Assessment of the use of industrial by-products to remediate a copper- and arsenic-contaminated soil

Two water treatment sludges (WTS-A, WTS-B), two red muds (RM), and red gypsum (RG), all rich in iron oxy-hydroxides, were added to a soil highly polluted with As and Cu at 2% (w/w) to reduce metal bioavailability. Because the amendments increased soil pH to approximately 6, a lime treatment to the same pH and an unamended treatment were included for comparison. All the amendments had significant positive effects on the soil microbial biomass and growth of ryegrass (Lolium multiflorum Lam. cv. Avance), but only WTS-A improved lettuce (Lactuca sativa L. cv. Tom Thumb) growth. The mineralization of added ammonium nitrogen was not significantly affected by the treatments, while a physiologically based extraction test (PBET) showed that bioaccessibility of As was low (< 5%) and decreased only in the WTS-A treatment. Concentrations of As in soil pore water and extractable As only decreased in the WTS and RG treatments. In contrast, Cu concentrations in soil pore water and extractable Cu decreased in all treatments, by more than 84% in the WTS, RM, and RG treatments. Non-isotopically exchangeable As and Cu were present in colloids in the soil pore water. Untreated soil had < 4% isotopically exchangeable As and this decreased by approximately 50%, with WTS, RM, and RG. The labile Cu pool represented a large proportion (34%) of the total Cu pool, and the isotopically exchangeable and soluble Cu were strongly correlated with soil pH. Acidification of the treated soils showed that the labile As and Cu both increased in the treated soils compared with untreated soils. The significance of the treatment effects on soil fertility and potential off-site transport of As and Cu to ground water are discussed.     

Government response to climate change in China: a study of provincial and municipal plans

In this paper, we provide an overview of local and regional climate change plans in China by scrutinizing planning documents from 16 cities, four autonomous regions, and 22 provinces. We develop and apply an evaluation protocol to understand goals, process, and strategies in these plans. We also conduct interviews with government officials to provide a context for subnational climate change planning. The results indicate that current climate change planning in China is characterized by the ‘top-down’ approach, in which the central governmental incentives play a vital role in shaping provincial and municipal plans. In addition, most plans have the following issues: vague definition of what characterizes a low-carbon city/region; deficiency in the quality of greenhouse gas inventory and reduction targets; insufficient strategies provided to respond to climate change; inadequate stakeholder engagement; and weak horizontal coordination. Finally, we offer recommendations to improve climate change planning in China.     

Revegetation of high zinc and lead tailings with municipal biosolids and lime: greenhouse study

Acidic (pH 4.1) and high Cd, Pb, and Zn mine tailings (mean +/- SD: 17 +/- 0.4, 3800 +/- 100, and 3500 +/- 100 mg kg(-1), respectively) from an alluvial tailings deposit in Leadville, Colorado were amended with municipal biosolids (BS) (224 Mg ha(-1)) and different types of lime (calcium carbonate equivalent of 224 Mg ha(-1) CaCO3) in a greenhouse column study to test the ability of the amendments to neutralize surface and subsoil acidity and restore plant growth. The types of lime included coarse, agricultural, and fine-textured lime (CL, AL, and FL), sugar beet lime (SBL), and lime kiln dust (LK). The FL was also added alone. All treatments increased bulk pH in the amended horizon in comparison to the control, with the most significant increases observed in the FL, SBL+BS, and LK+BS treatments (7.33, 7.34, and 7.63, respectively). All treatments, excluding the FL, increased the pH in the horizon directly below the amended layer, with the most significant increases observed in the SBL+BS and LK+BS treatments (6.01 and 5.41, respectively). Significant decreases in 0.01 M Ca(NO3)2-extractable Zn and Cd were observed in the subsoil for all treatments that included BS, with the largest decrease in the SBL+BS treatment (344 and 3.9 versus 4 and 0.1 mg kg(-1) Zn and Cd, respectively). Plant growth of annual rye (Lolium multiflorum L.) was vigorous in all treatments that included BS with plant Zn, Cd, and Pb concentrations reduced over the control.     

Agricultural soil greenhouse gas emissions: a review of national inventory methods

Parties to the United Nations Framework Convention on Climate Change (UNFCCC) are required to submit national greenhouse gas (GHG) inventories, together with information on methods used in estimating their emissions. Currently agricultural activities contribute a significant portion (approximately 20%) of global anthropogenic GHG emissions, and agricultural soils have been identified as one of the main GHG source categories within the agricultural sector. However, compared to many other GHG sources, inventory methods for soils are relatively more complex and have been implemented only to varying degrees among member countries. This review summarizes and evaluates the methods used by Annex 1 countries in estimating CO2 and N2O emissions in agricultural soils. While most countries utilize the Intergovernmental Panel on Climate Change (IPCC) default methodology, several Annex 1 countries are developing more advanced methods that are tailored for specific country circumstances. Based on the latest national inventory reporting, about 56% of the Annex 1 countries use IPCC Tier 1 methods, about 26% use Tier 2 methods, and about 18% do not estimate or report N2O emissions from agricultural soils. More than 65% of the countries do not report CO2 emissions from the cultivation of mineral soils, organic soils, or liming, and only a handful of countries have used country-specific, Tier 3 methods. Tier 3 methods usually involve process-based models and detailed, geographically specific activity data. Such methods can provide more robust, accurate estimates of emissions and removals but require greater diligence in documentation, transparency, and uncertainty assessment to ensure comparability between countries. Availability of detailed, spatially explicit activity data is a major constraint to implementing higher tiered methods in many countries.     

Landfill cover soil, soil solution, and vegetation responses to municipal landfill leachate applications

Municipal solid waste landfill leachate must be removed and treated to maintain landfill cover integrity and to prevent contamination of surface and ground waters. From 2003 to 2007, we studied an onsite disposal system in Ottawa County, Michigan, where leachate was spray irrigated on the vegetated landfill cover. We established six 20-m-diameter circular experimental plots on the landfill; three were spray irrigated as part of the operational system, and three remained as untreated control plots. We quantified the effects of leachate application on soil properties, soil solution chemistry, vegetative growth, and estimated solute leaching. The leachate had high mean levels of electrical conductivity (0.6-0.7 S m(-1)), Cl (760-900 mg L(-1)), and NH(4)-N (290-390 mg L(-1)) but was low in metals and volatile organic compounds. High rates of leachate application in 2003 (32 cm) increased soil electrical conductivity and NO(3)-N leaching, so a sequential rotation of spray areas was implemented to limit total leachate application to <9.6 cm yr(-1) per spray area. Concentrations of NO(3)-N and leaching losses remained higher on irrigated plots in subsequent years but were substantially reduced by spray area rotation. Leachate irrigation increased plant biomass but did not significantly affect soil metal concentrations, and plant metal concentrations remained within normal ranges. Rotating spray areas and timing irrigation to conform to seasonal capacities for evapotranspiration reduced the localized impacts of leachate application observed in 2003. Careful monitoring of undiluted leachate applications is required to avoid adverse impacts to vegetation or soils and elevated solute leaching losses.     

Comparison of plant families in a greenhouse phytoremediation study on an aged polycyclic aromatic hydrocarbon-contaminated soil

Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous, recalcitrant, and potentially carcinogenic pollutants. Plants and their associated rhizosphere microbes can promote PAH dissipation, offering an economic and ecologically attractive remediation technique. This study focused on the effects of different types of vegetation on PAH removal and on the interaction between the plants and their associated microorganisms. Aged PAH-polluted soil with a total PAH level of 753 mg kg(-1) soil dry weight was planted with 18 plant species representing eight families. The levels of 17 soil PAHs were monitored over 14 mo. The size of soil microbial populations of PAH degraders was also monitored. Planting significantly enhanced the dissipation rates of all PAHs within the first 7 mo, but this effect was not significant after 14 mo. Although the extent of removal of lower-molecular-weight PAHs was similar for planted and unplanted control soils after 14 mo, the total mass of five- and six-ring PAHs removed was significantly greater in planted soils at the 7- and 14-mo sampling points. Poaceae (grasses) were the most effective of the families tested, and perennial ryegrass was the most effective species; after 14 mo, soils planted with perennial ryegrass contained 30% of the initial total PAH concentration (compared with 51% of the initial concentrations in unplanted control soil). Although the presence of some plant species led to higher populations of PAH degraders, there was no correlation across plant species between PAH dissipation and the size of the PAH-degrading population. Research is needed to understand differences among plant families for stimulating PAH dissipation.     

The jurisdictional framework for municipal action to reduce greenhouse gas emissions: Case studies from Canada, the USA and Germany

This paper addresses two questions: (1) Given a commitment at the national level to reduce greenhouse gas (GHG) emissions, what tools are available to national-level governments to induce complimentary actions required at subnational levels? (2) In the absence of a serious commitment at national and regional levels to reduce GHG emissions, what is the scope for, and jurisdictional rights of, cities to undertake actions? In this context, federal, regional and municipal legislation relevant for GHG emissions is examined in Canada, the USA and Germany. Regarding the first question, different national governments find themselves in considerably different positions to implement climate initiatives at subnational levels, with the German government in the strongest position and the Canadian government in the weakest. The implications of this for a nation's willingness to adopt emission reduction targets could be serious. Regarding the second question, there are few significant differences among Canadian, US and German municipalities' jurisdictional capabilities (and limitations) to reduce GHG emissions. Though limited in their legal capacity, these municipalities demonstrate that through their own, often informal, initiatives they can reinforce and compliment the more formal, regulatory actions by senior-level governments, thereby paving the way for senior-level governments to deliver meaningful domestic emission reductions.     

Using a GIS model to assess terrestrial salamander response to alternative forest management plans.

A GIS model predicting the spatial distribution of terrestrial salamander abundance based on topography and forest age was developed using parameters derived from the literature. The model was tested by sampling salamander abundance across the full range of site conditions used in the model. A regression of the predictions of our GIS model against these sample data showed that the model has a modest but significant ability to predict both salamander abundance and mass per unit area. The model was used to assess the impacts of alternative management plans for the Hoosier National Forest (Indiana, USA) on salamanders. These plans differed in the spatial delineation of management areas where timber harvest was permitted, and the intensity of timber harvest within those management areas. The spatial pattern of forest openings produced by alternative forest management scenarios based on these plans was projected over 150 years using a timber-harvest simulator (HARVEST). We generated a predictive map of salamander abundance for each scenario over time, and summarized each map by calculating mean salamander abundance and the mean colonization distance (average distance from map cells with low predicted abundance to those with relatively high abundance). Projected salamander abundance was affected more by harvest rate (area harvested each decade) than by the management area boundaries. The alternatives had a varying effect on the mean distance salamanders would have to travel to colonize regenerating stands. Our GIS modeling approach is an example of a spatial analytical tool that could help resource management planners to evaluate the potential ecological impact of management alternatives.     

A process integration approach to industrial water conservation: a case study for a Chinese steel plant

A systematic approach to optimizing water network has traditionally been utilized to exam and plan water conservation in industrial processes. In the present case study, water-pinch technology was used to analyze and optimize the water network of a steel plant near China's Zhangjiakou city. A system design was developed and a limiting constraint (Cl(-) concentration) was identified based on investigations of water quality then the minimum freshwater and wastewater targets were determined without considering water losses. The analysis was then extended by calculating the additional input of freshwater required to balance the actual water losses. A nearest-neighbor algorithm (NNA) was used to distribute the freshwater and recycled water among each of the plant's operations. The results showed that with some reconstruction of the water network, the flow rates of freshwater and wastewater could be decreased by 57.5% and 81.9%, respectively.     

Monitoring forest biodiversity: a European perspective with reference to temperate and boreal forest zone

Recent state of forest biodiversity at the European level was reviewed and analysed with respect to the current requirements from the environmental policies as well as with respect to scientific findings in the field. The analysis reveals the main deficits and development needs, and outlines some possible courses for future action. Specific reference is given to the boreal, Atlantic and continental regions of Europe.Especially the operational definition of biodiversity, the selection of the scale and consideration of the most appropriate indicators and data collection methods are of primary importance when defining a monitoring approach. The results of a recent assessment at national scale contribute to an improved understanding, but show some shortcomings with respect to the level of detail. The high variability of the distribution, structure and composition of forests in Europe can be comprised only partially when the monitoring follows national borders. To detect changes in time for corrective measures and to be able to apply appropriate threshold values for biodiversity indicators a more detailed approach, which takes into account different bio-geographical regions and forest ecosystem types, is needed. Technically, this could be based on aggregation national forest inventories or European-wide sampling scheme combined with remote sensing data and distinct forest types or categories.     

Phytoremediation of polychlorinated biphenyl (PCB)-contaminated sediment: a greenhouse feasibility study

Contaminated sediments dredged from navigable waterways often are placed in confined disposal facilities to prevent further spread of the pollutants. Reducing contaminants to acceptable levels would allow for disposal of the sediments and further dredging activity. A greenhouse study was conducted to evaluate plant treatments and the addition of an organic amendment to decrease the concentration of PCB congeners found in Arochlor 1260. Sediment treated with the amendment and either low transpiring plants or no plants had the greatest removal of the PCB congeners. High-transpiring plants apparently prevented the highly reducing conditions required for reductive dechlorination of highly chlorinated PCBs. Most likely, the amendment provided labile carbon that initiated the reducing conditions needed for dechlorination. The sediment moisture content and moisture-related plant parameters were significant predictors of the PCB loss. Carex aquatalis and Spartina pectinata are predicted to be the most effective plant treatments for phytoremediation of PCBs.     

Associations between forest characteristics and socio-economic development: a case study from Portugal

The integration of socio-economic and environmental objectives is a major challenge in developing strategies for sustainable landscapes. We investigated associations between socio-economic variables, landscape metrics and measures of forest condition in the context of Portugal. The main goals of the study were to 1) investigate relationships between forest conditions and measures of socio-economic development at national and regional scales, 2) test the hypothesis that a systematic variation in forest landscape metrics occurs according to the stage of socio-economic development and, 3) assess the extent to which landscape metrics can inform strategies to enhance forest sustainability. A ranking approach and statistical techniques such as Principal Component Analysis were used to achieve these objectives. Relationships between socio-economic characteristics, landscape metrics and measures of forest condition were only significant in the regional analysis of municipalities in Northern Portugal. Landscape metrics for different tree species displayed significant variations across socio-economic groups of municipalities and these differences were consistent with changes in characteristics suggested by the forest transition model. The use of metrics also helped inform place-specific strategies to improve forest management, though it was also apparent that further work was required to better incorporate differences in forest functions into sustainability planning.     

Leaf litter dynamics and nitrous oxide emission in a Mediterranean riparian forest: implications for soil nitrogen dynamics

Mediterranean riparian zones can experience severe drought periods that lead to low soil moisture content, which dramatically affects their performance as nitrate removal systems. In the Mediterranean riparian zone of this study, we determined that N2O emission was practically nil. To understand the role of forest floor processes in nitrogen retention of a Mediterranean riparian area, we studied leaf litter dynamics of two tree species, London planetree [Platanus x acerifolia (Aiton) Willd.] and alder [Alnus glutinosa (L.) Gaertn.], for two years, along with soil nitrogen mineralization rates. Annual leaf litter fall equaled 562.6 +/- 10.1 (standard error) g dry wt. m(-2), 68% of which was planetree and 32% of which was alder. The temporal distribution of litterfall showed a two-peak annual cycle, one occurring in midsummer, the other in autumn. Planetree provided the major input of organic nitrogen to the forest floor, and the amount of planetree leaves remaining on the forest floor was equivalent to approximately four years of stock. Leaf litter decomposition was three times higher for alder (decay coefficient [k] = 1.13 yr(-1)) than for planetree (k = 0.365 yr(-1)). Mineralization rates showed a seasonal pattern, with the maximum rate in summer (1.92 mg N kg(-1) d(-1)). Although the forest floor was an important sink for nitrogen due to planetree leaf accumulation, 7.5% of this leaf litter was scoured to the streambed by wind. This loss was irrelevant for alder leaves. Due to the litter quality, the forest floor of this Mediterranean riparian forest acts as a nitrogen sink.     

Temporal distribution of Ephemeroptera, Plecoptera and Trichoptera (EPT) adults at a tropical forest stream: response to seasonal variations

Temporal changes in Ephemeroptera, Plecoptera and Trichoptera (EPT) abundance were investigated monthly from January to December 2008 at a tropical forest stream of Tupah River (TR) at Gunung Jerai Forest Reserve, Malaysia. A total of 1,689 adult individuals belong to 16 families of EPT were collected from TR. EPT populations peaked in May, June and December. Mean EPT abundance was significantly different among months (Kruskal–Wallis test, P < 0.05). Among the three orders, Trichoptera had the most diverse community with eight families reported, followed by Ephemeroptera (six families) and Plecoptera (two families). The family Baetidae was the most abundant ephemeropteran. Meanwhile, caddisfly families Hydropsychidae, Leptoceridae and Lepidostomatidae were abundant at TR. However, plecopterans were mainly represented by Perlidae. There was significant difference in abundance (t = 4.863, P < 0.05) and diversity (t = 7.857, P < 0.05) of EPT adults between dry and wet seasons. Interestingly, abundance of EPT adults was higher in the dry season compared to the wet season. Consequently, seasonality impact on abundance of EPT adults at TR was obvious. The adult population of Trichoptera was dominant during the dry season. However, adults of Ephemeroptera were abundant during the wet season.     

Controlling industrial pollution using EIA: Case study of a Kenyan tannery project

Summary Since the late 1970s, the National Environment Secretariat (NES) in Kenya has viewed environmental impact assessment (EIA) as a principal tool for meeting its environmental protection objectives. Prior to the formation of the Inter-Ministerial Committee on the Environment (IMCE), NES was ineffective in forcing any project proponents to take the EIA requirements seriously. The IMCE has provided NES with the ability to co-opt Committee members and to use the legislatively based mandates of those members to enforce its EIA requirements for industrial projects. A successful example of this co-optation is the case of the Leather Industries of Kenya (LIK), involving a new tannery whose final siting and wastewater treatment control facilities were substantially influenced by the EIA process. Although the LIK case does not offer a basis for generalisation, it provides insights into: (a) how EIA is implemented for new industrial facilities in Kenya, (b) the advantages and disadvantages of the EIA system, and (c) the constructive roles donor agencies can play in promoting institutional reforms for EIA.Dr Rafik Hirji is a Senior Engineer at James M. Montgomery Consulting Engineers, Inc., Suite 160, Sacramento, CA 95825. He was formerly a graduate research assistant in the Department of Civil Engineering at Stanford University. Dr Leonard Ortolano is the UPS Foundation Professor of Civil Engineering at Stanford University, Stanford, CA 94305-4020, USA.     

Soil microbial community response to hexavalent chromium in planted and unplanted soil

Theories suggest that rapid microbial growth rates lead to quicker development of metal resistance. We tested these theories by adding hexavalent chromium [Cr(VI)] to soil, sowing Indian mustard (Brassica juncea), and comparing rhizosphere and bulk soil microbial community responses. Four weeks after the initial Cr(VI) application we measured Cr concentration, microbial biomass by fumigation extraction and soil extract ATP, tolerance to Cr and growth rates with tritiated thymidine incorporation, and performed community substrate use analysis with BIOLOG GN plates. Exchangeable Cr(VI) levels were very low, and therefore we assumed the Cr(VI) impact was transient. Microbial biomass was reduced by Cr(VI) addition. Microbial tolerance to Cr(VI) tended to be higher in the Cr-treated rhizosphere soil relative to the non-treated systems, while microorganisms in the Cr-treated bulk soil were less sensitive to Cr(VI) than microorganisms in the non-treated bulk soil. Microbial diversity as measured by population evenness increased with Cr(VI) addition based on a Gini coefficient derived from BIOLOG substrate use patterns. Principal component analysis revealed separation between Cr(VI) treatments, and between rhizosphere and bulk soil treatments. We hypothesize that because of Cr(VI) addition there was indirect selection for fast-growing organisms, alleviation of competition among microbial communities, and increase in Cr tolerance in the rhizosphere due to the faster turnover rates in that environment.     

Regional industrial ecology: examples from regional economic systems of forest industry and energy supply in Finland

Industrial ecology (IE) promotes the development of industrial systems based on recycling of matter and cascading of energy through cooperation. In this paper, the local/regional industrial ecosystem approach is reflected in two examples from Finland. The local forest industry system is based on renewable resources, waste materials and energy utilisation between forestry companies, a saw-mill, a pulp mill, a paper mill and a forest industry power plant. Waste energy from electricity production is used for production of heat and process steam. Regional city energy supply systems in Finland are also to a large extent arranged around power plants that utilise waste energy. The potential of combining the forest industry system with the energy supply systems of cities is considered and the conditions for success in the Finnish case are discussed.     

Comparative effects of a tree crop (cocoa) and shifting cultivation on a forest soil in Nigeria

Summary This study examines the organic matter and nutrient levels in soils under a 26-year old cocoa plantation and shifting cultivation farmlands cropped with cassava and maize, in Nigeria. The characteristics of soils under the two contrasting agricultural modes were compared with those of soils under rain forest, in order to infer the differential effects. Relative to the forest levels, the soil organic matter and nutrient levels were not substantially reduced in soils under plantations of cocoa. This is largely because cocoa plantations replicate forest conditions. In contrast, organic matter and nutrient levels were much lower in shifting cultivation farmlands. This is attributable to the fact that the crops of cassava and maize have a low ground cover, they generate relatively small amounts of litter and so do not replicate forest conditions. Measures which might be adopted to conserve soil organic matter and nutrient status during shifting cultivation methods are discussed.Dr A.O. Aweto is a Senior Lecturer in the Department of Geography where Mr O.A. Obe was, until recently, a research worker.     

Removing solids improves response of grass to surface-banded dairy manure slurry: a multiyear study

Removing solids from slurry manure helps balance nutrients to plant needs and may increase soil infiltration rate toreduce loss of ammonia. The long-term effects of applying the separated liquid fraction (SLF) of dairy slurry with surface banding applicators are not well known. This 6-yr study compared the yield, N recovery, and stand persistence of tall fescue (Festuca arundinacea Schreb.) receiving SLF at 300 (SLF300) and 400 (SLF400) kg ha(-1) yr(-1) of total ammoniacal N (TAN); whole dairy slurry (WS) at 200 (WS200), 300 (WS300), and 400 (WS400) kg TAN ha(-1) yr(-1); and mineral fertilizerat 300 kg N ha(-1) yr(-1). The slurries were applied four times per year by surface banding, a technique that reduces ammonia emission and canopy contamination. Grass yield and N uptake were significantly higher for SLF300 than WS300 atequivalent rates of TAN. At similar total N, yield and N uptake were much greater for SLF than WS (2 Mg DM ha(-1) and 75 kg N ha(-1), respectively). Apparent total N recoverywas 63% greater for SLF300 than WS300 due to less ammonia loss and less immobile N. The apparent recovery of total N was 31% higher for Fert300 than for SLF300. Yield and N uptake for SLF300 and WS300 were similar in Harvests 1 and4, but SLF had higher values under hot and dry conditions in Harvests 2 and 3. Using SLF rather than WS will increase crop yield and allow higher application volumes near barns, whichwill reduce hauling costs.     

Evaluation of the economic and environmental impact of converting cropland to forest: a case study in Dunhua county, China

The Sloping Land Conversion Program (also known as "Grain for Green" or the Upland Conversion Program) for converting cropland to forest is one of China's most ambitious environmental initiatives, and is one of the world's largest land-conservation programs with a budget of RMB 337 billion (over US$ 40 billion). Although environmental impacts have played a vital role in the general reasoning and argumentation for forest plantations, environmental impact analyses have often received less attention than economic analyses in the planning of plantation forestry projects. The overall goal of this paper is to evaluate the program's environmental impact considering the farmer's interests and the potential social benefits due to carbon sequestration in different scenarios based on household and field survey data in Dunhua County. Our findings are that: (1) in many cases, the program did not give adequate consideration to land productivity and environmental heterogeneity when selecting plots; (2) more than half of the reforestation plots were on flat cropland (slopes of less than 5 degrees ); (3) in five of the eight townships, net incomes on reforested land were substantially above or below previous crop incomes, raising questions about the efficiency of the allocation of compensation to farmers participating in the program; (4) the potential carbon co-benefit increased the NPV of the program by 5954-7009 RMB/ha. In conclusion, we recommend that more attention should be paid to the quality of reforestation programs rather than just their scale and note that consideration of potential carbon sequestration co-benefits enhances the benefits of cropland conversion programs.