MUNICIPAL RESPONSES TO VOLATILE ORGANIC COMPOUNDS IN WISCONSIN GROUND WATER1

ABSTRACT: Contamination of ground water supplies with volatile organic compounds is a new and significant problem. Municipalities and their community water systems are often the first to discover ground water contamination because of the monitoring programs they are required to carry out. When contamination exceeds standards, some action is required. The responses of Wisconsin municipalities to volatile organic compounds that exceed standards in their ground water sources is described. Actions to protect human health are prompt, but the survey results indicate plumes of contaminated ground water are usually not treated. They may continue to migrate and contaminate other private and public wells.     

AUTOMATIC BOTTLE SEALING MECHANISM FOR SEQUENTIAL SAMPLING OF VOLATILE ORGANICS IN WATER1

ABSTRACT: The design, construction, and evaluation of two automatic bottle sealing mechanisms for the collection of volatile organic compounds in water are described. Manually collected samples were either stored in uncapped bottles or in bottles capped with the automatic bottle sealing mechanisms. After 24 hours' storage, significant losses of volatile compounds from uncapped samples occurred even if the samples were stored at 4°C, but not for the samples capped with the automatic bottle sealing mechanisms. The mechanism for sealing the sample bottles was integrated into a commercial sampler with minor modifications to the sampler. The sampling system was then evaluated under controlled conditions to simulate actual field sampling. The results showed that the system was suitable for taking sequential discrete water samples automatically for 24 hours without significant losses of volatile organic compounds.     

ENHANCEMENTS OF NONPOINT SOURCE MONITORING OF VOLATILE ORGANIC COMPOUNDS IN GROUND WATER1

ABSTRACT: The U.S. Geological Survey (USGS) has compiled a national retrospective data set of analyses of volatile organic compounds (VOCs) in ground water of the United States. The data are from Federal, State, and local nonpoint‐source monitoring programs, collected between 1985–95. This data set is being used to augment data collected by the USGS National Water‐Quality Assessment (NAWQA) Program to ascertain the occurrence of VOCs in ground water nationwide. Eleven attributes of the retrospective data set were evaluated to determine the suitability of the data to augment NAWQA data in answering occurrence questions of varying complexity. These 11 attributes are the VOC analyte list and the associated reporting levels for each VOC, well type, well‐casing material, type of openings in the interval (screened interval or open hole), well depth, depth to the top and bottom of the open interval(s), depth to water level in the well, aquifer type (confined or unconfined), and aquifer lithology. VOCs frequently analyzed included solvents, industrial reagents, and refrigerants, but other VOCs of current interest were not frequently analyzed. About 70 percent of the sampled wells have the type of well documented in the data set, and about 74 percent have well depth documented. However, the data set generally lacks documentation of other characteristics, such as well‐casing material, information about the screened or open interval(s), depth to water level in the well, and aquifer type and lithology. For example, only about 20 percent of the wells include information on depth to water level in the well and only about 14 percent of the wells include information about aquifer type. The three most important enhancements to VOC data collected in nonpoint‐source monitoring programs for use in a national assessment of VOC occurrence in ground water would be an expanded VOC analyte list, recording the reporting level for each analyte for every analysis, and recording key ancillary information about each well. These enhancements would greatly increase the usefulness of VOC data in addressing complex occurrence questions, such as those that seek to explain the reasons for VOC occurrence and nonoccurrence in ground water of the United States.     

VOLATILE ORGANIC COMPOUNDS IN GROUND WATER FROM RURAL PRIVATE WELLS, 1986 TO 19991

ABSTRACT: The U.S. Geological Survey (USGS) collected or compiled data on volatile organic compounds (VOCs) in samples of untreated ground water from 1,926 rural private wells during 1986 to 1999. At least one VOC was detected in 12 percent of samples from rural private wells. Individual VOCs were not commonly detected with the seven most frequently detected compounds found in only 1 to 5 percent of samples at or above a concentration of 0.2 microgram per liter (μg/l). An assessment level of 0.2 μg/l was selected so that comparisons of detection frequencies between VOCs could be made. The seven most frequently detected VOCs were: trichloromethane, methyl tert‐butyl ether, tetrachloroethene, dichlorodifluoromethane, methylbenzene, 1,1,1‐trichloroethane, and 1,2‐dibromo‐3‐chloropropane. Solvents and trihalomethanes were the most frequently detected VOC groups in private wells. The distributions of detections of gasoline oxygenates and fumigants seemed to be related to the use patterns of compounds in these groups. Mixtures were a common mode of occurrence of VOCs with one‐quarter of all samples with detections including two or more VOCs. The concentrations of most detected VOCs were relatively small and only 1.4 percent of samples had one or more VOC concentrations that exceeded a federally established drinking water standard or health criterion.     

A STAGE-ACTIVATED TRIGGERING DEVICE FOR AUTOMATIC PUMPING SAMPLERS1

A device to trigger automatic pumping samplers at discrete stages on headwater streams in southeastern Oklahoma was developed. The magnetic switch column employs a sequence of magnetic reed switches wired in parallel and set at 0.03 m (0.10 ft) intervals. A magnetic float inside the column closes the reed switches, therby triggering the sampler as stage rises and falls. The columns were constructed from inexpensive, readily-available materials. Following installation and field calibration, the columns provided relaible and representative sampling during 12 storms, at three sites. The magnetic switch column may be used in a wide range of research and monitoring sites to improve water quality sampling.     

EVALUATION OF A DEPTH PROPORTIONAL INTAKE DEVICE FOR AUTOMATIC PUMPING SAMPLERS1

ABSTRACT: A depth proportional intake boom for portable pumping samplers was used to collect suspended sediment samples in two coastal streams for three winters. The boom pivots on the stream bed while a float on the downstream end allows debris to depress the boom and pass without becoming trapped. This equipment modifies point sampling by maintaining the intake nozzle at the same proportion of water depth regardless of stage. Data taken by pumping samplers with intakes mounted on the boom were compared with depth integrated hand samples. Pumped samples showed higher concentrations than depth integrated hand samples. Results suggested that cross-sectional sampling can give high precision with proper placement and calibration of a boom mounted intake.     

A CLOSED WATER REUSE SYSTEM FOR POWER PLANT COOLING AND DIGESTER HEATING1

ABSTRACT: A model consisting of closed water reuse and productive use of various types of wastes for energy generation is presented. The sewage after treatment would be used as the cooling water for power plants, and the condenser discharge therefrom be used as heating water for sludge digesters. The water is then purified for municipal water supply for continuous use. The advantages of this system are that water resources and energy are conserved while various types of wastes including waste heat are controlled. With a preliminary system analysis, it appears that the design for power plant based on the total heating value of wastes and digester capacity based on sewage sludge generation is feasible in terms of acquisition and full utilization of various types of wastes as generated in a single metropolitan area. The system as shown in this design is in balance among various factors such as the generation rate of municipal refuse, municipal sewage, waste heat in the condenser discharge, and raw sewage sludge.     

CHANGING TIMES FOR WATER RESEARCH AND TECHNOLOGY TRANSFER1

In recent years, important changes have occurred in water resources research. There have been major shifts in attitudes of Congress, state legislatures and the general public toward water and related resource issues. Future water research and development will have to be environmentally oriented. Emphasis is shifting to research productivity. To justify research expenditures, hard facts must be produced which demonstrate payoff. Technology transfer (getting research results into the hands of users in an understandable and usable form) is gaining prominence. Research projects must be designed for total problem solution and technology transfer must be incorporated as a part of project objectives. Research must be planned and conducted to meet users' needs. Guidelines for modern research design and technology transfer are presented.     

GROUND WATER MONITORING FOR TEMIK (ALDICARB) IN FLORIDA1

ABSTRACT: Over 700 community drinking water supplies were sampled for the pesticide Temik (aldicarb and its oxidative metabolites aldicarb sulfoxide and aldicarb sulfone) in Florida. All community supply wells sampled for Temik were located in counties where Temik was reported to have been used and approximately one-half of the wells were located in counties where ground water was determined to be highly susceptible to contamination by Temik. Susceptibility was determined using ranking criteria that incorporated ground water recharge characteristics, water use, and Temik use patterns. Temik was not detected in any of the community supply wells sampled during the study. However, Temik was detected in shallow, private wells, as was the pesticide ethylene dibromide in counties with ground water characterized as highly susceptible to contamination.     

A DECISION SUPPORT SYSTEM FOR WATER QUALITY DATA AUGMENTATION: A CASE STUDY1

ABSTRACT: Recent developments in water quality monitoring have generated interest in combining non-probability and probability data to improve water quality assessment. The Interagency Task Force on Water Quality Monitoring has taken the lead in exploring data combination possibilities. In this paper we take a developed statistical algorithm for combining the two data types and present an efficient process for implementing the desired data augmentation. In a case study simulated Environmental Protection Agency (EPA) Environmental Monitoring and Assessment Program (EMAP) probability data are combined with auxiliary monitoring station data. Auxiliary stations were identified on the STORET water quality database. The sampling frame is constructed using ARC/INFO and EPA's Reach File-3 (RF3) hydrography data. The procedures for locating auxiliary stations, constructing an EMAP-SWS sampling frame, simulating pollutant exposure, and combining EMAP and auxiliary stations were developed as a decision support system (DSS). In the case study with EMAP, the DSS was used to quantify the expected increases in estimate precision. The benefit of using auxiliary stations in EMAP estimates was measured as the decrease in standard error of the estimate.     

DISTRIBUTED RUNOFF FORMULATION DESIGNED FOR A PRECISION AGRICULTURAL LANDSCAPE MODELING SYSTEM1

A precision scale landscape model designed for agricultural applications is described in this paper. The Precision Agricultural Landscape Modeling System (PALMS) is a combination of two process‐based models: a diffusive wave runoff model with ponding (described in detail) and a biosphere model with a crops module (briefly reviewed). Several innovations, including numerical formulations for the hydrologic properties of the soil surface with crusting, slope/tillage angle interactions, and change of roughness and detention storage with cumulative precipitation have been included. The model is compared to observations on one 1.8 ha field planted with maize and soybeans during four growing seasons, and one 24 ha field planted with maize during one growing season. Daily average soil moisture is simulated well (within 5 percent volumetric), except in extended runoff/ponding episodes. Physical processes not simulated in the model suggest possible explanations for model errors. Planned improvements for PALMS are also presented.     

DETERMINING THE SOURCE OF STREAM CONTAMINATION IN A KARST‐WATER SYSTEM,SOUTHWEST VIRGINIA,USA1

ABSTRACT: Karst terrane provides a linkage between surface water and ground water regimes by means of caves, sinkholes and swallets, and sinking streams, and facilitates the inter‐watershed transfer of water and contaminants through these subsurface systems. The goal of this study was to develop procedures to identify the sources of degradation of a creek situated in a complex karst‐water system. The study approach consisted of using dye tracing technique to determine subsurface flow paths through the karst system, a water‐sampling network to identify and characterize pollution sources within the surface watershed and subsurface flow regime, and evaluation of analytical data for several water quality parameters. The results of this study provide an interesting perspective of water and contaminant movement in karst‐water systems and pinpoint the sources of stream contamination for a case study site in southwest Virginia where two springs supply water to a contaminated freshwater stream.     

A SIMPLE METHOD FOR ESTIMATING BASEFLOW AT UNGAGED LOCATIONS1

ABSTRACT: Baseflow, or water that enters a stream from slowly varying sources such as ground water, can be critical to humans and ecosystems. We evaluate a simple method for estimating base‐flow parameters at ungaged sites. The method uses one or more baseflow discharge measurements at the ungaged site and longterm streamflow data from a nearby gaged site. A given baseflow parameter, such as the median, is estimated as the product of the corresponding gage site parameter and the geometric mean of the ratios of the measured baseflow discharges and the concurrent discharges at the gage site. If baseflows at gaged and ungaged sites have a bivariate lognormal distribution with high correlation and nearly equal log variances, the estimated baseflow parameters are very accurate. We tested the proposed method using long‐term streamflow data from two watershed pairs in the Driftless Area of southwestern Wisconsin. For one watershed pair, the theoretical assumptions are well met; for the other the log‐variances are substantially different. In the first case, the method performs well for estimating both annual and long‐term baseflow parameters. In the second, the method performs remarkably well for estimating annual mean and annual median baseflow discharge, but less well for estimating the annual lower decile and the long‐term mean, median, and lower decile. In general, the use of four measurements in a year is not substantially better than the use of two.     

STATISTICAL METHODS AND SAMPLING DESIGN FOR ESTIMATING STEP TRENDS IN SURFACE-WATER QUALITY1

ABSTRACT: This paper addresses two components of the problem of estimating the magnitude of step trends in surface water quality. The first is finding a robust estimator appropriate to the data characteristics expected in water-quality time series. The Hodges-Lehmann class of estimators is found to be robust in comparison to other nonparametric and moment-based estimators. A seasonal Hodges-Lehmann estimator is developed and shown to have desirable properties. Second, the effectiveness of various sampling strategies are examined using Monte Carlo simulation coupled with application of this estimator. The simulation is based on a large set of total phosphorus data from the Potomac River. To assure that the simulated records have realistic properties, the data are modeled in a multiplicative fashion incorporating flow, hysteresis, seasonal, and noise components. The results demonstrate the importance of balancing the length of the two sampling periods and balancing the number of data values between the two periods. The inefficiency of sampling at frequencies much in excess of 12 samples per year is demonstrated. Rotational sampling designs are discussed, and efficient designs, at least for this river and constituent, are shown to involve more than one year of active sampling at frequencies of about 12 per year.     

A MIXING MODEL FOR A SEPARATED MECHANICAL AERATION SYSTEM1

ABSTRACT: An input-output method, using a network of ideal continuous stirred-tank and plug-flow tublar reactors, is adopted to analyze residence time distribution data for a separated mechanical aeration system. The usefulness of this modeling concept is enhanced by its simplicity, especially in the presence of a first-order reaction. This facilitates use of the model format for wastewater quality prediction. Moreover, first-order rate constants can also be estimated from the model, if conversions due to the reaction rate are available.     

ECONOMICS OF SCREENING FOR PESTICIDES IN GROUND WATER1

ABSTRACT: In the United States, millions of dollars are currently spent to monitor water quality for a whole suite of organic compounds. However, results of several surveys conducted in the past decade indicate that only a few pesticides occur in a small proportion of wells. Screening methods based on historical evidence of contamination patterns and knowledge of the locales will have significant potential to reduce these costs and effectively identify contamination problems. In this paper, the economics of utilizing two screening methods, sequential analysis and sample compositing, in the design of monitoring strategies is captured In the form of mathematical models and illustrated for a state-level monitoring program. When the two methods are adopted, the total analytical cost to conclusively identify contaminated wells in a network of 4,000 wells is shown to range from $12,500 to $1,575,000 depending on the extent of contamination. In contrast, the total analytical cost of a conventional program where all the wells in the network are sampled and tested for a standard suite of pesticides at a cost of $250/sample is one million dollars. Given such wide range in costs, it is prudent to incorporate the screening concepts presented in this paper in the development of cost-effective monitoring programs.     

AN EMPIRICALLY‐BASED SEQUENTIAL GROUND WATER MONITORING NETWORK DESIGN PROCEDURE1

ABSTRACT: A procedure using a simple, empirically‐based model that makes efficient use of available information has been developed for designing a ground water monitoring well network. A moving plume is described by siting wells in a sequential manner, relying upon two‐dimensional concentration data obtained from previously installed wells to determine the locations of future wells. Data sets from two well known, densely monitored natural gradient tracer studies were used to test the procedure. Plumes defined by all information in the original networks were compared to those defined by reduced networks designed by the new procedure. The new procedure tracked the plumes using only a portion of that information. The new procedure could have reduced the number of wells in the original tests by about 50 percent without appreciable loss of plume information as measured by plume location and extent and by tracer mass.     

A SIPHON GAGE FOR MONITORING SURFACE-WATER LEVELS1

A device that uses a siphon tube to establish a hydraulic connection between the bottom of an onshore standpipe and a point at the bottom of a water body was designed and tested for monitoring surface-water levels. Water is added to the standpipe to a level sufficient to drive a complete slug of water through the siphoning tube and to flush all air out of the system. The water levels in the standpipe and the water body equilibrate and provide a measurable static water surface in the standpipe. The siphon gage was designed to allow quick and accurate year-round measurements with minimal maintenance. Currently available devices for monitoring surface-water levels commonly involve time-consuming and costly installation and surveying, and the movement of reference points and the presence of ice cover in cold regions cause discontinuity and inaccuracy in the data collected. Installation and field testing of a siphon gage using 0.75-in-diameter polyethylene tubing at Ashumet Pond in Falmouth, Massachusetts, demonstrated that the siphon gage can provide long-term data with a field effort and accuracy equivalent to measurement of ground-water levels at an observation well.