A future perspective on lithium-ion battery waste flows from electric vehicles

As a proactive step towards understanding future waste management challenges, this paper presents a future oriented material flow analysis (MFA) used to estimate the volume of lithium-ion battery (LIB) wastes to be potentially generated in the United States due to electric vehicle (EV) deployment in the near and long term future. Because future adoption of LIB and EV technology is uncertain, a set of scenarios was developed to bound the parameters most influential to the MFA model and to forecast “low,” “baseline,” and “high” projections of future end-of-life battery outflows from years 2015 to 2040. These models were implemented using technology forecasts, technical literature, and bench-scale data characterizing battery material composition. Considering the range from the most conservative to most extreme estimates, a cumulative outflow between 0.33 million metric tons and 4 million metric tons of lithium-ion cells could be generated between 2015 and 2040. Of this waste stream, only 42% of the expected materials (by weight) is currently recycled in the U.S., including metals such as aluminum, cobalt, copper, nickel, and steel. Another 10% of the projected EV battery waste stream (by weight) includes two high value materials that are currently not recycled at a significant rate: lithium and manganese. The remaining fraction of this waste stream will include materials with low recycling potential, for which safe disposal routes must be identified. Results also indicate that because of the potential “lifespan mismatch” between battery packs and the vehicles in which they are used, batteries with high reuse potential may also be entering the waste stream. As such, a robust end-of-life battery management system must include an increase in reuse avenues, expanded recycling capacity, and ultimate disposal routes that minimize risk to human and environmental health.     

Investigating household preferences for kerbside recycling services in London: a choice experiment approach

Recent developments in national and European Union waste management policy have prompted considerable interest in alternative waste management programs, such as recycling, which could divert a portion of the municipal solid waste stream from landfills. This paper examines household preferences for kerbside recycling services and uses a stated preference choice experiment method to estimate households' valuation of such services. Using a sample of 188 households in the London area, the empirical analysis yields estimates of the willingness to pay for the number of 'dry' materials collected, the collection of compost, textile collection and the frequency of collection.     

Costs and benefits of packaging waste recycling systems

This Special Issue provides several different perspectives on the complex issue of packaging waste recycling. It comprises a diverse and rich set of contributions with insights from very different disciplines that range from economics to engineering. All types of “costs and benefits” are addressed in this collection of articles. In addition to the economic and strictly financial impacts of selective collection and sorting of packaging waste, several authors discuss other types of impacts, such as the environmental and social ones. The reader will find articles that address recycling systems as a whole, pieces that focus on specific impacts and detailed discussions of particular material streams or waste management strategies. The Special Issue represents an indispensable resource for academics, policy-makers and practitioners with interests in recycling and packaging waste management.     

Life cycle inventory of recycling portable nickel–cadmium batteries

In this study, the environmental impact of recycling portable nickel–cadmium (NiCd) batteries in Sweden is evaluated. A life cycle assessment approach was used to identify life cycle activities with significant impact, the influence of different recycling rates and different time boundaries for emissions of landfilled metals. Excluding the user phase of the battery, 65% of the primary energy is used in the manufacture of batteries while 32% is used in the production of raw materials. Metal emissions from batteries to water originate (96–98%) from landfilling and incineration. The transportation distance for the collection of batteries has no significant influence on energy use and emissions. Batteries manufactured with recycled nickel and cadmium instead of virgin metals have 16% lower primary energy use. Recycled cadmium and nickel metal require 46 and 75% less primary energy, respectively, compared with extraction and refining of virgin metal. Considering an infinite time perspective, the potential metal emissions are 300–400 times greater than during the initial 100 years. From an environmental perspective, the optimum recycling rate for NiCd batteries tends to be close to 100%. It may be difficult to introduce effective incitements to increase the battery collection rate. Cadmium should be used in products that are likely to be collected at the end of their life, otherwise collection and subsequent safe storage in concentrated form seems to offer the best solution to avoid dissipative losses.     

An overview of waste materials recycling in the Sultanate of Oman

Various wastes and by-product materials are generated in the Sultanate of Oman including reclaimed asphalt pavement (RAP) aggregate, demolition concrete, cement by-pass dust (CBPD), copper slag, petroleum-contaminated soils (PCS), discarded tires, incinerator ash, and others. Recycling of such materials in construction is not practiced. Research data are also minimal into the potential use of selected materials in construction applications. This paper will present the results of several laboratory studies conducted into the use of PCS in asphalt concrete mixtures; on the use of CBPD in soil stabilization and flowable fill mixtures; on the utilization of copper slag and CBPD as cementitious materials; on the use of incinerator ash in cement mortars; and on the use of RAP aggregate in road bases and sub-bases. Laboratory data generally indicate that it is feasible to partially reuse some of these materials in construction provided that economic incentives and environmental concerns are taken into consideration.     

Current results and future perspectives for Japanese recycling of home electrical appliances

The Japanese system of recycling home electrical appliances has several unique aspects, including (1) a limited number of target appliances, (2) a recycling fee system that requires consumers to pay a recycling fee at the time of disposal, and (3) a direct recycling obligation for manufacturers, who have a physical, rather than a financial, responsibility for their end-of-life products. We studied data from 2001 to 2007 and found that the amount of four specified home electrical appliances and their materials that was recycled increased from about 319,249 tonnes in 2001 to about 447,262 tonnes—or 3.5 kg per inhabitant—in 2006. Recycling yield and development of recycling technologies have also improved. New recycling technologies have enabled a higher rate of material recycling of plastics (i.e., a closed-loop recycling). Improved eco-design, such as design for easier disassembly, has been promoted, and the higher quality of discarded appliances has enhanced the reuse market. Hazardous substances and fluorocarbons are being well managed. Problems with the recycling system include inelastic recycling fees, illegal dumping, illegal transfer by retailers, and the limited number of target appliances. Recycling fees could be reduced; this move might reduce the incidence of illegal dumping, as would engage stakeholders in collaborative efforts against illegal dumping. Illegal transfers could be reduced by improved traceability for retailers. Products such as liquid crystal displays, plasma display panels and clothes dryers have become increasingly common and should be also be targeted for recycling.     

The recycling of rare earths from waste tricolor phosphors in fluorescent lamps: A review of processes and technologies

Rare earths have become the most important strategic resources, widely used as functional materials in industry and many other aspects of life due to its optical, electrical, and magnetic characteristics. As a consequence, a considerable number of wastes containing rare earths such as abandoned fluorescent lamps are generated and lost. Considering the scarcity in availability and supply of certain raw materials, waste tricolor phosphors are viewed as potential resources that can be mined in urban areas for their reutilization as rare earths. A number of studies in this area have been carried out all over the world.The purpose of this paper is to review the current status of recycling technologies of rare earths from waste tricolor phosphors in fluorescent lamps. The main characteristics of the tricolor phosphors were introduced, and also a detail review of the typical single recycling and reusing technologies with regard to waste tricolor phosphors was carried out in present paper. After that, several combined recycling processes and technologies were evaluated. Based on the review, the prospects of recycling technologies were suggested.     

废弃电池能否进入废弃电器电子产品处理目录(第二批)管理的筛选评估分析

2009年2月,国务院发布《废弃电器电子产品回收处理管理条例》,成为我国废弃电器电子产品回收处理的纲领性文件。在《废弃电器电子产品处理目录(第一批)》中,明确将电视机、电冰箱、洗衣机、房间空调器、微型计算机等5种产品纳入第一批目录。同时,为了为了能够及时、客观地与经济发展、技术进步以及电器电子产品行业的发展变化等相适应,《目录》管理委员会起草了《制订和调整废弃电器电子产品处理目录的若干规定》,明确随着经济发展变化及电子产品废弃形势调整电器电子产品处理目录的原则。废弃电池在近几年来在我国增长速度很大,将来的管理形势十分紧迫。本文在此分析我国几种废弃电池(铅酸电池、镍氢电池及锂电池)的产生量、再生处理处置情况及管理政策导向。并在目录一批筛选原则的基础上利用权重分析法,筛选评估废弃电池能否进入废弃电器电子产品处理目录(第二批)管理的可能,研究显示铅酸电池已具备进入管理目录的资质。     

Electronic waste recycling: A review of U.S. infrastructure and technology options

The useful life of consumer electronic devices is relatively short, and decreasing as a result of rapid changes in equipment features and capabilities. This creates a large waste stream of obsolete electronic equipment, electronic waste (e-waste).Even though there are conventional disposal methods for e-waste, these methods have disadvantages from both the economic and environmental viewpoints. As a result, new e-waste management options need to be considered, for example, recycling. But electronic recycling has a short history, so there is not yet a solid infrastructure in place.In this paper, the first half describes trends in the amount of e-waste, existing recycling programs, and collection methods. The second half describes various methods available to recover materials from e-waste. In particular, various recycling technologies for the glass, plastics, and metals found in e-waste are discussed. For glass, glass-to-glass recycling and glass-to-lead recycling technologies are presented. For plastics, chemical (feedstock) recycling, mechanical recycling, and thermal recycling methods are analyzed. Recovery processes for copper, lead, and precious metals such as silver, gold, platinum, and palladium are reviewed. These processes are described and compared on the basis of available technologies, resources, and material input–output systems.     

Mixed signals: market incentives, recycling, and the price spike of 1995

Environmental economics assumes that reliance on price signals, adjusted for externalities, normally leads to efficient solutions to environmental problems. We explore a limiting case, when market volatility created ‘mixed signals’: prices of waste paper and other recycled materials were suddenly extremely high in 1994–1995, then plummeted back to traditional low levels in 1996. These rapid reversals resulted in substantial economic and political costs. A review of academic and business literature suggests six possible explanations for abrupt price spikes. An econometric analysis of the prices of wood pulp and waste paper shows that factor which explained price changes in 1983–1993 contribute very little to understanding the subsequent price spike. From the econometric analysis and from other sources, we conclude that speculation must have played a major role in the price spike, perhaps in combination with modest effects from changes in government policy and in export demand. If speculatively driven price spikes can disrupt an environmentally important industry such as recycling, what is the appropriate role for public policy? When price volatility is sufficiently disruptive, then measures to control or stabilize prices, rather than interfering with the market, might help to make it more efficient.     

Market imperfections in recycling markets: conceptual issues and empirical study of price volatility in plastics

The effectiveness of recycling depends upon efficient functioning of secondary material markets. This paper focus on the role that price volatility can play in slowing investment and market development. However, a statistical analysis of the relative volatility of secondary and primary material prices does not confirm the widely-held belief that relative price volatility is higher in secondary than in primary materials, at least at national levels.An econometric estimation of the determinants of plastic recovery volumes in Seattle contributes to the literature in four ways: the use of monthly (as opposed to annual) data; the use of local (as opposed to national) data; the use of an explanatory variable to reflect price volatility; and, the focus on plastics, which have not been examined previously. Some tentative conclusions can be made: the results generally support the principal hypothesis that price volatility has a negative effect on recovery of secondary materials; in addition, and consistent with previous studies, price elasticities are low and insignificant; and finally, policy factors are clearly important. The concluding section treats the economic and policy implications of market inefficiency in secondary material markets.     

The future place of recycling in household waste policy: the case of France

To be rightly implemented, an environmental policy ought to set an institutional framework (goals, rules and instruments) which incents decentralised actors to adopt the appropriate range of technologies. In the household waste management policy, the development of valorisation techniques (and particularly recycling) must be supported by convenient instruments and incentives. The paper analyses the problems encountered with the French household waste policy to ensure the takeoff of recycling techniques. At the moment, a rather under-proportioned institutional setting leads to favour the adoption of incineration with energy recovery at the expenses of recycling. This tends to create a structural bias in favour of incineration.     

Why recycle? A comparison of recycling motivations in four communities

Four Illinois communities with different sociode-mographic compositions and at various stages of planning for solid waste management were surveyed to determine the influence of sociodemographic variables and planning stages on the factors that motivate recycling behavior. A factor analysis of importance ratings of reasons for recycling and for not recycling yielded five factors interpreted as altruism, personal inconvenience, social influences, economic incentives, and household storage. The four communities were shown to be significantly different in multivariate analyses of the five motivational factors. However, attempts to explain these community differences with regression analyses, which predicted the motivational factors with dummy codes for planning stages, a measure of self-reported recycling behavior, and sociodemographic measures were unsatisfactory. Contrary to expectation, the solid waste management planning stages of the cities (curbside pickup, recycling dropoff center, and planning in progress) contributed only very slightly to the prediction of motivational factors for recycling. Community differences were better explained by different underlying motivational structures among the four communities. Altruistic reasons for recycling (e.g., conserving resources) composed the only factor which was similar across the four communities. This factor was also perceived to be the most important reason for recycling by respondents from all four communities. The results of the study supported the notion that convenient, voluntary recycling programs that rely on environmental concern and conscience for motivation are useful approaches to reducing waste.     

The effects on waste reduction and recycling rates when different components of the waste stream are counted

States differ in the components or solid waste management activities which they include when determining solid waste reduction and recycling rates. Thus, when attempting to draw comparisons among states, confusion arises in two ways: (1) use of two types of rates; and (2) use of different components or activities when calculating a given rate. This paper presents a mathematical basis for understanding the impacts on rate calculations when variations occur in the components and activities included in those calculations. Estimates of the incremental changes occurring in the rate calculations when incineration or selected components such as yard waste, construction and demolition wastes, and junked automobiles, are added to a base of municipal solid waste constituents are found using national data. Finally, the achieved rates reported by states counting different combinations are compared.     

Utilising of the oiled rolling mills scale in iron ore sintering process

Up to 5% of steel is lost with the scale at hot rolling operation. This waste contains 69-72% of iron in the form of oxides. However, its recycling is confronted with presence of up to 20% of oil and 10% of water. E.g. when the oiled scale is introduced as an additive to the iron ore sintering mixture, incomplete combustion of liberated oil at heating during sintering process creates problems for gas cleaning and may even lead to damage of the equipment. A possibility to improve combustion of the scale's oil at the sintering process by preparation of a mixture with peat was shown in the laboratory experiments. Industrial trials demonstrate possibility to increase the oil combustion degree at sintering 2.7 times as much. Consumption of the oiled scale was increased from zero to 12.8 kg (in a form of scale-peat blend) per ton of sinter, which allows for closing the loop of this waste at the integrated steelmaking factory.     

Life cycle assessment of waste paper management: The importance of technology data and system boundaries in assessing recycling and incineration

The significance of technical data, as well as the significance of system boundary choices, when modelling the environmental impact from recycling and incineration of waste paper has been studied by a life cycle assessment focusing on global warming potentials. The consequence of choosing a specific set of data for the reprocessing technology, the virgin paper manufacturing technology and the incineration technology, as well as the importance of the recycling rate was studied. Furthermore, the system was expanded to include forestry and to include fossil fuel energy substitution from saved biomass, in order to study the importance of the system boundary choices. For recycling, the choice of virgin paper manufacturing data is most important, but the results show that also the impacts from the reprocessing technologies fluctuate greatly. For the overall results the choice of the technology data is of importance when comparing recycling including virgin paper substitution with incineration including energy substitution. Combining an environmentally high or low performing recycling technology with an environmentally high or low performing incineration technology can give quite different results. The modelling showed that recycling of paper, from a life cycle point of view, is environmentally equal or better than incineration with energy recovery only when the recycling technology is at a high environmental performance level. However, the modelling also showed that expanding the system to include substitution of fossil fuel energy by production of energy from the saved biomass associated with recycling will give a completely different result. In this case recycling is always more beneficial than incineration, thus increased recycling is desirable. Expanding the system to include forestry was shown to have a minor effect on the results. As assessments are often performed with a set choice of data and a set recycling rate, it is questionable how useful the results from this kind of LCA are for a policy maker. The high significance of the system boundary choices stresses the importance of scientific discussion on how to best address system analysis of recycling, for paper and other recyclable materials.     

Analysis of the recycling potential of used automotive oil filters using the Life Cycle Assessment approach

The aim of this study is to evaluate whether a specific recycling system for used oil filters (UOFs) is environmentally viable by considering all steps of the product's life cycle. In that aspect an analysis of the environmental impacts regarding different waste management scenarios of UOFs in Greece is presented using the Life Cycle Assessment (LCA) approach. Waste scenarios varied from maximum feasible recycling and recovery of metals and used lubricant oil, to disposal of UOFs to landfills without any prior treatment. In order to perform this analysis, the principles of ISO 14040 were followed and a relevant LCA software was used (SimaPro 7.2). Additionally, the results of a previous work conducted by the authors were deployed, including some experimental measurements undertaken so as to evaluate and quantify the factors affecting the recovery of the lubricant oil contained in used automotive filters. Indicatively, it was estimated that a maximum of 1340 tons of used oil and 1810 tons of steel are disposed every year in Greece, as a result of the non-effective management of used automotive filters.     

Towards the estimation of demand for recycling in Chile: The case of Santiago

In developing countries, the recycling of municipal solid waste (MSW) as an alternative to the traditional MSW management requires an economic sustainability valuation. From this perspective, the estimation of demand for recycling is crucial. In this paper, we study the case of recycling MSW in Santiago, Chile. We estimate the relation between the monthly amount of MSW separated voluntarily from apartments located in Santiago and the monthly price required to participate in a municipal recycling program. We consider the transference of the municipal cost savings to the owners of the apartments due to the amount of MSW separated for recycling, which is not collected and deposited in the current MSW system. For the estimation, we use concepts from environmental economics and psychology, analyzing the operation and municipal costs incurred by current MSW management and designing and applying a survey based on a contingent valuation method (CVM) approach. The results indicate that the percentage of MSW separated for recycling varies between a 27.98% and 33.18%, that only four MSW types are affected by a variation of the monthly price, and that a reduction of monthly collection trips in the current MSW system from 24 to 18 can be obtained. Additionally, we discuss a number of methodological aspects to be considered in a similar study of valuation of recycling in developing countries. Our conclusion is that Santiago has favorable conditions for the implementation of a recycling program as an alternative to the current MSW system.     

Personality, individual differences, and demographic antecedents of self-reported household waste management behaviours

The present study sought to extend recent conceptual frameworks of waste management behaviours by examining personality, individual differences, and socio-demographic antecedents of self-reported waste recycling, reuse, and reduction behaviours. A total of 203 participants from a British community sample completed a questionnaire consisting of measures of their self-reported waste management behaviour, Machiavellianism, political cynicism, the Big Five personality traits, and socio-demographics. The results of structural equation modelling showed that individuals who were less Machiavellian, less politically cynical, older, and more conscientious were more likely to report positive waste management behaviours. In combination, these predictors explained 22.0% of the variance in waste management behaviours. Thus, these variables may improve the predictive validity of existing conceptual models of waste management behaviours. The results are discussed in relation to those models.     

Incorporation of recycling flows into economy-wide material flow accounting and analysis: A case study for the Czech Republic

Economy-wide material flow accounting and analysis (EW-MFA) is considered a convenient tool for monitoring the vast range of issues related to the consumption of materials. As an increase in recycling is considered a crucial way of decreasing environmental pressures from this consumption, it makes sense to develop an indicator based on EW-MFA which would incorporate recycling flows. A prominent example of such an indicator is the cyclical use rate, which was developed by the Japanese Fundamental Plan for Establishing a Sound Material-Cycle Society.We calculated this indicator for the Czech Republic for 2002–2011 and proved that it can also be calculated for countries other than Japan, even though we encountered some unclear methodological issues related to specific features of the Czech waste management system. We further developed two modifications of the indicator taking into consideration that one purpose of the cyclical use rate is to express the ratio of consumption of secondary (recycled) materials and primary raw materials. We discussed these modifications and showed that overall cyclical use rate in the Czech Republic lags behind Japan both in terms of absolute value and trend development, although the indicator is higher for biomass in the Czech Republic. We also showed that this unfavorable evaluation is in contradiction with some classic waste indicators, such as treatment of waste by main treatment methods which is favorably evaluated in the Czech Republic. We concluded that it would be advisable to analyze measures for increasing recycling rates introduced by Japan and assess their possible transposition into the Czech Republic's institutional and legal framework for waste management.