化-还原界面等条件下具有一定的迁移活性，即在上述条件下，石灰土中的部分U可释放进入周围水体或植物中；③石灰土中U的潜在释放量为036~150 g/t，平均U潜在释放量为076 g/t，因此，在酸雨和侵蚀等作用下，石灰土U释放可显著提高乌江河水U通量。     

Possible role of organic matter in radiocaesium adsorption in soils

The aim of this review is to examine the hypothesis that organic matter decreases the adsorption of radiocaesium on clay minerals. The factors that determine radiocaesium mobility and bioavailability in soil are briefly outlined to show why a relationship between soil organic matter content and enhanced Cs bioavailability is paradoxical. In all the investigations reviewed the ionic compositions of both the solid and the solution phases have been strictly controlled. We show that the addition of organic matter to reference clay minerals causes decreases of up to an order of magnitude in the distribution coefficient of radiocaesium. Similarly, the chemical removal of organic matter from the clay-sized fraction of soil usually leads to an increase in Cs adsorption. We suggest that the nature of the organic matter and its interaction with mineral surfaces are as important as the amount present.     

Economic and environmental value stream map (E2VSM) simulation for multi-product manufacturing systems

Value stream mapping (VSM) is a well-accepted tool within lean manufacturing concept which is often used for analysing and designing the flow of materials and information required to manufacture a product. However, the analysis is static and single product oriented, which fails to cope with either the variation of production plan or a multi-product environment. In addition, the environmental impact of a manufacturing system is highly associated with the dynamic consumption of energy and resources. Despite the recent integration of VSM with simulation or environmental studies (in the domain of energy efficiency), still neglected is the dynamic assessment of all the resources involved in a multi-product production environment. This paper presents a methodology for modelling multi-product manufacturing systems with dynamic material, energy and information flows with the aim to generate economic and environmental value stream maps (E²VSM). The proposed methodology is validated with an industrial case.     

芦山地震灾区次生山地灾害分布特征及其成因分析

选取芦山地震涉及的21个县（市、区）为研究对象,应用野外实地踏勘和遥感解译相结合的方法,结合当地国土、水利、建设等部门提供的相关统计资料,已查明芦山地震灾区782处次生山地灾害（滑坡、崩塌和泥石流）,获取了这些次生山地灾害的基础信息。在GIS信息技术的支持下,对芦山地震灾区次生山地灾害的发育环境背景、分布特征和成因进行了初步的探讨分析。研究表明：芦山地震灾区次生山地灾害主要集中分布在烈度为Ⅷ Ⅸ区、中低山区、坡度0°～40°、坡向为东西两向、第三系砂砾夹泥岩区、河流冲刷强烈和年降雨量＞1 200 mm的区域;发育成因主要是地形条件对次生山地灾害的形成的影响表现出与非地震条件下的新特征;地震效应重构了地表形态,为次生山地灾害发育提供了大量的松散固体物质;降水与河流冲刷作用的改变,影响边坡稳定性,为次生山地灾害提供动力;人类过度的社会经济活动加速了次生山地灾害的形成     

The risks of risk-based regulation: insights from the environmental policy domain

Risk-based regulation has become increasingly popular in recent years. Proponents argue that it facilitates robust governance, contributing to efficient and effective use of regulatory resources and delivering interventions in proportion to risk. Critics contend that the challenges of operationalising risk-based governance mitigate its potential benefits. In this paper we start by considering what we mean by risk-based governance and discuss some of the factors shaping the adoption of such strategies. We then consider the development and operation of risk-based approaches in the environmental policy domain, focusing specifically on the regulation of contaminated land and radioactive waste. We argue that whilst risk-based approaches can offer important benefits, they face a range of epistemic, institutional and normative challenges that can play an important role in shaping the way that organisations manage both risks to society and their own institutional risks. This has profound implications for achieving regulatory objectives and, for this paper, the environmental outcomes that the regulations are designed to deliver.     

Regional risk assessment for contaminated sites Part 3: Spatial decision support system

Large scale (e.g. regional or national) assessments of contaminated sites may be very costly in terms of investigation and methodological (i.e. risk assessment procedures) requirements and may produce a quantity of information that usually discourages examination by decision-makers. Moreover, most of the existing tools effectively support local environmental risk assessment and management, but lack the capabilities of larger scale analysis, not mentioning the absence of the relevant component of socio-economic prioritization. To respond to the concerns and the management needs of experts and decision makers, the Spatial decision support sYstem for Regional rIsk Assessment of Degraded land (SYRIADE DSS) was developed and is presented according to its three modules: Regional Risk Assessment, Socio-economic Assessment and Integrated Assessment, respectively. The system allows to rank potentially contaminated sites for priority of investigation, when no information on characterization and risk by site specific methodologies is available. This GIS-based system embeds an innovative spatial and relative risk assessment procedure, and proposes the integrated analysis of different data (environmental and socio-economic) for the concerned sites, eliciting when necessary experts' knowledge and stakeholders' values (through Multi Criteria Decision Analysis, MCDA, methodologies). The application to a Polish case-study shows the performance and the flexibility of the system in investigating and mapping (potentially) contaminated sites at the regional scale.     

Toxic Sublime: Imaging Contaminated Landscapes

This essay attempts to address the lack of critical analyses of images of toxins by examining the photography of landscape artists whose goal is to create a presence for contaminated sites. Imaging toxicity is no simple task as many pollutants are invisible and sites of contamination are concealed, especially for those of privilege. Contemporary artists who attempt this challenge are often criticized that the beauty of their images obfuscates the health and environmental risk of the polluted sites they photograph. In response, this essay introduces the concept of the toxic sublime as a means of analyzing the tensions arising from visual representations of environmental contamination: beauty and ugliness, magnitude and insignificance, the known and the unknown, inhabitation and desolation, security and risk. The essay charts the evolution of the sublime in the US, describing how it has evolved from sites of nature to sites of technology to human damaged landscapes, some of which produce a toxic sublime. Through a close examination of Manufactured Landscapes, a twenty-five year retrospective of the images of noted environmental photographer Edward Burtynsky, this essay extends our understanding of the invention of the sublime in images, reconceptualizes the sublime response to contaminated places, as well as adding to our knowledge of how visual texts function to encourage contemplation of the viewers’ position within a polluted world.     

It's Not Easy Being Green … Or Is It? A Content Analysis of Environmental Claims in Magazine Advertisements from the United States and United Kingdom

As corporations seek to appeal to environmentally conscious stakeholders, advertisements containing environmental claims have become increasingly prominent. A corporation's desire for an enhanced corporate reputation, combined with lenient environmental advertising regulation, has created the perfect environment for corporations to use—and misuse—environmental claims, resulting in “greenwashing.” Defined as the act of disseminating disinformation to consumers regarding the environmental practices of a company or the environmental benefits of a product or service, greenwashing occurs around the world. This study is a cross-national content analysis of 247 print ads from 84 issues of mainstream magazines from the United States and United Kingdom. Three-fourths (75%) of the ads analyzed contained one or more aspects of greenwashing. Firms advertising in US magazines were significantly more likely to employ misleading/deceptive environmental claims than UK firms and magazines. These findings suggest that without increased environmental advertisement regulation, greenwashing will persist as a disingenuous means for corporate reputation enhancement.     

Effect of indigenous bacterial activity on arsenic mobilization under anaerobic conditions

Batch biochemical leaching tests were carried out to investigate the mobility of arsenic from a contaminated soil collected from a French gold mining site. The specific objective of this research was to examine the effect of indigenous bacterial activity on arsenic mobilization under anaerobic conditions. In a first step, physical and chemical characterizations were performed to provide data concerning the liquid-solid partitioning and mobility of arsenic and other inorganic constituents. In a second step, batch bioleaching tests were conducted in shaker flasks to determine the effect of indigenous bacterial activity under different anaerobic conditions (i.e., addition of mineral nutrients and carbon sources) on arsenic mobilization. Results indicated that arsenic release during contact with deionized water was limited by its very low solubility in the interstitial solution and by the stability of the different arsenic compounds formed with the amorphous solid phases of the soil (mainly iron (oxy)hydroxides). However, an increased mobilization potential was observed over the long term under anaerobic conditions with indigenous bacterial activity enhanced by the addition of carbon sources.     

Stability of the conjugated species of environmental phenols and parabens in human serum

In humans, the metabolism of environmental phenols may include the formation of conjugated species (e.g., glucuronides and sulfates), but the free species—not the conjugated forms—are considered biologically active. Therefore, information on the concentration of these free species in blood or urine could be helpful for risk assessment. Because conjugates could hydrolyze to their corresponding free forms during collection, handling, and storage of biological specimens, information on the temporal stability of the conjugates is of interest. Previously, we reported the temporal stability of urinary conjugates of several environmental phenols, but data on the stability of phenols' conjugated species in serum, albeit critical if concentrations of free and conjugated species are compared, are largely unknown. In the present study, we investigate the stability of the conjugates of four phenols—bisphenol A, benzophenone-3, triclosan, and 2,5-dichlorophenol—and two parabens—methyl paraben and propyl paraben—in 16 human serum samples for 30 days at above-freezing temperature storage conditions (4 °C, room temperature, and 37 °C). These conditions reflect the worst-case scenarios that could occur during the short-term storage of biological samples before their long-term storage at controlled subfreezing temperatures. We found that the percentage of the conjugated species of the four detected compounds (2,5-dichlorophenol, triclosan, and methyl and propyl parabens) in these serum specimens even when stored at 37 °C for at least 30 days did not vary significantly. These preliminary data suggest that the phenols' serum conjugates appear to be more stable than their corresponding urinary conjugates, some of which started to hydrolyze within 24 h under similar storage conditions. The reported stability of these conjugated species in human serum also suggests that the free species are unlikely to have resulted from the hydrolysis of their corresponding conjugates. This information could be important for interpreting the low concentrations of free phenol species detected in serum samples of nonoccupationally exposed populations. To our knowledge, this is the first study to report on the stability of conjugated species in serum, and as such requires replication.     

Framing environmental indicators: moving from causal chains to causal networks

In recent years, there has been a boom in environmental assessment reports utilizing environmental indicators. Most of these publications are based on the casual chain frameworks (e.g., Pressure–State–Response (PSR), Driving force–State–Response (DSR), and Driving force–Pressure–State–Impact–Response (DPSIR)). These frameworks have made an important contribution by emphasising the importance of causality. However, the reliance on simple uni-directional chains is at the same time not very conducive to a good understanding of the complexity of the processes behind environmental indicators. This limits the usefulness of these frameworks for environmental (impact) assessments. In this paper we propose an enhanced DPSIR (eDPSIR) framework for environmental indicators that takes inter-relations of indicators into account by relying on the use of causal networks rather than causal chains. It will be shown how the concept of causal networks can increase insight into the inter-relation of environmental issues and associated indicators, can facilitate the identification of key indicators for particular kinds of questions, and can provide a useful first step to the establishment of dose–response functions. Working with causal networks can contribute to more appropriate environmental policies and better management decisions.     

Computerised Decision Support Systems for the management of freshwater radioecological emergencies: assessment of the state-of-the-art with respect to the experiences and needs of end-users

Assessment of the environmental and radiological consequences of a nuclear accident requires the management of a great deal of data and information as well as the use of predictive models. Computerised Decision Support Systems (CDSS) are essential tools for this kind of complex assessment and for assisting experts with a rational decision process. The present work focuses on the assessment of the main features of selected state-of-the-art CDSS for off-site management of freshwater ecosystems contaminated by radionuclides. This study involved both developers and end-users of the assessed CDSS and was based on practical customisation exercises, installation and application of the decision systems. Potential end-users can benefit from the availability of several ready-to-use CDSS that allow one to run different kinds of models aimed at predicting the behaviour of radionuclides in aquatic ecosystems, evaluating doses to humans, assessing the effectiveness of different kinds of environmental management interventions and ranking these interventions, accounting for their social, economic and environmental impacts. As a result of the present assessment, the importance of CDSS “integration” became apparent: in many circumstances, different CDSS can be used as complementary tools for the decision-making process. The results of this assessment can also be useful for the future development and improvement of the CDSS.     

Costs of the Wastewater Standard in Pig Production in Mexico

The objective of this article is to address the environmental costs of pig farms in the La Piedad region Mexico, through an analysis of the standard on wastewater discharges to national water bodies. Field work was carried out from April to September 1999; a survey was conducted on 23 farms and samples of wastewater were taken on 11 farms. Pig production is the third most important system in Mexican livestock production. Heterogeneity in production systems, dependence on imported inputs (genetics and feed grains), and weak internalization of environmental costs are the main characteristics of pig production in Mexico. With no specific environmental regulations on intensive livestock activities at the municipal or state levels, Mexican Official Standard 001 on wastewater discharges is the only environmental obligation that pig farms must meet. Standard 001 on wastewater contains the maximum permissible limits for 20 contaminant parameters, and is based on a cost-benefit analysis that points to secondary treatment for the regulation’s economic viability. Investment in treatment systems and the fees that pig producers must pay when they fail to comply with the limits stipulated in the regulation, are estimated assessed as an approach to environmental costs. In order to remain within the limits in the standard, pig farms must invest in tertiary treatment, and that makes meeting the standard unaffordable for this sector.     

税收竞争对环境污染的影响及传导机制分析

在中国经济高增长的背后,环境污染问题愈发凸显,不利于经济的可持续增长。税收竞争是影响环境污染的主要因素之一,但是学术界研究税收竞争对环境污染的影响及其作用机制的较少。本文按照污染物属性将其划分为外溢性污染物和非外溢性污染物,通过构建一个包含生产者、消费者、地方政府及中央政府的一般均衡模型,刻画了在税收竞争的背景下,地方政府的税收征管效率对不同属性污染物的影响及其传导机制。结果发现当污染物具有外溢性属性时,税收征管效率对该地环境污染的影响通过改变本地及周边地区资本存量渠道实现;当污染物具有非外溢性属性时,降低税收征管效率通过增加该地区资本存量而提高了环境污染。文章首先使用随机前沿模型测算了2007—2014年中国28个省份企业所得税的税收征管效率,并将其作为税收竞争的衡量指标,然后运用系统GMM法证实了所提的假说。研究显示:地方政府的税收竞争增加了本地区的资本存量;税收竞争是将本地资本存量作为其推高外溢性污染物(二氧化硫)及非外溢性污染物(固体废弃物)排放量的一个主要渠道,邻近地区资本存量则是推高外溢性污染物(二氧化硫)的次要渠道。这意味着,要想改善环境质量,中央政府应规范地方政府的税收竞争行为,尽快建立一套科学、有效的绿色GDP评价体系;完善地方转移支付制度;应针对各个地区的污染及经济发展情况利用财政激励手段引入环保、绿色的资本项目;地方政府应减少不利于环境改善的地方财政支出,增加环保投入比重。     

Speciation of radionuclides - analytical challenges within environmental impact and risk assessments

The mobility, biological uptake and accumulation of radionuclides are essentially dependent on the physico-chemical form of the nuclides. As a major fraction of refractory radionuclides released during historical nuclear events is associated with particles, a key analytical challenge within environmental impact and risk assessments is to characterise radioactive particles with respect to properties influencing particle weathering, remobilisation and the subsequent ecosystem transfer of associated radionuclides. Preanalysis techniques are needed to fractionate, identify and localize individual particles in contaminated samples. To obtain information on particle characteristics such as particle size distributions, structures, elemental and radionuclide particle composition as well as oxidation state of matrix elements, solid-state speciation techniques are needed. Electron microscopy as well as X-ray microscopic techniques utilising synchrotron X-ray radiation have proved most useful in providing such information. The present paper summarises the present status on advanced techniques and presents historical sources that have contributed to radioactive particle contamination.     

The Dakota Access Pipeline and the Breakdown of Participatory Processes in Environmental Decision-Making

This article employs a close reading of documents related to the permitting process for the Dakota Access Pipeline (DAPL) and ensuing legal battle in order to argue that extant regulatory frameworks for environmental decision-making are insufficient to promote environmental justice outcomes. By analyzing the US Army Corps of Engineer's responses to comments made during the public comment phase of the NEPA evaluation of the DAPL, I argue that regulatory frameworks may exacerbate environmental justice concerns by incentivizing decision makers to prioritize justification for their decisions and avoiding legal battles over meaningfully engaging with communities. This finding leads me to call for more engagement with energy democracy's orientation toward community-led processes as a corrective to current regulatory systems. This article expands on extant work in environmental communication by more thoroughly investigating the flaws in extant regulatory frameworks and calling for a perspectival shift in environmental decision-making.     

Amplifiers on the Commons: Using Indicators to Foster Place-Based Sustainability Initiatives

This essay proposes a heuristic conservation between the emerging field of environmental communication and the “crisis discipline” of conservation biology in order to generate a set of ethical postulates for research, teaching, and professional consultation. To the extent that social/symbolic representations of “environment” embody interested orientations, such discourses potentially constrain and/or enable societal responses to environmental signals, including signs of ecological crises. The essay argues that, implicit in this and other functional premises, lies a principal ethical duty of environmental communication: the obligation to enhance the ability of society to respond appropriately to environmental signals relevant to the well-being of both human communities and natural biological systems.     

Radionuclide applications in laboratory studies of environmental surface reactions

The advantages of using radionuclides for laboratory studies of environmental processes include the wide range of element concentrations that can be studied, the capability to simultaneously study several isotopes in a single experiment, the direct applicability to the behaviour of radioactive waste or fallout, and the ability to study the mechanisms, reversibility and kinetics of environmental reactions under controlled conditions. These attributes are demonstrated using specific examples drawn from case studies in Australia, including radionuclide fallout onto tropical soils, the association of trace metals with harbour sediments and the behaviour of uranium in natural and contaminated systems.