EVALUATION OF A STREAM AQUIFER ANALYSIS TEST USING ANALYTICAL SOLUTIONS AND FIELD DATA1

ABSTRACT: Considerable advancements have been made in the development of analytical solutions for predicting the effects of pumping wells on adjacent streams and rivers. However, these solutions have not been sufficiently evaluated against field data. The objective of this research is to evaluate the predictive performance of recently proposed analytical solutions for unsteady stream depletion using field data collected during a stream/aquifer analysis test at the Tamarack State Wildlife Area in eastern Colorado. Two primary stream/aquifer interactions exist at the Tamarack site: (1) between the South Platte River and the alluvial aquifer and (2) between a backwater stream and the alluvial aquifer. A pumping test is performed next to the backwater stream channel. Drawdown measured in observation wells is matched to predictions by recently proposed analytical solutions to derive estimates of aquifer and streambed parameters. These estimates are compared to documented aquifer properties and field measured streambed conductivity. The analytical solutions are capable of estimating reasonable values of both aquifer and streambed parameters with one solution capable of simultaneously estimating delayed aquifer yield and stream flow recharge. However, for long term water management, it is reasonable to use simplified analytical solutions not concerned with early‐time delayed yield effects. For this site, changes in the water level in the stream during the test and a varying water level profile at the beginning of the pumping test influence the application of the analytical solutions.     

Using heat to characterize streambed water flux variability in four stream reaches

Estimates of streambed water flux are needed for the interpretation of streambed chemistry and reactions. Continuous temperature and head monitoring in stream reaches within four agricultural watersheds (Leary Weber Ditch, IN; Maple Creek, NE; DR2 Drain, WA; and Merced River, CA) allowed heat to be used as a tracer to study the temporal and spatial variability of fluxes through the streambed. Synoptic methods (seepage meter and differential discharge measurements) were compared with estimates obtained by using heat as a tracer. Water flux was estimated by modeling one-dimensional vertical flow of water and heat using the model VS2DH. Flux was influenced by physical heterogeneity of the stream channel and temporal variability in stream and ground-water levels. During most of the study period (April-December 2004), flux was upward through the streambeds. At the IN, NE, and CA sites, high-stage events resulted in rapid reversal of flow direction inducing short-term surface-water flow into the streambed. During late summer at the IN site, regional ground-water levels dropped, leading to surface-water loss to ground water that resulted in drying of the ditch. Synoptic measurements of flux generally supported the model flux estimates. Water flow through the streambed was roughly an order of magnitude larger in the humid basins (IN and NE) than in the arid basins (WA and CA). Downward flux, in response to sudden high streamflows, and seasonal variability in flux was most pronounced in the humid basins and in high conductivity zones in the streambed.     

PESTICIDES IN GROUND WATER: DO ATRAZINE METABOLITES MATTER?1

ABSTRACT: Atrazine and atrazine-residue (atrazine + two metabolites - deethylatrazine and deisopropylatrazine) concentrations were examined to determine if consideration of these atrazine metabolites substantially adds to our understanding of the distribution of this pesticide in groundwater of the midcontinental United States. The mean of atrazine.residue concentrations was 53 percent greater than that of atrazine alone for those observations above the detection limit (> 0.05 μg/l). Furthermore, a censored regression analysis using atrazine-residue concentrations revealed significant factors not identified when only atrazine concentrations were used. Thus, knowledge of concentrations of these atrazine metabolites is required to obtain a true estimation of risk of using these aquifers as sources for drinking water, and such knowledge also provides information that ultimately may be important for future management policies designed to reduce atrazine concentrations in ground water.     

Effects of watershed-scale land use change on stream nitrate concentrations

The Walnut Creek Watershed Monitoring Project was conducted from 1995 through 2005 to evaluate the response of stream nitrate concentrations to changing land use patterns in paired 5000-ha Iowa watersheds. A large portion of the Walnut Creek watershed is being converted from row crop agriculture to native prairie and savanna by the U.S. Fish and Wildlife Service at the Neal Smith National Wildlife Refuge (NSNWR). Before restoration, land use in both Walnut Creek (treatment) and Squaw Creek (control) watersheds consisted of 70% row crops. Between 1990 and 2005, row crop area decreased 25.4% in Walnut Creek due to prairie restoration but increased 9.2% in Squaw Creek due to Conservation Reserve Program (CRP) grassland conversion back to row crop. Nitrate concentrations ranged between <0.5 to 14 mg L(-1) at the Walnut Creek outlet and 2.1 to 15 mg L(-1) at the downstream Squaw Creek outlet. Nitrate concentrations decreased 1.2 mg L(-1) over 10 yr in the Walnut Creek watershed but increased 1.9 mg L(-1) over 10 yr in Squaw Creek. Changes in nitrate were easier to detect and more pronounced in monitored subbasins, decreasing 1.2 to 3.4 mg L(-1) in three Walnut Creek subbasins, but increasing up to 8.0 and 11.6 mg L(-1) in 10 yr in two Squaw Creek subbasins. Converting row crop lands to grass reduced stream nitrate levels over time in Walnut Creek, but stream nitrate rapidly increased in Squaw Creek when CRP grasslands were converted back to row crop. Study results highlight the close association of stream nitrate to land use change and emphasize that grasslands or other perennial vegetation placed in agricultural settings should be part of a long-term solution to water quality problems.     

ORIGIN AND TRANSPORT OF DISSOLVED CHEMICALS IN A KARST WATERSHED,SOUTHWESTERN ILLINOIS1

ABSTRACT: An extensive base of water quality information emphasizing the effects of land use and hydrology was obtained in the karstified Fountain Creek watershed of southwestern Illinois to help resolve local water quality issues. Agrichemicals dominate the loads of most water quality constituents in the streams and shallow karstic ground water. Only calcium (Ca), magnesium (Mg), Aluminum (A1), and sulfate (SO₄) ions are predominantly derived from bedrock or soils, while agrichemicals contribute most of the sodium (Na), potassium (K), chlorine (Cl), nitrate (NO₃), fluorine (F), phosphorus (P), and atrazine. Concentrations of individual ions correlate with discharge variations in karst springs and surface streams; highly soluble ions supplied by diffuse ground water are diluted by high flows, while less soluble ions increase with flow as they are mobilized from fields to karst conduits under storm conditions. Treated wastewater containing detergent residues dominates the boron load of streams and provides important subordinate loads of several other constituents, including atrazine derived from the Mississippi River via the public water supply. Average surface water concentrations at the watershed outlet closely approximate a 92:8 mixture of karst ground water and treated wastewater, demonstrating the dominance of ground water contributions to streams. Therefore the karst aquifer and watershed streams form a single water quality system that is also affected by wastewater effluent.     

HERBICIDE AND NITRATE VARIATION IN ALLUVIUM UNDERLYING A CORN FIELD AT A SITE IN IOWA COUNTY,IOWA1

ABSTRACT: A hydrologic investigation to determine vertical and seasonal variation of atrazine, alachlor, cyanazine, and nitrate at one location and to relate the variation to ground-water movement in the Iowa River alluvium was conducted in Iowa County, Iowa, from March 1986 to December 1987. Water samples were collected at discrete intervals through the alluvial sequence from the soil zone to the base of the aquifer. Alachlor, atrazine, and cyanazine were detected most frequently in the soil zone but also were present in the upper part of the alluvial aquifer. Alachlor was detected sporadically, whereas, atrazine, cyanazine, and nitrate were present throughout the year. In the alluvial aquifer, the herbicides generally were not detected during 1986 and were present in detectable concentrations for only a short period of time in the upper 1.6 meters of the aquifer during 1987. Nitrate was present throughout the alluvium and was stratified in the alluvial aquifer. The largest nitrate concentrations were detected in the middle part of the aquifer. Nitrate concentrations were variable only in the upper 2 meters of the aquifer. Vertical movement of herbicides and nitrate in the soil correlated with precipitation and degree of saturation. A clay layer retarded vertical movement of atrazine but not nitrate from the soil layer to the aquifer. Vertical movement could not account for the chemical variation in the alluvial aquifer.     

RELATION BETWEEN STREAM-WATER QUALITY AND GEOHYDROLOGY DURING BASE-FLOW CONDITIONS,ROBERTS CREEK WATERSHED,CLAYTON COUNTY,IOWA1

ABSTRACT: An investigation to determine the relation between stream water quality and geohydrology in the Roberts Creek watershed, Clayton County, Iowa, was conducted during selected base-flow periods in 1988–90. Discharge measurements were made and water samples collected for analyses of nutrients and selected herbicides in 19 subbasins along the main stem and tributaries of Roberts Creek. The areal extent of unconsolidated and bedrock units subcropping in each subbasin was quantified. The hydrologic data were correlated statistically with the geologic data to determine relations. Roberts Creek generally gained water and had larger nitrogen concentrations in subbasins in which bess and alluvial material were underlain primarily by low-permeability till and shale units. Roberts Creek generally lost water and had lower nitrate concentrations in subbasins with subcroppmg karstic units. Nitrogen concentrations decreased in streams underlain by the karstic units because the nitrogen removed by biological processes was not replaced by ground-water inflow. Seepage from Roberts Creek to ground water in areas of subcropping karstic carbonate rocks reduced the flow, which reduced the velocity, causing increased residence time of water in the stream. The additional residence time may allow additional time for biological processes to remove nitrogen from solution. There was no significant relation between dissolved orthophosphate or atrazine and the underlying geology.     

Anaerobic degradation of atrazine and metolachlor and metabolite formation in wetland soil and water microcosms

The half-lives, degradation rates, and metabolite formation patterns of atrazine (6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine) and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamide] were determined in an anaerobic wetland soil incubated at 24 degrees C for 112 d. At 0, 7, 14, 28, 42, 56, and 112 d, the soil and water were analyzed for atrazine and metolachlor, and their major metabolites. The soil oxidation-reduction potential reached -200 mV after 14 d. Degradation reaction rates were first-order for atrazine in anaerobic soil and for metolachlor in the aqueous phase. Zero-order reaction rates were best fit for atrazine in the aqueous phase and metolachlor in anaerobic soil. In anaerobic soil, the half-life was 38 d for atrazine and 62 d for metolachlor. In the aqueous phase above the soil, the half-life was 86 d for atrazine and 40 d for metolachlor. Metabolites detected in the anaerobic soil were hydroxyatrazine and deethylatrazine for atrazine, and relatively small amounts of ethanesulfonic acid and oxanilic acid for metolachlor. Metabolites detected in the aqueous phase above the soil were hydroxyatrazine, deethylatrazine, and deisopropylatrazine for atrazine, and ethanesulfonic acid and oxanilic acid for metolachlor. Concentrations of metabolites in the aqueous phase generally peaked within the first 25 d and then declined. Results indicate that atrazine and metolachlor can degrade under strongly reducing conditions found in wetland soils. Metolachlor metabolites, ethanesulfonic acid, and oxanilic acid are not significantly formed under anaerobic conditions.     

UTILIZATION OF A GEOGRAPHIC INFORMATION SYSTEM TO IDENTIFY THE PRIMARY AQUIFER PROVIDING GROUND WATER TO INDWIDUAL WELLS IN EASTERN ARKANSAS1

ABSTRACT: A Geographic Information System (GIS) was used to develop an automated procedure for identifying the primary aquifers supplying ground water to individual wells in eastern Arkansas. As mandated by state law, water-use data are reported by ground-water withdrawers annually to the Arkansas Soil and Water Conservation Commission, and stored in the Arkansas Site-Specific Water-Use Data System provided and supported by the U.S. Geological Survey. Although most withdrawers are able to provide the amount of water withdrawn and the depth of their wells, very few are able to provide the name of the aquifer from which they withdraw water. GIS software was used to develop an automated procedure for identifying the primary aquifers supplying ground water to individual wells in eastern Arkansas. The software was used to generate a spatial representation of the bottom boundary for the Mississippi River Valley alluvial aquifer (the shallowest aquifer) in eastern Arkansas from well log-data collected by the U.S. Geological Survey. The software was then used to determine the depth of the aquifer bottom at reported well locations to ascertain whether the Mississippi River Valley alluvial aquifer or a deeper aquifer was the primary aquifer providing water to each well. The alluvial aquifer was identified as the primary aquifer for about 23,500 wells.     

Transport and fate of nitrate and pesticides: hydrogeology and riparian zone processes

There is continuing concern over potential impacts of widespread application of nutrients and pesticides on ground- and surface-water quality. Transport and fate of nitrate and pesticides were investigated in a shallow aquifer and adjacent stream, Cow Castle Creek, in Orangeburg County, South Carolina. Pesticide and pesticide degradate concentrations were detected in ground water with greatest frequency and largest concentrations directly beneath and downgradient from the corn (Zea mays L.) field where they were applied. In almost all samples in which they were detected, concentrations of pesticide degradates greatly exceeded those of parent compounds, and were still present in ground waters that were recharged during the previous 18 yr. The absence of both parent and degradate compounds in samples collected from deeper in the aquifer suggests that this persistence is limited or that the ground water had recharged before use of the pesticide. Concentrations of NO(-)(3) in ground water decreased with increasing depth and age, but denitrification was not a dominant controlling factor. Hydrologic and chemical data indicated that ground water discharges to the creek and chemical exchange takes place within the upper 0.7 m of the streambed. Ground water had its greatest influence on surface-water chemistry during low-flow periods, causing a decrease in concentrations of Cl(-), NO(-)(3), pesticides, and pesticide degradates. Conversely, shallow subsurface drainage dominates stream chemistry during high-flow periods, increasing stream concentrations of Cl(-), NO(-)(3), pesticides, and pesticide degradates. These results point out the importance of understanding the hydrogeologic setting when investigating transport and fate of contaminants in ground water and surface water.     

WALNUT CREEK WATERSHED MONITORING PROJECT,IOWA MONITORING WATER QUALITY IN RESPONSE TO PRAIRIE RESTORATION1

ABSTRACT: Land use and surface water data for nitrogen and pesticides (1995 to 1997) are reported for the Walnut Creek Watershed Monitoring Project, Jasper County Iowa. The Walnut Creek project was established in 1995 as a nonpoint source monitoring program in relation to watershed habitat restoration and agricultural management changes implemented at the Neal Smith National Wildlife Refuge by the U.S. Fish and Wildlife Service. The monitoring project utilizes a paired‐watershed approach (Walnut and Squaw creeks) as well as upstream/downstream comparisons on Walnut for analysis and tracking of trends. From 1992 to 1997, 13.4 percent of the watershed was converted from row crop to native prairie in the Walnut Creek watershed. Including another 6 percent of watershed farmed on a cash‐rent basis, land use changes have been implemented on 19.4 percent of the watershed by the USFWS. Nitrogen and pesticide applications were reduced an estimated 18 percent and 28 percent in the watershed from land use changes. Atrazine was detected most often in surface water with frequencies of detection ranging from 76–86 percent. No significant differences were noted in atrazine concentrations between Walnut and Squaw Creek. Nitrate‐N concentrations measured in both watersheds were similar; both basins showed a similar pattern of detection and an overall reduction in nitrate‐N concentrations from upstream to downstream monitoring sites. Water quality improvements are suggested by nitrate‐N and chloride ratios less than one in the Walnut Creek watershed and low nitrate‐N concentrations measured in the subbasin of Walnut Creek containing the greatest amount of land use changes. Atrazine and nitrate‐N concentrations from the lower portion of the Walnut Creek watershed (including the prairie restoration area) may be decreasing in relation to the upstream untreated component of the watershed. The frequencies of pesticide detections and mean nitrate‐N concentrations appear related to the percentage of row crop in the basins and subbasins. Although some results are encouraging, definitive water quality improvements have not been observed during the first three years of monitoring. Possible reasons include: (1) more time is needed to adequately detect changes; (2) the size of the watershed is too large to detect improvements; (3) land use changes are not located in the area of the watershed where they would have greatest effect; or (4) water quality improvements have occurred but have been missed by the project monitoring design. Longer‐term monitoring will allow better evaluation of the impact of restoration activities on water quality.     

Herbicides in ground water beneath Nebraska's Management Systems Evaluation Area

Profiles of ground water pesticide concentrations beneath the Nebraska Management Systems Evaluation Area (MSEA) describe the effect of 20 yr of pesticide usage on ground water in the central Platte Valley of Nebraska. During the 6-yr (1991-1996) study, 14 pesticides and their transformation products were detected in 7848 ground water samples from the unconfined water table aquifer. Triazine and acetamide herbicides applied on the site and their transformation products had the highest frequencies of detection. Atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4,-diamine] concentrations decreased with depth and ground water age determined with 3H/3He dating techniques. Assuming equivalent atrazine input during the past 20 yr, the measured average changes in concentration with depth (age) suggest an estimated half-life of >10 yr. Hydrolysis of atrazine and deethylatrazine (DEA; 2-chloro-4-amino-6-isopropylamino-s-triazine) to hydroxyatrazine [6-hydroxy-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4-diamine] appeared to be the major degradation route. Aqueous hydroxyatrazine concentrations are governed by sorption on the saturated sediments. Atrazine was detected in the confined Ogallala aquifer in ultra-trace concentrations (0.003 microg L(-1)); however, the possibility of introduction during reverse circulation drilling of these deep wells cannot be eliminated. In fall 1997 sampling, metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamide] was detected in 57% of the 230 samples. Metolachlor oxanilic acid [(2-ethyl-6-methylphenyl)(2-methoxy-1-methylethyl) amino]oxo-acetic acid] was detected in most samples. In ground water profiles, concentrations of metolachlor ethane sulfonic acid [2-[(ethyl-6-methylphenyl)(2-methoxy-1-methylethyl)amino]-2-oxo-ethanesulfonic acid] exceeded those of deethylatrazine. Alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide] was detected in <1% of the samples; however, alachlor ethane sulfonic acid [2-[(2,6-diethylphenyl)(methoxymethyl)amino]-2-oxoethanesulfonic acid] was present in most samples (63%) and was an indicator of past alachlor use.     

Chemical and toxicologic assessment of organic contaminants in surface water using passive samplers

Passive sampling methodologies were used to conduct a chemical and toxicologic assessment of organic contaminants in the surface waters of three geographically distinct agricultural watersheds. A selection of current-use agrochemicals and persistent organic pollutants, including polycyclic aromatic hydrocarbons, polychlorinated biphenyls, and organochlorine pesticides, were targeted using the polar organic chemical integrative sampler (POCIS) and the semipermeable membrane device passive samplers. In addition to the chemical analysis, the Microtox assay for acute toxicity and the yeast estrogen screen (YES) were conducted as potential assessment tools in combination with the passive samplers. During the spring of 2004, the passive samplers were deployed for 29 to 65 d at Leary Weber Ditch, IN; Morgan Creek, MD; and DR2 Drain, WA. Chemical analysis of the sampler extracts identified the agrochemicals predominantly used in those areas, including atrazine, simazine, acetochlor, and metolachlor. Other chemicals identified included deethylatrazine and deisopropylatrazine, trifluralin, fluoranthene, pyrene, cis- and trans-nonachlor, and pentachloroanisole. Screening using Microtox resulted in no acutely toxic samples. POCIS samples screened by the YES assay failed to elicit a positive estrogenic response.     

Groundwater and surface-water exchange and resulting nitrate dynamics in the Bogue Phalia basin in northwestern Mississippi

During April 2007 through September 2008, the USGS collected hydrogeologic and water-quality data from a site on the Bogue Phalia to evaluate the role of groundwater and surface-water interaction on the transport of nitrate to the shallow sand and gravel aquifer underlying the Mississippi Alluvial Plain in northwestern Mississippi. A two-dimensional groundwater/surface-water exchange model was developed using temperature and head data and VS2DH, a variably saturated flow and energy transport model. Results from this model showed that groundwater/surface-water exchange at the site occurred regularly and recharge was laterally extensive into the alluvial aquifer. Nitrate was consistently reported in surface-water samples (n = 52, median concentration = 39.8 μmol/L) although never detected in samples collected from in-stream piezometers or shallow monitoring wells adjacent to the stream (n = 46). These two facts, consistent detections of nitrate in surface water and no detections of nitrate in groundwater, coupled with model results that indicate large amounts of surface water moving through an anoxic streambed, support the case for denitrification and nitrate loss through the streambed.     

Herbicide loading to shallow ground water beneath Nebraska's Management Systems Evaluation Area

Better management practices can counter deterioration of ground water quality. From 1991 through 1996 the influence of improved irrigation practices on ground water pesticide contamination was assessed at the Nebraska Management Systems Evaluation Area. Three 13.4-ha corn (Zea mays L.) fields were studied: a conventional furrow-irrigated field, a surge-irrigated field and a center pivot-irrigated field, and a center pivot-irrigated alfalfa (Medicago sativa L.) field. The corn fields received one identical banded application of Bicep (atrazine [6-chloro-N-ethyl-N'-(1-methylethyl)-1,3,5-triazine-2,4,-diamine] + metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl) acetamidel) annually; the alfalfa field was untreated. Ground water samples were collected three times annually from 16 depths of 31 multilevel samplers. Six years of sample data indicated that a greater than 50% reduction in irrigation water on the corn management fields lowered average atrazine concentrations in the upper 1.5 m of the aquifer downgradient of the corn fields from approximately 5.5 to <0.5 microg L(-1). Increases in deethylatrazine (DEA; 2-chloro-4-amino-6-isopropylamino-s-triazine) to atrazine molar ratios indicated that reducing water applications enhanced microbial degradation of atrazine in soil zones. The occurrence of peak herbicide loading in ground water was unpredictable but usually was associated with heavy precipitation within days of herbicide application. Focused recharge of storm runoff that ponded in the surge-irrigated field drainage ditch, in the upgradient road ditch, and at the downgradient end of the conventionally irrigated field was a major mechanism for vertical transport. Sprinkler irrigation technology limited areas for focused recharge and promoted significantly more soil microbial degradation of atrazine than furrow irrigation techniques and, thereby, improved ground water quality.     

STREAMBED HYDRAULIC CONDUCTIVITY FOR RIVERS IN SOUTH‐CENTRAL NEBRASKA1

ABSTRACT: This paper presents hydraulic conductivities of streambeds measured in three rivers in south‐central Nebraska: the Platte, Republican, and Little Blue Rivers. Unlike traditional permeameter tests in streams that determine only the vertical hydraulic conductivity (K_v), the extended permeameter methods used in this study can measure K in both vertical and horizontal as well as oblique directions. As a result, the anisotropy of channel sediments can be determined from streambed tests of similar sediment volumes. Sandy streambeds with occasional silt/clay layers exist in the Republican and Platte Rivers. The average K_v values range from about 15 to 47 m/day for the sandy streambed and about 1.6 m/day for the silt/clay layers. Statistical analyses indicated that the K_v values of sand and gravel in the Platte and Republican Rivers essentially have the same mean; but the K_v values from the Little Blue River have a statistically different mean. K_v is about four times smaller than the horizontal hydraulic conductivity (K_h) for the top 40 cm of sandy streambed. Measured K_h values of the sandy streambed are in the same magnitude as the K_h of the alluvial aquifer determined using pumping tests. The smaller K_v value in the whole aquifer is the result of interbedded layers of silt and clay within the sand and gravel sediments.     

Differentiating nonpoint sources of deisopropylatrazine in surface water using discrimination diagrams

Pesticide degradates account for a significant portion of the pesticide load in surface water. Because pesticides with similar structures may degrade to the same degradate, it is important to distinguish between different sources of parent compounds that have different regulatory and environmental implications. A discrimination diagram, which is a sample plot of chemical data that differentiates between different parent compounds, was used for the first time to distinguish whether sources other than atrazine (6-chloro-N2-ethyl-N4-isopropyl-1,3,5-triazine-2,4-diamine) contributed the chlorinated degradate, deisopropylatrazine (DIA; 6-chloro-N-ethyl-1,3,5-triazine-2,4-diamine) to the Iroquois and Delaware Rivers. The concentration ratio of deisopropylatrazine to deethylatrazine [6-chloro-N-(1-methylethyl)1,3,5-triazine-2,4-diamine], called the D2R, was used to discriminate atrazine as a source of DIA from other parent sources, such as cyanazine (2-[[4-chloro-6-(ethylamino)-1,3,5-triazin-2-yl]amino]-2-methylpropionitrile) and simazine (6-chloro-N,N'-diethyl-1,3,5-triazine-2,4diamine). The ratio of atrazine to cyanazine (ACR) used in conjunction with the D2R showed that after atrazine, cyanazine was the main contributor of DIA in surface water. The D2R also showed that cyanazine, and to a much lesser extent simazine, contributed a considerable amount (approximately 40%) of the DIA that was transported during the flood of the Mississippi River in 1993. The D2R may continue to be a useful discriminator in determining changes in the nonpoint sources of DIA in surface water as cyanazine is currently being removed from the market.     

Evaluation of Ground‐Water and Surface‐Water Exchanges Using Streamflow Difference Analyses1

Abstract: In the karstic lower Flint River Basin, limestone fracturing, jointing, and subsequent dissolution have resulted in the development of extensive secondary permeability and created a system of major conduits that facilitate the exchange of water between the Upper Floridan aquifer and Flint River. Historical streamflow data from U.S. Geological Survey gaging stations located in Albany and Newton, Georgia, were used to quantify ground‐water and surface‐water exchanges within a 55.3 km section of the Flint River. Using data from 2001, we compared estimates of ground‐water flux using a time adjustment method to a water balance equation and found that these independent approaches yielded similar results. The associated error was relatively large during high streamflow when unsteady conditions prevail, but much lower during droughts. Flow reversals were identified by negative streamflow differences and verified with in situ data from temperature sensors placed inside large spring conduits. Long‐term (13 years) analysis showed negative streamflow differentials (i.e., a losing stream condition) coincided with high river stages and indicated that streamflow intrusion into the aquifer could potentially exceed 150 m³/s. Although frequent negative flow differentials were evident, the Flint River was typically a gaining stream and showed a large net increase in flow between the two gages when examined over the period 1989‐2003. Ground‐water contributions to this stream section averaged 2‐42 m³/s with a mean of 13 m³/s. The highest rate of ground‐water discharge to the Flint River occurred during the spring when regional ground‐water levels peaked following heavy winter and spring rains and corresponding rates of evapotranspiration were low. During periods of extreme drought, ground‐water contributions to the Flint River declined.     

RECHARGE TO ALLUVIAL VALLEY AQUIFERS FROM OVERBANK FLOW AND EXCESS INFILTRATION1

ABSTRACT: Recharge is an important parameter for models that simulate water and contaminant transport in unconfined aquifers. Unfortunately, measurements of actual recharge are not usually available causing recharge to be estimated or possibly added to the calibration procedure. In this study, differences between observed water-table elevations and water-table elevations simulated with a model based on the one-dimensional Boussinesq equation were used to identify both the timing and quantity of recharge to an alluvial valley aquifer. Observed water table elevations and river stage data were recorded during a five-year period from 1991 to 1995 at the Ohio Management Systems Evaluation Area located in south-central Ohio. Direct recharge attributed to overbank flow during and shortly after flood conditions accounted for 65 percent of the total recharge computed during the five-year study period. Recharge of excess infiltration to the aquifer was intermittent and occurred soon after large rainfall events and high river stage. Specification of constant recharge with time values in ground-water simulation models seems inappropriate for stream-aquifer systems given the strong influence of the river on water table elevations in these systems.     

SHALLOW AQUIFERS RELATIVE TO SURFACE WATER,LOWER NORTH PLATTE RIVER VALLEY,WYOMING1

ABSTRACT. The occurrence of ground water in the lower North Platte Valley, Goshen County, Wyoming, was studied to determine safe yield within the alluvial aquifer under varying discharge and recharge conditions. The alluvium of the North Platte is extensively developed for irrigation purposes and the effects of large-scale pumpage are of major concern. Actual withdrawals are estimated to be 46,000 acre-feet. Should pumping reach potentially higher levels an overdraft is expected. Effect of ground water withdrawals are established from projections of the flow regime within the alluvial aquifer. A time dependent, numerical model was employed to predict aquifer response to increased withdrawals. The results suggest that more efficient use of surface waters and/or increased use of ground water will reduce the annual subsurface return flow to the North Platte River and its tributaries by an amount equal to the reduced ground water recharge increment. Alternatives are available for management of the lower North Platte alluvial aquifer. The preferred course is to correlate surface and subsurface water rights, in light of convenience, economics, and best means of storage for maximum utilization of the single water resource.