Waste minimization study in a solvent-based paint manufacturing plant

Solvent-based paint manufacturing plants produce significant quantities of hazardous waste, which must be properly treated before it can be disposed. Since the cost for treating this waste is high, reducing the quantity of waste has become a crucial issue in this industry.Waste minimization options are beneficial for the owner of the plant as well as for the environment. The quantity of hazardous waste can be minimized by changing the plant's technology or by substituting hazardous substances, which are used in the paint manufacturing process, with environmentally friendly ones. Furthermore, separating the various waste streams makes it easier to recover raw materials and enhances the possibility of their reuse within the production process. This will decrease operational costs for the plant.This paper presents a case study of waste minimization in a solvent-based paint manufacturing plant. Source reduction, recovery, and recycling methods are taken into consideration. Its aim is to develop an understanding of the facility's waste generating processes, to suggest ways to reduce the waste production, and finally to select an appropriate waste minimization option to suggest to the plant. Some of the suggested methods are currently being practiced while others are at initial stage of development.     

城市生活垃圾源减量化技术与对策

解决垃圾问题最好的方式是避免其产生,这样就无需收集、运输或处置。此外,源减量化在能源利用、温室气体排放和其他环境影响方面,要远优于其他诸如焚烧和填埋等处理方式。生活垃圾源减量化具有环境和经济的双重效益。本文阐述了生活垃圾源减量化的概念和特征,并通过借鉴美国在生活垃圾源减量化问题上的成功经验和成熟技术,探讨了适合上海的生活垃圾源减量化对策。     

Relating disposal-based solid waste reduction rates to recycling rates

Some states measure progress in their waste reduction programs on the basis of recycling rates, while others use disposal-based reduction rates. It is generally recognized that these two measures are conceptually distinct. Nevertheless, when informational surveys of waste reduction activities are compiled, the data are usually combined in a manner that blurs this distinction and complicates the issues involved. In this paper, these two concepts are defined in a precise manner and equations are derived which clearly depict the relationship between recycling rates and disposal-based reduction rates. Information from a national survey and the US Environmental Protection Agency is used to illustrate the concepts which are developed in the paper.     

Source separation recycling schemes: A survey

Municipal waste arisings continued to increase during the 1970s in all the industrialized economies. Currently, in the midst of a severe international economic recession, the continuing escalation in the costs of waste disposal poses significant problems for municipal authorities. With the data constraints firmly in mind, this paper estimates the secondary materials supply potential of the municipal waste stream. The calculations suggest that a significant supply potential remains to be utilized despite ‘respectable’ overall recycling rates in most industrial economies. Resource recovery options can be divided into ‘low technology’ source separation schemes and ‘high technology’ mechanical separation schemes. The authors concentrate on the former option and appraise (on the basis of social cost-benefit analysis) a number of schemes that have operated in both Europe and North America.     

Waste separation at home: Are Japanese municipal curbside recycling policies efficient?

Recent studies have predicted that the costs and benefits of curbside recycling programs will vary considerably across municipalities. In this paper, we examine how the characteristics of municipalities are reflected in curbside recycling policies. Our analysis of Japanese municipal data reveals that municipalities implement recycling programs that fit the demographic profiles of their residents. Municipalities with a considerable number of single-recycler households tend to implement simple waste separation programs. The labor market positions of spouses have different impacts on recycling policies. We further find that the municipalities implementing comprehensive recycling programs collect plastic bottles and containers more frequently than do other municipalities. This implies that the municipalities need to take measures to effectively execute comprehensive recycling programs after implementing them.     

Municipal solid waste production and composition in Finland—Changes in the period 1960–2002 and prospects until 2020

Waste reduction was recognised as the main goal of waste management policy in the EU in the 1990s. Although knowledge of past waste generation is essential for effective waste reduction policy there are no comprehensive statistics on the past development of municipal solid waste (MSW) production. MSW management is currently under turmoil in many EU countries as the requirements of the EC landfill directive (1999/31/EC) are set into force. In this study, the production and composition of MSW in Finland between 1960 and 2002 is presented using historical data. The impact of population, affluence and technology on MSW production are analysed using the IPAT equation and three scenarios are constructed until year 2020. The results are compared with national future targets on MSW production. Production of MSW increased in Finland until 1990, declined to year 1997, increased to 2000 and then declined again. The share of organic and plastic waste increased over the study period while the share of paper and cardboard declined. The results suggest that so far national targets on MSW reduction have been set fairly low. Moreover, our scenarios depict a wide range of future MSW production, even though the time horizon is not longer than 15 years into the future. In order to narrow this range, continuous improvement of the statistics of MSW is essential.     

Cleaner production opportunity assessment for a milk processing facility

Possible cleaner production (CP) opportunities for a milk processing facility were examined in this study. The CP concept and its key tools of implementation were used to assess the potential CP opportunities in the facility studied. The general production process and its resulting environmental loads were investigated by taking possible CP opportunities as the basis of study. The methodology developed for CP opportunity assessment in the milk processing facility covered two major steps: preparation of checklists to assist auditing and CP opportunity assessment, and implementation of the mass-balance analysis. For mass-balance analysis, measurements and experimental analysis of the mass flows were utilized to determine the inputs and outputs. Prepared checklists were utilized to determine waste reduction options that could be implemented. Selected opportunities were evaluated considering their environmental benefits and economic feasibility. The results of the study indicated that 50% of the service water used, 9.3% of the current wastewater (WW) discharge, 65.36% of the chemical use and the discharge of 181.9 kg/day of chemical oxygen demand (COD) and 20.7 kg/day of total suspended solids (TSS) could be eliminated and 19.6% of the service water used could be recycled/reused.     

减污降碳背景下的工业园区清洁生产审核技术研究

工业园区具有产业集聚、污染物与温室气体排放集中的特点,是推动减污降碳协同治理的重要力量。清洁生产审核通过对生产和服务过程进行全链条调查诊断,提出节能降耗、减污增效的方案,与减污降碳具有高度的目标协同性和路径一致性。本研究从工业园区清洁生产审核“审什么”“如何审”“如何评”的三个核心问题着手,提出了园区清洁生产审核重点的识别技术、审核问题的诊断技术、审核绩效的评价技术以及园区清洁生产审核管理体系建立要点,构建了以工业园区清洁生产审核为抓手促进园区减污降碳的实施路径,并提出了推动园区清洁生产审核工作的政策建议。本研究基于三大核心技术构建的工业园区清洁生产审核路径可形成规范化、标准化、可复制的技术方法,为全面推进工业园区减污降碳协同增效提供技术支撑。     

Phosphorus resources,their depletion and conservation,a review

Yearly, about 22 × 10¹² g phosphorus (P) from mined fossil phosphate resources are added to the world economy. The size of remaining fossil phosphate resources is uncertain but practically finite. Thus, fossil P resources may become depleted by ongoing mining. Despite calls for resource conservation, fossil P resources have been depleted at an increasing rate. Geographically, fossil P supply and demand are distributed in an increasingly uneven way, which has geopolitical consequences and may well affect security of supply. Current use of P gives rise to negative environmental impacts due to P losses from the economy and contaminants derived from fossil P resources. There may also be negative impacts on human health. Reducing the demand for fossil phosphorus may reduce environmental burdens and may improve the future security of supply. Technically speaking, there is much scope for the reduction of current demand for fossil P resources. Limiting consumption of P to essential uses, increased efficiency of agricultural use and increased recycling of P may substantially contribute to the reduction of demand for fossil P resources. Recycling of P has to face concerns regarding the efficiency of P recovery, pathogenic organisms and contaminating substances. Much work remains to be done to effectively address those concerns.     

Junk-buyers as the linkage between waste sources and redemption depots in urban China: the case of Wuhan

This paper locates junk-buyers in the recycling chain that includes waste source, collection system and end-user. With increasing needs of convenience for recycling at waste sources but disappearing redemption depots in city blocks of China, junk-buyers play a role of linkage between waste sources and redemption depots. It is these door-to-door collectors who make the general public aware of cash value inside recyclable waste. Also, the motivation of getting cash back pushes junk-buyers become immediate suppliers to redemption depots. Without junk-buyers as door-to-door collectors, the current waste recovery system in post-Mao's China would brake down. However, as in other developing countries, the junk-buyer occupation in urban China currently is typically driven by economic incentives, and the door-to-door collection of recyclable waste completely falls into junk-buyer individual business. It is difficult for junk-buyers who mainly come from the countryside to establish stable relations with waste sources for lack of recognition from urban society. The appropriate allocation of individual time and space becomes crucial to conducting the door-to-door activities so as to collecting more recyclables. While the collecting territory as the condition of production is positively reflected by the usual extent of the collecting distance, junk-buyers mostly spend time in finding sellers instead of simply expanding their collecting territory. This is a typical example of the cheapest and lowest skilled labor forces being in relatively unlimited supply in a developing country.     

基于源流域水量水质模型研究小流域营养物管理方案

采用澳大利亚源流域水量水质模型模拟东山小流域内2001-2010年9种不同土地利用类型产生的降雨径流及总氮和总磷的污染负荷,模拟结果为:流域内多年平均径流量为6 150万m3/a,总氮输出负荷为270 t/a,总磷负荷为22 t/a。模拟结果表明:水产养殖塘和高地茶果树是东山地区主要的营养物来源。通过三个情景方案的模拟,说明当地环境管理方案可以有效地削减入湖的营养负荷,其中第二个情景方案的削减量最大,总氮和总磷负荷分别削减了18%和25%。     

What Is Source Reduction? A Critique and Comparative Analysis of Polish and American Students

/ Source reduction is recognized as the preferred form of waste management, but its definition is ambiguous. This study proposes four underlying dimensions of the source reduction concept. Source reduction is foremost a preventive activity that reduces the number or extent of environmental impacts. Second, source reduction can prevent both resource consumption and pollution generation impacts. Third, source reduction may be viewed as both a producer and consumer activity. Lastly, it may include frugal and more efficient activities. In surveys exploring these fourdimensions, Polish and American university students evaluated whether 20 activities were examples of source reduction. The American students gave higher ratings to preventive activities over adaptive activities. The Polish students most prominently rated efficient over frugal activities. Factor analysis indicated that both samples identified a group of consumer-based resource conservation activities, with the American students recognizing a cluster of recycling activities. In a separate ranking of environmental protection priorities, the Polish students endorsed pollution prevention, whereas the American students favored both efficient and frugal resource conservation. These findings suggest that the conceptualization of source reduction varies according to contextual factors and that prevention is still an obscure environmental management theme. KEY WORDS: Source reduction; Pollution prevention; Resource conservation; Frugality; Poland     

Usability of food industry waste oils as fuel for diesel engines

Two cogeneration units were each fitted with a prechamber (IDI) diesel engine in order to test the feasibility of using waste oils from the food industry as a fuel source, and additionally to test emissions generated by the combustion of these fuels. Esterified waste oils and animal fats as well as mustard oil were tested and compared to the more or less "common" fuels: diesel, rapeseed oil and rapeseed methyl ester. The results show that, in principle, each of these fuels is suitable for use in a prechamber diesel engine. Engine performance can be maintained at a constant level. Without catalytic conversion, the nitrogen oxides emissions were comparable. A significant reduction in NO(x) was achieved through the injection of urea. Combining a urea injection with the SCR catalytic converter reduced NO(x) emissions between 53% and 67%. The carbon monoxide emissions from waste oils are not significantly different from those of "common" fuels and can be reduced the same way as of hydrocarbon emissions, through utilization of a catalytic converter. The rate of carbon monoxide reduction by catalytic conversion was 84-86%. A lower hydrocarbon concentration was associated with fuels of agricultural origin. With the catalytic converter a reduction of 29-42% achieved. Each prechamber diesel engine exhibited its own characteristic exhaust, which was independent of fuel type. The selective catalytic reduction of the exhaust emissions can be realized without restriction using fuels of agricultural origin.     

石油天然气开采业(稠油)清洁生产指标体系的研究

本文给出了石油天然气开采业清洁生产审核的指标体系,可作为该行业清洁生产审核的主要依据。通过清洁生产审核,使我国相应的行业生产过程更加符合清洁生产的要求,使清洁生产工作标准化和规范化,并带动其他行业的清洁生产工作。其清洁生产指标经预测,可以反映当前我国石油天然气开采业的实际水平,为我国石油天然气开采业开展清洁生产审核工作,打下良好的技术基础。     

国内外建筑垃圾处理相关政策法规对比分析

综述了欧美、日本等发达国家和地区在建筑垃圾的处理、规范管理和再利用等方面的管理模式和政策法规。结合我国的国情和现行的法规政策进行了对比和分析,旨在为我国建筑垃圾的资源再利用提供参考。     

Heavy metal removal and cyanide destruction in the metal plating industry: an integrated approach from egypt

Wastewater produced from a metal plating is a major environmental problem. Industrial auditing revealed that the main source of pollution mainly originated from rinsing water. The characterization of final effluent showed that it is highly contaminated with hazardous heavy metals and cyanide. The concentration of copper, hexavalent chromium, nickel, and cyanide in the rinsing water of metal plating department was 14.8, 40.9, 13.3, and 19 mg/l, respectively. The concentration of cyanide and zinc from the galvanizing department reached 60 and 80 mg/l. The remediation scheme included the application of in-plant control measures via changing the rinsing process followed by the destruction of cyanide and reduction of hexavalent chromium bearing wastes. The pretreated wastes were then mixed with other industrial wastes prior to a combined chemical coagulation-sedimentation using lime and/or lime in combination with ferric chloride. The results indicated that, after applying the waste minimization measures alone at the source, prior to final treatment of industrial waste, removal rates of cyanide, copper, nickel, and chromium concentrations were 23.2%, 14.9%, 32.3%, and 55.3%, respectively in the rinse water from metal plating department. Furthermore, the removal rates of cyanide and zinc in the galvanizing department reached 59.7% and 24.3. The integrated control measures and treatment scheme led to more than 99% removal of copper, nickel, chromium, and zinc, while the complete removal of cyanide was achieved in the final effluent.     

The Pollution Prevention Act of 1990: A Policy Whose Time Has Come or Symbolic Legislation?

/ In 1990, the United States officially entered the era of pollution prevention with passage of the Pollution Prevention Act. This paper analyzes EPA's implementation of the Pollution Prevention Act from its passage in 1990 to the present. It examines the barriers EPA must overcome if it is to effectively integrate pollution prevention into its existing regulatory structure, including impediments created by statutory and organizational structure, the existing relationship between EPA and the groups it regulates, the fragmented implementation scheme of national environmental regulation, the balancing of conflicting demands advanced by powerful interests, industry's economic and technical concerns, and institutional inertia. It also examines issues such as industry commitment, the limits of prevention, and measurement concerns. The findings suggest that EPA's efforts at shifting to a pollution prevention regulatory ethic that holds primacy over pollution control are mixed. Its organizational structure, statutory authority, and incentives system still reflect a single-medium pollution control focus, appropriations for pollution prevention programs and activities are paltry compared to traditional pollution control programs, and participation in the program is voluntary. Yet, the findings also point to some promising programs that are working to institutionalize a pollution prevention regulatory ethic, and many states appear very committed to the concept.KEY WORDS: Pollution prevention; Source reduction; Pollution control; Alternative regulatory design; Barriers to implementation     

Source resolution and risk apportionment to augment the Bubble Policy: Application to a steel plant “bubble”

Source resolution and risk apportionment of emission source categories for risk reduction purposes can be used to enhance the Bubble Policy of the Clean Air Act. This is performed by incorporating receptor modeling techniques of factor analysis and chemical mass balances to assess noncarcinogenic and carcinogenic inhalation risks to a target population for certain pollutants coming from major emission source categories in a steel plant air shed. Source resolution, using factor analysis, statistically interprets a “source” from ambient data. By subsequently quantifying risks from identified metal emission sources using chemical mass balances and risk apportionment, a total additive risk from main source contributors in the steel plant is estimated. From this methodology, the Bubble Policy can be enhanced by targeting only main risk sources or by “risk-trading” with minor impact sources to reduce the total risk (if deemed significant) without arbitrarily reducing risk for all sources in an industrial source complex’s “bubble.”     

我国城市生活垃圾回收利用率测算及其统计数据收集对策

我国将生活垃圾分类收集定位为重要民生工程和生态文明建设的工作内容,并对实施生活垃圾强制分类的示范城市明确提出了\"生活垃圾回收利用率\"的绩效考核目标。由于城市生活垃圾处理和再生资源回收利用由不同职能部门负责管理,不同来源的生活垃圾回收利用统计数据未有效整合,目前还缺乏我国城市生活垃圾回收利用率指标测算的相关研究。本文界定了\"生活垃圾回收利用率\"的科学内涵,并以城市建设、再生资源利用等统计资料和物质流分析文献为基础,初步测算了全国尺度的城市生活垃圾回收利用率。研究表明,我国2006—2015年的城市生活垃圾回收利用率从12.1%上升至17.0%,然后又缓慢下降至15.6%,由于数据缺乏,该数值可能在-28%~+32%波动。生活垃圾中回收利用量较大的可再生资源分别为废纸、废塑料、废钢铁、废玻璃等。本文还分析了目前测算生活垃圾回收利用率的数据不确定性和局限性,提出了面向生活垃圾分类管理实际评价的统计数据收集对策。