SIMULATING NITROGEN LOSSES FROM AGRICULTURAL LAND: IMPLICATIONS FOR WATER QUALITY AND PROTECTION POLICY1

ABSTRACT: EPIC, a soil erosion/plant growth simulation model, is used to simulate nitrogen losses for 120 randomly selected and previously surveyed cropland sites. Simulated nitrogen losses occur through volatilization, surface water and soil runoff, subsurface lateral flow, and leaching. Physical and crop management variables explain a moderate but significant proportion of the variation in nitrogen losses. Site slope and tillage have offsetting effects on surface and ground water losses. Nitrogen applications in excess of agronomic recommendations and manure obtained off the farm and applied to the sites are significant contributors to nitrogen losses. Farm characteristics such as production of confined livestock, total manure nitrogen available, and farm income per cropland acre explain a relatively large portion of the variability in manure nitrogen applied to survey sites. The results help to identify farm characteristics that can be used to target nutrient management programs. Simulation modeling provides a useful tool for investigating variables which contribute to agricultural nitrogen losses.     

MERCURY CONTAMINATION AND FLOODPLAIN SEDIMENTATION FROM FORMER GOLD MINES IN NORTH GEORGIA1

ABSTRACT: Gold was discovered in Georgia in 1829 and mined until about 1940 in the Dahionega Gold Belt of the north Goorgia Piedmont. Streams there are characterized by gravel beds and fine sandy to silty banks. Historical mining-related alluvium is clearly distinguished from prehistoric alluvium because it is contaminated with mercury (Hg), which was used by miners to amalgamate gold. Mercury concentrations in historical floodplain sediments range from 0.04 to 4.0 mg kg^?1, exceeding background (0.04 mg kg¹) by as much as two orders of magnitude near the core of the mining district and decreasing in the downstream direction. Low levels (≤ 0.1 mg kg¹) of Hg are established within about 10–15 km from the source mines. The mercury-contaminated sediment exceeds sediment quality guidelines set by many agencies, and is a significant nonpoint source for mercury pollution. Hydraulic mining of saprolite, which began in 1868, and cutting of forests associated with mining and settlement caused unusually rapid sedimentation (1–3 cm yr^?l) and floodplain aggradation in the region. After mining ceased, streams adjusted by downcutting and forming an historical-age terrace. A new floodplain is currently being formed as streams migrate lateraily and erode the mining-related sediment of the historical terrace. High magnitude floods are contained within the confines of the historical terrace, thus limiting quantities of over-bank sedimentation, causing channel bank erosion, and transmitting high sediment yields to reservoirs in the region.     

BEST MANAGEMENT PRACTICES FOR STORM WATER AND INFILTRATION CONTROL1

ABSTRACT: Water quality controls of storm water runoff and infiltration should be a major part of a nonpoint source control program. Although surface runoff and ground water controls are often approached separately, coordination between the two is essential. For practical reasons, a rather simplified technology-based approach appears to be desirable. Areas affected vary greatly as to their sensitivity to pollution; and the various classes of pollutant source vary greatly as to their potential harmfulness. In effect, a matrix approach appears best, in which both vulnerability of the area and harmfulness of the pollutant source would have weight in determining which level of best management practices (BMP) would be appropriate, whether standard, special, or complete prohibition of the type facility under given circumstances.     

DETERMINATION OF BEST TIMING FOR POULTRY WASTE DISPOSAL: A MODELING APPROACH1

ABSTRACT: Confined production of poultry results in significant volumes of waste material which are typically disposed of by land application. Concerns over the potential environmental impacts of poultry waste disposal have resulted in ongoing efforts to develop management practices which maintain high quality of water downstream of disposal areas. The timing of application to minimize waste constituent losses is a management practice with the potential to ensure high quality of streams, rivers, and lakes downstream of receiving areas. This paper describes the development and application of a method to identify which time of year is best, from the standpoint of surface water quality, for land application of poultry waste. The procedure consists of using a mathematical simulation model to estimate average nitrogen and phosphorus losses resulting from different application timings, and then identifying the timings which minimize losses of these nutrients. The procedure was applied to three locations in Arkansas, and three different criteria for optimality of application timing were investigated. One criterion was oriented strictly to water quality, one was oriented only to crop production, and the last was a combination. The criteria resulted in different windows of time being identified as optimal. Optimal windows also varied with location of the receiving area. The results indicate that it is possible to land-apply poultry waste at times which both minimize nutrient losses and maximize crop yield.     

A COMPARISON OF RUNOFF QUALITY EFFECTS OF ORGANIC AND INORGANIC FERTILIZERS APPLIED TO FESCUEGRASS PLOTS1

ABSTRACT: Application of fertilizer can degrade quality of runoff, particularly during the first post-application, runoff-producing storm. This experiment assessed and compared runoff quality impacts of organic and inorganic fertilizer application for a single simulated storm occurring seven days following application. The organic fertilizers used were poultry (Gallus gallus domesticus) litter, poultry manure, and swine (Sus scrofa domesticus) manure. All fertilizers were applied at an application rate of 217.6 kg N/ha. Simulated rainfall was applied at 50 mm/h for an average duration of 0.8 h. Runoff samples were collected, composited, and analyzed for nitrate N (NO₃-N), ammonia N (NH₃-N), total Kjeldahl N (TKN), ortho-P (PO₄-P), total P (TP), chemical oxygen demand (COD), total suspended solids (TSS), fecal coliforms (FC), and fecal streptococci (FS). Application of the fertilizers did not alter the hydrologic characteristics of the receiving plots relative to the control plots. Concentrations of fertilizer constituents were almost always greater from treated than from control plots and were usually much greater. Flow-weighted mean concentrations of NH₃-N, PO₄-P, and TP were highest for the inorganic fertilizer treatment (42.0, 26.6, and 27.9 mg/L, respectively). Runoff COD and TSS concentrations were greatest for the poultry litter treatment. Concentrations of FC and FS were greater for fertilized than for control plots with no differences among fertilized plots, but FC concentrations for all treatments were in excess of Arkansas' primary and secondary contact standards. Mass losses of fertilizer constituents were low (≤ 3 kg/ha) and were small proportions (≤ 3 percent) of amounts applied.     

MODELING THE BUILDUP AND WASHOFF OF POLLUTANTS ON URBAN WATERSHEDS1

ABSTRACT: A model for urban stormwater quality was developed in this study. The basis for the model is the process by which pollutants build up on the watershed surface. For the wet climate of the study site, it was assumed that there exists an interval of time over which the pollutant buildup equals the pollutant washoff (no accumulation of pollutant). The buildup model was represented by a linear function of the antecedent dry time. The buildup function was then linked with a pollutant washoff model represented by a power function of the storm runoff volume. Various time intervals for no net accumulation were tested to calibrate the model. The model was calibrated to observed data for two small urban basins in Baton Rouge, Louisiana, and model results were used to analyze the behavior of phosphorus concentrations in storm runoff from these basins over a long period of time.     

EVALUATION OF BEST MANAGEMENT PRACTICES FOR CONTROLLING NONPOINT POLLUTION FROM SILVICULTURAL OPERATIONS1

ABSTRACT: Fifteen years of streamflow and water quality data were evaluated to determine the effectiveness of Best Management Practices (BMP's) in controlling nonpoint source pollution from an 110. acre commercial clearcut located in the Ridge and Valley Province of central Pennsylvania. The analyses addressed both short- and long-term changes in the physical and chemical properties and the hydro-logic regime of the stream draining this 257-acre watershed. Overall, the BMP's employed on this commercial clearcut were very effective in preventing serious deterioration of stream quality as a result of forest harvesting. Although statistically significant increases in nitrate and potassium concentrations and temperature and turbidity levels were measured the first two years following harvesting, the increases were relatively small and, with the exception of turbidity, within drinking water standards. Nevertheless, such increases may violate EPA's anti-degradation policy. Nitrate and potassium concentrations and turbidity levels remained above pre-harvesting levels for as long as nine years following harvesting. Clearcutting also significantly increased water yield, which in turn initially lowered the concentrations of most solutes because of dilution. Increased water yields returned to pro-harvesting levels within four years as a result of rapid regrowth. The export of some ions increased; however, the increased export appeared to be insufficient to affect site fertility. Implementation of periodic post-harvest inspections of harvested areas, increasing the width of the buffer zone, and utilizing buffer zones on all perennial and intermittent channels would reduce further impacts of silvi-cultural activities on water quality.     

NONPOINT SOURCE POLLUTION POTENTIAL IN AN AGRICULTURAL WATERSHED IN NORTHWESTERN PENNSYLVANIA1

ABSTRACT: A 155,947 ha portion of the Shenango River watershed in western Pennsylvania was evaluated as to the potential impact of agriculture drainage on water quality. Approximately a third of the area is being used as either cropland or pasture with approximately an equal percentage in forest lands. Eleven subwatersheds were evaluated as to their potential for nonpoint source pollution according to the criteria established by the Pennsylvania Department of Environmental Resources for the Chesapeake Bay Pollution Abatement Program. The individual components and overall rating for each subwatershed were then evaluated as to their correlation with four water quality variables based on 104 samples collected at 26 sampling stations throughout the watershed. There was a significant correlation between the overall rating factor for each subwatershed and each of the four water quality variables. In general, the watershed delivery factor, animal nutrient factor, and management factors were correlated with fecal coliform and phosphorus in the receiving streams, whereas the ground water delivery factor appeared to be more important in determining nitrate concentrations in these streams. These results indicate that manure and nutrient management, along with the exclusion of livestock from streams and the enhancement and/or replacement of riparian wetlands, are important approaches in reducing agricultural impacts in fresh water ecosystems.     

VARIABLES INDICATING NITRATE CONTAMINATION IN BEDROCK AQUIFERS,NEWARK BASIN,NEW JERSEY1

ABSTRACT: Variables that describe well construction, hydrogeology, and land use were evaluated for use as possible indicators of the susceptibility of ground water in bedrock aquifers in the Newark Basin, New Jersey, to contamination by nitrate from the land surface. Statistical analyses were performed on data for 132 wells located throughout the Newark Basin. Concentrations of nitrate (as nitrogen) did not exceed the U.S. Environmental Protection Agency maximum contaminant level of 10 milligrams per liter (mg/L) in any of the water samples (U.S. Environmental Protection Agency, 1991). Variables that describe hydrogeology and well construction were found not to be statistically significant in relation to concentrations of nitrate. This finding can be attributed to the complex nature of flow in bedrock aquifers and mixing of water from shallow and deep water-bearing zones that occurs within these wells, which are constructed with long open intervals. Distributions of nitrate concentrations were significantly different among land-use groups on the basis of land use within both a 400 and an 800-m radius zone of the well. The median concentrations of nitrate (as N) in water from wells in predominantly urban-residential (2.5 mg/L) and agricultural areas (1.8 mg/L) were greater than the median concentration of nitrate in water from wells in predominantly undeveloped areas (0.5 mg/L).     

AREWIDE WATER QUALITY MANAGEMENT IN AN ENERGY DEVELOPMENT AREA1

ABSTRACT: A Section 208, Areawide Waste Treatment Management Project, is attempting to develop an implementable water quality management plan for an energy impacted area. Staff members and consultants are investigating point and nonpoint sources. On a short-term basis, population growth and construction will have a greater impact on water quality than strip mining.     

MODELING CONCENTRATION VARIATIONS IN HIGH-CAPACITY WELLS: IMPLICATIONS FOR GROUNDWATER SAMPLING1

ABSTRACT: High-capacity wells are used as a convenient and economical means of sampling groundwater quality. Although the inherent limitations of using these wells are generally recognized, little has been done to investigate how these wells actually sample groundwater. A semi-analytical particle tracking model is used to illustrate the influence of variable vertical contaminant distributions and aquifer heterogeneity on the composition of water samples from these wells during short pumping periods. The hypothetical pumping well used in the simulations is located in an unconfined, alluvial aquifer with a shallow water table and concentration gradients of nitrate-nitrogen contamination. This is a typical setting for many irrigated areas in the United States. The main conclusions are: (1) high-capacity wells underestimate the average amount of contamination within an aquifer; (2) shapes of concentration-time curves for high-capacity wells appear to be governed by the distribution of the contaminant and travel times to the well; (3) variables such as well construction, pumping rate, and hydrogeologic properties contribute to the magnitude of the concentration-time curves at individual high-capacity wells; and (4) a sampling strategy using concentration-time curves based on the behavioral characteristics of the well rather than individual samples will provide a much better framework for interpreting spatial contaminant distributions.     

WATER QUALITY TRAP EFFICIENCY OF STORM WATER MANAGEMENT BASINS1

ABSTRACT: While the quality of rivers has received much attention, the degradation of small streams in upland areas of watersheds has only recently been recognized as a major problem. A major cause of the problem is increases in nonpoint source pollution that accompany urban expansion. A case study is used to examine the potential for storm water detention as a means of controlling water quality in streams of small watersheds. The storm water management basin, which is frequently used to control increases in discharge rates, can also be used to reduce the level of pollutants in inflow to receiving streams. Data collected on a 148-acre site in Maryland shows that a detention basin can trap as much as 98 percent of the pollutant in the inflow. For the 11 water quality parameters, most showed reductions of at least 60 percent, depending on storm characteristics.     

FOREST PRACTICES AS NONPOINT SOURCES OF POLLUTION IN NORTH AMERICA1

ABSTRACT: Forest management activities may substantially alter the quality of water draining forests, and are regulated as nonpoint sources of pollution. Important impacts have been documented, in some cases, for undesirable changes in stream temperature and concentrations of dissolved oxygen, nitrate-N, and suspended sediments. We present a comprehensive summary of North American studies that have examined the impacts of forest practices on each of these parameters of water quality. In most cases, retention of forested buffer strips along streams prevents unacceptable increases in stream temperatures. Current practices do not typically involve addition of large quantities of fine organic material to streams, and depletion of streamwater oxygen is not a problem; however, sedimentation of gravel streambeds may reduce oxygen diffusion into spawning beds in some cases. Concentrations of nitrate-N typically increase substantially after forest harvesting and fertilization, but only a few cases have resulted in concentrations approaching the drinking-water standard of 10 mg of nitrate-NIL. Road construction and harvesting increase suspended sediment concentrations in streamwater, with highly variable results among regions in North America. The use of best management practices usually prevents unacceptable increases in sediment concentrations, but exceptionally large responses (especially in relation to intense storms) are not unusual.     

GROUNDWATER DISCHARGE AND ITS IMPACT ON SURFACE WATER QUALITY IN A CHESAPEAKE BAY INLET1

ABSTRACT: Surface water, groundwater, and groundwater discharge quality surveys were conducted in Cherrystone Inlet, on Virginia's Eastern Shore. Shallow groundwater below agricultural fields had nitrate concentrations significantly higher than inlet surface waters and shallow groundwater underlying forested land. This elevated nitrate groundwater discharged to adjacent surface waters. Nearshore discharge rates of water across the sediment-water interface ranged from 0.02 to 3.69 liters·m^?2·hr^?1 during the surveys. The discharge was greatest nearshore at low tide periods, and decreased markedly with increasing distance offshore. Vertical hydraulic heads, E_h, and inorganic nitrogen flux in the sediments followed similar patterns. Nitrate was the predominant nitrogen species discharged nearshore adjacent to agricultural land use, changing to ammonium farther offshore. Sediment nitrogen fluxes were sufficient to cause observable impacts on surface water quality; nitrate concentrations were up to 20 times greater in areas of groundwater discharge than in the main stem inlet water. Based on DIN:DIP ratios, nitrogen contributions from direct groundwater discharge and tidal creek inputs appear to be of significant ecological importance. This groundwater discharge links land use activity and the quality of surface water, and therefore must be considered in selection of best management practices and water quality management strategies.     

EXAMPLES OF LANDFILL-GENERATED PLUMES IN LOW-RELIEF AREAS,SOUTHEAST FLORIDA1

ABSTRACT: Areas of low topographic relief have low water-table gradients and make the direction of movement of contaminants from land fills in the ground water difficult to predict from regional gradients alone. The landfill, nearby free-flowing ditches or canals, variations in hydraulic conductivity, and the influence of nearby pumping wells can all affect the direction of flow. In low-gradient areas the concepts of “upgradient” and “downgradient” are less useful in planning the location of monitoring wells than in areas of higher relief. Low-relief areas also may be affected by the discharge of mineralized water from deeper aquifers, naturally or through irrigation, which can mask geochemical surveys intended to detect landfill leachate. Examples of effects of low topographic relief are noted in southeast Florida where water-table gradients are 7×10^?-⁴ to 5×10^?-⁴ feet per foot. Water-table mounding beneath the landfill and the drainage effects of nearby ditches and well have created multiple leachate plumes in Stuart where one plume migrated in a direction opposite to the apparent regional gradient. In Coral Springs analysis suggests a bifurcating plume migrating along two narrow zones. In Fort Pierce it was difficult to detect leachate because of mineralized irrigation water and fertilizer runoff from an adjacent citrus grove.     

SPREADSHEET WATERSHED MODELING FOR NONPOINT-SOURCE POLLUTION MANAGEMENT IN A WISCONSIN BASIN1

ABSTRACT: Although several sophisticated nonpoint pollution models exist, few are available that are easy to use, cover a variety of conditions, and integrate a wide range of information to allow managers and planners to assess different control strategies. Here, a straightforward pollutant input accounting approach is presented in the form of an existing model (WATERSHED) that has been adapted to run on modern electronic spreadsheets. As an application, WATERSHED is used to assess options to improve the quality of highly eutrophic Delavan Lake in Wisconsin. WATERSHED is flexible in that several techniques, such as the Universal Soil Loss Equation or unit-area loadings, can be used to estimate nonpoint-source inputs. Once the model parameters are determined (and calibrated, if possible), the spreadsheet features can be used to conduct a sensitivity analysis of management options. In the case of Delavan Lake, it was concluded that, although some nonpoint controls were cost-effective, the overall reduction in phosphorus would be insufficient to measurably improve water quality.     

GROUNDWATER MANAGEMENT ON THE TEXAS HIGH PLAINS1

ABSTRACT The effects of major water management practices on the pumping requirement from the Ogallala aquifer are discussed. Demand on the aquifer may be reduced as much as 15 percent by recycling irrigation runoff, 25 percent by recycling irrigation runoff and irrigating with water from playas, and 29 percent by recycling irrigation water in combination with irrigation from playas and artificial recharge of playa water to the aquifer. Other practices that can result in more efficient use of precipitation and groundwater are limited irrigation, land forming, soil profile modification, and improved irrigation systems, thereby reducing the pumping demand on the Ogallala. Additional water supplies can possibly be obtained by water harvesting, weather modification, and water importation. Conclusions reached were that the overdraft on the aquifer can be reduced by the application of sound water management practices on an area-wide basis.     

A MODELING APPROACH FOR STORM WATER QUANTITY AND QUALITY CONTROL VIA DETENTION BASINS1

ABSTRACT: Storm water detention basins have historically been employed for quantity (i.e., flooding) control only. However, recently it has been suggested that these basins may also provide a practical means of storm water quality control. This paper presents the formulation of a mathematical modeling approach which may be used by professionals to simultaneously design detention basins for the dual purpose of storm water quantity and quality control. Model simulations demonstrate that for a given basin, pollutant removal increases as storm frequency increases. The importance of particle size distribution and settling velocity for net pollutant removal is illustrated, The design procedure is demonstrated, and pollutant loading diagrams for estimating pollutant removal as a function of storm size are developed.     

DEVELOPMENT OF A NONDEGRAIATION POLICY FOR HIGH QUALITY WATERS1

ABSTRACT: The development of a nondegradation policy for high quality waters is a complex and often controversial process. This paper discusses the development of a nondegradation policy for two components of the National Wild and Scenic Rivers System. Water quality in these reaches of the Delaware River is threatened by rapid growth and development and the cumulative impacts from numerous wastewater discharges and nonpoint sources of pollution. The Delaware River Basin Commission, with assistance from its member states and the National Park Service, conducted a highly public, six-year planning process to develop a nondegradation policy that protected existing water quality without impinging upon local and state economic development objectives. The resulting non-degradation policy includes such features as numeric definitions of existing water quality and measurable change; stringent point source requirements; nonpoint source requirements including watershed planning requirements; and other water quality management policies.