Seasonal monitoring of heavy metals and physicochemical characteristics in a lentic ecosystem of subtropical industrial region, India

Assessment of seasonal changes in surface water quality is an important aspect for evaluating temporal variations of lentic ecosystem (lakes and reservoirs) pollution due to industrial effluent discharge. In this study, nine metals and 15 physicochemical parameters, collected from four sampling sites in a tropical lake receiving the discharge from thermal power plant, coal mine, and chloralkali industry, during the years from 2004 to 2005, were analyzed. For greater efficacy in monitoring of heavy metals, particle-induced X-ray emission has been used during present investigation. Different statistical techniques like analysis of variance, Pearson correlation, principal component analysis, and factor analysis were employed to evaluate the seasonal correlations of physicochemical parameters. Most of the metals and physicochemical parameters monitored in the present study exhibited high spatial and temporal variability. Pertaining to metal pollution, the most polluted site was Belwadah, i.e., waters and sediments had the highest concentration of all the relevant metals. The reference site was characterized by the presence of low concentrations of metals in waters and in sediments. Based on the high metal concentration recorded in lake ambient, drinking, bathing, and irrigation water should not be used by the local people at the effluent discharge points.     

Heavy metals partitioning in sediments of the Kabini River in South India

Cu, Cr, Fe, Mn, Ni, Pb, and Zn in the sediments of the Kabini River, Karnataka, India was studied to determine the association of metal with various geochemical phases by sequential extraction. The variations of heavy metal concentration depend on the lithology of the river basin and partly on anthropogenic activities. The Kabini River sediments are dominated by Sargur supracrustals with amphibolites, gneisses, carbonates, and ultrabasic rocks weathering into gneissic and serpentine soils carrying a natural load of cationic heavy metals. The source of heavy metals in the Kabini riverbed sediments is normally envisaged as additional inputs from anthropogenic over and above natural and lithogenic sources. Geochemical study indicates the metals under study were present mostly in the least mobilizable fraction in the overlying water and it is concluded that heavy metals in these sediments are to a great extent derived from multisource anthropogenic inputs besides geochemical background contributions The results show that lead and chromium have higher potential for mobilization from the sediment due to higher concentration at the exchangeable ion and sulfide ion bounded, also Cu and Pb have the greatest percentage of carbonate fraction, it means that the study area received inputs from urban and industrial effluents. Association of the Fe with organic matter fraction can be explained by the high affinity of these elements for the humic substances. Further, Zn and Ni reveal a significant enrichment in sediment and it is due to release of industrial wastewater into the river. These trace metals are possible contaminants to enter into aquatic and food chain.     

Multivariate statistical and GIS-based approaches for toxic metals in tropical mangrove ecosystem,southeast coast of India

The heavy metal concentrations in water and sediment samples were investigated in the tropical Muthupet mangrove ecosystem, southeast coast of India. The results demonstrated that, ranges of metals in water comprise of Cd—0.05 to 3.72; Cu—0.5 to 4.43; Pb—6.31 to 17.87; Zn—0.0 to12.91 ppm and sediment comprises of Cd—0.06 to 0.57; Cu—4.46 to 20.59; Pb—2.90 to 21.35; Zn—4.41 to 39.18 ppm. In all the three sites, heavy metals in sediment exhibited significant higher concentrations compared to water, except Cd. The spatial distribution of metals in water and sediment samples followed a similar pattern except Cd with the preponderance of Zn (75% of total metals) followed by Cu and Pb. Muller’s Geoaccumulation indexes (Igeo) showed Cd is a potent pollutant in the ecosystem and moderately contaminated the study area. The aquaculture and agricultural culture practices follow improper disposal of municipal wastages, and idol immersion activities are the potent metallic sources for heavy metal pollution were identified by performing principle component analysis. In order to protect the ecosystem from further contamination, regular monitoring is needed to in order to control the anthropogenic discharges.

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Heavy metal pollution in water and sediments in the Kabini River, Karnataka, India

Critical to habitat management is the understanding of not only the location of animal food resources, but also the timing of their availability. Grizzly bear (Ursus arctos) diets, for example, shift seasonally as different vegetation species enter key phenological phases. In this paper, we describe the use of a network of seven ground-based digital camera systems to monitor understorey and overstorey vegetation within species-specific regions of interest. Established across an elevation gradient in western Alberta, Canada, the cameras collected true-colour (RGB) images daily from 13 April 2009 to 27 October 2009. Fourth-order polynomials were fit to an RGB-derived index, which was then compared to field-based observations of phenological phases. Using linear regression to statistically relate the camera and field data, results indicated that 61% (r (2)?= 0.61, df = 1, F?= 14.3, p?= 0.0043) of the variance observed in the field phenological phase data is captured by the cameras for the start of the growing season and 72% (r (2)?= 0.72, df = 1, F?= 23.09, p?= 0.0009) of the variance in length of growing season. Based on the linear regression models, the mean absolute differences in residuals between predicted and observed start of growing season and length of growing season were 4 and 6?days, respectively. This work extends upon previous research by demonstrating that specific understorey and overstorey species can be targeted for phenological monitoring in a forested environment, using readily available digital camera technology and RGB-based vegetation indices.     

Assessment of heavy metals in aquatic sediments

The concentration of heavy metals in the bottom sediment and interstitial water collected from two reservoirs in Singapore was found to be enriched. A distribution coefficient,K _d , was used to assess the chemical stability of heavy metals in the sediments. Numerical models were used to assess (1) the redistribution of heavy metals in a changing environment, and (2) long-term self clean-up capabilities of a reservoir.     

Heavy metals concentration in edible fishes from coastal region of Kalpakkam, southeastern part of India

Concentrations of Cu, Mn, Zn, Fe, Cr, and Pb were estimated using ICP-MS in nine commercially important and locally consumed fish species (Sarda orientalis, Scomberomorus commerson, Rastrelliger kanagurta, Sardinella longiceps, Paraplagusia bilineata, Cynoglossus lida, Cynoglossus macrostomus, Lepturacanthus savala, and Siganus javus) collected from coastal waters of Kalpakkam, eastern part of India. Their concentration (μg g(-1)) in the examined fish species ranged as follows: Cu (0.8-6.5), Zn (14.3-27.9), Mn (0.5-8.8), Fe (17.6-117.0), Cr (0.24-1.78), and Pb (0.18-2.29). Concentrations of most of the metals in the fish species studied were found to be safe for human consumption barring Mn.     

Distribution and speciation of selected metals in surface sediments, from the tropical Zuari estuary, central west coast of India

Estuarine sediments are major reservoirs for the metals. Distribution and mobility of metals within estuaries depends strongly on their specific chemical form. In the present study, surface sediments from Zuari estuary, Goa were analysed by a sequential procedure for Fe, Mn, Cu, Zn, Cr and Co to determine their distribution in five geochemical phases (Exchangeable, carbonate, Fe-Mn oxide (reducible) organic bound (oxidisable) and residual). The total metal content, sand, silt, clay and organic carbon were also determined of the surface sediments. The total metal contents were found to be greater than the background concentrations of average shale values as well as to that of earlier studies indicating enrichment probably due to the anthropogenic origin of metals. The results obtained from sequential procedure showed that among the studied elements, Mn and Co are potentially available in the bioavailable fractions (exchangeable, carbonate and Fe-Mn oxide bound fractions) indicating their importance in toxicity whereas rest of the metals viz. Fe, Cu, Zn and to some extent Cr are largely available in residual phase although they are available in other fractions. The main source of metals to the estuary is mining and its associated activities in the study area. Chemical speciation by sequential extraction procedure has helped in assessing the mobility, bioavailability, diagenesis and toxicity of metals and hence giving a better insight into the ultimate fate of pollutants, which are introduced into the estuarine environment. To understand the risk of the metals to the sediment dwelling organisms the data were compared with the Sediment Quality Values (SQV) using SQUIRT. Also, correlation and Factor analysis were carried out to understand the associations of metals in the different fractions with sand, silt, clay, organic carbon and with other metals.     

Distribution of heavy metals in surface water of Ranipet industrial area in Tamil Nadu, India

Ranipet industrial area is about 120 km from Chennai on Chennai-Bangalore highway and is a chronic polluted area identified by Central Pollution Control Board of India. It is one of the biggest exporting centers of tanned leather in India. The total number of industries located in and around Ranipet town are 240 tanneries along with ceramic, refractory, boiler auxiliaries plant, and chromium chemicals. Studies were carried out to find out the contamination of surface water bodies due to industrial effluents. The results reveal that the surface water in the area is highly contaminated showing very high concentrations of some of the heavy/toxic metals like Cadmium ranging from 0.2 to 401.4 μg/l (average of 51.1 μg/l), Chromium 2.4–1,308.6 (average of 247.2 μg/l), Copper 2.1–535.5 μg/l (average of 95.5 μg/l), Nickel 1.6–147.0 μg/l (average of 36.7 μg/l), Lead 6.4–2,034.4 μg/l (average of 467.8 μg/l) and Zinc 20.8–12,718.0 μg/l (average of 3,760.4 μg/l). The concentration levels of these metals are much above the permissible limits in surface water and are health hazards especially for the people working in the tannery industries. It was observed that the people in the area are seriously affected and suffering from occupational diseases such as asthma, chromium ulcers and skin diseases. Distribution of metals, their contents at different locations, and their effects on human health are discussed in this paper.     

Metal biomonitoring in water resources of Eastern Ghats,Koraput (Orissa), India by aquatic plants

Biomonitoring of toxic metals in the water resources used by indigenous tribal communities in Koraput district, Orissa, India was carried out under the National Technology Mission Project. Most of the water bodies catering for the day-to-day needs of the local inhabitants were found to contain high concentrations of Fe and Mn in addition to Cr, Cd, Pb and Cu. The water bodies supported by a great number of phytodiversity and the plants growing therein accumulated significantly high amounts of these toxic metals, submerged plants being more efficient than floating ones. The species like Chara corallina and Spirogyra spp. showed significant potential to magnify Cd and Pb in their tissue several times more than the concentrations in surrounding water. The levels of metals in the plants occurring at places where the metal content is very high could be used for indicating the status of water.NBRI Research Publication No. (437) NS.     

Heavy metals in water,periphytonic algae,detritus, and insects from two streams in Shillong,Notheastern India

Cadmium, copper, manganese, lead and zinc concentrations were determined in water, periphytonic algae, detritus, and larvae of three aquatic insects, viz. Baetis sp. (Ephemeroptera: Baetidae), Hydropsyche sp. (Trichoptera: Hydropsychiidae), and Chironomus ramosus Choudhury and Das (Diptera: Chironomidae), during two surveys from an unpolluted and a polluted stream in Shillong, Meghalaya State, Northeastern India. Metal concentrations were higher in all the samples from the polluted stream, possibly reflecting the contributions from various non-point sources of metal contamination present in its catchment. Among the three insects, Baetis sp. was found to accumulate cadmium, copper, and zinc, and Hydropsyche sp. manganese, to concentrations significantly higher than those found in the other taxa. The concentrations of all the metals were higher in fine detritus than in C. ramosus, although Cd and Zn concentrations were elevated in Baetis as compared to those in periphytonic algae and fine detritus, indicating possible bioconcentration of these metals by this animal.     

Heavy metals in the SPM of air in the environment surrounding a ferro-alloy industrial plant in India

Prices for ferro-alloys have hardened due to the closure of plants in developed countries on account of increasingly stringent pollution control legislation, resulting in a higher cost of production. A ferro-alloy industry with a capacity of 80000 MT per annum was selected to study the nature of pollution. Because of the objectionable nature of polluting air in and around the plant it was located in a rural area where there was no other industry. The area was agriculturally active and there was no effective control system for this plant.The quality of ambient air around the plant site is discussed in this paper along with the meteorological conditions. The maximum concentration of suspended particulate matter (SPM) was 768 µg/NM³ downwind of the plant, minimum 184 µg/NM³, and the average was more than 446 µg/NM³. The presence of heavy metals, viz. Fe, Mn, Cr and Pb, was also assessed. The concentration of Fe was 50 µg/NM³ downwind and 10 µg/NM³ upwind. The concentration of other metals followed a similar trend.     

Heavy metals fractionation in surface sediments of Gowatr bay-Iran

Establishing the effectiveness of habitat features to act as surrogate measures of diversity and abundance of juvenile reef fish provides information that is critical to coral reef management. When accurately set on a broader spatial context, microhabitat information becomes more meaningful and its management application becomes more explicit. The goal of the study is to identify coral reef areas potentially important to juvenile fishes in Ngederrak Reef, Republic of Palau, across different spatial scales. To achieve this, the study requires the accomplishment of the following tasks: (1) structurally differentiate the general microhabitat types using acoustics; (2) quantify microhabitat association with juvenile reef fish community structure; and (3) conduct spatial analysis of the reef-wide data and locate areas optimal for juvenile reef fish settlement. The results strongly suggest the importance of branching structures in determining species count and abundance of juvenile reef fish at the outer reef slope of Ngederrak Reef. In the acoustic map, the accurate delineation of these features allowed us to identify reef areas with the highest potential to harbor a rich aggregation of juvenile reef fish. Using a developed spatial analysis tool that ranks pixel groups based on user-defined parameters, the reef area near the Western channel of Ngederrak is predicted to have the most robust aggregation of juvenile reef fish. The results have important implications not only in management, but also in modeling the impacts of habitat loss on reef fish community. At least for Ngederrak Reef, the results advanced the utility of acoustic systems in predicting spatial distribution of juvenile fish.     

Distribution of heavy metals in water and sediments of selected sites of Yamuna river (India)

The concentration of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn metals in water and sediments of Yamuna river were determined by atomic absorption spectrophotometry in the year 1981. The data showed that there was considerable variation in the concentration of elements from one sampling station to the other which may be due to the variation in the quality of industrial and sewage wasters being added to the river at different sampling stations. The sediment samples collected from different sampling stations were also analysed for calcium carbonate, organic matter, potassium, and phosphorus.     

Enrichment and fractionation of heavy metals in bed sediments of River Narmada, India

A metal fractionation study on bed sediments of River Narmada in Central India has been carried out to examine the enrichment and partitioning of different metal species between five geochemical phases (exchangeable fraction, carbonate fraction, Fe/Mn oxide fraction, organic fraction and residual fraction). The river receives toxic substances through a large number of tributaries and drains flowing in the catchment of the river. The toxic substances of particular interest are heavy metals derived from urban runoff as well as municipal sewage and industrial effluents. Heavy metals entering the river get adsorbed onto the suspended sediments, which in due course of time settle down in the bottom of the river. In this study fractionation of metal ions has been carried out with the objective to determine the eco-toxic potential of metal ions. Although, in most cases (except iron) the average trace/heavy metal concentrations in sediments were higher than the standard shale values, the risk assessment code as applied to the present study reveals that only about 1–3% of manganese, <1% of copper, 16–19% of nickel, 4–20% of chromium, 1–4% of lead, 8–13% of cadmium and 1–3% of zinc exist in exchangeable fraction and therefore falls under low to medium risk category. According to the Geo-accumulation Index (GAI), cadmium shows high accumulation in the river sediments, rest of other metals are under unpolluted to moderately polluted class.     

Heavy metals in bottom sediments of Lake Umbozero in Murmansk Region, Russia

Sediment cores collected from different locations of Lake Umbozero were studied with respect to concentration and mobility of trace and heavy metals Co, Cu, Fe, Mn, Ni, Pb, U, and Zn. Lake Umbozero is the second largest lake in the Murmansk Region and subjected to contamination by air-borne emissions and river transportation from the nearby metallurgical and mining industries. Unlike its neighboring, more industry-prone Lake Imandra, Lake Umbozero is relatively unexplored with respect to its state of pollution. In our study, metal distribution in sediments was found to vary with respect to the cores, although in general the concentrations were at the same level throughout the lake indicating uniform horizontal distribution of metals. When compared to Lake Imandra, the concentrations of most of the metals studied were significantly lower and represented the levels in sediments measured in lakes of Kola Peninsula located further off from industrial pollutant sources. An exception was Pb the concentration of which was at the same level as in Lake Imandra, probably due to long-distance transport. Sediment layers were subjected to four-step sequential extraction procedure to reveal the metal distribution in soluble, exchangeable, acid-soluble, and residual fractions. Indicative of their potential higher lability, Mn, U, and Zn were generally found in exchangeable fraction; as also Mn and U extensively in the acid-soluble fraction.     

Characterization of heavy metals in water and sediments in Taihu Lake, China

To explore a comprehensive status of heavy metals in the Taihu Lake, which is one of the most important waters in China, water and sediment samples were taken throughout the lake during April to May of 2010, and metal elements (Cu, Cd, Cr, Ni, Pb, Sn, Sb, Zn, Mn) were analyzed in the water column, interstitial water and sediment. Relevant standards were used to assess the sediment and water quality. Results show that, in the lake water column, the average concentration of all metals ranged from 0.047 μg/l (Cd) to 8.778 μg/l (Zn). The concentration in the river water was usually higher than in the lake water for many metals. In the interstitial water Mn was significantly higher than that in water column, and other metals had no significant difference between the two media. In the surface sediment, average metal content ranged from 1.325 mg/kg (Cd) to 798.2 mg/kg (Mn). Spatially, contents of many metals were higher in Zhushan Bay than in other lake areas, and there existed a clear content gradient from the river to the lake for both water and sediment. On the sediment profiles, many metals presented an increasing trend from the depth of 15-20 cm to the top, which is indicative of the impact of increasingly intensive human activities from that period. Quality assessment indicates that metals in water phase are generally safe compared with USEPA "National Recommended Water Quality Criteria," with the exception of Mn in the interstitial water and Sb in the river water. Whereas the sediment is widely contaminated with metals to some extent compared with the "Consensus-Based Sediment Quality Guidelines," and Cu, Cr, and Ni are more likely to raise ecological risks. This work could be a basis for the ongoing China's criteria strategy.     

Depositional behaviour of C-org, N, P and K in the surface sediments of two shallow water bodies in a tropical coast, India

The present paper deals with the distribution of sediment and sediment-bound nutrients in two important coastal lagoons of southern Kerala such as the Ashtamudi Estuarine Lagoon in the Kollam district and the Kadinamkulam Lagoon in the Thiruvananthapuram district. Among the two lagoons, the former is coast perpendicular, and the latter is coast parallel. An analysis of the textural characteristics reveals that, in both lagoons, the estuarine mouth and areas close to it are dominated by sand and sand-rich sediment species, indicating a high-energy depositional regime prevailing the region. On the other hand, the silt and clay dominant arms are almost sheltered and enjoy a low-energy depositional environment. The nutrient and organic carbon contents in the sheltered areas are significantly higher than the most dynamic high-energy estuarine mouth regions. This peculiar behaviour of these coastal water bodies has to be given adequate importance while laying down strategies for the conservation and management of these fragile aquatic systems in the south-western coast of India in particular and tropical coasts of the world in general.     

Fractionation of heavy metals and phosphorus in suspended sediments of the Yamuna river,India

The Yamuna river is the largest tributary of the Ganges river system. It originates in the Himalayas and flows through a varied geological terrain encompassing a large basin area. Metals Fe, Mn, Pb, Zn, Cu in different chemical fractions of suspended sediments such as exchangeable, carbonates, Fe–Mn oxides, organics and residual fractions were studied. Phosphorus associated with different chemical forms are discussed. The metals are mostly associated with residual fractions in the sediments followed by organics, Fe–Mn oxides, exhangeable and carbonates. Intensive use of chemical fertilizers and pesticides in agriculture in the basin affects the high inorganic phosphorus content in sediments.