Design guidelines for an optimum scrubber system

The revised New Source Performance Standards (NSPS) for the utility industry mandates reduced particulate matter and sulfur dioxide emissions from new utility boilers. A wet scrubber system can be an advantage in controlling both of these emissions. Existing wet scrubber systems may meet the new standards with significant increase in power consumption. A careful design of the entire scrubber system, based on the experience gained at the existing installations, is necessary to ensure cost effectiveness. The experience with existing wet scrubber systems used on coal-fired utility boilers is reviewed and their performance is correlated with power consumptions. Based on a correlation of scrubber pressure drop against outlet concentration, conventional scrubber systems would be able to meet the revised NSPS for particulate matter with a theoretical scrubber pressure drop of 43±5 cm H₂O. Overall system pressure drop, however, could easily run as high as 76 cm H₂O. Novel scrubber systems such as the electrostatically augmented scrubber may provide the necessary collection performance at lower pressure drops. The performance of the various scrubber components such as mist eliminators and reheaters is reviewed. Operating problems are also discussed.     

Seasonal distribution and modeling of diesel particulate matter in the Southeast US

The fine and ultra fine size of diesel particulate mater (DPM) are of great health concern and significantly contribute to the overall cancer risk. In addition, diesel particles may contribute a warming effect on the planet's climate. The composition of these particles is composed principally of elemental carbon (EC) with adsorbed organic compounds, sulfate, nitrate, ammonia, metals, and other trace elements. The purpose of this study was to depict the seasonality and modeling of particulate matter in the Southeastern US produced by the diesel fueled sources (DFSs). The modeling results came from four one-month cases including March, June, September, and December to represent different seasons in 2003 by linking Models-3/CMAQ and SMOKE. The 1999 National Emissions Inventory Version 3 (NEI99) was used in this analysis for point, area, and non-road sources, whereas the National Mobile Inventory Model (NMIM) was used to create the on-road emissions. Three urban areas, Atlanta, Birmingham, and Nashville were selected to analyze the DPM emissions and concentrations. Even though the model performance was not very strong, it could be considered satisfactory to conduct seasonal distribution analysis for DPM. Important hourly DPM seasonality was observed in each city, of which higher values occurred at the morning traffic rush hours. The EC contributions of primary DPM were similar for all three sites (~ 74%). The results showed that there is no significant daily seasonality of DPM contribution to PM_2.5 for any of these three cities in 2003. The annual DPM contribution to total PM_2.5 for Atlanta, Nashville, and Birmingham were 3.7%, 2.5%, and 2.2%, respectively.     

Assessing concentrations and health impacts of air quality management strategies: Framework for Rapid Emissions Scenario and Health impact ESTimation (FRESH-EST)

In air quality management, reducing emissions from pollutant sources often forms the primary response to attaining air quality standards and guidelines. Despite the broad success of air quality management in the US, challenges remain. As examples: allocating emissions reductions among multiple sources is complex and can require many rounds of negotiation; health impacts associated with emissions, the ultimate driver for the standards, are not explicitly assessed; and long dispersion model run-times, which result from the increasing size and complexity of model inputs, limit the number of scenarios that can be evaluated, thus increasing the likelihood of missing an optimal strategy. A new modeling framework, called the “Framework for Rapid Emissions Scenario and Health impact ESTimation” (FRESH-EST), is presented to respond to these challenges. FRESH-EST estimates concentrations and health impacts of alternative emissions scenarios at the urban scale, providing efficient computations from emissions to health impacts at the Census block or other desired spatial scale. In addition, FRESH-EST can optimize emission reductions to meet specified environmental and health constraints, and a convenient user interface and graphical displays are provided to facilitate scenario evaluation. The new framework is demonstrated in an SO₂ non-attainment area in southeast Michigan with two optimization strategies: the first minimizes emission reductions needed to achieve a target concentration; the second minimizes concentrations while holding constant the cumulative emissions across local sources (e.g., an emissions floor). The optimized strategies match outcomes in the proposed SO₂ State Implementation Plan without the proposed stack parameter modifications or shutdowns. In addition, the lower health impacts estimated for these strategies suggest that FRESH-EST could be used to identify potentially more desirable pollution control alternatives in air quality management planning.     

Characteristics of oxidant precursor emissions from anthropogenic sources in the United States

Hydrocarbons (HC) and nitrogen oxides (NO_x) have been identified as the most important precursor pollutants for oxidant formation in the atmosphere. These pollutants are emitted both from natural and anthropogenic sources; however, these two types of sources are generally geographically separated. Anthropogenic emissions are dominant in and around urban centers, where the majority of severe oxidant problems occur. Based on data gathered by the MAP3S/RAINE emissions inventory project, anthropogenic emissions of HC in the conterminous United States were 24.8 million metric tons in 1979. HC emissions were predominantly from area sources, the transportation sector being the largest contributor with 39.8% of the total. State-by-state breakdowns are also included. Based on analyses by other emissions inventory projects, the nonreactive fraction of the emissions from the transportation sector is less than 20% by weight. The highest proportion of HC emissions occur at low altitudes (0–50 m range) in high population density areas. Anthropogenic emissions of NO_x were 23.7 million metric tons in 1979; 50.8% were from point sources. The transportation sector and the electric utilities sector account for 37.1% and 30.9% of the NO_x emissions, respectively. The NO₂ fraction of the emissions from the transportation and electric utilities sectors is less than 10% by weight, based on NO/NO₂ speciation data from two other emissions inventories. Highest rates of NO_x emissions occur in high population density areas and are released at low altitude (0–50 m); three areas of high electric generating capacity were found to have high release altitudes.     

Effect of hydrogen addition to CNG in a biodiesel-operated dual-fuel engine

Alternative fuels for diesel engine applications are gaining more prominence as they have numerous advantages compared to fossil fuels. They are renewable, biodegradable; provide food and energy security and foreign exchange savings. They address environmental concerns and socio-economic issues as well. Gaseous fuels such as compressed natural gas and hydrogenated compressed natural gas (HCNG) appear more attractive fuels for diesel engine applications operated in dual-fuel mode. Such dual fuel engines can replace considerable amount of liquid-injected pilot fuels by gaseous fuels besides being friendly to the environment. A small quantity of liquid fuel injected towards the end of the compression stroke initiates combustion of the inducted gas in the dual-fuel engines. The main advantage of dual-fuel engines is their lower nitrogen oxides (NO_x) and particulate emissions. Hence renewable fuels such as biodiesels and gaseous fuels can be used predominantly for transportation and power generation applications. Gaseous fuels are clean burning and are more economical as well. A suitable carburettor was designed to supply a stoichiometric mixture of air and HCNG to the modified diesel engine operated in dual-fuel mode. The biodiesel used in this study is derived from Honge oil called the Honge oil methyl ester (HOME). This paper presents the performance, combustion and exhaust emission characteristics of a single cylinder, four stroke, direct injection, stationary diesel engine operated on HOME and HCNG in dual-fuel mode. From the results it is observed that HOME–HCNG combination gave lower brake thermal efficiency (BTE) and improved emission levels when compared with diesel/HOME in single fuel operation. Lower smoke and particulate matter were obtained with dual-fuel operation. Comparative measures of BTE, peak pressure, pressure–crank angle variation, smoke opacity, hydrocarbon, carbon monoxide and NO_x emissions have been made and analysed.     

An assessment of the environmental effects of energy systems, with emphasis on oil

This paper describes the approach of the VESE project undertaken by ENEA to assess the environmental and socioeconomic effects of various energy systems, and it refers to the fundamental choices adopted for the development of the project, to the work plan and to the analytical methods employed. This paper also reports the findings of an oil system case study concerning the Italian province of Piacenza: a set of oil-fired electric power plants, together with industrial and civil installations burning oil products. Fuel consumption and air pollution emissions were characterized through a field survey. The emission inventory of sulfur and nitrogen oxides and particulate matter were estimated with reference to area and point sources. A multisource dispersion model (DIMULA) was developed, which took into account certain meteorological peculiarities of the area (e.g., calm weather and/or fog). The model, first applied to the dispersion of sulfur oxides, has given encouraging results. A study of comparative forced expiratory volumes in elementary school children has been chosen to determine the air pollution health effects in the Piacenza province. Plant and animal resources in the province of Piacenza were identified through a field investigation. Published data on crop damage by air pollutants are discussed and statistically analyzed. A dose-response relationship was obtained for the yield loss of alfalfa caused by SO₂.     

Particle size distribution and its elemental composition in the ambient air of Delhi

This study examines the chemical composition of PM10, the thoracic fraction of the atmospheric particulate matter. An eight-stage Anderson impactor is used to separate the PM10 from other fractions with different aerodynamic behaviour at three different area representative sites in Delhi from February to May 1998. PM10 particulate are subdivided into two fractions, coarse (> 2.1-10 microns) and fine (< 2.1 microns). The concentrations of major heavy metals such as Pb, Zn, Cd, Ni, and Fe are determined by atomic absorption spectrophotometer. The average concentration of coarse fraction of PM10 is found to be 68.3 +/- 17 micrograms/m3 while the fine fraction of PM10 is 71.3 +/- 15 micrograms/m3 for Delhi. Metal concentration (except Fe) in fine fraction exceeds by a factor of up to 6, as compared to that in the coarse fraction. In order to identify the major sources of fine and coarse fraction of PM10, principle component analysis (PCA) was undertaken and three major sources were identified, namely vehicular emissions, industrial emission, and soil resuspension.     

Particle size measurements of automotive diesel emissions

The automative diesel engine has long been acknowledged as being “dirtier” than the spark ignition engine and its particulate emissions may be carcinogenic. Possible solutions to the diesel emission problem are combustion modification or aftertreatment devices. Selection of candidate aftertreatment devices requires knowledge of the physical and chemical properties of the particles, including particle morphology, size distribution, mass concentration and emission rates in the exhaust gas stream. The study reported here represents the first of a series of experiments designed to characterize the exhaust emissions and test various aftertreatment devices. This paper deals only with the particulate characterization phase of the program. Results of size distribution, particle concentration and mass emission rate measurements for a 5.71 displacement Oldsmobile diesel engine are given for a variety of engine operating conditions.     

Greenhouse Gas Fluxes in Tropical and Temperate Agriculture: The need for a Full-Cost accounting of Global Warming Potentials

Agriculture's contribution to radiative forcing is principally through its historical release of carbon in soil and vegetation to the atmosphere and through its contemporary release of nitrous oxide (N_2O) and methane (CHM₄). The sequestration of soil carbon in soils now depleted in soil organic matter is a well-known strategy for mitigating the buildup of CO₂ in the atmosphere. Less well-recognized are other mitigation potentials. A full-cost accounting of the effects of agriculture on greenhouse gas emissions is necessary to quantify the relative importance of all mitigation options. Such an analysis shows nitrogen fertilizer, agricultural liming, fuel use, N_2O emissions, and CH₄ fluxes to have additional significant potential for mitigation. By evaluating all sources in terms of their global warming potential it becomes possible to directly evaluate greenhouse policy options for agriculture. A comparison of temperate and tropical systems illustrates some of these options.     

Modeling the effects of emission controls in the Netherlands

A photochemical air quality simulation model was applied to an area covering a large portion of The Netherlands and nearby source areas in Belgium and Germany. Simulations of an O₃ episode typical of those that occur during summer months yielded good agreement between predicted and observed O₃ levels. The level of performance for NO₂ and NO was somewhat less than that for O₃. The model was used to study the influence of mobile and stationary sources within the region, as well as the inflow of pollutants from outside the region on predicted O₃, NO₂, and NO levels within the modeling region. Pollutants transported into the region appear to have a significant influence on O₃ levels. The influence of stationary source emissions on O₃ and NO₂ levels is greater than that of mobile source emissions. The model has been a valuable tool in evaluating the possible influence of different source categories and control regulations on pollutant concentration levels.     

CO2 emissions in German, Swedish and Colombian manufacturing industries

This study evaluates and compares the trends in CO₂ emissions for the manufacturing industries of three countries: two developed countries (Germany and Sweden) that have applied several measures to promote a shift towards a low-carbon economy and one developing country (Colombia) that has shown substantial improvements in the reduction of CO₂ emissions. This analysis is conducted using panel data cointegration techniques to infer causality between CO₂ emissions, production factors and energy sources. The results indicate a trend of producing more output with less pollution. The trends for these countries’ CO₂ emissions depend on investment levels, energy sources and economic factors. Furthermore, the trends in CO₂ emissions indicate that there are emission level differences between the two developed countries and the developing country. Moreover, the study confirms that it is possible to achieve economic growth and sustainable development while reducing greenhouse gas emissions, as Germany and Sweden demonstrate. In the case of Colombia, it is important to encourage a reduction in CO₂ emissions through policies that combine technical and economic instruments and incentivise the application of new technologies that promote clean and environmentally friendly processes.     

Mutagenic and carcinogenic potency of extracts of diesel and related environmental emissions: Study design, sample generation, collection, and preparation

A major diesel emissions research program has been initiated by the U.S. Environmental Protection Agency to assess the human health risk associated with increased use of diesel automobiles. This program is intended to establish the mutagenic and carcinogenic potency of complex organics associated with diesel particles as well as comparative particle-bound organics from other environmental emissions for which human epidemiological data are available. The mobile source samples selected for this study were collected from a heavy-duty diesel engine, a series of light-duty diesel passenger cars, and a gasoline catalyst automobile. The comparative source samples incorporated into the study were cigarette smoke condensate, coke oven emissions, roofing tar emissions, and benzo(a)pyrene. The samples were tested using three mutagenic assays and four carcinogenic assays as prescribed by a test matrix. This report describes the study design, particle generation, and sample collection and preparation. A brief summary of the bioassays is also included.     

Sidestream tobacco smoke constituents in indoor air modelled in an experimental chamber— Polycyclic aromatic hydrocarbons

Exposure to sidestream tobacco smoke is concerned with constituents in suspension in the indoor atmosphere. The natural dissipation of sidestream tobacco smoke has been investigated in a static atmosphere in a 10 m³ experimental chamber, and the rate of dissipation is expressed as T_0.5, the half-life of residence in the air. Respective T_0.5 of smoke components are calculated from the various sample data points, assuming a kinetic equation of the first-order process. Sidestream smoke has been generated by a smoking machine according to the Coresta standard protocol and then left to age over an 8-hour period, with subsequent sampling at defined time intervals. The experiments have been repeated over five days, and eight data point samples are obtained for each experiment. Besides nicotine, CO, and smoke particulate matter, interest has been focused on polycyclic aromatic hydrocarbons (PAH). The initial concentrations, C₀ for smoke particulate matter and nicotine (gas and particulate phases) are found to be 13.8 mg and 92 μg per cigarette per cubic meter, with T_0.5 being 2.6 and 2.1 hours, respectively. Low molecular-weight PAH have T_0.5 up to 20 hours, explainable only by their high concentrations in the gas phase, while the 3- to 7-ring PAH have T_0.5 of about 2 hours. The contribution of CO to ambient concentration is 91 mg per cigarette per cubic meter. The data can be useful in mathematical modellization studies regarding ventilation or exposure to sidestream smoke.     

Mutagenic and carcinogenic potency of extracts from diesel related environmental emissions: Simultaneous morphological transformation and mutagenesis in BALB/c 3t3 cells

Particulate extracts from six different environmental emission sources were assayed for genotoxic activity in mouse BALB/c 3T3 clone A31-1 cells. All compounds were tested simultaneously for both transforming and mutagenic (induction of ouabain-resistance) potential with and without exogenous metabolic activation in the form of a 9000 × g postmitochondrial hepatic supernatant fraction from Aroclor-1254 induced Fischer 344 rats. Dichloromethane particulate extracts from the exhaust of two light duty diesel engines (Oldsmobile and Nissan), one heavy duty diesel engine (Caterpillar) and one late model gasoline engine (Mustang II) were assayed in an identical manner to particulate extracts from the emissions of a roofing tar pot and a coke oven. No clear dose-dependent responses were observed, but several of the samples showed significant transforming and mutagenic activity. A qualitative ranking system showed the activity of these particulate extracts for either mutagenesis or transformation was: coke oven = Mustang II gasoline engine > Nissan diesel engine > roofing tar. Particulate extracts from the Oldsmobile diesel engine and the Caterpillar diesel engine showed essentially no activity.     

Smoke-haze pollution: a review of the 1997 episode in Southeast Asia

In the second half of 1997, large areas in Southeast Asia were severely affected by a smoke-haze pollution episode caused by the emissions of an estimated 45,600 km² of vegetation that burnt on the Indonesian islands Kalimantan and Sumatra. To document the impacts of these fires on air quality, data for total suspended particulate matter (TSP) and for particulate matter below or equal to 10 microns in diameter (PM₁₀) from selected sites in Indonesia, Malaysia and Singapore are analysed in this paper. These data are supplemented by meteorological data, satellite images and a summary of related research. TSP was above 2,000 μg m^–3 for several days in Indonesian locations close to the most extensive fire activity. In Malaysia and Singapore, ambient particle concentrations increased to several times their average September levels. Characteristically for emissions from vegetation burning, the additional atmospheric particle loading during the smoke-haze episode was predominantly due to an increase of the fraction below or equal to 2.5 microns in diameter (PM_2.5). Due to the dominance of respirable particles (PM_2.5) in the smoke-haze, air quality reporting based on TSP or PM₁₀ may be inadequate to assess the health risk. Upgrading of PM_2.5 monitoring facilities is therefore needed. Reducing the probability of similar smoke-haze events in future would require appropriate fire use and smoke management strategies. Electronic Publication     

Control of salt laden particulate emissions from hogged fuel boilers

This paper presents the results of an evaluation of excessive salt emissions from 16 hogged fuel boilers in Washington, Oregon, and Alaska. Logs transported or stored in sea water, absorb substantial amounts of salt which is noncombustible, and is emitted as a fine particulate when the hogged fuel is burned, contributing to opacity and particulate emissions. Control measures considered are fuel pretreatment, combustion modification, use of conventional particulate control devices (electrostatic precipitators, fabric filters, and wet scrubbers), and several novel particulate control devices.The best available control technology appears to be a mechanical collector-fabric filter combination; some electrostatic scrubber type devices have also shown excellent capability.     

Methane and Nitrogen Oxide Fluxes in Tropical Agricultural Soils: Sources, Sinks and Mechanisms

Tropical soils are important sources and sinks of atmospheric methane (CH₄) and major sources of oxides of nitrogen gases, nitrous oxide (NM_2O) and NO_x (NO+NO₂). These gases are present in the atmosphere in trace amounts and are important to atmospheric chemistry and earth's radiative balance. Although nitric oxide (NO) does not directly contribute to the greenhouse effect by absorbing infrared radiation, it contributes to climate forcing through its role in photochemistry of hydroxyl radicals and ozone (O₃) and plays a key role in air quality issues. Agricultural soils are a primary source of anthropogenic trace gas emissions, and the tropics and subtropics contribute greatly, particularly since 51% of world soils are in these climate zones. The soil microbial processes responsible for the production and consumption of CH₄ and production of N-oxides are the same in all parts of the globe, regardless of climate. Because of the ubiquitous nature of the basic enzymatic processes in the soil, the biological processes responsible for the production of NO, N_2O and CH₄, nitrification/denitrification and methanogenesis/methanotropy are discussed in general terms. Soil water content and nutrient availability are key controls for production, consumption and emission of these gases. Intensive studies of CH₄ exchange in rice production systems made during the past decade reveal new insight. At the same time, there have been relatively few measurements of CH₄, N_2O or NO_x fluxes in upland tropical crop production systems. There are even fewer studies in which simultaneous measurements of these gases are reported. Such measurements are necessary for determining total greenhouse gas emission budgets. While intensive agricultural systems are important global sources of N₂O and CH₄ recent studies are revealing that the impact of tropical land use change on trace gas emissions is not as great as first reports suggested. It is becoming apparent that although conversion of forests to grazing lands initially induces higher N-oxide emissions than observed from the primary forest, within a few years emissions of NO and N₂O generally fall below those from the primary forest. On the other hand, CH₄ oxidation is typically greatly reduced and grazing lands may even become net sources in situations where soil compaction from cattle traffic limits gas diffusion. Establishment of tree-based systems following slash-and-burn agriculture enhances N₂O and NO emissions during and immediately following burning. These emissions soon decline to rates similar to those observed in secondary forest while CH₄ consumption rates are slightly reduced. Conversion to intensive cropping systems, on the other hand, results in significant increases in N₂O emissions, a loss of the CH₄ sink, and a substantial increase in the global warming potential compared to the forest and tree-based systems. The increasing intensification of crop production in the tropics, in which N fertilization must increase for many crops to sustain production, will most certainly increase N-oxide emissions. The increase, however, may be on the same order as that expected in temperate crop production, thus smaller than some have predicted. In addition, increased attention to management of fertilizer and water may reduce trace gas emissions and simultaneously increase fertilizer use efficiency.     

Electrostatic enhancement of moving-bed granular filtration

The electrostatic granular filter developed by Combustion Power Company combines a moving-bed filter with an electrostatic grid for high-efficiency collection of particulate. The coulomb charge occurring naturally on particulate from combustion or other processes in which tribocharging occurs is sufficient such that imposition of an electric field substantially enhances mechanical collection in the packed filter. A mathematical model is presented which accounts for the major parameters affecting electrostatic performance. Experimental data developed in an industrial unit retrofitted with electrostatic equipment and a pilot-scale filter demonstrates dramatic improvement in opacity and outlet loading; the industrial unit achieved 99% collection efficiency with less that 4 Iwd (1kPa) pressure drop. Data from the pilot-scale filter has shown that collection of micron-size particulate is especially enhanced with the electric field and has confirmed the 99% overall collection capability demonstrated in the industrial unit. The design of a 420,000 acfm (1200 m³/min) system being installed at Weyerhaeuser Company's Longview, Washington plant is also discussed.     

Effective coordination and integration of energy and transport policies for CO2 mitigation in Thailand

Cross-cutting government policies that are designed to mitigate CO₂ emissions have caused an increased interdependence between government agencies. This leads to fragmentation in the public administration of climate change mitigation. The need for more coordination among government agencies involved in drafting and implementing energy and transportation policies is necessary to create collaborative strategies that can affect energy demand and reduce CO₂ emissions. The study aims to use Thailand as a case study to examine and discuss how effective coordination and integration of energy and transport policies and actions in the domain of GHG mitigation in Thailand can be successful. The authors applied a mixed-method information gathering approach combined with data from panel discussions. A thorough literature review guided the evidence, which was reinforced by the expert opinions of 35 industry professionals and governmental officers. Importance-performance analysis was applied as a policy assessment method. The study proposes applying a combination of several factors and conditions regarding institutional aspects of transport and energy sectors into a new greater strategies and actions toward CO₂ mitigation. In findings, a combination of instruments and autonomy of sectors is the greatest important and successful opportunity to enable effective coordination and integration of policies for CO₂ mitigation. Insightful discussions on integrated approach and recommendations would contribute to collaboratively administrative mechanism.     

Tidal variations in dissolved and particulate phase radionuclide activities in the Esk estuary,England, and their distribution coefficients and particulate activity fractions

Measurements have been made of the radionuclide activities, particularly for plutonium isotopes, of the particulate and dissolved fractions of the tidal waters of the Esk Estuary. A wide range of K_d values indicates the lack of equilibrium conditions in this dynamically changing environment. The particulate activity contributes a major part of the activity of the suspension, with reworked estuarine sediment providing an important component of this. The estuarine circulation system results in the dispersion of particulate radionuclides into the low salinity upper reaches of the estuary, where plutonium isotopes are apparently mobilised, enriching the dissolved fraction activity.