Variability of the sorption of Cs, Zn, Sr, Co, Cd, Ce, Ru, Tc and I at trace concentrations by a forest soil along a transect

The variability of the sorption properties (characterized by the distribution coefficient K_d) of a forest soil for Cs, Zn, Sr, Co, Cd, Ce, Ru, Tc, and I were determined along a transect of 150 m in regular intervals of 3 m. Radioactive tracers were used to ensure trace concentrations of these elements. For comparison, for each soil sample the loss on ignition, as a measure of the soil organic matter content, and the pH were also determined. On average, the K_d values increase in the sequence Tc < I < Ru ≈ Co ≈ Zn ≈ Sr < Cd < Ce < Cs; the spatial variability in the sequence I < Zn ≈ Sr ≈ Co ≈ Cd ≈ Ru ≈ Tc < Cs, and I ≈ Ce < Tc. Correlation analysis revealed that, when moving along the transect, the K_d values for some elements changed in a similar, and for others in a dissimilar pattern. In a few cases a correlation between the pH or the loss on ignition and the K_d values was also present. The spatial structure of the data was examined by semivariograms. For the elements Co, Cd, Zn, and Sr, the K_d values showed an almost periodic behaviour along the transect, which is probably due to periodic changes of some soil properties in a forest with regularly spaced trees.     

Aquatic arsenic: Toxicity,speciation, transformations,and remediation

This paper reviews the current knowledge on the toxicity, speciation and biogeochemistry of arsenic in aquatic environmental systems. The toxicity of arsenic is highly dependent on the chemical speciation. The effects of pH, E_h, adsorbing surfaces, biological mediation, organic matter, and key inorganic substances such as sulfide and phosphate combine in a complex and interwoven dynamic fashion to produce unique assemblages of arsenic species. The number of different arsenic species found in environmental samples and an understanding of the transformations between arsenic species has increased over the past few decades as a result of new and refined analytical methods. Changes in arsenic speciation and in total arsenic content of foods upon processing have suggested possible risks associated with processed and unprocessed food. Arsenic removal from water using adsorbents, chemical oxidation, photolysis and photocatalytic oxidation techniques is also reviewed.     

劳动力转移、性别差异与农地流转及合约选择

通过构建“劳动力转移-性别差异-农地流转及合约选择”分析框架,分析劳动力转移性别差异背后的行为经济学含义,进而探讨不同性别的劳动力转移对农户农地流转供给决策与合约选择的差异化影响机制。理论研究表明,女性在家庭中起粘结家庭成员的作用,女性劳动力非农就业更能体现家庭的“离农”,因而女性劳动力的非农就业行为对农户农地流转供给决策具有更明显的促进作用;男性是农户家庭在村庄中排他能力的标志,具有不可忽视的农地流转风险规避功能,因而男性劳动力的外出就业距离对农户农地流转的合约选择起决定性作用。利用全国9省(区)4772个农户样本数据进行实证分析,计量结果表明:①女性劳动力非农就业比例每增加10%,农户转出农地面积占承包地面积比例增加1.06%;②男性劳动力县外就业比例每增加10%,农户转出农地时签订关系型合约的可能性增加1.11%;③男性劳动力县外就业比例每增加10%,意愿合约形式为无合同的可能性增加0.63%,意愿合约形式为口头合同的可能性增加0.29%,意愿合约形式为书面合同的可能性减少0.91%。这意味着,为了劳动力流转市场与农地流转市场更流畅地互动,应为农村女性劳动力营造一个更加合适、有利和公平的非农就业环境,这可成为未来农村劳动力就业扶持政策的重要方向。另一方面,促进正式契约与关系型合约的有机衔接,有利于农地流转合约的正式化与规范化,从而为农地流转市场的健康发育提供有力保障。     

Evaluation of the sensitivity of marine microalgal strains to the heavy metals, Cu, As, Sb, Pb and Cd

The sensitivity of nine marine microalgal species (consisting of five divisions and seven genera) to the five heavy metals, Cu(II), As(V), Sb(III), Pb(II) and Cd(II) was studied by using a fluorometric growth-inhibition assay with 96-well microplates. The algal strains studied were Cylindrotheca sp. and the LPP group that respectively characterize aggregating and filamentous types, and Chlorococcum littorale, Chlorococcum sp., Isochrysis galbana, Tetraselmis tetrathele, Heterocapsa sp., Synechococcus sp. and Prasinococcus sp. for types that occur as single cells. A good linear relationship was observed between the chlorophyll a concentration and intensity of chlorophyll fluorescence (485-nm excitation filter and 645-nm emission filter) when the chlorophyll a concentration was within the range of 0.10-5.0 microg ml(-1). A starting cell concentration of 0.10 or 0.25 microg Chl a ml(-1) was therefore selected. In accordance with OECD 201 standard procedures, the IC(50) value (concentration of a metal producing 50% growth inhibition relative to the control) was determined 72 h after adding a heavy metal by using the biomass integral. The microplate toxicity test used in this study is considered to be applicable to diverse algae, not only enumerating species but also hardly enumerating ones.     

Gyttja,a low-level,high-organic reference material

Gyttja, the bottom sediment from Perch Lake at Chalk River Nuclear Laboratories, was collected to prepare a low-level, high-organic standard radioactivity reference material. In the natural state it contained about 92% water and when dried the residue was about 50% organic material. The surface layer of this sediment contains small quantities of ⁶⁰Co, ⁹⁰Sr, ¹³⁷Cs and ²³⁹Pu. The material was collected from depth using a sludge pump and the radioactivity content adjusted with addition of surface-layer material. It was then dewatered by centrifuge and freeze-dried. The overall exercise was a demonstration of co-operation between the National Bureau of Standards, Washington, D.C., Atomic Energy of Canada Limited, the Ontario Department of Labour, the Environmental Protection Service of Environment Canada, the Department of Agriculture, the Atomic Energy Control Board and two commercial firms, Rush Engineering and Freeze-Dried Foods, Incorporated.     

Contamination of terrestrial gastropods, Helix aspersa maxima, with 137Cs, 85Sr, 133Ba and 123mTe by direct, trophic and combined pathways

(137)Cs, (85)Sr, (133)Ba and (123m)Te contaminations of terrestrial gastropods, Helix aspersa maxima, by direct deposition, labelled food ingestion or combined (trophic and direct pathways) exposure were carried out under laboratory conditions. The aim of this study was to compare the three contamination pathways: direct, trophic and combined, in terms of individual mortality, radionuclide uptake, depuration and distribution in the tissues. An initial group of 30 snails (2 years old) was exposed to radioactive aerosols during a 20-h period. These aerosols were assumed to be representative of those that would be released during a nuclear accident occurring in a PWR. A second group of 50 snails (same age) was submitted to an ingestion of commercial food contaminated by the same aerosols, twice a week for 21 days (flour at a feeding rate of about 0.2g). A third group of 40 snails was submitted to a combined exposure: exposure to radioactive aerosols (20h), followed by ingestion of flour contaminated by the same aerosols, twice a week for 21 days. No significant difference between the three groups and a reference group of 10 snails was observed, neither in growth nor in mortality. Concerning the direct pathway, at the end of direct deposition (about 1 day after the beginning), cesium was the most bioavailable element, distributed rather homogeneously throughout the whole body (13% of the total Cs in all organs excepting the digestive system and 28% in the muscle). Strontium was measured in the shell (about 70%). Barium was found in the muscle (20%) and in the shell (65%). Tellurium was mainly present in the shell (70%) and in the digestive system (20%). After 21 days of depuration, the faeces eliminated 42% of the Te. As for contamination by ingestion, Te mainly accumulated in the digestive system (72% of Te present in the total body), Ba accumulated in the muscle (75%) and Sr in the shell (70%). Concerning contamination by combined pathways, at the end of the 21-day exposure, the 4 radionuclides had the same tendency as direct deposition. However, the effect of the trophic pathway was significant: it causes an 18% increase of Sr in the shell and an 7% increase of Cs in the digestive system in comparison to direct deposition, resulting in a final 86% in the shell and 27% in the digestive system.     

Effects of brine injection wells, dry holes, and plugged oil/gas wells on chloride, bromide, and barium concentrations in the Gulf Coast Aquifer, southeast Texas, USA

Data from 1,122 brine injection wells, 24,515 dry holes, 20,877 plugged oil/gas wells, and 256 water wells were mapped with a geographic information system (GIS) and statistically analyzed. There were 9, 107, and 58 water wells within 750 m of a brine injection well, dry hole, or plugged oil/gas well, respectively. Computed median concentrations were 157 mg/l for chloride, 0.8 mg/l for bromide, and 169 microg/l for barium. The maximum chloride concentration was 2,384 mg/l, close to 10 times the secondary drinking water standard. Shallow water wells and water wells near plugged oil/gas wells had significantly higher chloride and bromide levels.     

Mixed oligopoly,foreign penetration,and environmental taxes

This paper examines the impact of foreign penetration on the public firm in a mixed oligopolistic market. Through the establishment of a mixed double oligopoly market, this paper analyzes how the share of foreign investment affects the environmental policy, the pollutant emission, and the social welfare under the condition of the state tax. The results show that: first, the introduction of foreign investment has some crowding-out effects on the social level of output. Second, the entry of foreign investment increases the profit of the public firm by a large margin, and the maximum profit of the private firm has been reduced. Third, the increase of foreign investment in public firm does not necessarily improve the environment.     

Changing air quality in Delhi,India: determinants,trends, and policy implications

Air pollution is a major environmental problem in urban areas worldwide. Delhi, the capital city of India, is no exception to the universal pattern of deteriorating urban air quality with concentration of pollutants being well above the recommended WHO levels. The magnitude and urgency of the problem as a global environmental issue needs a systematic understanding of the potential causes of pollution and their contribution to air quality. In the present study, ambient air quality data (1987–2006) of SO₂, NO₂, SPM, and RSPM were analyzed to asses the changing air quality in the study area and to evaluate the effect of measures taken to control it. The primary data were collected from 1,583 households to examine the relationship between outdoor and indoor pollution level. Based on the data, the current study concludes that despite the implementation of different pollution-controlling measures, the pollutants, especially the particulate pollutants, were well above the standard limits set by CPCB. Integration between technological and social approach of urban planning is required to mitigate and manage urban environmental problems in sustainable manner.     

Nature Documentaries,Connectedness to Nature,and Pro-environmental Behavior

We investigate the effects of nature documentaries on pro-environmental cognition and behavior. Of central interest is the concept of connectedness to nature, which describes an individual's sense of being connected to nature. Based on previous research showing that a direct nature experience in zoos can increase connectedness to nature, we questioned whether watching a nature documentary could increase connectedness to nature and pro-environmental behavior. An experiment using one control group (watching a documentary about Einstein's theory of relativity) and one treatment group (watching a nature documentary) revealed that a mediated nature experience is not sufficient to elicit an increase in connectedness to nature. However, we found that exposure increased actual donation behavior for animal and environmental protection organizations. It is important to note that nature documentary exposure increased pro-environmental donation behavior only in those already having a strong sense of connectedness. We discuss real-world implications for donation-accepting, non-profit organizations.     

Formaldehyde in China: Production, consumption, exposure levels, and health effects

Formaldehyde, an economically important chemical, is classified as a human carcinogen that causes nasopharyngeal cancer and probably leukemia. As China is the largest producer and consumer of formaldehyde in the world, the Chinese population is potentially at increased risk for cancer and other associated health effects. In this paper we review formaldehyde production, consumption, exposure, and health effects in China. We collected and analyzed over 200 Chinese and English documents from scientific journals, selected newspapers, government publications, and websites pertaining to formaldehyde and its subsequent health effects.Over the last 20 years, China's formaldehyde industry has experienced unprecedented growth, and now produces and consumes one-third of the world's formaldehyde. More than 65% of the Chinese formaldehyde output is used to produce resins mainly found in wood products — the major source of indoor pollution in China. Although the Chinese government has issued a series of standards to regulate formaldehyde exposure, concentrations in homes, office buildings, workshops, public places, and food often exceed the national standards. In addition, there have been numerous reports of formaldehyde-induced health problems, including poisoning and cancer. The lack of quality epidemiological studies and basic data on exposed populations emphasizes the need for more extensive studies on formaldehyde and its related health effects in China.     

Climate change,food stress,and security in Russia

Farming in higher latitudes is generally believed to benefit from a warmer climate due to extended growing season, reduced risk of frost, availability of more productive cultivars, and an opening potential of farming in northern locations. We analyzed the impact of climate change on production of cereals in Russia and found that this general perception of beneficiary effect of a warmer climate is unlikely to hold, primarily due to increasing risk of droughts in the most important agricultural areas of the country. Past impacts of droughts on food security throughout the twentieth century suggest that a number of adaptation options are available to mitigate the increasing risks of crop failure. We analyze the effectiveness of these measures in connection with a set of climate change projections, under two contrasting scenarios of interregional grain trade: “Fortress Market” and “Open Market.”     

A science of integration: frameworks,processes, and products in a place-based,integrative study

Integrative research is increasingly a priority within the scientific community and is a central goal for the evolving field of sustainability science. While it is conceptually attractive, its successful implementation has been challenging and recent work suggests that the move towards interdisciplinarity and transdisciplinarity in sustainability science is being only partially realized. To address this from the perspective of social-ecological systems (SES) research, we examine the process of conducting a science of integration within the Southcentral Alaska Test Case (SCTC) of Alaska-EPSCoR as a test-bed for this approach. The SCTC is part of a large, 5 year, interdisciplinary study investigating changing environments and adaptations to those changes in Alaska. In this paper, we review progress toward a science of integration and present our efforts to confront the practical issues of applying proposed integration frameworks. We: (1) define our integration framework; (2) describe the collaborative processes, including the co-development of science through stakeholder engagement and partnerships; and (3) illustrate potential products of integrative, social-ecological systems research. The approaches we use can also be applied outside of this particular framework. We highlight challenges and propose improvements for integration in sustainability science by addressing the need for common frameworks and improved contextual understanding. These insights may be useful for capacity-building for interdisciplinary projects that address complex real-world social and environmental problems.     

Composition, sources, and potential toxicological significance of PAHs in the surface sediments of the Meiliang Bay, Taihu Lake, China

Twenty-five surface sediment samples were collected from Meiliang Bay, Taihu Lake, China, in 2003. The concentrations of 16 polycyclic aromatic hydrocarbons (PAHs), identified as priority pollutants by the USEPA, were determined by gas chromatography equipped with a mass spectrometry detector (GC-MS). Total concentrations of the PAHs ranged from 1207 to 4754 ng/g dry weight. Sediment samples with the highest PAH concentrations were from the northern site of the bay, which is in proximity to the incoming PAH source; the PAH levels in the southern part were relatively low. The observed PAH levels were higher than those in river sediments in China but were lower than those found in sediments of urban areas and harbors. According to the observed molecular indices, PAHs originated largely from the high-temperature pyrolytic process, whereas the petrogenic process was more commonly responsible for PAH contamination in harbors. A good correlation existed between the benzo[a]pyrene level and the total PAH concentration (r=0.97), making benzo[a]pyrene a potential molecular marker for PAH pollution. According to the numerical effect-based sediment quality guideline (SQGs) of the United States, the levels of PAHs at most studied sites in Meiliang Bay, except some sites in the northern part of the bay, should not exert adverse biological effects. In the northern part of the bay, the PAH levels at sites 21 and 22 exceed the effects range low (ERL) and could thus cause acute biological impairments, in comparison with the sediment quality guidelines. The total PAH levels were expressed as the B[a]P toxicity equivalents (TEQs(carc)) and compared to the contaminated sediments from Guba Pechenga, Barents Sea, Russia.     

Blood cadmium,mercury, and lead in children: An international comparison of cities in six European countries,and China,Ecuador, and Morocco

Children's blood-lead concentration (B-Pb) is well studied, but little is known about cadmium (B-Cd) and mercury (B-Hg), in particular for central Europe. Such information is necessary for risk assessment and management. Therefore, we here describe and compare B-Pb, B-Cd and B-Hg in children in six European, and three non-European cities, and identify determinants of these exposures. About 50 school children (7–14 years) from each city were recruited (totally 433) in 2007–2008. Interview and questionnaire data were obtained. A blood sample was analyzed: only two laboratories with strict quality control were used. The European cities showed only minor differences for B-Cd (geometric means 0.11–0.17 μg/L) and B-Pb (14–20 μg/L), but larger for B-Hg (0.12–0.94 μg/L). Corresponding means for the non-European countries were 0.21–0.26, 32–71, and 0.3–3.2 μg/L, respectively. For B-Cd in European samples, traffic intensity close to home was a statistically significant determinant, for B-Hg fish consumption and amalgam fillings, and for B-Pb sex (boys higher). This study shows that European city children's B-Cd and B-Pb vary only little between countries; B-Hg differs considerably, due to varying tooth restoration practices and fish intake. Traffic intensity seemed to be a determinant for B-Cd. The metal concentrations were low from a risk perspective but the chosen non-European cities showed higher concentrations than the cities in Europe.     

Wildfire,climate, and perceptions in Northeast Oregon

Regional Environmental Change - Wildfire poses a rising threat in the western USA, fueled by synergies between historical fire suppression, changing land use, insects and disease, and shifts toward...     

Science, Research, Knowledge and Capacity Building

A small part of the scientific community is seeking hard to enhance the contribution of science, knowledge and capacity building to environmentally sustainable and socially fair human development around the world. Many researchers over the globe share the same commitment – anchored in concerns for the human condition. They believe that science and research can and have influenced sustainability. Therefore their main goals are to seek and build up knowledge, know-how and capacity that might help to feed, nurture, house, educate and employ the world's growing human population while conserving its basic life support systems and biodiversity. They undertake projects, that are essentially integrative, and they try to connect the natural, social and engineering sciences, environment and development of communities, multiple stakeholders, geographic and temporal scales. More generally, scientists engaged in sustainable development are bridging the worlds of knowledge and action. This pro-active, heavily ethics- and wisdom-based "science for sustainability" can be seen as the conclusion of all dialogues and discussions amongst scientists at the World Summit on Sustainable Development (WSSD) 2002 in Johannesburg. The "Plan of Implementation" after WSSD will be based on political will, practical steps and partnerships with time-bound actions. Several "means of implementation" are going to be proofed and initiated: finance, trade, transfer of environmentally sound technology, and, last but not least, science and capacity building.Some characteristics of working scientific sustainability initiatives are that they are regional, place-based and solution-oriented. They are focusing at intermediate scales where multiple stresses intersect, where complexity is manageable, where integration is possible, where innovation happens, and where significant transitions toward sustainability can start bottom-up. And they have a fundamental character, addressing the unity of the nature – society system, asking how that interactive system is evolving and how it can be consciously, if imperfectly, steered through the reflective mobilization and application of appropriate knowledge and know-how. The aims of such sustainability-building initiatives conducted by researchers are: first to make significant progress toward expanding and deepening the research agenda of science and knowledge-building for sustainability; secondly to strengthen the infrastructure and capacity for conducting and applying science, research and technology for sustainability – everywhere in the world where it is needed; and thirdly, to connect science, policy and decision-making more effectively in pursuit of a faster transition towards real sustainable development. The overall characteristic is, that sustainability initiatives are mainly open-ended networks and dialogues for the better future. A world society that tries to turn towards sustainable development has to work hard to refine their clumsy technologies, in "earthing" their responsibility to all creatures and resources, in establishing democratic systems in peace and by heeding human rights, in building up global solidarity through all mankind and in commit themselves to a better life for the next generations.     

Radioecology, radiobiology, and radiological protection: frameworks and fractures

A framework for the protection of the general public has been in existence for a very long time, although steps have recently been made by the ICRP to ensure that it is more fully comprehensive with regard to all actual and potential exposure situations. Protection of the environment, however, has only recently begun to be addressed in a structured manner, and is still an evolving subject. Nevertheless, it needs to be centred around some form of parallel framework to that which has evolved for the protection of human beings, although clearly on a different scale. It also needs to be embedded within the basic science of radiobiology, and form a central part of radioecology.     

Mapping large areas of radioactively contaminated land with a self adapted, handheld, GPS coupled, scintillation detector

In Belgium, during several decennia, a phosphate plant discharged radium chloride containing waste water into two small rivers. One of those is part of a hydrographically very complex ecosystem with lots of small tributaries and hundreds of hectares of flooding zones. Hence, the river banks and large parts of these flooding zones have become contaminated with radium, heavy metals and chlorides. During a foot campaign, using a home made portable data logging system, consisting of a commercial 2.5 kg NaI detector, a computer mouse sized GPS, and a small pocket PC, the radioactive contamination of about 600 ha of sometimes very rough terrain was measured and mapped. The resulting very detailed radium contamination maps shed a whole new light on the water flow patterns of the ecosystem. The apparatus can also be used for efficiently guiding sampling campaigns for investigating other types of contamination. The ground maps are also compared to existing maps from helicopter measurements, evaluating strengths and weaknesses from both methods.