热带海水养殖清洁生产技术模式探讨

采用太阳光化学修复原理对典型热带地区--海南省某养殖场废水进行清洁闭环生态养殖技术初步探讨.采用现场定位观测实验研究方法,探讨高位池光化学循环净化装置对养殖废水中COD、SS等污染物的去除效应、脱氮解毒效应以及增氧效应等.结果表明,本实验装置能有效地实现热带地区高位池循环水养殖及养殖污水的"零排放",是满足环保要求的一种多功能、低成本、效果好的水体净化方法.     

Metal accumulation in the greentail prawn, Metapenaeus bennettae, in Sydney and Port Hacking estuaries, Australia

Metal concentrations of the inshore greentail prawn, Metapenaeus bennettae, and surface sediments from locations within Sydney estuary and Port Hacking (Australia) were assessed for bioaccumulation and contamination. The current study aimed to assess metal concentrations in prawn tissue (tail muscle, exoskeleton, hepatopancreas and gills), relate whole body prawn tissue metal concentrations to sediment metal concentrations and animal size, as well as assess prawn consumption as a risk to human health. Metal concentrations were highest in sediment and prawns from contaminated locations (Iron Cove, Hen and Chicken Bay and Lane Cove) in Sydney estuary compared with the reference estuary (Port Hacking). Concentrations in sediments varied considerably between sites and between metals (As, Cd, Cr, Cu, Ni, Pb and Zn), and although concentrations exceeded Interim Sediment Quality Guideline-Low values, metals (As, Cd, Cr, Cu, Ni, Pb and Zn) were below Australian National Health and Medical Research Council human consumption guidelines in prawn tail muscle tissue. Metal concentrations in prawn tail muscle tissue were significantly different (p?≤?0.05) amongst locations for Pb, Zn and Cd, and metal concentrations were generally highest in gills tissue, followed by the hepatopancreas, exoskeleton and tail muscle. The exoskeleton contained the highest Sr concentration; the hepatopancreas contained the highest As, Cu and Mo concentrations; and the gills contained the highest Al, Cr, Fe and Pb concentrations. Concentrations of Pb, As and Sr were significantly different (p?≤?0.05) between size groups amongst locations.     

基于指标规范值的环境质量的指数幂乘积指数公式

传统的环境质量指数幂乘积指数的分级标准值随指标不同和指标数目不同而不同,因而综合指数的分级标准值不能规范和统一.在适当设定指标参照值和指标值的规范变换式基础上,使同类环境不同指标的同级标准的规范值差异尽可能小,而不同标准的指标规范值差异尽可能大,从而可以认为,用规范值表示的同类环境的各指标皆等效于某个规范指标,因而同类环境的任意m项指标的指数幂乘积综合指数可以有共同的分级标准值,使基于指标规范值的环境质量指数幂乘积指数公式具有普适性、可比性和通用性.     

Influence of solute dissociation constants on the optimum adsorption of weak electrolytes on activated carbons

The pH of solutions has dramatic effects on the adsorption capacity of activated carbons from solutions, while the adsorption curves for weak electrolytes acquired as a function of pH show maxima at some intermediate pH. This intermediate pH is usually near the pKa of the electrolyte. Some apparent controversy inherent in these statements has, however, motivated experimental and analytical investigation of these systems. The present investigation therefore employed standard ASTM techniques in the study of adsorption systems, as well as non-linear least squares regression techniques to predict adsorption on activated carbon. It was observed that the adsorption isotherms do not indicate the existence of clear adsorption maxima for pKa values above 10. The existence of both a maximum as well as a minimum on the adsorption of a range of moderately weak electrolytes is indicated. Good agreement was observed between experimental and predicted adsorption isotherms.     

基于生物表面活性剂的柴油微乳体系构建与性能研究

以生物表面活性剂鼠李糖脂（RL）为表面活性剂,中长碳链正构醇（正丁醇、正戊醇、正己醇、正庚醇及正辛醇）为助表面活性剂,采用滴定法制备RL／柴油／正构醇／水柴油微乳体系,并考察了表面活性剂用量（Km）、助表面活性剂醇的种类及用量（δas）及离子强度对柴油微乳体系最大增溶水量（Wo）的影响,并对不同条件下获得的柴油微乳体系的运动粘度（μ）和表面张力（γ）进行了表征。通过荧光法测得RL在柴油中的临界胶束浓度CMC为7g／L。当生物表面活性剂与柴油的质量比Km为0．02,助表面活性剂选用正庚醇且醇与表面活性剂的质量比δgs为0．1,NaOH溶液质量分数为0．06％时,柴油微乳体系的肛和T较低,形。最大,性能较佳。     

基于平均负荷的降雨径流污染负荷模型研究

在九寨沟旅游景区,对公路和栈道进行人工降雨径流污染负荷的过程研究。浓度过程曲线表明,初始高浓度与平台期浓度之间相差3~5倍,而负荷过程曲线表明,各时段负荷曲线无明显峰值存在。这意味着污染物平均浓度的获取,需要降雨径流的水量水质同步监测数据的较大样本,才能消除随机性影响。而各时段负荷数据向平均负荷期望收敛的速度,将比平均浓度期望更快。利用这一规律,以平均负荷值代替降雨事件的污染物平均浓度(EMC),构建了基于平均负荷值的年地表径流负荷模型。本模型只需要有限场水量水质同步监测数据,就可获得特定地区面源污染物的平均负荷值。在消除随机不确定性同时,提高了可操作性。采用研制的模型,计算出九寨沟各子区公路面源的TP排放负荷,在0.87~2.07 kg/a之间,栈道面源TP排放负荷,在0.27~1.22 kg/a之间。     

淀粉废水处理方法综述

由于淀粉加工企业分布广且废水COD浓度高,淀粉废水处理方法的研究越来越受到重视。就目前国内外淀粉废水的各种处理方法和工艺进行综述,重点介绍了淀粉废水处理方面的最新研究成果,并介绍了废水资源化的一些途径。     

外电阻对MFC型生物毒性检测器性能的影响

利用微生物燃料电池对含汞废水的生物毒性进行检测,结果表明,汞等重金属有毒物质会对阳极产电细菌的活性有一定抑制作用。汞浓度在0.5~5.0 mg/L范围内,其抑制作用的大小与重金属的浓度呈正相关;外电阻为25~35 Ω条件下,最低检测限为0.5 mg/L,最大抑制率为21.74%;外电阻越小,微生物燃料电池检测生物毒性的灵敏度也越高,响应时间越短,检测限越小。然而,外电阻太小,不利于微生物燃料电池的长期稳定运行。因此,微生物燃料电池检测生物毒性时,最佳外电阻选择范围为0.5 R内~0.7R内。     

Propolis efficacy on SARS-COV viruses: a review on antimicrobial activities and molecular simulations

Environmental Science and Pollution Research - This current study review provides a brief review of a natural bee product known as propolis and its relevance toward combating SARS-CoV viruses....     

Effects of tungsten on environmental systems

Tungsten is a metal with many industrial and military applications, including manufacturing of commercial and military ammunition. Despite its widespread use, the potential environmental effects of tungsten are essentially unknown. This study addresses environmental effects of particulate and soluble forms of tungsten, and to a minor extent certain tungsten alloy components, present in some munitions formulations. Dissolution of tungsten powder significantly acidifies soils. Tungsten powder mixed with soils at rates higher than 1% on a mass basis, trigger changes in soil microbial communities resulting in the death of a substantial portion of the bacterial component and an increase of the fungal biomass. It also induces the death of red worms and plants. These effects appear to be related with the soil acidification occurring during tungsten dissolution. Dissolved tungsten species significantly decrease microbial yields by as much as 38% for a tungsten media concentration of 89 mg l(-1). Soluble tungsten concentrations as low as 10(-5) mg l(-1), cause a decrease in biomass production by 8% which is possibly related to production of stress proteins. Plants and worms take up tungsten ions from soil in significant amounts while an enrichment of tungsten in the plant rhizosphere is observed. These results provide an indication that tungsten compounds may be introduced into the food chain and suggest the possibility of development of phytoremediation-based technologies for the cleanup of tungsten contaminated sites.     

两种电子供体对光合藻类微生物燃料电池产电性能及小球藻生长的影响

通过构建光合藻微生物燃料电池(PAMFC),研究了分别以乙酸钠或葡萄糖作为唯一电子供体时,对PAMFC的产电性能及其中小球藻生长的影响。结果表明,在外电阻为1 000 Ω时,以乙酸钠为电子供体的PAMFC最大输出电压是285 mV、最大输出功率为3.42 mW/m2;以葡萄糖为电子供体的PAMFC最大输出电压是247 mV、最大输出功率为2.68 mW/m2。同时,分别以乙酸钠或葡萄糖为电子供体的PAMFC中小球藻生长所达到的生物量分别是1.8 g/L和1.26 g/L,而对照组中的小球藻生物量仅为0.83 g/L。简单电子供体的电池性能优于复杂电子供体,同时更能促进PAMFC中阴极光合藻生长,使电池阴极得以固定更多阳极所排放的二氧化碳。     

Toxic effects of arsenic on Sinorhizobium-Medicago sativa symbiotic interaction

Recently, the Rhizobium-legume symbiotic interaction has been proposed as an interesting tool in bioremediation. However, little is known about the effect of most common contaminants on this process. The phytotoxic effects of arsenic on nodulation of Medicago sativa have been examined in vitro using the highly arsenic resistant and symbiotically effective Sinorhizobium sp. strain MA11. The bacteria were able to grow on plates containing As concentrations as high as 10 mM. Nevertheless, as little as 25-35 microM arsenite produced a 75% decrease in the total number of nodules, due to a 90% reduction in the number of rhizobial infections, as could be determined using the strain MA11 carrying a lacZ reporter gene. This effect was associated to root hair damage and a shorter infective root zone. However, once nodulation was established nodule development seemed to continue normally, although earlier senescence could be observed in nodules of arsenic-grown plants.     

絮凝剂的开发进展

分别对无机高分子絮凝剂、有机高分子絮凝剂、微生物絮凝剂和废物回收制备絮凝剂的物性、应用状况进行了简要介绍，并列出了近年来大量研究人员对这儿类絮凝剂的研究成果和开发进展。     

基于人工神经网络的街道峡谷NOx浓度的数值模型研究

通过对反向传播人工神经网络的算法和网络结构的研究,发现拟牛顿算法训练速度较快,能够较好地接近误差目标值,同时建立了包括输入层、隐含层、输出层的人工神经网络三层拓扑结构。通过对街道峡谷人工神经网络的训练,模拟计算了街道峡谷NOx浓度分布值。结果显示,训练误差和测试误差比为1．11,训练样本的模拟值与实测值的相关系数为0．93,测试样本的模拟值与实测值的相关系数为0．87,模拟值与实测值的相关系数均高于显著水平为α=0．05与α=0．01所对应检验性表的相关系数临界值。该模型能够用于街道峡谷污染物浓度的模拟计算,具有较好的泛化能力。     

Effect of substrate Henry's constant on biofilter performance

Butanol, ether, toluene, and hexane, which have Henry's constants ranging from 0.0005 to 53, were used to investigate the effects of substrate solubility or availability on the removal of volatile organic compounds (VOCs) in trickle-bed biofilters. Results from this study suggest that, although removal of a VOC generally increases with a decrease in its Henry's constant, an optimal Henry's constant range for biofiltration may exist. For the treatment of VOCs with high Henry's constant values, such as hexane and toluene, the transfer of VOCs between the vapor and liquid phases or between the vapor phase and the biofilm is a rate-determining step. However, oxygen (O2) transfer may become a rate-limiting step in treating VOCs with low Henry's constants, such as butanol, especially at high organic loadings. The results demonstrated that in a gas-phase aerobic biofilter, nitrate can serve both as a growth-controlling nutrient and as an electron acceptor in a biofilm for the respiration of VOCs with low Henry's constants. Microbial communities within the biofilters were examined using denaturing gradient gel electrophoresis to provide a more complete picture of the effect of O2 limitation and denitrification on biofilter performance.     

Review of recent ecotoxicological studies on cladocerans

Cladocerans have been widely used as the bioassay organisms in evaluating the impact of different toxic substances. Literature survey during the last 10 years revealed that cladoceran ecotoxicological research has been in an exponential phase constituting nearly 10% of publications on this group. Many studies have considered typically planktonic taxa such as Daphnia magna, D. pulex, Moina macrocopa, M. micrura and Ceriodaphania dubia. Experimental data on toxicity tests, to a lesser extent, are also available for littoral-benthic genera such as Simocephalus, Macrothrix and Alona. Most toxicity tests are limited to the derivation of median lethal concentrations of various durations but mostly at 24 or 48 h. Studies related to the evaluation of changes in the life history variables of cladocerans as a result of sublethal exposure to toxic substances are not many, but gaining importance. The common toxic substances used in the cladoceran toxicity tests appear to be heavy metals, pesticides and a few natural toxins such as cyanotoxins. We review here the effect of different toxic substances on cladocerans based on both the field and the laboratory studies from an ecotoxicology point of view. Suggestions for the future cladoceran ecotoxicology are also commented on.     

Assessing and forecasting the impacts of global change on Mediterranean rivers. The SCARCE Consolider project on Iberian basins

Introduction

The Consolider-Ingenio 2010 project SCARCE, with the full title ??Assessing and predicting effects on water quantity and quality in Iberian Rivers caused by global change?? aims to examine and predict the relevance of global change on water availability, water quality, and ecosystem services in Mediterranean river basins of the Iberian Peninsula, as well as their socio-economic impacts. Starting in December 2009, it brought together a multidisciplinary team of 11 partner Spanish institutions, as well as the active involvement of water authorities, river basin managers, and other relevant agents as stakeholders.

Methods

The study areas are the Llobregat, Ebro, Jucar, and Guadalquivir river basins. These basins have been included in previous studies and projects, the majority of whom considered some of the aspects included in SCARCE but individually. Historical data will be used as a starting point of the project but also to obtain longer time series. The main added value of SCARCE project is the inclusion of scientific disciplines ranging from hydrology, geomorphology, ecology, chemistry, and ecotoxicology, to engineering, modeling, and economy, in an unprecedented effort in the Mediterranean area. The project performs data mining, field, and lab research as well as modeling and upscaling of the findings to apply them to the entire river basin.

Results

Scales ranging from the laboratory to river basins are addressed with the potential to help improve river basin management. The project emphasizes, thus, linking basic research and management practices in a single framework. In fact, one of the main objectives of SCARCE is to act as a bridge between the scientific and the management and to transform research results on management keys and tools for improving the River Basin Management Plans. Here, we outline the general structure of the project and the activities conducted within the ten Work Packages of SCARCE.     

基于Fluent的闭合环型缺氧反应器构造优化

为提高闭合环型缺氧反应器混合效果,选用基于Fluent软件的三维RNG k-ε紊流数学模型对闭合环型缺氧反应器进行流场模拟,以池底可能淤积面积比例作为混合效果的评价标准,分别从导流直墙长度、导流墙偏心距离及水下推进器偏置等3个方面对缺氧池的系统构造的最优设置进行研究。结果显示,在相同推进器功率下,导流直墙长度2.0 m为佳,导流墙偏心距离0.5 m为佳,推进器向内偏置0.5 m为佳。该研究方法及其结果可以作为闭合环型缺氧反应器的设计依据,具有较佳的技术参考价值。     

分离剂甲酸溶液浓度和温度对于铝塑湿法分离的影响研究

主要针对无菌复合包装废弃物中去除了纸浆后的铝塑部分的湿法分离工艺进行研究,选用甲酸作为分离溶剂,分析其反应机理。并着重对分离过程的影响控制因素进行实验研究,就不同的分离剂浓度、不同反应温度以及不同液固比条件下铝塑分离的效果及反应速率的变化分别进行分析研究,寻找铝塑片分离各影响因素之间的关系,为工业化生产应用提供参考,以提高无菌复合包装废弃物的再生利用率。