基于改进的安全检查表法的尾矿库安全现状定量评价

尾矿库作为矿山选矿企业的重要组成部分,也是矿山企业最大的危险源之一。提出了一种改进的安全检查表法,用于尾矿库安全现状的定量评价与分析。该方法先根据尾矿库的特点划分评价单元,对不同评价单元赋予不同权重;再根据相关规范和标准列举各评价单元的检查项目,并根据对尾矿库安全的影响程度划分检查项目的等级并量化;最后对尾矿库各检查项目进行现场勘察并赋分,计算尾矿库各评价单元的得分率和尾矿库的总得分率,据此对尾矿库的安全现状进行定量评价与分级。以北京市怀柔区8座闭库尾矿库为例,利用改进的安全检查表法对其安全现状进行定量评价,验证了该方法的可行性和有效性。     

基于“天地一体化”指标的尾矿库安全预警技术研究

尾矿库是一项巨大的环境风险源,一旦发生事故,会给周边环境带来严重危害,因而成为环境监管的重点。近年来,尾矿库事故频发,严重危害周边环境安全,使得尾矿库环境应急管理工作面临严峻形势。尾矿库安全预警可为尾矿库自身安全及周边环境安全管控等提供重要决策支持。为此,文章综合前人已有的相关研究成果,在充分利用现有以地面调查指标为主的指标体系的基础上,利用遥感补充获取尾矿库所在区域宏观背景指标信息,以此构建基于"天地一体化"指标和模糊层次分析法的尾矿库安全预警技术方法;并在广西河池市为例,开展该方法的试点应用,对试点尾矿库的安全风险进行评估和识别,针对其中的重点风险尾矿库进行了事故后的影响范围和响应时间的预警分析。相关的技术方法拓展了遥感技术应用,发展了尾矿库预警的方法,同时相关的试点应用成果可为当地尾矿库环境应急管理工作提供支持。     

基于证据理论的尾矿库安全评价

在尾矿库安全评价中,各种因素指标之间的关系存在不确定性,而证据理论作为一种处理不确定性的有效工具,已经被广泛应用到很多研究领域。本文尝试应用证据理论解决尾矿库安全评价中的不确定性问题,建立了基于D-S证据理论的尾矿库安全评价模型,并通过实例计算验证了证据理论应用于尾矿库安全评价的可行性和有效性。     

SPA和模糊数学在尾矿库安全评价中的应用研究

在传统安全评价中,由于安全系统的灰色性、评价环境的复杂性以及评价者知识储备的有限性,导致安全评价方法对尾矿库安全性难以做出全面准确的有效评价。为了更好地对尾矿库的安全状况进行综合评价,将模糊数学与集对分析引入到聚类分析和安全评价过程中,建立了基于SPA模糊聚类的综合评价方法,削弱了评价过程中的主观性,利用了灰色信息,结合工程实例证明该方法在尾矿库安全评价中的有效性,为尾矿库安全科学评价提供了一种新途径。     

水量平衡法在尾矿库废水排放量计算中的应用

尾矿库废水排放量的计算和确定在尾矿库建设项目地表水环境影响评价工作中至关重要。本文采用水量平衡计算方程计算尾矿库中水的盈亏量,根据尾矿库调洪库容,确定尾矿库废水排放量。该方法的运用,为尾矿库建设项目地表水环境影响评价提供了一定的借鉴。     

基于可拓学的尾矿库安全评价

为综合评价尾矿库的安全状态,基于尾矿库灾变机理和大量工程实践构建了一套包括3级指标、22个因素的评价指标体系,并确定了评价指标的等级量值区间。采用EAHP和熵权法结合的方式确定指标权重,基于可拓理论评价尾矿库的安全等级。以湖南黄金集团责任有限公司旗下的7座尾矿库为案例,评价其安全状态,根据蒙特卡洛模拟基本理论,基于Crystal Ball对案例进行敏感性分析,找出具体敏感因素,为后期尾矿库安全管理提供简单有效的控制方法。     

尾矿库溃坝及尾矿泄漏事故树安全评价与预防

对尾矿库的危害、安全评价方法以及预防措施进行了系统研究。采用事故树分析方法对某尾矿库进行安全评价,结果表明:引起尾矿库溃坝及尾矿泄漏的途径及原因均是多方面的,二者的途径分别为17种和12种,应在实际生产过程中密切关注这些途径,努力排查,加强预控;针对尾矿库可能出现的不同情况制定出科学合理的应对措施,加强事前预控,可减少尾矿库溃坝及尾矿泄漏事故。     

因子分析法在尾矿库环境评价中的应用

尾矿库作为矿山中最大的危险源之一,极易引发泥石流、滑坡和溃坝等地质灾害。造成尾矿库灾害的因素多样,针对尾矿库风险因素的不确定性等问题,本文采用因子分析方法对尾矿库风险指标进行评价。根据尾矿库灾难成因及特点,结合相关工程实际,确定库容、坝高等十项风险指标,建立因子分析风险评价模型,对各因子进行定量分析,确定主要风险成因,明确因子间的相互关系,为尾矿库风险控制提供参考。分析结果表明主矿种、附属矿种、库容和坝高是引起尾矿库风险的主要因素。     

我国金属矿山尾矿库安全管理模式的探讨

在概述我国金属矿山尾矿库安全管理及安全管理模式研究现状的基础上,结合实际尾矿库安全管理中存在的问题,建立了适合我国金属矿山尾矿库基于问题管理的安全管理模式。该模式具有较强的实用性和操作性,能促进尾矿库安全管理的法制化、规范化、专业化,提高尾矿库的安全管理水平,从而减少尾矿库事故的发生。     

我国尾矿库安全现状及管理措施探讨

针对我国尾矿库目前的基本情况,对其灾害事故进行了分类,有针对性地提出了减少尾矿库事故发生的切实可行的安全管理措施,对企业做好尾矿库的安全管理工作具有重要意义.     

Toxic effects of acetochlor, methamidophos and their combination on nifH gene in soil

Toxic effects of two agrochemicals on nifH gene in agricultural black soil were investigated using denaturing gradient gel electrophoresis （DGGE） and sequencing approaches in a microcosm experiment. Changes of soil nifH gene diversity and composition were examined following the application of acetochlor, methamidophos and their combination. Acetochlor reduced the nifH gene diversity （both in gene richness and diversity index values） and caused changes in the nifH gene composition. The effects of acetochlor on nifH gene were strengthened as the concentration of acetochlor increased. Cluster analysis of DGGE banding patterns showed that nifH gene composition which had been affected by low concentration of acetochlor （50 mg/kg） recovered firstly. Methamidophos reduced nifH gene richness that except at 4 weeks. The medium concentration of methamidophos （150 mg/kg） caused the most apparent changes in nifH gene diversity at the first week while the high concentration of methamidophos （250 mg/kg） produced prominent effects on nifH gene diversity in the following weeks. Cluster analysis showed that minimal changes of nifH gene composition were found at 1 week and maximal changes at 4 weeks. Toxic effects of acetochlor and methamidophos combination on nifH gene were also apparent. Different nifH genes （bands） responded differently to the impact of agrochemicals： four individual bands were eliminated by the application of the agrochemicals, five bands became predominant by the stimulation of the agrochemicals, and four bands showed strong resistance to the influence of the agrochemicals. Fifteen prominent bands were partially sequenced, yielding 15 different nifH sequences, which were used for phylogenetic reconstructions. All sequences were affiliated with the alpha- and beta-proteobacteria, showing higher similarity to eight different diazotrophic genera.     

Arsenic uptake by arbuscular mycorrhizal maize （Zea mays L.） grown in an arsenic-contaminated soil with added phosphorus

The effects of arbuscular mycorrhizal (AM) fungus (Glomus mosseae) and phosphorus (P) addition (100 mg/kg soil) on arsenic (As) uptake by maize plants (Zea mays L.) from an As-contaminated soil were examined in a glasshouse experiment.Non-mycorrhizal and zero-P addition controls were included.Plant biomass and concentrations and uptake of As,P,and other nutrients,AM colonization,root lengths,and hyphal length densities were determined.The results indicated that addition of P significantly inhibited root colonization and development of extraradical mycelium.Root length and dry weight both increased markedly with mycorrhizal colonization under the zero-P treatments,but shoot and root biomass of AM plants was depressed by P application.AM fungal inoculation decreased shoot As concentrations when no P was added,and shoot and root As concentrations of AM plants increased 2.6 and 1.4 times with P addition,respectively.Shoot and root uptake of P,Mn,Cu,and Zn increased,but shoot Fe uptake decreased by 44.6%,with inoculation, when P was added.P addition reduced shoot P,Fe,Mn,Cu,and Zn uptake of AM plants,but increased root Fe and Mn uptake of the nonmycorrhizal ones.AM colonization therefore appeared to enhance plant tolerance to As in low P soil,and have some potential for the phytostabilization of As-contaminated soil,however,P application may introduce additional environmental risk by increasing soil As mobility.     

Impact of atrazine and nitrogen fertilizers on the sorption of chlorotoluron in soil and model sorbents

Sorption of chlorotoluron in ammonium sulfate, urea and atrazine multi-solutes system was investigated by batch experiments. The results showed application of nitrogen fertilizers to the soil could affect the behavior of chlorotoluron. At the same concentration of N, sorption of chlorotoluron decreased as the concentration of atrazine increased on the day 0 and 6 in soil, respectively. The sorption of chlorotoluron increased from 0 to 6 d when soils were preincubated with deionized water, ammonium sulfate and urea solution for 6 d. That indicated incubation time was one of the most important factors for the sorption of chlorotoluron in nitrogen fertilizers treatments. The individual sorption isotherms of chlorotoluron in rubbery polymer and silica were strictly linear in single solute system, but there were competition sorption between pesticides or between pesticides and nitrogen fertilizers. That indicated the sorption taken place by concurrent solid-phase dissolution mechanism and sorption on the interface of water-organic matter or water-mineral matter.     

Degradation of metabolites accumulated of benzo[a]pyrene by coupling Penicillium Chrysogenum with KMnO4

Several main metabolites of benzo[a]pyrene （BaP） formed by Penicillium chrysogenum, Benzo[a]pyrene-1,6-quinone （BP 1,6- quinone）, trans-7,8-dihydroxy-7,8-dihydrobenzo[a]pyrene （BP 7,8-diol）, 3-hydroxybenzo[a]pyrene （3-OHBP）, were identified by high-performance liquid chromatography （HPLC）. The three metabolites were liable to be accumulated and were hardly further metabolized because of their toxicity to microorganisms. However, their further degradation was essential for the complete degradation of BaP. To enhance their degradation, two methods, degradation by coupling Penicillium chrysogenum with KMnO4 and degradation only by Penicillium chrysogenum, were compared; Meanwhile, the parameters of degradation in the superior method were optimized. The results showed that （1） the method of coupling Penicillium chrysogenum with KMnO4 was better and was the first method to be used in the degradation of BaP and its metabolites; （2） the metabolite, BP 1,6-quinone was the most liable to be accumulated in pure cultures; （3） the effect of degradation was the best when the concentration of KMnO4 in the cultures was 0.01% （w/v）, concentration of the three compounds was 5 mg/L and pH was 6.2. Based on the experimental results, a novel concept with regard to the bioremediation of BaP-contaminated environment was discussed, considering the influence on environmental toxicity of the accumulated metabolites.     

Potential of plant polyphenol oxidases in the decolorization and removal of textile and non-textile dyes

In this study an effort has been made to use plant polyphenol oxidases; potato （Solanum tuberosum） and brinjal （Solanum melongena）, for the treatment of various important dyes used in textile and other industries. The ammonium sulphate fractionated enzyme preparations were used to treat a number of dyes under various experimental conditions. Majority of the treated dyes were maximally decolorized at pH 3.0. Some of the dyes were quickly decolorized whereas others were marginally decolorized. The initial first hour was sufficient for the maximum decolorization of dyes. The rate of decolorization was quite slow on long treatment of dyes. Enhancement in the dye decolorization was noticed on increasing the concentration of enzymes. The complex mixtures of dyes were treated with both preparations of polyphenol oxidases in the buffers of varying pH values. Potato polyphenol oxidase was significantly more effective in decolorizing the dyes to higher extent as compared to the enzyme obtained from brinjal polyphenol oxidase. Decolorization of dyes and their mixtures, followed by the formation of an insoluble precipitate, which could be easily removed simply by centrifugation.     

Effects of two sludge application on fractionation and phytotoxicity of zinc and copper in the soil

The potential harm of heavy metals is a primary concern in application of sludge to the agricultural land. A pot experiment was conducted to evaluate the effect of two sludges on fractionation of Zn and Cu in soil and their phytotoxicity to pakchoi. The loamy soil was mixed with 0%, 20%, 40%, 60% and 80% (by weight) of digested sewage sludge (SS) and composted sludge (SC). The additions of both sludges caused a significant raise in all fractions, resulting in that exchangeable (EXCH) and organic bound (OM) became predominance of Zn and organic bound Cu occupied the largest portion. There was more available amount of Zn and Cu in SS treatments than SC treatments. During the pot experiment, the concentration of Zn in EXCH, carbonate (CAR) and OM and Cu in EXCH and OM fractions decreased in all treatments, so their bioavailability reduced. Germination rate and plant biomass decreased when the addition rate was high and the best yield appeared in 20% mixtures at the harvest of pakchoi. The two sludges increased tissue contents of Zn and Cu especially in the SS treatments. Zn in pakchoi was not only in relationship to ΔEXCH and ΔCAR forms but also in ΔOM forms in the sludge-soil mixtures. Tissue content of Cu in pakchoi grown on SC-soils could not be predicted by ΔEXCH. These correlation rates between Zn and Cu accumulation in pakchoi and variation of different fractions increased with time, which might indicate that sludges represented stronger impacts on the plant in long-term land application.     

Intraspecific differences in effects of co-contamination of cadmium and

A hydroponic experiment was carried out to study intraspecific differences in the effects of different concentrations of cadmium (Cd)(0-10 mg/L) and arsenate (As(V)) (0-8 mg/L) on the growth parameters and accumulation of Cd and As in six wheat varieties Jing-9428, Duokang-1, Jingdong-11, Jing-411, Jingdong-8 and Zhongmai-8. The endpoints of wheat seedlings, including seed germination,biomass, root length and shoot height, decreased with increasing the Cd and As concentrations. Significant differences in seed germination, biomass, root length, shoot height and the accumulation of Cd and As were observed between the treatments and among the varieties (p ＜ 0.05). The lethal dosage 50% were about 20, 80, 60, 60, 80 and 20 mg As/L for Jing-9428, Duokang-1, Jingdong-11,Jing-411, Jingdong-8 and Zhongmai-8, respectively, and the corresponding values for Cd were about 30, 80, 20, 40, 60 and 10 mg Cd/L, respectively. Among the six varieties, Duokang-1 was found to be the most resistant to Cd and As toxicity, and Zhongmai-8 was the most sensitive to Cd and As co-contamination. The resistance of the six varieties was found dependant on the seedling uptake of Cd and As. Duokang-1 was the most suitable for cultivation in Cd and As co-contaminated soils.     

Removal of heavy metals from sewage sludge by low costing chemical method and recycling in agriculture

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Isolation and preliminary characterization of a 3-chlorobenzoate degrading bacteria

A study was conducted to compare the diversity of 2-, 3-, and 4-chlorobenzoate degraders in two pristine soils and one contaminated sewage sludge. These samples contained strikingly different populations of mono-chlorobenzoate degraders. Although fewer cultures were isolated in the uncontaminated soils than contaminated one, the ability of microbial populations to mineralize chlorobenzoate was widespread. The 3- and 4-chlorobenzoate degraders were more diverse than the 2-chlorobenzoate degraders. One of the strains isolated from the sewage sludge was obtained. Based on its phenotype, chemotaxonomic properties and 16S rRNA gene, the organism S-7 was classified as Rhodococcus erythropolis. The strain can grow at temperature from 4 to 37℃. It can utilize several （halo）aromatic compounds. Moreover, strain S-7 can grow and use 3-chlorobenzoate as sole carbon source in a temperatures range of 10-30℃ with stoichiometric release of chloride ions. The psychrotolerant ability was significant for bioremediation in low temperature regions. Catechol and chlorocatechol 1,2-dioxygenase activities were present in cell free extracts of the strain, but no （chloro）catechol 2,3- dioxygenase activities was detected. Spectral conversion assays with extracts from R. erythropolis S-7 showed accumulation of a compound with a similar UV spectrum as chloro-cis,cis-muconate from 3-chlorobenzoate. On the basis of these results, we proposed that S-7 degraded 3-chlorobenzoate through the modified ortho-cleave pathway.     

Single and joint effects of pesticides and mercury on soil urease

The influence of two pesticides including chlorimuron-ethyl and furadan and mercury （Hg） on urease activity in 4 soils （meadow burozem and phaeozem） was investigated. The soils were exposed to various concentrations of the two pesticides and Hg individually and simultaneously. Results showed that there was a close relationship between urease activity and organic matter content in soil. Chlorimuron-ethyl and furadan could both activate urease in the 4 soils. The maximum increment of urease activity by chlorimuronethyl was up to 14%-18%. There was almost an equal increase （up to 13%-21%） in the urease activity by furadan. On the contrary, Hg markedly inhibited soil urease activity. A logarithmic equation was used to describe the relationship （P〈0.05） between the concentration of Hg and the activity of soil urease in the 4 tested soils. Semi-effect dose （ED50） values by the stress of Hg based on the inhibition of soil urease in the 4 soils were 88, 5.5, 24 and 20 mg/kg, respectively, according to the calculation of the corresponding equations. The interactive effect of chlorimuron-ethyl or furadan with metal Hg on soil urease was mainly synergic at the highest tested concentrations.