垃圾处理厂不应成为新的污染源

垃圾填埋场在填埋垃圾以后,会产生高浓度的有机废水,即渗滤液。渗滤液的特点是成分复杂、有机物含量高,垃圾填埋以后渗滤液会连续多年持续产生。因此,为防止对环境的污染,垃圾填埋场必须对渗滤液进行处理,达标后方可排放。     

生活垃圾填埋场渗滤液全量处理模式探索——以四川某填埋场环境整治为例

为解决生活垃圾填埋场渗滤液系统的设计处理能力与实际需求不匹配，以及处理过程产生的膜浓缩液回灌等将引发一系列环境风险和隐患。以四川省某生活垃圾填埋场渗滤液处理改造项目为例，采用“两级A/O+两级Fenton+BAF”处理工艺，实现了渗滤液的“全量化”处理，有效避免了膜浓缩液的产生。运行结果表明，全量处理模式能有效提高渗滤液处理系统的处理效果和能力，保证渗滤液能及时有效排出，避免了渗滤液处理系统的膜液产生和回灌问题，从而缓解和改善填埋场存在的环境风险和隐患。     

垃圾填埋场渗滤液回灌技术研究

垃圾填埋场会产生大量的垃圾渗滤波,垃圾渗滤液回灌可以利用填埋场内微生物加速分解其中的有机物,同时可以利用回灌控制填埋场的含水量,促进填埋场的稳定.本文概括了渗滤液回灌处理的理论基础、工艺流程,分析了回灌技术的影响因素,并对表面回灌和地下回灌方式进行了比较,指出了推广应用垃圾渗滤液回灌处理技术需要解决的几点问题.     

城市垃圾填埋场渗滤液处理工艺综述

城市垃圾对环境的影响越来越严重，垃圾填埋导致垃圾渗滤液的大量产生，渗滤液中含有大量的有机物、大量的病菌、病毒、寄生虫等以及一些有毒有害的物质，若渗滤液不加以妥善处理、肆意排放，必将对地下水、地表水构成严重威胁，因此垃圾渗滤液的有效处理就成为一个亟待解决的问题。本文对城市垃圾填埋场渗滤液的处理工艺进行了分析和探讨，介绍了国内外垃圾渗滤液处理的主要技术，包括土地处理法、生物法和物化法，并对电解法处理垃圾渗滤液进行了详细的介绍。     

垃圾填埋场渗滤液组合处理技术

正由沈阳光大环保科技有限公司开发的垃圾填埋场渗滤液组合处理技术,适用于生活垃圾填埋场渗滤液处理。主要技术内容一、基本原理主体工艺为"预处理+反硝化+好氧生化(硝化)+膜法"处理。渗滤液废水收集排入调节池,经预处理后进入高效A池,由后续TMBR分离系统回流的活性污泥在缺氧条件下发生反硝化反应;反硝化池出水重力流入好氧硝化池内,利用活性污泥将碳源有机物降解,将污水中的氨氮氧化成亚硝酸盐和硝酸盐,使氨氮得到降解。     

不同埋龄垃圾渗滤液中有机物在矿化垃圾床内的转化与去除

研究利用矿化垃圾床在准好氧工况下处理不同埋龄垃圾渗滤液,对渗滤液水质如COD、BOD、氨氮和总氮等几项指标进行了监测,分析了矿化垃圾床对两种渗滤液的处理效果。结果表明,矿化垃圾床对老龄和年轻垃圾渗滤液的COD处理率分别达70.21%和88.09%,但两者出水的B/C值均0.04。同时,在对三维荧光和紫外可见光谱的分析中得出,年轻垃圾渗滤液的出水中几乎不含小分子色氨酸类有机物。并且分子量分布结果表明两体系内的小分子类有机物占比均有所提高,表明了准好氧矿化垃圾床优先降解渗滤液中的大分子有机物,使得小分子有机物占比提高。因此,准好氧矿化垃圾床可应用于不同填埋龄垃圾渗滤液的前处理中,且效果良好。     

厌氧-准好氧型填埋的渗滤液实验研究

通过室内模拟试验，在渗滤液回灌的厌氧填埋柱基本进入稳定状态后，改用准好氧运行方式。同时监测了渗滤液中有机物浓度以压温度、pH值的变化。改变模拟垃圾柱的运行方式两个月以后。氨氯浓度由2000mg／L迅速下降至101．48mg／L，试验结果显示，准好氧运行方式可以解决生物反应器填埋场进入稳定阶段后存在的氨氮浓度高的问题，加速填埋场的稳定。     

生活垃圾生物反应器填埋场的试验研究--渗滤液处理技术的发展与改良

采用生物反应器填埋场消纳生活垃圾，通过改变模拟生物反应器填埋场实验垃圾柱的装填方式和运行方式，对不同垃圾柱的渗滤液水质变化特征进行分析，试验表明，生物反应器填埋场具有稳定时间短，渗滤液污染强度削减快，给后续的渗滤处理系统的设计及运行带来极大的便利。     

应用反渗透技术处理垃圾填埋场渗滤液

垃圾填埋场渗滤液属于高浓度氨氮废水,其水量、水质特性变化大,成分复杂,因此较难处理。反渗透分离技术能有效截留垃圾渗滤液中溶解态的有机和无机污染物。采用三级反渗透处理垃圾渗滤液工艺处理后的出水水质,能够满足《生活垃圾填埋污染控制标准》（DB16889-2008）要求,并把渗滤液浓缩液回灌于填埋场。     

北京市垃圾填埋场地下水中砷、汞含量分析

生活垃圾的处置一直以填埋为主,垃圾填埋承载着巨大的环境压力,尤其是垃圾填埋产生的渗滤液会对地下水造成砷、汞污染。为了解北京市生活垃圾填埋场地下水砷、汞污染水平,在北京市5座生活垃圾填埋场布设采样点,采集36个地下水样品,采用氢化物发生-原子荧光法,分析了地下水砷、汞含量特征。结果表明,36个地下水样品砷浓度范围0.41~4.82μg/L,汞浓度范围0.024~0.121μg/L,北京市典型垃圾填埋场地下水样品不存在砷、汞污染问题。     

Quality and Quantity of Leachate in Aerobic Pilot-Scale Landfills

In this study, two pilot-scale aerobic landfill reactors with (A1) and without (A2) leachate recirculation are used to obtain detailed information on the quantity and quality of leachate in aerobic landfills. The observed parameters of leachate quality are pH, chloride (Cl⁻), chemical oxygen demand (COD), biological oxygen demand (BOD), total Kjeldahl nitrogen (TKN), ammonia nitrogen (NH₃-N), and nitrate (NO₃^–-N). pH values of the leachate increased to 7 after 50 days in reactor A1 and after 70 days in reactor A2. Cl⁻ concentrations increased rapidly to 6100 (A1) and 6900 (A2) mg/L after 80 days, from initial values of 3000 and 2800 mg/L, respectively. COD and BOD values decreased rapidly in the A1 landfill reactor, indicating the rapid oxidation of organic matter. The BOD/COD ratio indicates that leachate recirculation slightly increases the degradation of solid waste in aerobic landfills. NH₃-N concentrations decreased as a result of the nitrification process. Denitrification occurred in parts of the reactors as a result of intermittent aeration; this process causes a decrease in NO₃⁻ concentrations. There is a marked difference between the A1 and A2 reactors in terms of leachate quantity. Recirculated leachate made up 53.3% of the leachate generated from the A1 reactor during the experiment, while leachate quantity decreased by 47.3% with recirculation when compared with the aerobic dry landfill reactor.     

Critical review for the quantification of leachate production: Evaluation example for the “Oum Azza” public landfill in Rabat city,Morocco

The estimation of leachate quantities produced in landfills is necessary to dimension the treatment plants allowing to reduce the polluting load of these effluents and consequently avoid their negative impacts on the environment. Different leachate quantification methods were used in this study to assess the leachate volume produced at the Oum Azza landfill. The water balance method give comparable estimations of leachate production to the Ouled Berjal landfill ratio. The first method showed average values between 487 and 495 m³/day for 2015, 2018, and 2019, and at the same time, the second method gave values between 470 and 477 m³/day for the same years. In contrast, the World Bank ratio showed high values that vary between 2260 and 2295 m³/day for 2015, 2018, and 2019. The on-site data and the statistical analysis showed us that the World Bank ratio is not adapted for the estimation of the leachates produced in Oum Azza landfill, while the water balance and the ratio of Ouled Berjal landfill allowed to give comparable results to reality.     

Landfill Bioreactor Cells as Ecofilters for Extraction of Bio-energy and Nutrients from Solid Wastes

This paper describes a modified, ecologically based waste treatment technique, where municipal solid waste is anaerobically treated in landfill reactorcells in a way that both bio-energy and nutrients can be recovered. The controlled landfill reactorcell ('bioreactor-cell') serves as an anaerobic filter, where energy is extracted as biogas while nutrients are recovered through the leachates. The leachates can be used as fertilizer in e.g. energy forests within the controlled landfill area, and thus nutrients can be brought back into an ecocycle. At the same time anaerobic conditions result in an effective immobilization of heavy metals and other pollutants, e.g. through complexation to organic matter or as insoluble metal sulphides, which are immobilized in the fermentation residue. The long-lived organic fraction, remaining after the fermentation process has declined, containing a high content of lignine, serves as a water-holding matrix. Thus it helps to enforce a sustainable high moisture level, resulting in sustainable anaerobic conditions with heavy metals retained on a long-term basis. Also non-degradable products, like plastics, help to shield off oxygen and maintain reliable anaerobic conditions. Landfilling of organic matter under anaerobic conditions is a measure to counteract increasing concentrations of CO₂ in the atmosphere, resulting from human activities. A small fraction of the organic matter is long-term accumulated in the landfill, and the processes can be compared to those of natural wetlands.     

磷酸氨镁法处理晚期垃圾渗滤液氨氮最佳工艺条件

高浓度氨氮（NH^＋4-N）是造成晚期垃圾渗滤液难以生物处理的重要原因之一,当前物化法处理垃圾渗滤液中氨氮存在不足。磷酸氨镁（MAP）沉淀法可以彻底地去除晚期垃圾渗滤液中NH^＋4-N,而且生成的沉淀物是非常好的缓释肥料,具有较高的经济价值及应用前景。研究结果表明,最佳的工艺条件为：pH=8.5-9.5,n（N）：n（Mg）：n（P）=1：1：1时,处理效果较好,NH^＋4-N去除率大于96％,且残余总磷（TP）浓度小于原水值。     

Screening for organotin compounds in European landfill leachates

As industrial chemicals, organotin compounds are predominantly applied as polyvinyl chloride (PVC) stabilizers and biocides. They are widely encountered in environmental samples and may be introduced into landfills by disposal of municipal solid waste or sewage sludge. In the present study, leachate samples were obtained from several sanitary landfill sites in Sweden, Italy, and Germany. These samples were analyzed by means of a highly sensitive and species-selective method for methyltin, butyltin, and octyltin species. In total, twelve samples from eight different landfill sites at various ages were investigated. The findings of all target compounds range between less than the limit of detection at 0.1 microg/L and, at maximum, 4 microg/L. Only octyltin compounds can be attributed to PVC products with any certainty, whereas for methyltin and butyltin compounds alternative and less distinct sources exist. Organotin compounds are subject to microbial transformation, such as dealkylation and methylation processes. Consequently, caution should be exercised when attributing findings to potential sources and deriving any predicted environmental concentrations.     

GROUND AND SURFACE WATER QUALITY IMPACTS OF NORTH CAROLINA SANITARY LANDFILLS1

ABSTRACT: Ground and surface water quality monitoring data from 71 municipal sanitary landfills in North Carolina were analyzed to determine the nature and extent of current contamination problems and identify any common characteristics associated with this contamination. A total of 322 surface and 411 ground water quality records were analyzed using the SAS data system. Almost all the landfill records included inorganic and heavy metal analyses while approximately half of the records also included organic analyses by CC/MS. Our analysis indicates that landfills are having measurable impacts on ground and surface water quality, but these impacts may not be as severe as is commonly assumed. Statistically significant increases were detected in the average concentrations in ground water and downstream surface water samples when compared to upstream surface water samples. The largest percentage increases were observed for zinc, turbidity, total organic carbon, conductivity, total dissolved solids, and lead. Violations of ground water quality standards for heavy metals and hazardous organic compounds were detected at 53 percent of the landfills where adequate data existed. The moat common heavy metal violations were for lead (18 percent), chromium (18 percent), zinc (6 percent), cadmium (6 percent), and arsenic (6 percent) (percentage of landfills violating shown in parenthesis). The organic compounds that appear to pose the greatest threat to ground water are the chlorinated solvents (8 percent), petroleum derived hydrocarbons (8 percent), and pesticides (5 percent). A comparison of monitoring data from sanitary landfills and secondary wastewater treatment plants suggests that the concentrations of heavy metal and organic pollutants discharged to surface waters from these two sources are similar.     

渗滤液回灌在实际应用中应注意的问题

本文介绍了垃圾填埋场渗滤液回灌的机理、优缺点,“干填埋”与“湿填埋”之间的区别。渗滤液回灌可增加填埋废物的含水率,加快垃圾的降解速率,减少渗滤液的处理时间,提高填埋气中甲烷的含量,加速填埋场稳定化进程。鉴于以上这些优点,渗滤液回灌作为一种渗滤液处理方式将会有极大的应用前景。但在实际应用中回灌的渗滤液容易泄漏而导致地下水污染,这是影响渗滤液回灌广泛应用的主要原因。为了避免使地下水受污染,本文总结和分析了渗滤液回灌在实际应用中应注意的问题。     

Metal pollution in sediments of Jamaica Bay,New York,USA—An urban estuary

Calculations of the annual input of heavy metals to Jamaica Bay, New York, USA, reveal that sewage effluent carries the largest quantities of Ni, Zn, Cu, and Cd to the bay. Storm sewers and atmospheric fallout are the main sources of Pb. Atmospheric fallout of Zn, Cu, and Cd, although smaller than the combined input from sewers, contributes a significant fraction of these metals. The metal input from landfill leachate is far smaller than that from other sources. Analysis of available data shows that metal concentrations in the sediment of the bay correlate with each other and with percent total organic carbon (%TOC). This is consistent with the observation that the input of metals is predominantly associated with sewage. It is demonstrated that metal-TOC ratios, rather than metal concentrations, must be used in efforts to detect local intensive sources of metals in solution; metal-TOC ratios in intertidal sediment adjacent to these landfills are elevated by the adsorption of leachate metals, while metal concentrations are not. Subtidal sediment within a few hundred meters from two landfills shows no evidence of the addition of metals from that source, which is consistent with the small input of metals estimated for these landfills. The evidence cited in this study sharply contradicts the implication made in a widely publicized report issued by an environmental advocacy group that a significant link exists between metals found in subtidal sediment of Jamaica Bay and landfill leachate.