Speciation of heavy metals in marine sediments from the East China Sea by ICP-MS with sequential extraction

Twelve elements (V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Mo, Sn, Cd and Pb) in 24 sediment samples at eight sites (S1-S8) from the East China Sea were analyzed with the BCR sequential extraction (SE) protocol to obtain the metal distribution patterns in this region. The results showed that the heavy metal pollutions in S4 and S8 were more severe than in other sampling sites, especially Cd and Pb pollution. In the top sediments at S4 and S8, both the total contents and the most dangerous non-residual fractions of Cd and Pb were extremely high. More than 90% of the total concentrations of V, Cr, Mo and Sn existed in the residual fraction. Fe, Co, Ni, Cu and Zn mainly (more than 60%) occurred in the residual fraction. While Mn, Pb and Cd dominantly presented in the non-residual fractions in the top sediments. The metal distribution patterns with depth and the correlations between total organic carbon (TOC) and the total Fe-Mn content were also investigated. The results showed that, for most of the elements except Fe, the concentration of elements in fraction A in the top sediments was higher than that in other depth. The similar rule was also found in fraction B but not in fraction C. Besides, the distributions of V, Cd in fraction B and Pb, Cd, Cu in fraction C might be affected by TOC.     

Occurrence and distribution of organochlorine pesticides (HCH and DDT) in sediments collected from East China Sea

Sediments used in this study were collected from different depths of eight sites in East China Sea in November 2002. The levels and distribution patterns of the selected organochlorine pesticides (OCPs=p,p'-DDT, o,p'-DDT, p,p'-DDE, p,p'-DDD, alpha-, beta-, gamma- and delta-HCH) in samples were investigated by the technique of sonication extraction followed by the analysis of gas chromatography (GC) coupled with a micro-electron capture detector (muECD). The concentrations of SigmaHCH and SigmaDDT in the surface sediments were in the range of <0.05-1.45 ng/g (mean 0.76 ng/g), <0.06-6.04 ng/g (mean 3.05 ng/g) based on dry weight (dw), respectively. In the vertical distributions, the SigmaHCH and SigmaDDT were in the range of <0.05-2.52 ng/g, <0.06-10.94 ng/g dw, respectively. Residues of OCPs varied significantly with different sampling sites. SigmaDDT in the surface sediments was correlated well with total organic carbon (TOC) content (r2=0.71), while SigmaHCH showed no obvious correlation. The distribution showed that the sediments from the vicinity estuary or near shore had higher TOC contents, and higher OCPs concentrations. The contamination record indicated an extensive use of OCPs in the catchments from Yangtze River in the past might greatly affect the OCP residues.     

Projecting ozone-related mortality in East China

BackgroundThe concentrations of ozone (O₃) in China are increasing, especially in East China, but its future trends and potential health impacts remain to be explored.ObjectivesThe objective was to assess future trends in O₃ concentrations and related premature death in East China between 2005 and 2030.MethodsFirst, a global chemical transport model (MIROC-ESM-CHEM) and regional chemical transport modelling system (including the Weather Research and Forecasting model and the Community Multiscale Air Quality model) were combined to estimate daily O₃ concentrations in 2005 and 2030 in East China under the “current legislation” (CLE) and “maximum technically feasible reduction” (MFR) scenarios which were applied globally. O₃ concentrations were then linked with population projections, mortality projections, and O₃-mortality associations to estimate changes in O₃-related mortality in East China.ResultsThe annual mean O₃ concentration was projected to increase in East China between 2005 and 2030 under the CLE scenario, while decrease under the MFR scenario. Under the CLE scenario, O₃-attributable health burden could increase by at least 40,000 premature deaths in East China, without considering the population growth. Under the MFR scenario, the health burden could decrease by up to 260,000 premature deaths as a result of the reduction in O₃ concentration with a static population. However, when the population growth was considered, O₃-attributable health burden could increase by up to 46,000 premature deaths in East China under the MFR scenario.ConclusionsThe results suggest that the health burden attributable to O₃ may increase in East China in 2030.     

Time trends of polybrominated diphenyl ethers in East China Seas: Response to the booming of PBDE pollution industry in China

The East China Seas (ECSs) are the receptors of the land-based persistent organic pollutants (POPs), such as polybrominated diphenyl ethers (PBDEs) mainly from China through atmospheric deposition driven by the East Asian winter monsoon and fluvial discharge (e.g., Yangtze River and Yellow River), making the offshore sediments to be a good proxy to reconstruct history of those pollutants in China. In this work, four well-placed sediment cores were extracted from the mud areas in the ECSs, and the ²¹⁰Pb-dated cores were analyzed to yield historical concentration profiles of PBDEs in the area. The results showed that there was a persistent increase from 1970s and almost no clear sign in the decline of PBDEs until recently in China. More importantly, there was a faster increase of PBDEs from 1990s in China; while this period was just shown as gradually leveling off or even declining trends in developed countries. The persistently increasing trend of PBDEs in China since 1990s could be largely due to the booming of the manufacturing industry and unexpectedly transfer of PBDE pollution from developed countries to China. Besides, the relative high concentrations and fluxes of PBDEs in the core from coastal ECS located near a well-known electrical/electronic waste (e-waste) recycling area suggests an important contribution of PBDE emissions from recycling centers of e-waste in China. Although efforts in environmental monitoring of PBDE contamination have been substantially increased over the last decade, China is still lagging behind in terms of nationwide regulation of PBDE usage and treatment of disposal PBDE-containing products.     

陆域产业结构演进对海洋环境的动态影响研究——以长江流域与东海沿岸地区为例

以往研究已经证明海洋经济发展中产生的污染对海洋环境质量的变化没有显著性影响,海洋污染物的主要来源是陆地,海洋环境与陆域经济之间存在着较为密切的关系,但关于陆域产业结构演进对海洋环境影响的研究非常少见,加深该研究对推动海洋环境改善具有重要的意义。利用VAR模型和Tapio脱钩模型,研究2001～2017年间长江流域和东海沿岸地区的产业结构高度化和产业结构合理化对东海海域的海洋环境的动态冲击,借助它们的脱钩状态证实该影响。研究结果显示:(1)陆域产业结构高度化有利于海洋环境改善,其原因包括产业间优势地位的更替和产业内部的技术创新;陆域产业结构合理化的发展存在波动性,导致它对海洋环境的影响不够显著;一部分海洋污染物可以通过海水自身的净化能力而消解,残存污染给海洋环境带来了不利影响。(2)在2002～2017年,东海的海洋环境与长江流域和东海沿岸地区的产业结构高度化、合理化分别表现为"大幅变化-稳步变化-脱钩持续"、"剧烈变化-起伏波动-脱钩持续"的脱钩变化规律,该脱钩分析结果证实了陆域产业结构演进对海洋环境的影响。     

Towards Sustainable Urban Environmental Management in Jiangyin city,East China

Abstract

Dramatic economic and social changes have taken place in Jiangyin city due to rapid and uneven urbanization and industrialization. The environmental degradation has followed driven by these changes since the 1980's. With the pressures and effects of environmental deterioration, the city has implemented environmental management to hold back the trends of negative environmental changes. From the viewpoint of systems, DPSER is a good model for urban environmental changes to understand the causes, pressure, state, effect, existing responses and future action strategies. We took Jiangyin city, a developed city in South Jiangsu province, East China, as an example, and analyzed the characteristics of environmental changes and urban responses using DPSER model. Some operational strategies have been put forward to direct the city environmental management towards a sustainable road step by step.     

Towards Sustainable Urban Environmental Management in Jiangyin city, East China

Dramatic economic and social changes have taken place in Jiangyin city due to rapid and uneven urbanization and industrialization. The environmental degradation has followed driven by these changes since the 1980's. With the pressures and effects of environmental deterioration, the city has implemented environmental management to hold back the trends of negative environmental changes. From the viewpoint of systems, DPSER is a good model for urban environmental changes to understand the causes, pressure, state, effect, existing responses and future action strategies. We took Jiangyin city, a developed city in South Jiangsu province, East China, as an example, and analyzed the characteristics of environmental changes and urban responses using DPSER model. Some operational strategies have been put forward to direct the city environmental management towards a sustainable road step by step.     

Assessment of the red-crowned crane habitat in the Yellow River Delta Nature Reserve, East China

As wildlife habitat is in constant evolution, periodic monitoring is essential to assess its quality. In this study, the change to the red-crowned crane habitat in the Yellow River Delta Nature Reserve was detected from multi-temporal remote sensing data from 1992 to 2008 in a geographic information system. Habitat fragmentation was derived from both physical constraints and human disturbance. The changing habitat quality was assessed against five landscape indices. The results obtained from Landsat TM images indicate that potential habitat shrank 37.9 % during 1992–2001, but recovered 99.4 % by 2008. Suitable habitat shrank by 4,329 ha to a level below that of 1992 despite an increase of 4,747 ha in potential habitat due to an increase of 9,075 ha in fragmented areas. Both landscape indices and the red-crowned crane population reveal that suitable habitat was the most fragmented in 2001, but the least fragmented in 1992. Therefore, it is inadequate to just restore wetland through artificial diversion of channel flow to the Reserve to preserve the crane habitat. Commensurate efforts should also be directed at improving habitat quality by minimizing human activities and spatially juxtaposing water and reed marshes harmoniously inside the Reserve.     

Response of herbivorous geese to wintering habitat changes: conservation insights from long-term population monitoring in the East Dongting Lake,China

Regional Environmental Change - The majority of Eastern China’s herbivorous geese overwinter in the East Dongting Lake, China, and there is growing concern about how changes in their habitats...     

Modelling radioactivity in the Irish Sea: From discharge to dose

In order to support authorised discharges of low level radioactive liquid effluent into coastal regions, mathematical models are required to robustly predict radiological impacts on critical groups of current and proposed changes to liquid discharges. The grid model presented here simulates the long term dispersion and transport of radioactivity discharged from the Sellafield site in Cumbria, UK, and the subsequent exposure of critical groups in Cumbria and across the Irish Sea in Northern Ireland. The fine grid of the model allows a good resolution of the seabed sediment distribution. This benefits the predictions for the last decades of low discharge level, when bed sediment can become a source of contamination by bringing back the legacy of past high discharges. This is highlighted by the dose comparison, where the predicted dose to Cumbria critical group follows well the dose estimated from environmental data during the low discharge level period.     

On shrimp,salt and security: livelihood risks and responses in South Bangladesh and East India

Bangladesh and India are among the world’s most populous but also most vulnerable countries to environmental risks. In addition to storms, sea-level rise, floods and droughts, local communities face a multitude of pre-existing and concomitant economic and socio-political risks. To understand these risks and how communities respond to them is critical in securing community livelihoods. We therefore ask what are the livelihood risks; how do they impact the human security of environment sensitive communities in Satkhira, Bangladesh and in Odisha, India; and, what are the responses of these communities to the livelihood risks? The communities studied in Bangladesh depend mainly on the shrimp and fish resources of the Sundarbans mangrove forest. The two communities researched at Lake Chilika in India depend on fishing and salt farming, respectively. The field research, conducted in 2012 and 2013, shows that the communities face multiple and interacting livelihood risks. While storms and floods are common environmental risks in both countries, related livelihood risks are case-specific. In Bangladesh, attacks by criminals are the major threat to human well-being, while in India, it is violent conflict between lake users. Unsustainable resource extraction is found in both study countries. In Bangladesh, shrimp farming weakens the flood protection, while in India, illegal prawn farming marginalizes poorer lake users. Accessing loans and labor migration are responses observed in both countries. We conclude that adaptation to environmental changes needs to be sensitive to the interaction between governance, local institutions and socio-economic developments.     

Climatic and human drivers of recent lake-level change in East Juyan Lake,China

Drying of an inland river’s terminal lake in arid regions is an important signal of environmental degradation in downstream regions. A long-term, high-resolution understanding of the lake’s retreat and expansion and the driving mechanisms will inform future adaptive water management strategies, ecosystem restoration, and government decision-making in the context of a growing water scarcity in the inland river basin. The shrubs that grow along the shore of a lake often provide evidence of lake retreat or expansion. The chronological results showed that the earliest germination dates of the lakeshore shrubs, tamarisk, were in 1901, 1943, 1966, 2009, and 1990 from the higher terrace to the lower terrace of East Juyan Lake, a terminal lake of China’s Heihe River. Coupled with river and lake hydrological data, six obvious lake’s fluctuations were identified: shrinkage from 1900 to 1940s and during the early 1990s, expansion and retreat in the late 1950s and early 1970s, continued expansion from 2002 to 2008, and stabilization at a water area of around 40 km² from 2009 to the present. The water elevation in the 1900s was below 905 m a.s.l., resulting in a water area <80 km², but decreased to 40 km² after 1960 and dried up completely by the 1990s. By analysing climatic and hydrological records since 1950, tree-ring climate proxy data, river runoff outside the observation period, and water resource consumption in the middle and lower reaches of the Heihe River, we found that the periodic expansion and retreat of East Juyan Lake was influenced by both climate change and human activities, but especially by human activities. The lake’s recent recovery and stability was achieved by government policy designed to provide environmental flows to the lake.     

Distribution of radionuclides in the guano sediments of Xisha Islands, South China Sea and its implication

Several natural and anthropogenic radionuclides (²¹⁰Pb, ²²⁶Ra and ¹³⁷Cs) in guano-phosphatic coral sediments and pure guano particles collected from Ganquan, Guangjin, Jinqing and Jinyin Islands of the Xisha archipelago, South China Sea, were analyzed. The Constant Initial Concentration (CIC) model and the Constant Rate of Supply (CRS) model were applied for age calculation. The average supply rate of ²¹⁰Pb was 126 Bq m⁻² a⁻¹, very close to the flux of northern hemisphere average (125 Bq m⁻² a⁻¹). The activities of anthropogenic radionuclides in the sediments were very low, indicating that human nuclear tests did not notably impact this region. The main source of radionuclides in the sediments was from atmospheric precipitation, and the organic matter derived from plant and produced by nutrient-rich guano could further enhance them.     

Quantitative modeling of freshwater stress in the nine water basins of Tanzania

Freshwater scarcity is a global issue of environmental concern that threatens agricultural production and human health. In this study, we established freshwater stress indices (WSIs) for the nine water basins of Tanzania by using the quantity of freshwater available and various water uses. The relationship between water availability and different water uses, including environmental water requirements, was analyzed, with uncertainty and sensitivity analysis performed by a Monte Carlo simulation technique. Extreme WSI values close to 1.00 were obtained in the Rufiji, Pangani, and Wami-ruvu basins, Internal drainage, and Lake Rukwa, while low and moderate WSI values ranging from 0.03 to 0.84 were found in Lake Victoria and the Ruvuma, Tanganyika, and Nyasa basins. This study adds further knowledge on the level of freshwater scarcity, relationships between water availability and different water uses, and suggests policy options to reduce freshwater scarcity at the basin level for sustainable water supply.     

Quantitative modeling of freshwater stress in the nine water basins of Tanzania

Freshwater scarcity is a global issue of environmental concern that threatens agricultural production and human health.In this study,we established freshwater stress indices(WSIs) for the nine water basins of Tanzania by using the quantity of freshwater available and various water uses.The relationship between water availability and different water uses,including environmental water requirements,was analyzed,with uncertainty and sensitivity analysis performed by a Monte Carlo simulation technique.Extreme WSI values close to 1.00 were obtained in the Rufiji,Pangani,and Wami-ruvu basins,Internal drainage,and Lake Rukwa,while low and moderate WSI values ranging from 0.03 to 0.84 were found in Lake Victoria and the Ruvuma,Tanganyika,and Nyasa basins.This study adds further knowledge on the level of freshwater scarcity,relationships between water availability and different water uses,and suggests policy options to reduce freshwater scarcity at the basin level for sustainable water supply.     

Economic Development and Conservation of Biological and Cultural Diversity in Yunnan Province, China

Chinese and American scientists are co-operating to develop concepts, strategies, agreements, and proposals in support of an economic development and sustainable ecosystems project in Yunnan Province, People's Republic of China. Yunnan's Provincial Government has initiated a major programme to develop and further utilise its biological resources to help improve economic conditions for its citizens. They are co-operating with the US Geological Survey (USGS) on evaluation and management of biological resources so economic development will be compatible with sustainable ecological systems. Scientists from the USGS and co-operating universities will provide expertise on synthesising biological data, conducting a Gap Analysis for the Province, evaluating innovative economic opportunities, and designing an effective education, training, and outreach programme.     

Regional industrial growth and environmental impacts in the Bohai Sea rim region of China: uncertainty in location choice

Regional industrial growth is facing the problems of no control and disorder in rapidly transitioning China, especially in mega-regional areas. These problems have significantly intensified the use of regional resources and the level of environmental stress. The integration of industrial development and the environmental pollution pressure simulation at the mega-regional level must be supported at the planning stage. In this study, a Computational System for Regional Industrial Distribution Simulation and Environmental Impact Assessment (RESEA) that combines a multi-nominal logit model and uncertainty analysis was developed. This system aimed to explore efficient industrial spatial distribution simulations and potential environmental pressures at the mega-regional level. This study also developed an uncertainty analysis framework to identify and apply a bottom-up system with aggregate and sparse data following the basic processes of an HSY algorithm and Global-Formed Regional Sensitivity Analysis, which is capable of considering both input uncertainty and parameter uncertainty. By applying the RESEA system, a process of model estimation and sensitivity analysis was implemented based on historic data from 2002 to 2008 for the Bohai Sea rim region in China. The future industry distribution for the year 2015 was later aggregated based on the chosen sizes and locations of newly added industrial plants. Finally, the pollution loads of surface water into every sub-region were calculated, and the potential environmental impacts of different strategies were discussed.     

Seasonal variation in photosynthesis in relation to differing environmental factors of dominant plant species in three successional communities in Hangzhou Bay Wetlands,East China

We investigated the ecophysiology (physiological ecology) of plant succession within a coastal wetland community. The photosynthetic characteristics of six plants were studied; Scirpus mariqueter and Carex scabrifolia in early successional communities, Phragmites communis and Tamarix chinensis in mid successional communities, and Salix matsudana and Imperata cylindrica in later successional communities. Environmental factors were concurrently determined for each community. Relationships between photosynthetic and environmental factors were analyzed by path analysis, and the dependence of photosynthesis on particular environmental factors was shown to vary between plants in the differing successional communities. Ability to cope with irradiation appears to be one of the most important factors influencing plant succession. The increasing stratification of plant communities following colonization of new coastal land necessitates differing physiological strategies and photosynthetic dynamics in the later colonizing plants.