Green chemistry

A grand challenge facing government, industry, and academia in the relationship of our technological society to the environment is reinventing the use of materials. To address this challenge, collaboration from an interdisciplinary group of stakeholders will be necessary. Traditionally, the approach to risk management of materials and chemicals has been through inerventions intended to reduce exposure to materials that are hazardous to health and the environment. In 1990, the Pollution Prevention Act encouraged a new tact-elimination of hazards at the source. An emerging approach to this grand challenge seeks to embed the diverse set of environmental perspectives and interests in the everyday practice of the people most responsible for using and creating new materials—chemists. The approach, which has come to be known as Green Chemistry, intends to eliminate intrinsic hazard itself, rather than focusing on reducing risk by minimizing exposure. This chapter addresses the representation of downstream environmental stakeholder interests in the upstream everyday practice that is reinventing chemistry and its material inputs, products, and waste as described in the “12 Principles of Green Chemistry”.     

Reducing the harms associated with risk assessments

Risk assessments are the intellectual products of dedicated public health and environmental professionals. Like many other products, risk assessments carry with them the potential for both good and harm. This paper briefly examines some of the harms to which risk assessments have contributed, and then suggests that the legal “duty to warn” doctrine offers a logical and practical way to reduce some of these harms. The paper suggests concepts that could be incorporated into warnings accompanying every formal risk assessment as routine “boiler plate” addenda, just as other potentially harmful products, such as lawn mowers and cook stoves, are accompanied by warnings. Finally, the paper briefly examines the “Code of Ethics and Standards of Practice for Environmental Professionals” (promulgated by the National Association of Environmental Professionals) and shows that the suggested warnings are consistent with recommended practices for environmental professionals.     

Building consensus on divisive issues: a case study of the Yukon wolf management team

This article presents a case study of a successful effort to reach agreement on one of the most intractable environmental issues of our time: wolf management. This case is unusual in several ways. In this case, the members of the negotiating team were ordinary citizens rather than leaders of organized groups. This team was given an unusually high level of authority to write the plan as they saw fit; the agency pledged to implement “whatever they came up with.” The agency convened the process, but agency personnel were not members of the team and attended only when they were invited. The team members were able to reach agreement on this tough issue even though polar opposites were at the table—one who felt that wolves are a “spiritual essence” and another who felt that, as he put it, “wolves, coyotes, and cockroaches have a lot in common”. They produced a detailed plan that addressed all the issues in just 5 months. Another unusual aspect of this effort is that the final agreement does not list the team members. They explained that they wanted their plan to “stand alone” and be judged based on what it said, not on who was involved.However, just after their agreement was completed, a new, pro-wolf control government was elected that refused to endorse the plan. While the government gave various reasons for not ratifying the plan, more and more diverse interest groups came out in support for both the plan and the process that created it. Eventually, overwhelming public support forced the government to sign and implement the plan as written. This demonstrates that, while it is important for a team to seek the sanction of decision-makers, it is perhaps even more important for the general public to see the effort and the final agreement as fair. Strong support from a broad spectrum of the public can help win the necessary political support.In addition to discussing the unorthodox aspects of this consensus-building effort, this article also attempts to give the reader a front row seat to this process by using the informants' own words—words rich in detail, brimming with color and spoken straight from the heart. Certainly their experience dispels any notion that such efforts are simply a matter of following a recipe. During the process, members of the negotiating team experienced the entire gamut of emotions—anger, defeat, humor and, finally, a genuine sense of pride. As team member Patty Denison put it, “We showed that a random group of people could work together and do something truly monumental.”     

Planning for sustainability at the local government level

While the primary objective of the 1992 Earth Summit was to generate new commitments from national governments on global environmental issues, one of the most tangible outcomes of the summit was to focus international attention on the role of cities as central actors in the Earth's ecosystem. As a result, the recent UN Conference on Human Settlements (Habitat II) extended its focus, originally on housing only, to sustainable human settlements. The final product of the meeting, the Habitat Agenda, provides the greatest recognition ever offered by the United Nations to the role of local governments in the sustainable development process. The success of the Habitat Agenda will be defined by the ability of local governments to effectively adopt its recommendations.This article is a “report from the field” on local adaptations of environmental assessment andplanning procedures in order to implement the various components of the sustainable development mandate.     

The precautionary principle stimulus for solutions- and alternatives-based environmental policy

The precautionary principle is increasingly discussed in debates over appropriate measures to address complex and uncertain risks. The principle has generally been defined as having two main components: preventive action in the face of uncertainty and reversing the burden of proof. In isolation, these two components would suggest that precaution is primarily reactive to potential problems rather than proactive. More recent statements have suggested that thorough assessment of alternatives is critical to the effective implementation of the precautionary principle. Alternatives assessment—also referred to as options analysis and facility planning—redirects environmental science and policy debates from characterizing problems to identifying solutions. In this commentary, we examine the rationale for a focus on alternatives assessment in implementing the precautionary principle. We examine methods and examples of alternatives assessment, as well as opportunities for the principle's integration in environmental policy. We argue that a greater focus on alternatives assessment can enhance the ability of decision makers to make truly precautionary decisions, stimulate innovation toward sustainable production, and more effectively place burdens on to those creating risks. Such a focus forms an essential component of a shift from “problem-based” environmental policy to “solutions-based” policy. This shift requires adequate research resources, tools, and a government commitment to a new paradigm of environmental protection. We conclude that we will only reach the goal of sustainable production if we change our environmental protection focus from figuring out how bad the situation will be to seeking alternatives to problematic activities and designing the conditions for a more sustainable future.     

Not so Black and White: environmental justice and cumulative impact assessments

A growing number of scientific studies in recent years have investigated disparate exposure to ecological hazards in American society. Working from an environmental justice perspective, this body of research consistently reveals that poor communities of color are most likely to bear a disproportionate burden of negative externalities. These studies utilize a wide range of research methodologies, including various indicators of ecological hazards (e.g., proximity to waste sites, industrial emissions, ambient air quality), but few, if any, utilize composite measures to approximate cumulative environmental impact. Consequently, the environmental justice (EJ) literature is characterized by a failure to effectively measure overall impact from an extensive range of ecological hazards. Limitations on available data make this a serious problem for present and future studies. We argue that cumulative measures of environmental impact can play an important role in furthering our understanding of environmental injustices in the United States. In this study of Massachusetts, we develop and implement such a cumulative measure of negative environmental impacts. By controlling for the density and severity of ecological hazardous sites and facilities within every community in the state, we demonstrate that exposure patterns take a generally linear distribution when analyzed by race and class. So, while our results reaffirm previous findings that low-income communities and communities of color bear significantly greater ecological burdens than predominantly White and more affluent communities, our findings also suggest that environmental injustices exist on a remarkably consistent continuum for nearly all communities. In other words, as the minority population and lower-income composition of a community increases, correspondingly, so does cumulative exposure to environmental hazards. In this respect, communities which are more racially mixed and of moderate income status that are not typically identified as meeting EJ criteria (in demographic terms) also face more significant ecological hazards. Thus, the strict bifurcation of communities into categories of Environmental Justice and Non-Environmental Justice is problematic, and poses a serious dilemma for policy makers, public health officials, and community activists. To overcome this challenge requires the adoption of a cumulative environmental justice impact assessment (CEJIA), which in addition to the demographic characteristics of a community, also takes into account the total environmental burden and related health impacts upon residents. Furthermore, through the adoption of the precautionary principle, source reduction, and alternative forms of “cleaner” production, environmental justice advocates must work for policies which reduce the environmental threat for the full range of communities, as well as their own.     

Variability in Voc Concentrations in an Urban Area of Delhi

The variability of pollutants is an important factor in determining human exposure to the chemicals. This study presents the result of investigation of variability of Volatile organic compounds (VOCs) in urban area of Delhi, capital of India. Fifteen locations, in five categories namely residential, commercial, industrial, traffic intersections and petrol pump were monitored for one year every month during peak hours in morning and evening. Measurement focused on target VOCs as defined by USEPA. Variability was divided into measurement, spatial, temporal and temporal–spatial interaction components. Temporal component along with temporal–spatial interaction were found to be the major contributors to the variability of measured VOC concentrations. Need of continuous monitoring to capture short–term peak concentration and averages is evident.     

Controlling pollution in rural areas by economic instruments

The most interesting economic instruments for the control of environmental pollution belong to the categories of taxes (or charges) and of tradeable pollution permits. After the basic theoretical propositions of the seventies and their early applications, the search now is for practical methodologies and for a correct and effective use of such instruments. With this aim in view, the paper begins by introducing the concepts of environmental externality and of optimal level of pollution, then illustrates the two main options of control (taxation and market of tradeable permits) and briefly discusses their application in reducing pollution in wide rural areas.Sections 1, 2, 3, e 4.Section 5.     

环境监测项目监测边界和参数设计方法

针对环境监测项目的一般性要求,系统地提出环境监测边界和监测参数的设计方法。将环境监测边界划分为空间地理边界、空间生态边界、动力空间边界、项目空间边界和时间期限,并阐述了这5种划分的具体内容。同时,介绍了监测参数设计的一般流程、环境质量监测参数选择原则及选择方法。     

2006—2012年江苏省环境安全综合评估研究

从江苏省环境安全形势出发,借鉴“压力-状态-响应”（PSR）模型的框架思路,构建了环境安全度量的层次指标体系。从环境安全的压力、状态、响应3个方面确定相应的指数及对应的评估指标,通过基于德尔斐法的层次分析法确定权重,计算环境安全综合指数,并建立环境安全等级划分标准。应用建立的环境安全评估体系,对2006-2012年江苏省环境安全进行了评估。结果表明：2006-2012年,全省环境安全综合指数呈明显下降趋势,安全等级由中警状态好转为预警状态,江苏省环境安全形势不断改善。但2012年以来,大气灰霾、酸雨等复合型污染有所加重,环境安全接近中警状态,全省环境安全形势亟需进一步采取措施进行有效保障。     

Life cycle assessment based environmental impact estimation model for pre-stressed concrete beam bridge in the early design phase

The late rise in global concern for environmental issues such as global warming and air pollution is accentuating the need for environmental assessments in the construction industry. Promptly evaluating the environmental loads of the various design alternatives during the early stages of a construction project and adopting the most environmentally sustainable candidate is therefore of large importance. Yet, research on the early evaluation of a construction project's environmental load in order to aid the decision making process is hitherto lacking. In light of this dilemma, this study proposes a model for estimating the environmental load by employing only the most basic information accessible during the early design phases of a project for the pre-stressed concrete (PSC) beam bridge, the most common bridge structure. Firstly, a life cycle assessment (LCA) was conducted on the data from 99 bridges by integrating the bills of quantities (BOQ) with a life cycle inventory (LCI) database. The processed data was then utilized to construct a case based reasoning (CBR) model for estimating the environmental load. The accuracy of the estimation model was then validated using five test cases; the model's mean absolute error rates (MAER) for the total environmental load was calculated as 7.09%. Such test results were shown to be superior compared to those obtained from a multiple-regression based model and a slab area base-unit analysis model. Henceforth application of this model during the early stages of a project is expected to highly complement environmentally friendly designs and construction by facilitating the swift evaluation of the environmental load from multiple standpoints.     

Assessing the Response of Estuarine Intertidal Assemblages to Urbanised Catchment Discharge

Measurement of intertidal rock assemblages was investigated as a potential biological indicator to provide a quantitative estimate of the impact of urbanised catchment discharge on the estuaries of Sydney, Australia, from 1995 to 1999. Based on the presence and characteristics of adjacent human activities, sampling locations were categorised as: Bush; Urban; Urban with Sewer Overflows; and Industry with Sewer Overflows. In Sydney Harbour, variation in assemblage structure was measured between most impact categories, however differences between impact categories were not consistent for each year. Nevertheless, in years of above average rainfall (1998–1999), reference assemblages adjacent to national parks and distant from urbanisation were different to all other putatively impacted assemblages. Variability within assemblages was least at reference locations in each year and greatest at locations adjacent to stormwater canals and sewer overflows, particularly in 1998–1999. Variation in assemblage structure in Sydney estuaries was most strongly correlated with chlorophyll – a concentrations. Univariate analysis also identified highly significant differences for a number of factors, however, interactions between year, impact categories and location for numerous analyses, confounded the differentiation between impact categories. The results suggest that intertidal rock assemblages in Sydney Harbour and surrounding estuaries appear to be responding to the quality and quantity of discharge from urbanised catchments and, furthermore, that assemblages are more suitable than individual taxa to indicate the difference between Bush and anthropogenically disturbed estuarine locations.     

Measurement of atmospheric concentrations of common household pesticides: A pilot study

Air concentrations of 28 of the most commonly used household pesticides were measured inside nine homes in Jacksonville, Florida, and compared with corresponding outdoor levels. The households selected were sorted into three categories according to the degree of pesticide indoor usage. Personal air monitoring was also performed on one resident of each household by means of a portable sampler, which was kept with the person at all times. Five of the pesticides were found in the air inside of the majority of the homes at concentrations as high as 15 gm^–3 (average concentrations, 12 ngm^–3 to 2.4 gm^–3). Indoor levels were generally one to two ordrrs of magnitude higher than surrounding outdoor air levels and personal air measurements were within ± 50% of corresponding indoor values. All samples were collected over 24-hr periods on polyurethane foam and analyzed by capillary colum gas chromatography with mass spectrometric and/or electron capture detection.     

Environmental impact of Information Communication Technology: A review of econometric assessment methods,influential mechanism,and influential direction

In recent decades, the rapid development of the global society and economy has brought serious environmental problems, such as air pollution, greenhouse effect, and ecosystem degradation, all of which have attracted wide attention. Simultaneously, the use of Information Communication Technology (ICT) has been on the rise since the 1980s, which stimulates the growth of the economy and has a certain degree of impact on the ecological environment. Accordingly, the scientific community's interest in assessing this impact has grown considerably, and econometric methods are widely used as evaluation tools. However, the research results are often different in different regions, periods, environmental proxies, and ICT. Some studies indicate that the development of ICT is beneficial to environmental improvement, while others state that it is not. Therefore, a comprehensive analysis of the methods, mechanisms, and relative policy suggestions of this topic is desiderated. To address this gap, this paper carries out a systematic literature review of the usage of econometric methods in the assessment of the environmental impact of ICT. Among the 472 articles retrieved from scientific literature databases, 46 met the inclusion criteria and were analyzed in detail. This study aims to provide scholars with a mental picture of the current state of scientific research, identify the factors that influence the direction of ICT's impact on the environment, and enable future researchers to use more reliable and accurate estimation methods. The methods used in selected articles were divided into two main groups (i.e., time series models and panel data models), and panel data models were further subdivided into five categories. The detailed flow of these methods is summarized, and new advanced pre-test methods and estimators are highlighted. Furthermore, the analysis also indicates that among all the countries and regions involved in the selected articles, there is a non-strict inverted U-shaped curve between the level of socio-economic development and the direction of the impact of ICT on the environment. Finally, current research challenges are discussed, and potential directions for future research on this topic are also projected.     

Techno-economic and environmental assessment of wastewater management systems: Life cycle approach

The septic-tank and tanker (STT) system is a traditional wastewater management practice commonly used in many developing countries. The system is based on septic tanks that are pumped out by sewage tankers on a regular basis. Although the STT system is gradually being replaced by conventional gravity sewers (CGS), the high capital cost of this shift remains a major obstacle. This research aims to investigate the economic feasibility and environmental footprint of an alternative wastewater management system compared to existing sanitation systems. The study examines the small-bore sewers (SBS) system which utilizes the existing septic tanks to separate solids from gravity-conveyed effluent. A comparative assessment of the three systems (STT, CGS, and SBS) along with their treatment facilities was conducted on a residential area in the United Arab Emirates. Local design criteria of the SBS system were proposed based on current CGS guidelines and international SBS standards. A cost-integrated life cycle assessment (LCA) was carried out in order to evaluate the environmental and economic aspects of the three management strategies. The total present value of the SBS strategy was found to be significantly higher than those of STT and CGS, respectively. Moreover, a 67% smaller treatment plant was sufficient to serve the SBS effluent. The LCA results revealed that the CGS strategy imparted the highest damage to the environment in all impact categories considered including global warming potential, whereas, the STT system produced a higher impact than SBS in six out of the eleven tested impact categories. Overall, while the STT strategy was the least financially feasible, the CGS had the largest environmental footprint. The eco-efficiency assessment revealed that the SBS strategy was the most favored among the examined strategies.     

Framework for enhancing the statistical design of aquatic environmental studies

Aquatic environmental studies can be categorized by the breadth of their scope and the types of desired results. The use of this categorization coupled with a clear specification of objectives and a judicious knowledge of the environmental variability should lead to more statistically efficient studies. This paper discusses the types of lacustrine studies commonly encountered in terms of their categorization. It provides examples of how the intrinsic environmental variability can influence their design and stresses the importance of properly stated objectives, the developing of testable hypotheses, the design of robust and powerful studies, and the importance of evaluating the implication of changes as critical factors for conducting effective and efficient environmental studies.An early version of this paper was presented at the First International Conference on Environmentrics, Cairo, Egypt, April 4–7, 1989, under the title Framework for the Design of Aquatic Environmental Studies.     

Life cycle assessment of solar photo-Fenton and solar photoelectro-Fenton processes used for the degradation of aqueous α-methylphenylglycine

A comparative Life Cycle Assessment (LCA) of solar photo-Fenton and solar photoelectro-Fenton, two solar-driven advanced oxidation processes (AOPs) devoted to the removal of non-biodegradable pollutants in water, is performed. The study is based on the removal, at laboratory scale, of the amino acid α-methylphenylglycine, a good example of soluble and non-biodegradable target pollutant. The system under study includes chemicals, electricity, transport of all raw materials to the plant site, and the generation of emissions, but it does not take into account the impact of the infrastructure needed to build a hypothetical solar plant. Nine environmental impact categories are included in the LCA: global warming potential, ozone depletion potential, aquatic eutrophication potential, acidification potential, human toxicity potential, photochemical ozone formation potential, fresh water aquatic ecotoxicity potential, marine aquatic ecotoxicity potential, and terrestrial ecotoxicity potential and abiotic resource depletion potential. Although previous experimental results show that both AOPs are able to efficiently degrade the pollutant, the LCA indicates that solar-driven photo-Fenton is the most environmentally friendly alternative, mainly because the use of electricity in solar photoelectro-Fenton experiments involves high environmental impacts.     

Empowered native community, modified SIA: The case of hydaburg, alaska

This paper reviews a social impact assessment of Hydaburg, Alaska, to illustrate the modifications of non-NEPA SIAs in response to “empowered” Native communities. Hydaburg has been influenced by three organizations designed to promote greater self-determination: the Native Village Corporation, a Native municipal government, and the Native Sovereignty Movement. The Hydaburg SIA incorporated community-based research, cultural assessment, and advocacy mitigation to accommodate the demands of this“empowerment”. The paper suggest that modified SIAs of this sort are likely to become more prevalent as self-determination among Native communities increases.     

Health impact assessment in multinationals: A case study of the Royal Dutch/Shell Group

Health impact assessment is part of the risk management process of multinational corporations/companies. Sexually transmitted infections, including HIV/AIDS, and the “paradox of plenty” are used as examples of the challenges they face. The “business case” for impact assessment is explained. The policies, procedures, standards, and activities used by Shell to manage such risks are described. An approach to capacity building and competency development is presented that applies to both company staff and external contractors.     

Parasites of Fish as Indicators of Environmental Stress

During the 1994/1995 EMAP-Estauries program in the Carolinian Province we investigated the feasibility of using parasites of fish as response indicators. Parasites of fish are an indigenous component of healthy ecosystems. Within the EMAP-E design, the suite of environmental parameters which may affect parasite abundance, richness, prevalence, and diversity can be divided into three categories: 1) the physical and chemical characteristics of the water and sediment (including contaminants) external to the fish; 2) the internal environment defined by the physical condition (physiological) of individual fish; and 3) the presence and relative abundance of benthic macroinvertebrates, many of which serve as intermediate hosts. The biotic response of parasites to environmental stressors is also reflected in the health of fish. Parasite assemblages of silver perch Bairdiella chrysura respond to both natural and anthropogenic stressors. Our results showed that particular environmental stressors and specific parasites that respond include: temperature and monogeneans; contaminants and nematodes; low dissolved oxygen and protists; and salinity, together with a mixture of metal and organic contaminants and crustacea. Parasites of fish are useful biomarkers and appear to be more sensitive to environmental stressors than are the fish themselves. Parasite responses to selected environmental stressors may be used to discriminate polluted and unpolluted sites. The use of parasites of fish as biomarkers has relevant application to fisheries management and coastal monitoring programs.