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1.
Theoretical mathematical models of primary sedimentation and column settling tests have failed until now to predict the behaviour of sedimentation tanks under actual operating conditions due to the difficulties in simulating the effect of the density currents and the complex phenomenon of flocculation. Therefore, empirical models can be helpful in the design of sedimentation tanks. Using performance data from three different pilot-scale sedimentation tanks, empirical mathematical models were developed in this paper relating suspended solids (SS) removal efficiency to surface overflow rate, influent SS concentration, and sewage temperature. The model coefficients were derived from the combined analysis of three well correlated sets of data, thus giving a good indication for their possible general applicability. The analysis of experimental data also gave a relationship between SS and chemical oxygen demand (COD) removal efficiencies.  相似文献   

2.
Nine dredged material land containment areas, located at upland, lowland, and island sites, were monitored during hydraulic dredging operations in fresh and brackish-water riverine, lake, and estuarine environments. Influent/effluent sampling at the diked disposal areas showed that, with proper retention of suspended solids, most chemical constituents could be removed to near background water levels. Most heavy metals, oil and grease, chlorinated pesticides, and PCBs were almost totally associated with solids in both the influent and effluent samples. The parameters that appear to have the greatest potential impact as a result of land disposal of dredged material are ammonia, soluble manganese, total mercury, and dissolved oxygen; soluble iron, zinc, and copper may occasionally exceed criteria or background levels.v However, none of these should present serious problems after dillution of the effluent discharge in the receiving waters. Actively growing vegetation in disposal areas appeared to be efficient in removing ammonium nitrogen to low levels and also for filtering out suspended solids. Dissolved oxygen in effluents ranged from 0.6 to 12.5 ppm. Geochemical phase partitioning of influent and effluent solids indicated that carbonate solids of several heavy metals tended to form during dredged slurry containment, promoted by high alkalinity and increased pH in site waters. Metal adsorption onto effluent suspended particles (exchangeable phase) increased slightly, along with a significant increase in cation exchange capacity.  相似文献   

3.
Human breast milk samples collected in 2007–2008 from four countries, Vietnam (Hanoi), China (Beijing), Korea (Seoul) and Japan (Sendai, Kyoto and Takayama), were analyzed for persistent organic pollutants (POPs) such as dichlorodiphenyltrichloroethane and its metabolites (DDTs), chlordane-related compounds (CHLs), hexachlorocyclohexanes (HCHs), hexachlorobenzene (HCB), polychlorinated biphenyls (PCBs) and polybrominated diphenyl ethers (PBDEs). Comparing with previous surveys, the present study indicates that the DDTs in breast milk from China and Vietnam had gradually decreased during the last decade, but were still 5–10 times higher than those in other nations. The ratios of p,p′-DDE/p,p′-DDT and o,p′-DDT/p,p′-DDT were higher in Beijing than in the other countries, suggesting that there is less fresh intake of commercial DDT products and a possible exposure to dicofol in China. CHL and PCB levels were relatively higher in mothers from Japan, whereas β-HCH and HCB were more common in Chinese women. In Japan, it is suspected that mothers in the urban/coastal area (Sendai) were more continuously exposed to organochlorine pesticides (OCPs) than mothers in the rural/inland area (Takayama). In addition, OCP levels in primiparae were significantly higher than those in multiparae from Japan and Korea. These indicate that both parity and regional factors are major determinants of the levels of OCPs and PCBs in human milk. On the other hand, higher concentrations of PBDEs were observed in mothers' milk from Korea. The congener was dominated by BDE-47 (43–54%), followed by BDE-153 (23–33%) in all regions except for Beijing where BDE-28 (23%) was relatively abundant. In Japanese breast milk, regional and parity-dependent distributions were not observed for PBDEs. Among PBDE congeners, age-dependency was observed for BDE-153, which was negatively correlated (p < 0.05) to the age of mothers in Kyoto (17 participants were housewives), while it increased with age in Sendai (10 participants were clerks). No such correlation was seen for BDE-47, indicating that BDE-47 was ingested and assimilated via different kinetics or routes from BDE-153 in Japan.  相似文献   

4.
Leachate samples were collected from the West New Territory Landfill (WENT), Hong Kong, and characterized in the laboratory. The analytical results confirmed that it has a typical nature of aged leachate with a low BOD5/COD ratio of 0.22 and a high strength of ammonia-nitrogen around 5 g/L. A lab-scale study was conducted to investigate the inhibition of microbial activity of the activated sludge. In the first test, glucose-based synthetic wastewater was used in two parallel reactors. The experimental results demonstrated that COD removal declined from 95.1 to 79.1% and the dehydrogenase activity of the sludge decreased from 11.04 to 4.22 μg TF/mg mixed liquor suspended solids (MLSS), when the ammonia-nitrogen concentration increased from 50 mg/L to 800 mg/L progressively. The remaining NH3+-N residue in the treated wastewater increased from 0.58 mg/L to 649 mg/L extensively. In the second test, mixed wastewater samples containing glucose and raw leachate were fed into six parallel biological reactors and operated on batch mode. The experimental results showed COD removal decreased from 97.7 to 78.1% and the dehydrogenase activity decreased from 9.29 to 4.93 μg triphenyl formazon (TF)/mg MLSS, respectively, when the ammonia-nitrogen concentration increased within the same range. Microbial inhibition could also be substantiated by a decrease of specific oxygen uptake rate (SOUR) from 68 to 45 mg O2/g MLSS. These results suggested leachate containing high-strength ammonia-nitrogen should be pretreated to an acceptable NH4+-N level before it is fed into biological reactors.  相似文献   

5.
Effects of lime [Ca(OH)2] stabilization upon the pathogenic population in accumulated solids associated with the operation of two aerated wastewater lagoons in Alaska and two facultative wastewater lagoons in northern Utah were evaluated. The subsequent drying, at a temperature of 12 °C, of the lime stabilized sludges on sand and soil beds was also investigated. The lime stabilization of the lagoon sludges was evaluated by dosing the sludges with lime and applying sludges to bench scale drying beds. Lime addition produced high fecal coliform reduction, and the limed sludges readily dewatered on both sand and soil beds.  相似文献   

6.
We report on the comparative bioaccumulation, biotransformation and/or biomagnification from East Greenland ringed seal (Pusa hispida) blubber to polar bear (Ursus maritimus) tissues (adipose, liver and brain) of various classes and congeners of persistent chlorinated and brominated contaminants and metabolic by-products: polychlorinated biphenyls (PCBs), chlordanes (CHLs), hydroxyl (OH-) and methylsulfonyl (MeSO2-) PCBs, polybrominated biphenyls (PBBs), OH-PBBs, polybrominated diphenyl ether (PBDE) and hexabromocyclododecane (HBCD) flame retardants and OH- and methoxyl (MeO-) PBDEs, 2,2-dichloro-bis(4-chlorophenyl)ethene (p,p′-DDE), 3-MeSO2-p,p′-DDE, pentachlorophenol (PCP) and 4-OH-heptachlorostyrene (4-OH-HpCS). We detected all of the investigated contaminants in ringed seal blubber with high frequency, the main diet of East Greenland bears, with the exception of OH-PCBs and 4-OH-HpCS, which indicated that these phenolic contaminants were likely of metabolic origin and formed in the bears from accumulated PCBs and octachlorostyrene (OCS), respectively, rather than being bioaccumulated from a seal blubber diet. For all of the detectable sum of classes or individual organohalogens, in general, the ringed seal to polar bear mean BMFs for ΣPCBs, p,p′-DDE, ΣCHLs, ΣMeSO2-PCBs, 3-MeSO2-p,p′-DDE, PCP, ΣPBDEs, total-(α)-HBCD, ΣOH-PBDEs, ΣMeO-PBDEs and ΣOH-PBBs indicated that these organohalogens bioaccumulate, and in some cases there was tissue-specific biomagnification, e.g., BMFs for bear adipose and liver ranged from 2 to 570. The blood-brain barrier appeared to be effective in minimizing brain accumulation as BMFs were ≤ 1 in the brain, with the exception of ΣOH-PBBs (mean BMF = 93 ± 54). Unlike OH-PCB metabolites, OH-PBDEs in the bear tissues appeared to be mainly accumulated from the seal blubber rather than being metabolic formed from PBDEs in the bears. In vitro PBDE depletion assays using polar bear hepatic microsomes, wherein the rate of oxidative metabolism of PBDE congeners was very slow, supported the probability that accumulation from seals is the main source of OH-PBDEs in the bear tissues. Our findings demonstrated from ringed seal to polar bears that organohalogen biotransformation, bioaccumulation and/or biomagnification varied widely and depended on the contaminant in question. Our results show the increasing complexity of bioaccumulated and in some cases biomagnified, chlorinated and brominated contaminants and/or metabolites from the diet may be a contributing stress factor in the health of East Greenland polar bears.  相似文献   

7.
High natural radiation areas in the coastal and peninsular India were studied for airborne thorium and resultant population exposure due to inhalation. Four locations covering three states viz., Ayiramthengu and Neendakara in Kerala, Kudiraimozhi in Tamil Nadu and Bhimilipatnam in Andhra Pradesh were investigated. External gamma radiation fields 1 m above the monazite ore bodies ranged from 200 to 3000 nGy h-1. Soil samples showed 232Th specific activity varying from 0·1 to 1·5 Bq g-1 with surface alpha activity in the range of 1·0–12·5 Bq cm-2. Suspended particulates in the samples ranged from 60–140 μg m-3 with 232Th showing a wider variation of <0·03–0·3 mBq m-3. There was poor correlation between suspended particulates and long-lived alpha airborne activity . The resuspension factors for 232Th were in the range of 1·5×10-8–7·9×10-7 cm-1. Higher resuspension was correlated with dry sand dunes. The upper limits for Committed Effective Dose (CED) due to inhalation of airborne 232Th at the respective high natural radiation areas were estimated to range from 50±30 to 300±130 μSv (5–30 mrem) per year per adult member of public assuming an activity median aerodynamic diameter of 1 μm for the airborne particulates.  相似文献   

8.
Advantages and disadvantages of the concept of an industrial complex are discussed. From an environmental standpoint an ideal industrial complex is one containing a group of compatible industrial plants utilizing completely each other's wastes and products as raw materials and manufacturing products with no adverse environmental impact and at a minimum of cost. A typical complex centering about a pulp and papermill is pictured in this paper. This complex produces six products for external sale and four products for internal use. In addition, all major wastes of suspended solids, cooking liquor, fillers, heat and bark are reused within the complex in the manufacture of these products. A literature review evolved typical concentrations of recoverable suspended solids in various process effluents. A mass balance was prepared assuming that the total production of fine paper is 907.2 kg × 103 (1000 tons) per day. Little or no air or water pollution results from this complex. In addition, it is anticipated that no expensive waste-water treatment plant would be required for this complex. Ten additional practices are described which, when used, will reduce operating costs even further. A continuing study with more precise data on the production requirements for the service plants in the complex will yield a more balanced and realistic system.  相似文献   

9.
One hundred and ninety-four randomly selected nonsmoking subjects collected air samples in their breathing zone by wearing personal monitors for 24 h. The study was centered in Hong Kong, and comprised housewives in one group, primarily for assessing exposures in the home, and office workers in a second group to assess the contribution of the workplace to overall exposure. Samples collected were analysed for respirable suspended particles (RSP), nicotine, 3-ethenylpyridine, and environmental tobacco smoke (ETS) particles using ultraviolet absorbance (UVPM), fluorescence (FPM), and solanesol measurements (SolPM). Saliva cotinine analyses were also undertaken to confirm the nonsmoking status of the subjects and to investigate their correlation with ETS exposure measurements. Approximately 6% of the subjects in Hong Kong misclassified their nonsmoking status. Median time-weighted average (TWA) RSP concentrations varied from 43 to 54 μg m−3 with no significant differences detected between any of the groups investigated. Office workers who lived and worked with smokers were exposed to 2.6 μg m−3 ETS particles (SolPM) and 0.44 μg m−3 nicotine, based on median TWA concentrations. Median concentrations of ETS particles and nicotine were below the limits of quantification for housewives living with smokers and were not significantly different from those for housewives living with nonsmokers. It would therefore be unreliable in Hong Kong to use a smoking spouse as a marker for assessing health risks related to ETS exposure. The office workers in this study were significantly more exposed to ETS than housewives from either smoking or nonsmoking homes, and the workplace was estimated to contribute over 33% of the annual exposure to ETS particles and nicotine. Exposure estimates suggest that the most highly exposed office workers in this study receive between 11 and 50 cigarette equivalents per year, based upon upper decile levels for ETS particles and nicotine, respectively.  相似文献   

10.
Procedures are given for containment area sizing for retention of suspended solids based on the settling characteristics of the dredged material. Separate sizing procedures for freshwater and saltwater sediments provide for determination of the respective surface area or detention time required to accomodate continuous dredged material disposal. Procedures are given for the laboratory testing required to obtain data for sediment characterization, containment area sizing, and estimates of storage capacity required. These procedures can also be used for designing containment areas for other slurries having high suspended solids concentrations. Settling tests performed in a 20-cm-diam column were found to be satisfactory for defining dredged material settling behavior. Settling behavior in the freshwater environment was best described by a flocculent settling test, while behavior in a saltwater environment was best described by a zone settling test. The same settling columns were used for both tests withonly minor procedural changes. Procedures are presented for designing new containment areas for suspended solids retention and for evaluating the suspended solids retention potential of existing containment areas during planned disposal activities.  相似文献   

11.
A badge-type personal sampler was developed for measuring personal exposure to nitrogen dioxide (NO2). An absorbent sheet containing triethanolamine (TEA) solution absorbed NO2 which diffused through five layers of hydrophobic fiber filter. Wind effects on absorption rate were suppressed by these filter layers. NO2 was measured by the sampler with a sensitivity of 124.8 μg h/m3 (66 ppb h) and an accuracy of within ± 20%. It could be used for measuring personal exposure to NO2 without interfering with the wearer's daily activities. Nitric oxide (NO) could be measured after a small modification to the sampler provided oxidation ability to the layers of diffusion filter. Three layers of hydrophobic fiber filter were replaced by 12 layers of glass fiber filter containing chromium trioxide solution. NO was oxidized to NO2 in the oxidation layers and absorbed by the absorbent sheet together with the coexisting NO2. Sensitivity and accuracy of the sampler for NO were nearly equal to that for NO2.  相似文献   

12.
It is known that in soils and sediments moisture adsorbed on particle surfaces and in the pore system significantly affects the behaviour of recoiling radon (222Rn) atoms after decay of parent 226Ra, leading to increased 222Rn emanation. As a first step in an effort to characterize the 222Rn source term in mineralised sediments in the present study, complementing previous studies in the area, granitic esker sand samples were collected in order to test how moisture content affects 222Rn emanation at different grain size fractions. Emanation fractions measured for natural samples were compared with theoretical calculations. Six different grain size fractions were studied at 0%, 5% and 10% moisture contents relative to the mass of solids. In a further study necessary complementary information on the chemical and structural distribution of 226Ra was gained by selective leaching experiments. The results showed that 226Ra concentration increases from 50 Bq/kg at grain size 1-2 mm to 200 Bq/kg at grain size <0.063 mm. Respectively, the emanation factor increased from 0.12 to 0.30 at 5% moisture content. Both emanation factor and radium concentration increased significantly when grain size was below 0.125-0.250 mm. Above this fraction, the emanation fraction was approximately constant, 0.13 at 5% moisture content. In most of the grain size fractions, emanation reaches its maximum at 5% moisture content, being twice as high as in a dry sample. For the small particles (<0.063 mm) the 226Ra distribution is rather complex and depends on the mineral composition compared to larger particles wherein emanation from the internal pore system and the adjacent matrix is dominating over the contribution from external surface.  相似文献   

13.
An experimental apparatus has been constructed to investigate aerosol filtration by a cocurrent moving granular bed filter (CMGBF). In a CMGBF, aerosol passes downward through a descending bed of dirty granules while clean granules are added continously at the bed top. The effect of an intergranular dust deposit on penetration in a CMGBF was investigated in a 24 factorial experiment in which the control variables were superficial gas velocity (100 and 250 mm/s), bed depth (130 and 230 mm), granule size (2.1 and 2.7 mm), and the intergranular dust deposit expressed as percent by weight of collected dust in the bed (1% and 5%). All tests were conducted at ambient temperature and pressure using resuspended utility boiler fly ash as the test aerosol.Mass penetration data identified two major penetration mechanisms: (1) straight through penetration and (2) reentrainment due to granular motion. A static, intergranular dust deposit produced high filtration efficiency (>99%) at the low superficial velocity. When the bed was moving, reentrainment of collected dust was significant and accounted for about three-quarters of the penetrating dust. Particle size analyses reveal that the two penetration mechanisms are size dependent. Most particles larger than about one micrometer in diameter that penetrate the CMGBF do so by reentrainment after being collected initially. Virtually no particles smaller than about 0.3 μm in diameter penetrate by reentrainment; when these small particles penetrate, they pass straight through without being collected.  相似文献   

14.
在对镇江古运河2009~2013年的降雨量、降雨径流污染物量监测的基础上,运用回归分析建立降雨量-径流污染方程,并采用灰色理论对未来降雨量进行预测,进而得出降雨径流面源污染年负荷值。结果表明:2014~2020年间,镇江古运河降雨径流中污染物TP、NH3-N和SS的年负荷与降雨量同向变化,2020年降雨量达到1 381.2 mm时,污染物TP、NH3-N和SS的年负荷可分别达到217.15 t、421.4 t、5 811.87 t,数值较大;灰色理论与回归分析结合所提出的降雨径流面源污染年负荷预测方法,能够在小样本、贫信息和波动数据序列情况下,简捷有效的对降雨径流面源污染负荷进行高精度的预测,实用与推广价值较大。  相似文献   

15.
This study was conducted to: (1) assess the role of wetland vegetation in the removal of oxygen demand and nitrogen under tropical conditions, (2) estimate the uptake of nitrogen and copper by wetland plants and (3) investigate the speciation of Cu in wetland media among four operationally defined host fractions, namely exchangeable, carbonate, reducible and organically bound. Four laboratory-scale wetland units, two free-water-surface (FWS) and two subsurface-flow (SF) with one of each planted with cattails (Typha augustifolia), were fed with primary-treated sewage and operated at nominal retention times of 0.6-7 days. The influent and effluent BOD/COD and nitrogen concentrations were monitored to assess the performance of the wetland units for various mass loading rates. At the end of the study, all cattail plants were harvested and analyzed for total Kjeldahl nitrogen (TKN). Four other wetland units, which were identical to the first four, were fed with domestic wastewater spiked with copper in increasing concentrations. Copper speciation patterns in the sand layer were determined at the end of the study. The results showed that wetland vegetation did not play an important role in oxygen demand removal but were capable of removing about 22% and 26% of the nitrogen input in the FWS and SF wetland units, respectively. Mass balance analysis indicated that less than 1% of copper introduced was taken up by the cattails. Copper speciation patterns in the sand media showed that the exchangeable fraction contributed 30-57% and 63-80% of the nonresidual copper in the planted and unplanted FWS wetlands, respectively. For SF units, the percentages were 52-62% and 59-67%, respectively. This indicates that large amount of copper in the media were potentially remobilizable.  相似文献   

16.
To collect regional information on internal levels of pollutants in humans in Flanders, 1196 mother–child pairs were systematically recruited in 2002–2003 via 25 maternities across Flanders. Cd, Pb, PCB congeners 118, 170, 138, 153 and 180, p,p′-DDE — a key metabolite of DDT- and hexachlorobenzene (HCB) were measured in cord blood or plasma. Cd was detected in 64% of the samples (geometric mean 0.21 µg/L cord blood). p,p′-DDE (110 ng/g plasma lipids) and Pb (14.7 µg/L blood), were measurable in nearly all samples. The individual PCB congeners could be detected in 40 to 81% of the newborns (138 + 153 + 180 = 64.4 ng/g plasma lipids). HCB (18.9 ng/g plasma lipids) and dioxin-like compounds measured by DR-CALUX® (23 pg CALUX-TEQ/g lipids) were above detection limit in more than 75% of the samples. Age and smoking habits of the mothers, did not influence the cord blood Pb and Cd levels. The organochlorines increased 4 to 9% per year of the mother's age (partial R= 0.05 to 0.22). Mothers had 2.6% less PCBs in cord blood (partial R= 0.02) for each unit increase in pre-pregnancy BMI. Season of delivery, breastfeeding previous children or consumption of local dairy products, were minor determinants. Up to 20% of the variability in organochlorine concentrations was explained by residence area. It was concluded that the place of birth in Flanders is an important determinant of the load of pollutants measured at the start of life. This underlines the validity of human biomonitoring on (relatively) small geographical scale.  相似文献   

17.
The genotoxic activity of water samples collected in 9 different sites within the area of the Santos estuary was preliminary evaluated, and related to previous data on the genotoxicity of sediments and the contents of PAHs in both water and sediment samples. The liquid discharge of a steel mill (coke plant), known to be mutagenic, was chemically analyzed to determine its PAH content. For the water evaluation we employed the Salmonella/microsome assay with the strains TA98 and TA100 with and without S9 mix in the plate incorporation method. The water was filtered with an AP20 membrane before being extracted with XAD4 at natural and acidic pH. The industrial effluent was filtered in 0.45 microm membranes before being extracted with the liquid/liquid method. Both membranes containing the particulate material were extracted using ultrasonication. PAHs were found associated with the suspended particles present in the industrial effluent in accordance with mutagenicity data previously reported. In relation to the estuarine waters, sites 1 and 5 presented low levels of mutagenic activity only in the filtered water (liquid fraction) extracts. At site 3, both the filtered water and particulate solids presented also low mutagenicity. Results show that the mutagenic activity observed in water could not be directly related to the genotoxic activity and PAHs contents of the bottom sediments.  相似文献   

18.
Effects of acute γ-irradiation were investigated in the aquatic microcosm consisting of green algae (Chlorella sp. and Scenedesmus sp.) and a blue–green alga (Tolypothrix sp.) as producers; an oligochaete (Aeolosoma hemprichi), rotifers (Lecane sp. and Philodina sp.) and a ciliate protozoan (Cyclidium glaucoma) as consumers; and more than four species of bacteria as decomposers. At 100 Gy, populations were not affected in any taxa. At 500–5000 Gy, one or three taxa died out and populations of two or three taxa decreased over time, while that of Tolypothrix sp. increased. This Tolypothrix sp. increase was likely an indirect effect due to interspecies interactions. The principal response curve analysis revealed that the main trend of the effects was a dose-dependent population decrease. For a better understanding of radiation risks in aquatic microbial communities, effect doses of γ-rays compared with copper, herbicides and detergents were evaluated using the radiochemoecological conceptual model and the effect index for microcosm.  相似文献   

19.
Fragile coastal areas suffer from human activities. Environmental quality is one of the most important aspects in a tourist destination of sun and sand. The quality of bathing water and sand became indicators in the worldwide competition of beach destinations. We studied the water and sand quality along the beach of Puerto Velero, in northern Colombia. Water and sand beach quality were monitored during thirteen months. This allowed identifying the most significant sources of pollution along the beach, and understanding the interrelationship between tourism and the effects on the environment. Linear correlations allow assessing the association between the number of visitors and the physicochemical and microbiological parameters. The number of visitors was directly correlated with the presence of grease and oils, both in water and sand, as well as with fecal coliforms in water. A relation between the suspended solids and the presence of fecal coliforms in water and sand was observed. This statistical approach allows understanding the origin of beach sand and swimming water pollution at tourist beaches. Overall, sand quality has an important influence and is directly related to the water quality of the beach. Both the number of tourists and their activities are main factors explaining the contamination of the water and sand. This shows the importance of management of waste and wastewater in combination with awareness raising initiatives. More research should include monitoring and evaluating of both water and sand beach and provide data to revise the existing legal framework.  相似文献   

20.
Optimum operating conditions for sewage treatment via combined biological-physico chemical treatment has been studied. The biological unit was a trickling filter. The non-settled biological effluent was subjected to coagulation followed by rapid solid-liquid separation via dissolved air flotation. The impact of organic load on the over-all efficiency of the system has been investigated using three different organic loads namely, 9.48, 20.0, and 27.85 g BOD5m?2d?1. The coagulants used were ferric chloride and alum. Calcium oxide was used as a coagulant aid with ferric chloride. Factors affecting the efficiency of dissolved air flotation process such as detention time, air solids ratio, and position of coagulant's addition have been investigated. The results obtained showed that the use of biological, extended physico-chemical technique leads to the removal of organic as well as inorganic contaminants. Moreover, sludge with high solids content can be obtained.  相似文献   

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