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Morihiro Osada Nobuhiro Tanigaki Shin Takahashi Shin-ichi Sakai 《Journal of Material Cycles and Waste Management》2008,10(2):93-101
The End-of-life Vehicles Recycling Act went into effect on January 1, 2005, in Japan and requires the proper treatment of
airbags, chlorofluorocarbons (CFCs), and automobile shredder residue (ASR). The need for optimal treatment and recycling of
ASR, in particular, has been increasing year after year because ASR is regarded as being difficult to treat. Dioxin-related
compounds, brominated flame retardants (BFRs), heavy metals, chlorine and organotin compounds are all present in high concentrations
in ASR. The authors conducted ASR melting treatment tests using a 10-tons/day-scale direct melting system (DMS), which employs
shaft-type gasification and melting technology. The results obtained showed that dioxin-related compounds and BFRs were decomposed
by this melting treatment. The high-temperature reducing atmosphere in the melting furnace moved volatile heavy metals such
as lead and zinc into the fly ash where they were distributed at a rate of more than 90% of the input amount. This treatment
was also found to be effective in the decomposition of organotin, with a rate of decomposition higher than 99.996% of the
input amount. Via the recovery of heavy metals concentrated in the fly ash, all the products discharged from this treatment
system were utilized effectively for the complete realization of an ASR recycling system that requires no final disposal sites. 相似文献