Chemical composition of <Emphasis Type="Italic">Juniperus sibirica</Emphasis> needles (Cupressaceae) in the forest–tundra ecotone,the Khibiny Mountains

The needles of juniper growing in spruce and birch forests of the Khibiny Mountains have been analyzed to evaluate the pattern of changes in their chemical composition (ADF, lignin, cellulose, lignin/cellulose, lipids, phenolic compounds, proanthocyanidins, flavonoids, N, C, and also Ca, Mg, K, Mn, Zn, P, S, Al, and Fe). It has been shown that the concentrations of lignin, lipids, phenolic compounds, Ca, Al, and Fe in the needles increase with age, while those of flavonoids, soluble and bound proanthocyanidins, N, P, K, Mg, Zn, and Mn decrease. The needles of juniper from spruce and birch forests differ in the contents of nutrient elements, which is explained by differences in the composition of soils. The contents of lignin, cellulose, and lipids in aging needles are lower in birch forests than in spruce forests.     

长江中游城市群城市效率水平测度及空间分异研究

运用超效率DEA模型对2013年长江中游城市群城市效率进行测度评价。结果发现:长沙、天门、常德、黄冈、南昌、景德镇、武汉、娄底、新余、衡阳、仙桃、鄂州、潜江和九江为城市效率相对高水平区;抚州、湘潭、鹰潭、上饶、岳阳、黄石、荆州和株洲为城市效率相对较高水平区;萍乡、宜春、益阳、吉安、咸宁、孝感、襄阳、宜昌和荆门为城市效率相对低水平区。在此基础上,分析长江中游城市群城市效率的空间分异特征,发现长江中游城市群城市效率发展水平相似的地区在空间分布上呈现出一定的异质性特征,但并不显著。     

Pollution profile of damodar river sediment in Raniganj-Durgapur industrial belt,West Bengal,India

This paper reports on the pollution profile of Damodar river sediment as obtained from analysis of the river sediment at suitable selected sites in the Raniganj-Durgapur industrial belt, West Bengal, India. The parameters measured include (a) silica, mixed oxide, calcium, magnesium, total water-soluble exchangeable cation and anion, chemical oxygen demand, and (b) some toxic and other elements, such as sodium, potassium, arsenic, cadmium, chromium, mercury, manganese, lead, zinc, cobalt, copper, iron nickel, phosphorus, sulphur, and vanadium. The parameters listed under (a) led to the characterization of the sediment, and those under (b) gave an index of metal pollution of the sediment. The elements were estimated by inductively coupled plasma emission spectrometry.     

Environmental and dietary exposure of young children to inorganic trace elements

Children are exposed to toxic metals and metalloids via their diet and environment. Our objective was to assess the aggregate chronic exposure of children aged 3–6 years, living in France, to As, Cd, Cr, Cu, Mn, Pb, Sb, Sr, and V present in diet, tap water, air, soil and floor dust in the years 2007–2009. Dietary data came from the French Total Diet Study, while concentrations in residential tap water, soil and indoor floor dust came from the ‘Plomb-Habitat’ nationwide representative survey on children's lead exposure at home. Indoor air concentrations were assumed to be equal to outdoor air concentrations, which were retrieved from regulatory measurements networks. Human exposure factors were retrieved from literature. Data were combined with Monte Carlo simulations. Median exposures were 1.7, 0.3, 10.2, 34.1, 60.3, 0.7, 0.1, 44.3, 1.5 and 95th percentiles were 4.4, 0.5, 15.8, 61.3, 98.3, 2.5, 0.1, 111.1, 2.9 μg/kg bw/d for As, Cd, Cr, Cu, Mn, Pb, Sb, Sr, and V respectively. Dietary exposures dominate aggregate exposures, with the notable exception of Pb - for which soils and indoor floor dust ingestion contribute most at the 95th percentile. The strengths of this study are that it aggregates exposures that are often estimated separately, and uses a large amount of representative data. This assessment is limited to main diet and residential exposure, and does not take into account the relative bioavailability of compounds. These results could be used to help target prevention strategies.     

Trace element and radionuclide mass balances at a coal-fired electric generating station

Coal, bottom ash, and fly ash from Milliken Station, a coal-fired 270 MW power plant, were analyzed for 20 elements (Ag, Al, As, Be, Cd, Co, Cr, Cu, Ga, Hg, Mn, Ni, Pb, Sb, Se, Sn, Te, Tl, V, and Zn) and the major natural radionuclides (²³⁸U series, ²³²Th series, and ⁴⁰K). Mass balance calculations showed that most of the Hg, and some of the Sb and Se, were unaccounted for by ash collection, suggesting their possible discharge into the atmosphere. Silver, As, Hg, Pb, Cd, and Zn were more concentrated in the fly ash than in the bottom ash while all of the other elements were equally distributed, by concentration, between the ash fractions. The radionuclides showed a 46% higher concentration in fly ash than in bottom ash, and ²¹⁰Pb was enriched in the fly ash relative to the other radionuclides by a factor of 2.4. Mass balance calculations indicated a balance within statistical error for the radionuclides, except for ²¹⁰Pb.     

长江三角洲各城市综合实力的主成分分析

运用主成分分析方法,通过建立一套涵盖5个层次16个方面共34个指标的城市指标体系, 对长江三角洲15个城市的综合实力进行计算和比较。运用SPSS10．0统计软件对上述指标进行标准化处理,用方差最大法正交旋转,并通过载荷 系数分析得出六个主成分。将各主成分得分结合主成分权数进行综合计算得出各城市的综合得分,按得分由高到低依次是上海、南京、杭州、苏州、无锡、宁波、镇江、绍兴、常州、南通、扬州、泰州、舟山、嘉兴和湖州。根据各城市的综合得分水平,将长江三角洲的城市分为一个核心三个圈层,并比较分析各个城市的相对优势、薄弱环节及其差异引致因素,对其今后的发展提出若干建议。认为长江三角洲在今后的发展中,应以上海为核心,以南京、杭州、苏州为三个支点,加强区域内的分工与协作,促进区域的共同繁荣。     

多年冻土区工程迹地人工恢复区植物和土壤的矿质元素含量特征

选择青藏高原多年冻土区工程迹地的人工恢复植物和紫花针茅草原的优势植物以及对应的土壤样品进行对照,利用原子吸收法分析了它们的矿质元素含量特征。结果表明：多年冻土区工程迹地人工恢复区植物的元素含量：＞1 000 μg/g的元素有Ca、P和Na,100～1 000 μg/g的元素有Mn、K、Fe、Mg和Al;而对照紫花针茅草原优势植物的元素含量：＞1 000 μg/g的元素有Ca和Na,100～1 000 μg/g的元素有P、Mn、K、Fe、Mg和Al。人工恢复区土壤元素含量：＞1 000 μg/g的元素有Ca、Fe和Mn,100～1000 μg/g的元素有Mg、K、Al、P和Na;对照紫花针茅草原土壤元素含量：＞1 000 μg/g的元素有Ca、Fe,100～1 000 μg/g的元素有Mn、Mg、Al、K、P和Na。该区域植物和土壤元素含量都属于Ca > K 型。人工恢复植物和对照的紫花针茅草原植物对土壤元素的吸收能力具有较高的相似性。K和Al元素的累积与其他元素没有显著的相关关系,其他元素之间为正相关关系,元素之间的吸收累积属于协同作用,无明显的撷抗作用     

Heavy metals in organisms and sediments from Turkish Coast of the Black Sea, 1997-1998

During the period 1997-1998, macroalgae, sea snail, mussel, fish and sediment samples were collected at different stations of the Turkish Black Sea coast in order to establish the concentration of selected heavy metals. Heavy metals analyzed were Cd, Co, Cr, Ni, Zn, Fe, Mn, Pb and Cu. The results showed that the Turkish Black Sea coast is facing heavy metal pollution. The metal concentrations in macroalgae, sea snail, mussel and sediment samples are very high. However, Cd, Pb and Cu concentrations in anchovy fish decreased, while Co, Fe, Zn, Cr, Mn and Ni contents had changed when compared previous data. The metal levels in macroalgae did not follow the same pattern as concentrations in sediments at the same station. On the other hand, concentrations of Cd, Co, Cr, Zn, Fe, Mn and Cu in sea snail, mussel and fish samples were related to sediment data in the examined stations.     

Organochlorine and organophosphorous pesticide residues in the Ouémé River catchment in the Republic of Bénin

The Ouémé River is one of the most important rivers in the Republic of Bénin. It is 510 km long and its catchment drains 75% of the country. In this study, organochlorine and organophosphorous pesticide residues were measured in more than 35 sediment samples collected on nine locations along the Ouémé River from upstream to downstream. Except for one location, Tanéka-Koko, all areas were contaminated by more than 20 pesticides. Organochlorine pesticides identified in sediment samples included pp'-DDE, op'-DDD, pp'-DDD, op'-DDT, pp'-DDT, alpha-endosulfan, beta-endosulfan, endosulfan sulphate, alpha-HCH, beta-HCH, lindane, aldrin, dieldrin, endrin, telodrin, isodrin, cis- and trans-heptachlorepoxide, hexachlorbutadiene, hexachlorobenzene and octachlorostyrene. The organophosphorous pesticide chlorpyrifos, used in a new formulation to protect cotton, was also identified. In some areas, the concentrations of organochlorine pesticides in the sediment of the Ouémé River exceeded environmental quality standards and are reason for concern.     

The relationship of climatic and hydrological parameters to surface water quality in the lower Mekong River

The relationship between climatic, hydrological and water quality parameters of the lower Mekong River flowing through four different countries (Thailand, Cambodia, Lao PDR and Vietnam) was studied. The Mekong River Commission (MRC) secondary data of climatic and hydrological parameters included precipitation, evaporation, average air temperatures, mean water level and discharge flow. Water quality parameters consisted of TSS, NO(3)(-), PO(4)(3-), DO, pH, conductivity, Ca, Mg, Na, K, alkalinity, Cl, SO(4)(2-), Fe, TP, Si and COD. Pearson's correlation was used to determine their relationship. The results reveal that the correlations of climatic, hydrological and water quality parameters in those four countries located along the lower Mekong River had the same trend. Precipitation had fair positive correlations with mean water level (ranging 0.375-0.661), discharge flow (ranging 0.526-0.659) and mean air temperature (ranging 0.515-0.621), however had weak negative correlation with evaporation (ranging 0.169-0.468). Concerning relationship with water quality, the results show that TSS, NO(3)(-), PO(4)(3-), TP and COD had weak to fair positive correlations with precipitation, mean water level, discharge flow. However, DO, pH, conductivity, Ca, Mg, Na, K, alkalinity, Cl, SO(4)(2-) and Si had fair to strong negative correlations with all hydrological parameters. Finally, TSS, alkalinity and conductivity were proposed as sensitive water quality parameters for monitoring impacts of changing climate in the lower Mekong River.     

嘉陵江干流鱼类群落生态结构分析

鱼类群落生态结构是群落生态学研究的一个热点问题。通过野外调查和资料分析发现,嘉陵江干流分布鱼类有156种,隶属于7目18科85属。依据所摄取食物类型的不同,这些鱼类可以划分为浮游动物食性、浮游植物食性、着生藻类食性、水生植物食性、水生昆虫食性、软体动物食性、肉食性和杂食性等8种食性类型。使用相似性指数和相似性分析方法,对嘉陵江上、中和下游的鱼类组成及群落生态结构组成分析发现：（1）从上游到下游,鱼类物种逐渐增加;（2）整个嘉陵江干流中,水生昆虫食性的鱼类占3141%,肉食性占1923%,着生藻类食性占1859%,软体动物食性的占1154%,浮游动物食性占1026%,杂食性占641%,水生植物食性占192%,浮游植物食性占064%;（3）从上游到下游,肉食性鱼类所占比例逐渐增加,以水生昆虫和着生藻类为食的鱼类所占比例则逐渐减少,相似性分析表明,嘉陵江各江段鱼类群落生态结构组成的差异不显著。嘉陵江干流鱼类群落生态结构的组成和变化与水生态系统结构和功能的变化密切相关     

湖北省2008年初低温雨雪冰冻灾害特点及影响分析

008年初,湖北省出现了自1954/1955年冬季以来最严重的低温雨雪冰冻灾害,直接经济损失高达110亿元以上,分析评估此次灾害的基本特点及对各行各业的影响,可为今后抗御类似灾害提供依据。结果表明：①此次灾害影响范围广,受灾人数多,损失重,第三、四场雪使危害迅速加剧,后续效应强、时间长;②影响行业可分为交通、电网及供电系统、通讯、农业、林业、企业和市政设施、居民生活、湖泊结冰等8大类,并可细分为24小类,涉及社会和人们生活的众多方面,足见影响面之广,危害之重;③影响因子以低温、冰冻（道路结冰、电线覆冰）、雪压等为主,另外还有大风、雪雾、湖泊封冻、冰雪融化等;④由于降雪及低温持续时间长、雪量大,对农林业危害严重;由于电力、〖JP2〗通讯、建筑设施以及道路结冰严重,对电网、电力供应、交通安全以及社会公众生产、生活等造成极大的影响。〖     

赤水河赤水市江段鱼类资源现状

根据2011～2013年赤水河赤水市江段的渔获物调查数据,对该江段的鱼类资源现状进行了研究。调查期间共采集到鱼类58种,隶属于3目10科47属。唇(Hemibarbus labeo)、中华倒刺鲃(Spinibarbus sinensis)、蛇鮈(Saurogobio dabryi)、瓦氏黄颡鱼(Pelteobagrus vachelli)、大鳍鳠(Mystus macropterus)、吻鮈(Rhinogobio typus)、粗唇鮠(Leiocassis crassilabris)、银鮈(Squalidus argentatus)、鲤(Cyprinus carpio)、鳜(Siniperca chuatsi)、切尾拟鲿(Pseudobagrus truncates)、鲫(Carassius auratus)和鲇(Silurus asotus)等13种为调查江段的主要优势种类,它们在渔获物中的总数量百分比和总重量百分比分别为92.61%和93.82%。从捕捞规格来看,目前赤水市江段主要经济鱼类均以小型个体为主,平均体长多在200 mm以下,平均体重多在100 g以下,与历史调查数据相比,捕捞规格小型化趋势较为明显。建议相关部门加快渔民转产安置工作,争取早日实现赤水河流域全面禁渔,并建立流域统一协调管理机制,切实保护好赤水河这一长江上游珍稀特有鱼类的最后庇护所。     

经济发达县域耕地土壤重金属污染评价及其影响因素分析——以江苏省昆山市为例

通过对昆山市14个区镇91个土壤样品中As、Cd、Cr、Cu、Pb、Ni、Hg、Zn 8种重金属测定分析,对该市耕地土壤重金属污染进行评价并进行重金属污染的影响因素分析.结果表明,昆山市耕地土壤存在不同程度的轻微污染,重金属Cd、Cr、Cu、Pb、Hg、Zn均超过国家土壤背景值,旱地、水田中均以Hg污染范围较广、变异系数较大.综合污染指数表现为水田(1.15)＞旱地(1.00).区镇耕地重金属污染评价表明千灯、陆扬、石浦、锦溪、石牌处于警戒值之内,蓬朗、周庄、张浦、正仪、周市、巴城、淀山湖、花桥、陆家轻度污染;昆山市耕地土壤中重金属元素均未超过土壤环境基本容量,能够保证作物品质和农业持续发展.同时,研究表明区域重金属轻微污染具有复合污染的特性,Cd、Pb相关性最高(P=0.621 0), Pb与Hg、Cu、Zn、Cu与Cr也有相关性(0.438 7、0.426 0、0.350 9、0.394 0),区域重金属的轻微污染受人为因素影响显著,研究指出应加强对区域优先控制污染物Hg、次优先控制污染物Pb、Cd、Zn、Cu、Cr的控制与治理.     

Creating an academic landscape of sustainability science: an analysis of the citation network

Sustainability is an important concept for society, economics, and the environment, with thousands of research papers published on the subject annually. As sustainability science becomes a distinctive research field, it is important to define sustainability clearly and grasp the entire structure, current status, and future directions of sustainability science. This paper provides an academic landscape of sustainability science by analyzing the citation network of papers published in academic journals. A topological clustering method is used to detect the sub-domains of sustainability science. Results show the existence of 15 main research clusters: Agriculture, Fisheries, Ecological Economics, Forestry (agroforestry), Forestry (tropical rain forest), Business, Tourism, Water, Forestry (biodiversity), Urban Planning, Rural Sociology, Energy, Health, Soil, and Wildlife. Agriculture, Fisheries, Ecological Economics, and Forestry (agroforestry) clusters are predominant among these. The Energy cluster is currently developing, as indicated by the age of papers in the cluster, although it has a relatively small number of papers. These results are compared with those obtained by natural language processing. Education, Biotechnology, Medical, Livestock, Climate Change, Welfare, and Livelihood clusters are uniquely extracted by natural language processing, because they are common topics across clusters in the citation network.     

江苏省农业比较优势格局及与周边省市比较分析

:将江苏省置于长江中下游种植区内 ,运用国内资源成本系数DRCC(DomesticResourcesCostCoefficient)和RDRCC(RatioDomesticResourcescostCoefficients)指标考察了江苏省与周边省市 (包括上海、安徽、浙江、江西、湖北和湖南 )农业生产比较优势的差异 ,从而全面地认识了相对于长江中下游种植区六省市江苏省农业生产的比较优势格局。根据分析 ,与周边地区相比 ,江苏省秋收作物粳稻、大豆 ,夏收作物油菜籽、棉花和早籼稻 ,常年生作物茶叶生产都具有不同程度的相对比较优势 ,可考虑通过适当的政策将资源导向这些产品的生产上 ;同时重点压缩小麦、中籼稻、玉米、花生、烤烟等不具相对比较优势产品的生产。此外 ,江苏桑蚕茧可考虑稳定现有的生产 ,而苹果生产可适当调减。主要饲养业产品中 ,蛋鸡、肉鸡和淡水鱼具有相对比较优势 ,其饲养总量可以考虑进一步扩大 ,相反 ,生猪和菜羊不具相对比较优势 ,饲养规模应适当压缩。而江苏奶牛饲养总规模可考虑稳定 ,并适当扩大国营集体饲养的规模     

Study on the contamination of heavy metals and their correlations in mollusks collected from coastal sites along the Chinese Bohai Sea

Mollusks living in seas can accumulate heavy metals, and may serve as excellent passive biomonitors. During a period of 1 year, bioaccumulation of As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Se, and Zn was examined in nine kinds of mollusks (Rapana venosa, Neverita didyma, Scapharca subcrenata, Mytilus edulis, Amusium, Crassostrea talienwhanensis, Meretix meretrix, Ruditapes philippinarum, and Mactra veneriformis), which were collected at eight coastal sites along the Chinese Bohai Sea. Metal concentrations were directly determined by inductively coupled plasma mass spectrometer (ICP-MS). Two certified reference materials, dogfish muscle (DORM-2) and mussel (GBW 08571), were used to validate the methods, and the recoveries were within 83.72-112.30% of the certified values. Bioaccumulation of metals varied strongly among sampling sites and species. Statistical analysis (one-way ANOVA) indicated that different species examined showed different bioaccumulation of metals, and perhaps they could be used as potential biomonitors to investigate the contamination levels of heavy metals. Principal component analysis (PCA) and correlation analysis were used to study the relationships between these heavy metals. The results showed that, in nine mollusks' tissues, there are significant correlations between these elements in adjacent main group or subgroup in periodic table of elements.     

Selenium and 17 other largely essential and toxic metals in muscle and organ meats of Red Deer (Cervus elaphus)--consequences to human health

Concentrations, composition and interrelationships of selenium and metallic elements (Ag, Ba, Cd, Co, Cr, Cs, Cu, Ga, Mn, Mo, Pb, Rb, Sb, Sr, Tl, V and Zn) have been examined in muscle and organ meats of Red Deer hunted in Poland. The analytical data obtained were also discussed in terms of Se supplementation and deficit to Deer as well as the benefits and risk to humans associated with the essential and toxic metals intake resulting from consumption of Deer meat and products. These elements were determined in 20 adult animals of both sexes that were obtained in the 2000/2001 hunting season from Warmia and Mazury in the north-eastern part of Poland. The whole kidneys contained Ba, Cd, Cr, Ga, Pb, Se, Sr and Tl at statistically greater concentrations than liver or muscle tissue from the same animal. Liver showed statistically greater concentrations of Ag, Co, Cu, Mn and Mo than kidneys or muscle tissue, and muscle tissue was richer in Zn, when compared to the kidneys or liver. Cs and Rb were similarly distributed between all three tissue types, while V was less abundant in liver than kidneys or muscle tissue. There were significant associations between some metallic elements retained in Red Deer demonstrated by Principal Component Analysis (PCA) of the data set. In organ and muscle meats (kidneys, liver and muscle tissue considered together) the first principal component (PC1) was strongly influenced by positively correlated variables describing Se, Ba and Cd and negatively correlated variables describing Ag, Co, Cs, Mn, Pb, Tl and V; PC2, respectively, by Cu, Mn and Mo (+) and Zn (-); PC3 by Ga (+) and PC4 by Sb (+). Selenium occurred in muscle tissue, liver and kidneys at median concentrations of 0.13, 0.19 and 4.0mg/g dry weight, respectively. These values can be defined as marginally deficient (< 0.6mg Se/kg liver dw) or satisfactory (≤ 3.0mg Se/kg kidneys dw) for the amount required to maintain the Deer's body condition and health, depending on the criterion for supplementation used. In terms of human nutritional needs, a relatively high selenium content of kidneys can be beneficial. The muscle meat, liver and kidneys of Red Deer can be considered as a very good source of essential Co, Cr, Cu, Mo, Mn, Se and Zn in the human diet. Lead is generally considered as toxic, and the concentrations found in Red Deer (via the food chain intake) were well below the European Union tolerance limit. Pb from the lead bullets can always create food hygienic problem, if not well recognized during sanitary inspection, and this was noted for one muscle meat sample in this study (5% surveyed). There is no tolerance limit of Cd in game animal meats. The median values of Cd noted in fresh muscle tissue, liver and whole kidneys were 0.07, 0.18, and 3.3mg/kg wet weight, respectively. Cd exists as a chemical element present at trace levels in plants and mushrooms in Deer's food chain in background (uncontaminated) areas. When these are consumed by the Deer, the amount of Cd sequestered with metallothioneins and retained in the organ and muscle meat in this study is low enough to be considered safe for human consumption.     

长三角地区一体化背景下的人口优化布局研究

人口问题是制约区域全面协调可持续发展的重大问题,是影响区域经济社会发展的关键因素。作为我国重要的经济核心区,长三角地区经济和人口快速集聚,近年来出现了中心城市人口过度膨胀、生态环境敏感区受到挤占、后发地区人口集聚动力不足等问题。从长三角地区一体化发展要求出发,合理布局该区域的人口,已经成为该地区迫切需要解决的问题之一。利用统计数据和GIS空间分析方法,采用多种模型对本区人口规模与增长、人口空间分布特征进行分析,在人口预测与适宜性评价的基础上优化和调控长三角地区的人口布局,将研究区域划分为优化增长区、快速增长区、较快增长区、限制增长区等人口增长类型区     

蓝藻水华的成因及其生态控制进展

从水体生态系统的平衡、供水水质、人类及其它动物的健康风险、水域生态景观等方面分析了蓝藻水华的危害。对蓝藻水华形成的内在因素（高温适应的一系列特殊的生化调控机制或特性、三套色素系统——低光补偿机制、奢侈消费机制、固氮——营养补偿机制、休眠——回避不良条件机制、产生天然毒素来抑制竞争者和捕食者的机制）和环境因素（物理,如温度、光照、扰动及混合和水的滞留时间等;化学,如主要营养盐、微量营养元素、溶解无机碳、溶解有机碳和盐度等;生物因子,如牧食、微生物作用和与较高等动植物的共生等）进行了分析。并对蓝藻水华的生态控制（微生物控藻、大型水生植物抑藻、水生动物控藻如经典生物操纵、非经典生物操纵和罗非鱼控藻）的研究进展进行了综述。〖