Thermodynamic analysis on post-combustion CO2 capture of natural-gas-fired power plant

A chemical absorption, post-combustion CO₂ capture unit is simulated and an exergy analysis has been conducted, including irreversibility calculations for all process units. By pinpointing major irreversibilities, new proposals for efficient energy integrated chemical absorption process are suggested. Further, a natural-gas combined-cycle power plant with a CO₂ capture unit has been analyzed on an exergetic basis. By defining exergy balances and black-box models for plant units, investigation has been made to determine effect of each unit on the overall exergy efficiency. Simulation of the chemical absorption plant was done using UniSim Design software with Amines Property Package. For natural-gas combined-cycle design, GT PRO software (Thermoflow, Inc.) has been used. For exergy calculations, spreadsheets are created with Microsoft Excel by importing data from UniSim and GT PRO. Results show the exergy efficiency of 21.2% for the chemical absorption CO₂ capture unit and 67% for the CO₂ compression unit. The total exergy efficiency of CO₂ capture and compression unit is 31.6%.     

A Thermodynamic View of Partial Oxidation,Steam Reforming,and Autothermal Reforming on Methane

Abstract

Thermodynamic analysis on three thermo-chemical reforming processes, i.e., partial oxidation (POX), steam reforming (STR), and autothermal reforming (ATR) with methane as the feedstock fuel are conducted in this study. The focus of this article is to show the effect of air-fuel (AF) ratio, water-fuel (WF) ratio, temperature and pressure on hydrogen (H₂) yield, hydrogen/carbon monoxide (H₂/CO) ratio, carbon (C), and carbon monoxide (CO) formation. Optimal operating conditions under no solid carbon formation in the reaction are recommended for each thermochemical reforming technique.     

Exergy analysis as a tool for the integration of very complex energy systems: The case of carbonation/calcination CO2 systems in existing coal power plants

A common characteristic of carbon capture and storage systems is the important energy consumption associated with the CO₂ capture process. This important drawback can be solved with the analysis, synthesis and optimization of this type of energy systems. The second law of thermodynamics has proved to be an essential tool in power and chemical plant optimization. The exergy analysis method has demonstrated good results in the synthesis of complex systems and efficiency improvements in energy applications.In this paper, a synthesis of pinch analysis and second law analysis is used to show the optimum window design of the integration of a calcium looping cycle into an existing coal power plant for CO₂ capture. Results demonstrate that exergy analysis is an essential aid to reduce energy penalties in CO₂ capture energy systems. In particular, for the case of carbonation/calcination CO₂ systems integrated in existing coal power plants, almost 40% of the additional exergy consumption is available in the form of heat. Accordingly, the efficiency of the capture cycle depends strongly on the possibility of using this heat to produce extra steam (live, reheat and medium pressure) to generate extra power at steam turbine. The synthesis of pinch and second law analysis could reduce the additional coal consumption due to CO₂ capture 2.5 times, from 217 to 85 MW.     

Evaluation of different CHP options for refinery integration in the context of a low carbon future

This study presents a comparison of different concepts for delivering combined heat and power (CHP) to a refinery in Norway. A reference case of producing high pressure steam from natural gas in boilers and electricity in a combined cycle power plant, is compared to a: (1) natural gas fueled CHP without any CO₂ capture; (2) hydrogen fueled CHP with hydrogen produced from steam methane reforming (SMR); (3) hydrogen fueled CHP with hydrogen produced from autothermal reforming (ATR); and finally (4) natural gas fueled CHP with postcombustion CO₂ removal. The options are compared on the basis of first law efficiency, emissions of CO₂ and a simplified cash flow evaluation. Results show that in terms of efficiency the standard natural gas fueled CHP performs better than the reference case as well as the options with carbon capture. The low carbon options in turn offer lower emissions of greenhouse gases while maintaining the same efficiency as the reference case. The cash flow analysis shows that for any option, a certain mix of prices is required to produce a positive cash flow. As expected, the relationship between natural gas price and electricity price affects all options. Also the value of heat and CO₂ emissions plays an important role.     

Performance of a large-scale greenhouse solar dryer integrated with phase change material thermal storage system for drying of chili

ABSTRACT

Large-scale greenhouse solar dryers have been used for drying various products and this type of dryer is usually equipped with LPG burner as auxiliary heater, which creates more operating cost. To overcome this problem, phase change material (PCM) thermal storage was proposed to substitute for the LPG burner. In this work, the performance of a large-scale greenhouse solar dryer integrated with a PCM as a latent heat storage for drying of chili was investigated. Experimental studies were conducted to compare the performance of this dryer with that of another large-scale greenhouse solar dryer without the PCM thermal storage and open sun drying. Chili with an initial moisture content of 74.7% (w.b.) was dried to a final moisture content of 10.0% (w.b.) in 2.5 days, 3.5 days, and 11 days using the solar dryer integrated with the PCM thermal storage, the solar dryer without the PCM thermal storage and the open sun drying, respectively. The performance of the solar dryer integrated with the PCM thermal storage was also evaluated using exergy analysis. The exergy efficiency of the drying room of the solar dryer integrated with the PCM thermal storage and the solar dryer without the PCM thermal storage for drying of chili was found to be 13.1% and 11.4%, respectively and the thermal storage helps to dry chili during adverse weather conditions. The results of exergy analysis implied that the exergy losses from the dryer with the PCM should be reduced.     

Second Law Analysis for Solar Cookers

Abstract

This article presents the importance and usefulness of Second Law (exergy) analysis for evaluating and comparing solar cookers in meaningful ways. The thermodynamic considerations required for the development of rational and meaningful methodologies for the evaluation and comparison of the efficiency of the solar cookers were defined. Energy and exergy equations were also developed to obtain energy and exergy efficiencies of the solar cookers. The evaluation of the solar cookers requires a measure of efficiency, which is rational, meaningful, and practical. Exergy analysis provides an alternative means of evaluating and comparing the solar cookers. Since exergy is a measure of the quality or usefulness of energy, exergy efficiency measures are more significant than energy efficiency measures, exergy analysis should be considered in the evaluation of the solar cookers.     

A stochastic approach for the operation of a wind and pumped storage plant under a deregulated environment

To improve the competiveness in the energy market, it is necessary that the wind power plants provide guaranteed power generation, although, it is not possible to forecast power availability from wind power plant accurately. This paper presents a stochastic model and solution technique for the combined operation of wind and pumped storage power plants to improve the power availability and increasing the profit considering uncertainties of wind power generation. In this model, uncertainties in wind data have been forecasted for grid connected day-ahead market using Weibull distribution model. The imbalances in the forecasted wind data and the market demand have been reduced by operating the pumped storage power plant. In this stochastic mixed integer problem, pumped storage plant can take the supply either from the grid or from the wind power plant for the pumping operation to store the energy in order to utilize this energy during peak hours for increasing the overall revenue. The reliability of the pumped storage is improved by replacing the conventional unit with the adjustable speed type pumped storage unit. In order to prove the optimality of the solution, two case studies were considered. In case study–I, scheduling is provided by operating the conventional pumped storage unit, whereas in case study–II, adjustable speed pumped storage unit has been used. It has been found that the adjustable speed pumped storage unit has further reduced the imbalance between generated power and demand. The complete approach has been formulated and implemented using AMPL software.     

Design and off-design analyses of a pre-combustion CO2 capture process in a natural gas combined cycle power plant

In this study, a cycle designed for capturing the greenhouse gas CO₂ in a natural gas combined cycle power plant has been analyzed. The process is a pre-combustion CO₂ capture cycle utilizing reforming of natural gas and removal of the carbon in the fuel prior to combustion in the gas turbine. The power cycle consists of a H₂-fired gas turbine and a triple pressure steam cycle. Nitrogen is used as fuel diluent and steam is injected into the flame for additional NO_x control. The heat recovery steam generator includes pre-heating for the various process streams. The pre-combustion cycle consists of an air-blown auto-thermal reformer, water–gas shift reactors, an amine absorption system to separate out the CO₂, as well as a CO₂ compression block. Included in the thermodynamic analysis are design calculations, as well as steady-state off-design calculations. Even though the aim is to operate a plant, as the one in this study, at full load there is also a need to be able to operate at part load, meaning off-design analysis is important. A reference case which excludes the pre-combustion cycle and only consists of the power cycle without CO₂ capture was analyzed at both design and off-design conditions for comparison. A high degree of process integration is present in the cycle studied. This can be advantageous from an efficiency stand-point but the complexity of the plant increases. The part load calculations is one way of investigating how flexible the plant is to off-design conditions. In the analysis performed, part load behavior is rather good with efficiency reductions from base load operation comparable to the reference combined cycle plant.     

A qualitative reliability and operability analysis of an integrated reforming combined cycle plant with CO2 capture

Most of the current CO₂ capture technologies are associated with large energy penalties that reduce their economic viability. Efficiency has therefore become the most important issue when designing and selecting power plants with CO₂ capture. Other aspects, like reliability and operability, have been given less importance, if any at all, in the literature.This article deals with qualitative reliability and operability analyses of an integrated reforming combined cycle concept. The plant reforms natural gas into a syngas, the carbon is separated out as CO₂ after a water-gas shift section, and the hydrogen-rich fuel is used for a gas turbine. The qualitative reliability analysis in the article consists of a functional analysis followed by a failure mode, effects, and criticality analysis (FMECA). The operability analysis introduces the comparative complexity indicator (CCI) concept.Functional analysis and FMECA are important steps in a system reliability analysis, as they can serve as a platform and basis for further analysis. Also, the results from the FMECA can be interesting for determining how the failures propagate through the system and their effects on the operation of the process. The CCI is a helpful tool in choosing the level of integration and to investigate whether or not to include a certain process feature. Incorporating the analytical approach presented in the article during the design stage of a plant can be advantageous for the overall plant performance.     

Exergy analysis of the transcritical N2O refrigeration cycle with a vortex tube

In this article, a comparative study is presented for the transcritical cycle with expansion valve (TCEV) and transcritical cycle with vortex tube (TCVT) mainly based on the second law of thermodynamics. Natural refrigerant nitrous oxide (N₂O) is used in both the cycles for analysis. The evaporator and gas cooler temperatures are varied from ?55°C to 5°C and 35°C to 60°C, respectively. The effects of various operating and design parameters on the optimum heat rejection pressure, coefficient of performance (COP), exergy loss (irreversibility), and the exergetic efficiency are studied. Exergy analysis of each component in TCEV and TCVT is performed to identify the amount and locations of irreversibility. It is observed that the use of the vortex tube in place of the expansion valve reduces the total exergy losses and increases the exergetic efficiency as well as COP. The exergetic efficiency and COP of the TCVT are on average 10–12% higher compared to TCEV for the considered operating conditions. The computed values of the exergetic efficiency for TCVT using refrigerant N₂O are the highest at an evaporator temperature of ?55°C, and the corresponding values of exergetic efficiency and exergy losses varies between 25.35% and 15.67% and between 74.65% and 84.33%, respectively. However, COP at the same evaporator temperature of ?55°C varies between 0.83 and 0.51. Furthermore, the optimum heat rejection pressure in TCVT is lower compared to that in TCEV. The results offer significant help for the optimum design and operating conditions of TCVT with refrigerant N₂O.     

Energy-Related Education and Awareness: The Role and Place for Exergy in Policy Development

Abstract

Exergy can play a key role in developing appropriate and beneficial energy-related policies relating to education and awareness. Two main areas where exergy can have an impact on policies are discussed in this article: public education and awareness and student education. The former is more general, but is supported by the latter. Regarding public education and awareness about exergy, it appears that the public is often confused when it discusses energy, and needs to be better educated about exergy if energy issues and problems are to be addressed appropriately. Regarding the education of students about exergy, it appears that the coverage of exergy in thermodynamics education is often insufficient and inappropriate. Better coverage of exergy is needed to improve thermodynamics education and to make it more interesting to students, and a basic level of “exergy literacy” is needed among engineers and scientists—particularly those involved in decision making.     

Solar Assisted Small-Scale Biomass District Heating System in the Northern Part of Sweden

Abstract

This article presents a case study of a projected solar assisted biomass district heating system in the north of Sweden. It is generally known that a biomass district heating system combined with solar heat brings many important benefits. The most common system solution is to install a heat store and a large solar collector field near the heating central. No plant of this type is however in operation in the northern part of Sweden. The main reason for this is that the solar irradiation at these latitudes is very low when the demand for heat is high. Solar heat could however be useful during summer in order to generate hot tap water. One problem is that the heat losses, calculated as percentage of the delivered heat, become very large during these months. This article presents the idea of allowing the connected households to generate their own hot tap water using solar collectors and heat stores installed in each house. The district heating network can therefore be closed in summer, which eliminates the heat losses outside the heating period. A case study of a projected plant has been carried out and it is shown that it is possible to reduce the heat losses by 20% compared to a conventional system. This idea also provides many other important technical and economic benefits.     

Energy,exergy analysis,and sustainability assessment of different engine powers for helicopter engines

The rapid decrease of energy resources has accelerated studies on energy efficiency. Energy efficiency refers to the effective use of energy, in other words, completing a specific task to the required standard by using less energy. Exergy is an effective instrument to indicate the effective and sustainable use of energy in systems and processes. Transportation is an important part of human life. The studies on energy saving and the effective use of energy in different areas around the world have also increased for transportation systems and vehicles. With the more effective use of fuel, there will be potential benefits for the environment as well as a reduction in operating costs. This study includes energy and exergy analyses as well as a sustainability assessment by using C₈H₁₆ as a fuel at different engine powers (150–600 SHP (shaft horse power)), for the piston-prop helicopter engine. The maximum exergetic sustainability index was found at the power that provided the maximum energy and exergy efficiency. As a result of this index, the lowest waste exergy ratio, the lowest exergy destruction factor, and the lowest environmental impact factor were obtained. The highest exergy destruction and the highest exergy loss value were obtained at maximum power (600 SHP).     

Grey relational analysis of an integrated cascade utilization system of geothermal water

With the drastic decrease in fossil resources and rapid deterioration of the global environment, the utilization of geothermal resources has been strongly advocated. The combination of heat, power, and cold utility generation is commonly used to increase the utilization efficiency of geothermal resources. In this study, an integrated cascade utilization system of waste geothermal water (ICUWGW) from a flash geothermal power plant in China is established to increase the utilization efficiency of geothermal water. The waste geothermal water leaving the power plant is proposed for further use in cascade for two-stage LiBr/H₂O absorption cooling, agricultural product drying, and residential bathing. Twelve candidate temperature schemes showing different inlet and outlet temperatures of every subsystem are proposed for the ICUWGW. Several criteria are selected for the evaluation and screening of the candidate schemes. Grey relational analysis incorporating analytic hierarchy process is conducted to screen the optimal temperature scheme for the ICUWGW to meet the comprehensive criteria of thermodynamics and economics. Results show that the optimal scheme features significant improvement in energy efficiency, exergy efficiency, and equivalent electricity generation efficiency compared with those of the current geothermal power plant. The investment payback time of the additional subsystems for cooling, drying, and bathing is 1.85 years. Exergy analysis is also conducted to determine the further optimization potential of the optimal ICUWGW. Sensitivity analysis of electricity price on the performance of the optimal ICUWGW is also performed.     

Hybrid input-output analysis to evaluate economic impacts of biomass energy

ABSTRACT

The introduction of the new biomass industry exerts influences that change the interactions among economic sectors by drawing the resources for generating electricity, pricing alterations from the existing market and competitively selling electricity to the power grid. These influences should be described and identified to ensure the benefits to the local economy. In this article, we deem to test the potential of hybrid I-O analysis to analyze the economic impacts and address the change in characteristics of the economic impacts of the biomass power plant. The resource utilization data from the existing biomass power plant located in Kochi Prefecture (Japan) is collected and then analyzed by a hybrid input-output (I-O) analysis. We found that (1) the use of cutoff function could determine the new economy’s structure included the biomass power plant where the allocation of resource in the economy is changed according to the consumption and production of the biomass power plant, (2) The power plant increases the total production of Kochi prefecture’s economy, and this benefit overthrows the negative effect of the loss of resource demand of the existing economic sectors. The use of the hybrid I-O to forecast the economic impacts on the local economy could enhance the decision made by the policymaker.     

Energy and exergy analysis of a combined Brayton/Brayton power cycle with humidification

ABSTRACT

First and second law approaches have been used to analyze the performance of a humidified Brayton/Brayton power cycle. The energy efficiency and exergy destruction rates consistently improved when the combustion temperature was increased. Both performance indicators improved, reached an optimum, and then deteriorated when the topping cycle pressure ratio increased, while their sensitivity to the bottoming cycle pressure ratio depended on the humidification rate used at the bottoming cycle. Upon increasing the mass flowrate of air through the bottoming cycle, the energy efficiency of the power cycle increased linearly, while the irreversibility generation had a non-monotonic variation. In all cases, a higher degree of humidification always resulted in greater first and second law performances.     

Off-design performance analysis of a transcritical CO2 Rankine cycle with LNG as cold source

The transcritical CO₂ Rankine cycle with liquefied natural gas (LNG) as cold source is a promising power system to utilize mid- and low-temperature heat source. Most previous works focused on thermodynamic and thermoeconomic analysis or optimization for the system. In this article, an off-design performance analysis for the system is conducted. An off-design mathematical model for the system is established to examine the variation of system performance with the variations of heat source mass flow rate and temperature. A modified sliding pressure regulation control strategy, which regulates turbine inlet pressure to keep the temperature difference between heat source temperature and turbine inlet temperature constant, is applied to control the system when off-design conditions happen. The results show that when the mass flow rate or the temperature of heat source is less or lower than that of design condition, both the net power output of system and the system exergy efficiency decrease, whereas when they are more or higher than the values of design condition, the net power output of system increases but the system exergy efficiency still decreases. In addition, both CO₂ turbine and NG turbine could almost keep the designed efficiency values under the applied control strategy.     

Investigation of sustainable energy alternatives for powering remote communities in northern Ontario

ABSTRACT

Remote communities in the North of Ontario survive in isolation as their proximity to the southern industrial sector of the province limits their accessibility to the major grid. The lack of grid connection has led to antiquated methods of power generation which pollute the environment and deplete the planet of its natural resources. Aside from the primary means of electricity generation being by diesel generators, generation infrastructure is deteriorating due to age and the stagnation of the power supply has led to communities facing load restrictions. These challenges may be resolved by introducing clean energy alternatives and providing a fuel blend option. The primary energy sources investigated in this research are solar, wind, and hydrogen. To assess the viability of these energy production methods in Northern communities, an exergy analysis is employed as it utilizes both the first and second law of thermodynamics to determine systems’ efficiency and performance in the surroundings. Local weather patterns were used to determine the viability of using wind turbines, solar panels and/or hydrogen fuel cells in a remote community. Through analysis of the resources available at the community, it was determined that the hydrogen fuel cell was best suited to provide clean energy to the community. Wind resulted in low efficiency in the range of 2–3% while solar efficiencies resulted in ranges of 18 – 19%, as the seasonal variations between the three years is not very great. Due to the higher operating efficiencies observed of the PV panels it would also be an attractive alternative to diesel generators however, the lack of consistent operation above 30% efficiency throughout the year, resulted in hydrogen fuel cells being a better alternative.     

Pre-combustion CO2 capture from natural gas power plants,with ATR and MDEA processes

Among the various configurations of fossil fuel power plants with carbon capture, this paper focuses on pre-combustion techniques applied to natural gas combined cycles. With more detail, the plant configuration here addressed includes: (i) the steam reforming of natural gas, based on an air-blown autothermal process, following a recuperative pre-reforming treatment, (ii) the water gas shift producing CO₂ and H₂, (iii) the separation of CO₂ by means of a mixed physical–chemical absorption system using a MDEA solution, and (iv) a hydrogen fuelled combined cycle.Similar configurations have been studied quite extensively, being among the most attractive for full-scale realizations in a near-mid term future. This paper proposes a detailed thermodynamic study and optimization of the plant configuration, bringing to a reliable performance estimation based on today's best available technology as far as the various plant sections are concerned (gas and steam turbine, natural gas reforming process, CO₂ separation). The predicted LHV efficiency for the base configuration is about 50%. Being this value at the top of the range quoted in the open literature studies (35–50%), the paper includes a quite extensive sensitivity analysis, showing that more conservative assumptions may bring to significantly poorer performance, especially considering the pretty large number of operating parameters involved in the process.     

An Exergy Aware Optimization and Control Algorithm for Sustainable Buildings

Abstract

Heating and air-conditioning systems have very low exergetic efficiency as they dissipate primary energy resources at low temperatures usually between 90 and 60°C. This compounds the problem that buildings spend approximately 30% of all the energy consumed in the U.S. for heating and air-conditioning. The overall result is a large entropy production and long-term environmental degradation that can be resolved only by substituting primary energy resources by low-temperature, waste, or alternative energy resources, usually available below 50°C. For such a replacement to be feasible the environmental cost of exergy production must be factored into calculations and compatible HVAC systems must be developed without any need for temperature peaking or equipment oversizing. This article addresses environmental and often-conflicting problems associated with exergy production by HVAC systems and presents an analytical optimization and control algorithm. Results indicate that when a careful design optimization is accompanied by a dynamic control of the split between radiant and convective means of satisfying thermal HVAC loads, exergy efficient sustainable buildings may be cost effective and environmentally benign.