Assessment of Lead Exposure in Thohoyandou, South Africa

Lead levels in different environmental media (soil, grass leaves, water, ceramics, pencil, paint, crayons and cosmetics) were determined to assess the major sources of lead exposure in Thohoyandou, South Africa. Soil and plant leaves were used as indicators of Pb pollution from vehicle exhaust emissions. After digestion with concentrated acids (HNO₃, HCl and HClO₄) Pb concentrations were determined in triplicate using a flame atomic absorption spectrometer. The mean Pb concentrations at the kerb of selected busy roads were 205.5 ± 90, 273.0 ± 90 and 312.8 ± 81 μg g⁻¹ and 154.7 ± 67, 182.9 ± 76 and 240.6 ± 66 μg g⁻¹ for soil and plant leaves (dry weight) respectively. These concentrations were substantially higher than the values found on soils 50 m away from the roads (97.4 ± 11 μg g⁻¹). Pb concentrations in plants collected further away from the road (50 m) were substantially lower (71.8 ± 9.0 μg g⁻¹). The observed levels on soil are lower than the UK critical value of 500 μg g⁻¹ for gardens and allotments; and 2000 μg g⁻¹ for parks and open space as well as the Canadian values for agricultural (375 μg g⁻¹), residential (500 μg g⁻¹ and industrial (1000 μg g⁻¹). From these data it was clear that Pb concentrations in soil samples were substantially higher than the levels obtained for plant leaves. The Pb levels in green crayons, blue crayons, pencils (from China & Germany), were 10650 ± 75.2, 8200 ± 52.4, 1160 ± 50.2, 79 ± 10.1 μg g⁻¹ for the inner contents; and 4870 ± 58.1, 5650 ± 55.5, 1950 ± 46.6, 60 ± 12.9 μg g⁻¹ for the outer surface paint respectively. The ceramics showed Pb levels of 630 ± 50.3 μg g⁻¹ (saucer) and 560 ± 32.2 μg g⁻¹ (cup), while the inner contents and outer surface paint showed 480 ± 32.4 and 318 ± 21.2 μg g⁻¹ of Pb respectively. Early morning tap water flush gave a Pb level of 20.6 ± 5.6 μg Pb l⁻¹. This value is higher than the WHO and FDA maximum permissible concentrations of 10 μg l⁻¹ and 15 μg l⁻¹ respectively.     

Response to environmental flows in the lower Tarim River, Xinjiang, China: ground water

In China's west since the 1950s large-scale ecosystem degeneration has occurred through water diversions for agricultural purposes. Since 2000, 1038 x 10(6) m(3) of water have been released into the Tarim River with the result that water reached the terminal Taitema Lake for the first time in 30 years. This environmental flow raised water-table levels along 350 km of the river. To assess the response of the water-table, a comparison "pristine" site is compared with downstream monitored sites. The results show huge changes in water-table levels. The study verifies that the water-table is extremely responsive to environmental flows, that strong internal similarities exist along the length of the river, and that the effect on the water-table and hence likely riparian vegetation recovery can be tentatively predicted. The actual impacts of the restoration strategy are less than those originally expected politically, socially and within the scientific community. We make recommendations on more effective release strategies.     

Utilization of waste product (tamarind seeds) for the removal of Cr(VI) from aqueous solutions: Equilibrium, kinetics, and regeneration studies

In the present study, an adsorbent was prepared from tamarind seeds and used after activation for the removal of Cr(VI) from aqueous solutions. The tamarind seeds were activated by treating them with concentrated sulfuric acid (98% w/w) at a temperature of 150 °C. The adsorption of Cr(VI) was found to be maximum at low values of initial pH in the range of 1–3. The adsorption process of Cr(VI) was tested with Langmuir, Freundlich, Redlich–Peterson, Koble–Corrigan, Tempkin, Dubinin–Radushkevich and Generalized isotherm models. Application of the Langmuir isotherm to the system yielded a maximum adsorption capacity of 29.7 mg/g at an equilibrium pH value ranging from 1.12 to 1.46. The adsorption process followed second-order kinetics and the corresponding rate constants obtained were 2.605 × 10⁻³, 0.818 × 10⁻³, 0.557 × 10⁻³ and 0.811 × 10⁻³ g/mg min⁻¹ for 50, 200, 300 and 400 mg/L of initial Cr(VI) concentration, respectively. The regenerated activated tamarind seeds showed more than 95% Cr(VI) removal of that obtained using the fresh activated tamarind seeds. A feasible solution is proposed for the disposal of the contaminants (acid and base solutions) containing high concentrations of Cr(VI) obtained during the regeneration (desorption) process.     

Role of Alternative Electron Acceptors (AEA) to control methane flux from waterlogged paddy fields: Case studies in the southern part of West Bengal, India

The rice fields, depleted of O₂, contain large amount of moisture and organic substrates to provide an ideal anaerobic environment for methanogenesis and are one of the principal anthropogenic sources of methane. In order to mitigate this emission Alternative Electron Acceptors (AEA) were altered in the soil. The experiments were carried out in four seasons at the site of Balarampur, near Baruipur, South 24 Parganas, West Bengal, namely September–December, 2005 (Cultivar: Sundari), February–May, 2006 (Cultivar: Sundari), September–December, 2006 and February–May, 2007 (Cultivar: Swarna-Pankaj). The seasonal average methane flux (Fe treated), for the cultivar type “Sundari” (season: September–December, 2005), is 4.41 t ha⁻¹, as compared to the value of 6.40 t ha⁻¹ for the untreated soil. Similarly for February–May, 2006, the seasonal average methane flux (Fe treated) is 5.52 t ha⁻¹, whereas the untreated flux is 5.69 t ha⁻¹. In the third and fourth seasons we had two treatments with Ammonium Thiosulphate and Ferric Hydroxide. The seasonal average methane flux (treatment: Ammonium Thiosulphate) is 4.35 t ha⁻¹ and 5.41 t ha⁻¹ respectively, whereas for the ferric hydroxide treated soil it is 4.35 t ha⁻¹ and 6.14 t ha⁻¹ respectively. The properties related to the nutrient quality of the harvested paddy seeds supplement these results.     

Environmental Impact Assessment of Sand Mining from the Small Catchment Rivers in the Southwestern Coast of India: A Case Study

In the past few decades, the demand for construction grade sand is increasing in many parts of the world due to rapid economic development and subsequent growth of building activities. This, in many of the occasions, has resulted in indiscriminate mining of sand from instream and floodplain areas leading to severe damages to the river basin environment. The case is rather alarming in the small catchment rivers like those draining the southwestern coast of India due to limited sand resources in their alluvial reaches. Moreover, lack of adequate information on the environmental impact of river sand mining is a major lacuna challenging regulatory efforts in many developing countries. Therefore, a scientific assessment is a pre-requisite in formulating management strategies in the sand mining-hit areas. In this context, a study has been made as a case to address the environmental impact of sand mining from the instream and floodplain areas of three important rivers in the southwestern coast of India namely the Chalakudy, Periyar and Muvattupuzha rivers, whose lowlands host one of the fast developing urban-cum-industrial centre, the Kochi city. The study reveals that an amount of 11.527 million ty⁻¹ of sand (8.764 million ty⁻¹ of instream sand and 2.763 million ty⁻¹ of floodplain sand) is being mined from the midland and lowland reaches of these rivers for construction of buildings and other infrastructural facilities in Kochi city and its satellite townships. Environmental Impact Assessment (EIA) carried out as a part of this investigation shows that the activities associated with mining and processing of sands have not only affected the health of the river ecosystems but also degraded its overbank areas to a large extent. Considering the degree of degradation caused by sand mining from these rivers, no mining scenario may be opted in the deeper zones of the river channels. Also, a set of suggestions are made for the overall improvement of the rivers and its biophysical environment.     

Screening analysis of volatile organic contaminants in commercial inorganic coagulants used for drinking water treatment

A method for quality screening is suggested to detect volatile impurities in inorganic coagulants that are used for drinking water treatment. Static headspace gas chromatography with mass spectrometry detection (HS–GCMS) is sensitive and selective to detect volatiles in low concentrations. This study has discovered that volatile organic impurities are detectable in ferric and aluminium-based coagulants which are used for drinking water treatment. For ferric chloride, 2-propanol was detected at a level of 17–24 μg ml⁻¹, acetone at 0.7–1.7 μg ml⁻¹, 1,1,1-trichloroacetone at 0.02–0.04 μg ml⁻¹, trichloromethane at 0.01–0.02 μg ml⁻¹ and toluene at 0.01–0.12 μg ml⁻¹. For ferric chloride sulfate, acetone was detected at a level of 0.12 μg ml⁻¹, 1,1,1-trichloroacetone at 0.06–0.08 μg ml⁻¹, trichloromethane at 0.13–0.23 μg ml⁻¹, bromodichloromethane at 0.04–0.06 μg ml⁻¹ and dibromochloromethane at 0.04–0.05 μg ml⁻¹. For aluminium hydroxide chloride, only trichloromethane was detectable, but below the method detection limits (MDL). Although the concentrations of these impurities in commercial coagulants are low, this observation is important and should have impact on water industries for them to pay attention to the chemicals they are using for drinking water production.     

Batch and continuous biosorption of Cu by immobilized biomass of Arthrobacter sp.

The ability of free and polysulphone immobilized biomass of Arthrobacter sp. to remove Cu²⁺ ions from aqueous solution was studied in batch and continuous systems. The Langmuir and Freundlich isotherm models were applied to the data. The Langmuir isotherm model was found to fit the sorption data indicating that sorption was monolayer and uptake capacity (Q^o) was 175.87 and 158.7 mg/g for free and immobilized biomass respectively at pH 5.0 and 30 °C temperature, which was also confirmed by a high correlation coefficient, a low RMSE and a low Chi-square value. A kinetic study was carried out with pseudo-first-order reaction and pseudo-second-order reaction equations and it was found that the Cu²⁺ uptake process followed the pseudo-second-order rate expression. The diffusivity of Cu²⁺ on immobilized beads increased (0.402 × 10⁻⁴ to 0.435 × 10⁻⁴ cm²/s) with increasing concentration from 50 to 150 mg/L. The maximum percentage Cu²⁺ removal (89.56%) and uptake (32.64 mg/g) were found at 3.5 mL/min and 20 cm bed height. In addition to this the Bed Depth Service Time (BDST) model was in good agreement with the experimental data with a high correlation coefficient (>0.995). Furthermore, sorption and desorption studies were also carried out which showed that polysulphone immobilized biomass could be reused for up to six sorption–desorption cycles.     

AutoRAPID: A Model for Prompt Streamflow Estimation and Flood Inundation Mapping over Regional to Continental Extents

This article couples two existing models to quickly generate flow and flood‐inundation estimates at high resolutions over large spatial extents for use in emergency response situations. Input data are gridded runoff values from a climate model, which are used by the Routing Application for Parallel computatIon of Discharge (RAPID) model to simulate flow rates within a vector river network. Peak flows in each river reach are then supplied to the AutoRoute model, which produces raster flood inundation maps. The coupled tool (AutoRAPID) is tested for the June 2008 floods in the Midwest and the April‐June 2011 floods in the Mississippi Delta. RAPID was implemented from 2005 to 2014 for the entire Mississippi River Basin (1.2 million river reaches) in approximately 45 min. Discretizing a 230,000‐km² area in the Midwest and a 109,500‐km² area in the Mississippi Delta into thirty‐nine 1° by 1° tiles, AutoRoute simulated a high‐resolution (~10 m) flood inundation map in 20 min for each tile. The hydrographs simulated by RAPID are found to perform better in reaches without influences from unrepresented dams and without backwater effects. Flood inundation maps using the RAPID peak flows vary in accuracy with F‐statistic values between 38.1 and 90.9%. Better performance is observed in regions with more accurate peak flows from RAPID and moderate to high topographic relief.     

Factors affecting nitrate distribution in shallow groundwater under a beef farm in South Eastern Ireland

Groundwater contamination was characterised using a methodology which combines shallow groundwater geochemistry data from 17 piezometers over a 2 yr period in a statistical framework and hydrogeological techniques. Nitrate–N (NO₃-N) contaminant mass flux was calculated across three control planes (rows of piezometers) in six isolated plots. Results showed natural attenuation occurs on site although the method does not directly differentiate between dilution and denitrification. It was further investigated whether NO₃-N concentration in shallow groundwater (<5 m below ground level) generated from an agricultural point source on a 4.2 ha site on a beef farm in SE Ireland could be predicted from saturated hydraulic conductivity (K_sat) measurements, ground elevation (m Above Ordnance Datum), elevation of groundwater sampling (screen opening interval) (m AOD) and distance from a dirty water point pollution source. Tobit regression, using a background concentration threshold of 2.6 mg NO₃-N L⁻¹ showed, when assessed individually in a step wise procedure, K_sat was significantly related to groundwater NO₃-N concentration. Distance of the point dirty water pollution source becomes significant when included with K_sat in the model. The model relationships show areas with higher K_sat values have less time for denitrification to occur, whereas lower K_sat values allow denitrification to occur. Areas with higher permeability transport greater NO₃-N fluxes to ground and surface waters. When the distribution of Cl⁻ was examined by the model, K_sat and ground elevation had the most explanatory power but K_sat was not significant pointing to dilution having an effect. Areas with low NO₃ concentration and unaffected Cl⁻ concentration points to denitrification, low NO₃ concentration and low Cl⁻ chloride concentration points to dilution and combining these findings allows areas of denitrification and dilution to be inferred. The effect of denitrification is further supported as mean groundwater NO₃-N was significantly (P < 0.05) related to groundwater N₂/Ar ratio, redox potential (Eh), dissolved O₂ and N₂ and was close to being significant with N₂O (P = 0.08). Calculating contaminant mass flux across more than one control plane is a useful tool to monitor natural attenuation. This tool allows the identification of hot spot areas where intervention other than natural attenuation may be needed to protect receptors.     

Spatial and Temporal Patterns in Fish Assemblages Following an Artificially Extended Floodplain Inundation Event, Northern Murray-Darling Basin, Australia

Water extraction from dryland rivers is often associated with declines in the health of river and floodplain ecosystems due to reduced flooding frequency and extent of floodplain inundation. Following moderate flooding in early 2008 in the Narran River, Murray-Darling Basin, Australia, 10,423 ML of water was purchased from agricultural water users and delivered to the river to prolong inundation of its terminal lake system to improve the recruitment success of colonial waterbirds that had started breeding in response to the initial flooding. This study examined the spatial and temporal patterns of fish assemblages in river and floodplain habitats over eight months following flooding to assess the possible ecological benefits of flood extension. Although the abundances of most fish species were greater in river channel habitats, the fish assemblage used floodplain habitats when inundated. Young-of-the-year (4–12 months age) golden perch (Macquaria ambigua) and bony bream (Nematalosa erebi) were consistently sampled in floodplain sites when inundated, suggesting that the floodplain provides rearing habitat for these species. Significant differences in the abundances of fish populations between reaches upstream and downstream of a weir in the main river channel indicates that the effectiveness of the environmental water release was limited by restricted connectivity within the broader catchment. Although the seasonal timing of flood extension may have coincided with sub-optimal primary production, the use of the environmental water purchase is likely to have promoted recruitment of fish populations by providing greater access to floodplain nursery habitats, thereby improving the ability to persist during years of little or no flow.     

Acid-forming emissions in Alberta,Canada

The sulphur dioxide and nitrogen oxides emissions from all sources in Alberta, Canada, during 1982 amounted to 488,297 and 353,511 tonnes, respectively. During this year deposition of wet sulphate from all stations in the province, 8 kg ha^–1 yr^–1, compares well with the five-year average (1978–1982) value of 10 kg ha^–1 yr^–1. These measurements are about one-half of the wet sulphate deposition criteria of 20 kg ha^–1 yr^–1 established for protecting the moderately sensitive aquatic ecosystem in eastern Canada. Due to dry, cold, continental climate conditions of Alberta, dry sulphate or sulphur deposition is equally or more important than wet deposition. No effects of the long-range transport of atmospheric pollutants (LRTAP) on the ecosystems in Alberta have been observed to date. Atmospheric deposition target loadings of SO₄ ^–2, NO₃ ^–, and H⁺ for Alberta and western Canadian environmental conditions should be developed to protect the highly sensitive ecosystems. Some future research and monitoring priorities for Alberta and western Canada are outlined.     

Comparison of biosorbents with inorganic sorbents for removing copper(II) from aqueous solutions

In comparison with several other reported inorganic sorbents, Camellia tree leaf and primary sludge obtained from a settling tank as a pretreatment to the activated sludge system in a Hong Kong sewage treatment plant were evaluated for removing Cu(II) from aqueous solutions. Experimental data were modeled by the Langmuir isotherm equation to estimate the maximum sorption capacity (q_max). Results show that, at pH 5.6, biosorbents, Camellia tree leaf and primary sludge in particular, exert higher sorption capacities (q_max > 40 mg g⁻¹) than inorganic sorbents, Na-montmorillonite (q_max = 33.3 mg g⁻¹), fly ash (q_max = 18.8 mg g⁻¹), and goethite powder (10.3 mg g⁻¹). Furthermore, a pseudo second-order kinetic model was found to properly describe the experimental data for both bio- and inorganic sorbents. Sorption of Cu(II) on the Camellia tree leaf and primary sludge were much faster than that on the inorganic sorbents. In addition, desorption tests revealed that the desorption capacities of the two biomaterials are higher than the other selected materials; and much more Cu(II) can be retrieved from the Cu(II)-loaded biosorbents. Finally, increasing solution pH was found to greatly increase q_max and accelerate sorption processes.     

Growth and macronutrient removal of water hyacinth in a small secondary sewage treatment plant

Studies have been made of the growth characteristics of water hyacinth, Eichhornia crassipes (Mart.) Solms, and its ability to remove N, P and K, in a secondary settling pond of a small secondary sewage treatment plant serving both the academic and residential blocks of the Swire Marine Laboratory, University of Hong Kong. The treatment plant consists of, in series, a primary settling tank, a trickling filter compartment and a secondary settling pond from which part of the treated wastewater is recycled to the primary settling tank while the remaining effluent (1 to 2 m³ daily) mixes with and hence is diluted by the outflowing seawater from the aquarium system of the Swire Marine Laboratory before discharge to the sea. Samples of wastewater have been taken regularly from the primary sedimentation pond, the outflow of the trickling filter, the secondary settling pond and the effluent of the treatment plant (before mixing with aquarium outflow) since January, 1992. Physical, chemical and biological characteristics of the samples have been determined and are typical of secondary effluents, with a mean pH of about 7.5, total solids 1200 mg L⁻¹, suspended solids 45 mg L⁻¹, conductivity 2000 μS cm⁻¹, salinity 1 ppt, dissolved oxygen 2 mg L⁻¹, BOD₅ 45 mg L⁻¹, Kjeldahl-N 30 mg L⁻¹, NH₄,-N 25 mg L⁻¹, NO₃-N 4 mg L⁻¹, total P 10 mg L⁻¹, K 35 mg L⁻¹ and total coliforms of less than 10⁵ colonies 100 ml⁻¹.Water hyacinth plants have been stocked in the secondary settling pond as an integral part of the treatment plant so as to improve the quality of, as well as to retrieving and recycling nutrient elements from, the wastewater. The plants are periodically harvested to maintain an active growing crop. The growth rate, standing crop biomass, tissue nutrient composition, nutrient storage and accumulation rate of two growth cycles, one from February 25 to March 18 (mean temperature 17.6°C) and the other from 22 April to 12 May (24.8°C) are reported. The water hyacinth assumed a relatively high standing crop biomass of 10 kg m⁻² (5 to 6 t DM ha⁻¹), and growth rates of 48 and 225 g m⁻² day⁻¹, respectively, for the first and second growth period. Nutrient storage capacities were relatively high, at about 20, 7.5 and 16.5 g m⁻² for N, P and K, respectively. The nutrient composition was very high, reaching 5.42% for N, 1.97 for P, and 4.57 for K. Both the stem and lamina accumulated high levels of N, while the petiole had the highest level of P and K. Apart from nutrient removal, the water hyacinth also helped to decrease the suspended solids, BOD₅ value and total coliforms of the wastewater.It is concluded that water hyacinth improves the quality of wastewater in such small-scale sewage treatment plants and it is recommended that frequent harvests of water hyacinth would increase the treatment efficiency, especially during the active growing season with high temperatures coupled with intense solar radiation.     

Assessment of Future Climate Change Impact on Water Quality of Chungju Lake,South Korea,Using WASP Coupled with SWAT

This study is to evaluate the future potential impact of climate change on the water quality of Chungju Lake using the Water Quality Analysis Simulation Program (WASP). The lake has a storage capacity of 2.75 Gm³, maximum water surface of 65.7 km², and forest‐dominant watershed of 6,642 km². The impact on the lake from the watershed was evaluated by the Soil and Water Assessment Tool (SWAT). The WASP and SWAT were calibrated and validated using the monthly water temperatures from 1998 to 2003, lake water quality data (dissolved oxygen, total nitrogen [T‐N], total phosphorus [T‐P], and chlorophyll‐a [chl‐a]) and daily dam inflow, and monthly stream water quality (sediment, T‐N, and T‐P) data. For the future climate change scenario, the MIROC3.2 HiRes A1B was downscaled for 2020s, 2050s, and 2080s using the Change Factor statistical method. The 2080s temperature and precipitation showed an increase of +4.8°C and +34.4%, respectively, based on a 2000 baseline. For the 2080s watershed T‐N and T‐P loads of up to +87.3 and +19.6%, the 2080s lake T‐N and T‐P concentrations were projected to be 4.00 and 0.030 mg/l from 2.60 and 0.016 mg/l in 2000, respectively. The 2080s chl‐a concentration in the epilimnion and the maximum were 13.97 and 52.45 μg/l compared to 8.64 and 33.48 μg/l in 2000, respectively. The results show that the Chungju Lake will change from its mesotrophic state of 2000 to a eutrophic state by T‐P in the 2020s and by chl‐a in the 2080s. Editor's note: This paper is part of a featured series on Korean Hydrology. The series addresses the need for a new paradigm of river and watershed management for Korea due to climate and land use changes.     

Model prediction on the rise of pCO2 in uniform flows by leakage of CO2 purposefully stored under the seabed

A numerical study was conducted to predict pCO₂ change in the ocean on a continental shelf by the leakage of CO₂, which is originally stored in the aquifer under the seabed, in the case that a large fault connects the CO₂ reservoir and the seabed by an earthquake or other diastrophism. The leakage rate was set to be 6.025 × 10⁻⁴ kg/m²/sec from 2 m × 100 m fault band, which corresponds to 3800 t-CO₂/year, referring to the monitored seepage rate from an existing EOR field. The target space in this study was limited to the ocean above the seabed, the depth of which was 200 or 500 m. The computational domain was idealistically rectangular with the seabed fault-band perpendicular to the uniform flow. The CO₂ takes a form of bubbles or droplets, depending on the depth of water, and their behaviour and dissolution were numerically simulated during their rise in seawater flow. The advection–diffusion of dissolved CO₂ was also simulated. As a result, it was suggested that the leaked CO₂ droplets/bubbles all dissolve in the seawater before spouting up to the atmosphere, and that the increase in pCO₂ in the seawater was smaller than 500 μ atm.     

Nutrients and suspended solids in dry weather and storm flows from a tropical catchment with various proportions of rural and urban land use

The results of an investigation characterizing the nutrients and suspended solids contained in stormwater from Kranji Catchment in Singapore are reported in this paper. Stormwater samples were collected from 4 locations and analyzed for the following eleven analytes: TOC, DOC, TN, TDN, NH₄⁺, NO₂⁻ + NO₃⁻ (NO_x), TP, TDP, OP, SiO₂ and TSS. Stormwater was sampled from catchments with various proportions of rural and urban land use, including forested areas, grassed areas, agricultural and residential and commercial areas. The event mean concentrations (EMCs) of nutrients and TSS from sampling stations which have agricultural land use activities upstream were found to be higher. Comparison of site EMCs (SMCs) with published data showed that the SMCs of the nutrients and TSS are generally higher than SMCs reported for forested areas but lower than published SMCs for urban areas. Positive correlations (p < 5%) were found between loading and peak flow at locations most impacted by ubanisation or agricultural activities. Correlation between loading and rainfall variables was less distinct. EMC was found to correlate less with rainfall and flow variables compared to pollutant loading. Unlike loading, no consistent pattern exists linking EMC to any particular storm or flow variable in any of the catchments. Lastly, positive correlations were obtained between the particulate forms of nitrogen and phosphorus and TSS.     

Understanding Stream Geomorphic State in Relation to Ecological Integrity: Evidence Using Habitat Assessments and Macroinvertebrates

Scientists have long assumed that the physical structure and condition of stream and river channels have pervasive effects on biological communities and processes, but specific tests are few. To investigate the influence of the stream-reach geomorphic state on in-stream habitat and aquatic macroinvertebrate communities, we compared measures of habitat conditions and macroinvertebrate community composition between stable and unstable stream reaches in a paired-study design. We also explored potential associations between these ecological measures and individual geomorphic characteristics and channel adjustment processes (degradation, aggradation, overwidening, and change in planform). We found that habitat quality and heterogeneity were closely tied to stream stability, with geomorphically stable reaches supporting better habitat than unstable reaches. Geomorphic and habitat assessment scores were highly correlated (r = 0.624, P < 0.006, n = 18). Stable reaches did not support significantly greater macroinvertebrate densities than unstable reaches (t = −0.415, P > 0.689, df = 8). However, the percent of the macroinvertebrate community in the Ephemeroptera, Plecoptera, and Trichoptera (EPT) taxa was significantly correlated with the overall habitat assessment scores as well as with individual measures of geomorphic condition and habitat quality. While there is a clear need for more work in classifying and quantifying the responses of aquatic and aquatic-dependent biota to various geomorphic states and processes, this study provides solid preliminary evidence that macroinvertebrate communities are affected by the geomorphic condition of the stream reaches they inhabit and that geomorphic assessment approaches can be used as a tool for evaluating ecological integrity.     

Monitoring the volume and lateral spread of disposed sediments by acoustic methods, Oslo Harbor, Norway

Acoustic equipment, including interferometric sonar and parametric sub-bottom profiler, have been used to determine the volume and lateral spread of dredged sediments disposed in the natural submarine depression in the Bekkelag Basin, inner Oslofjord since the beginning of the Oslo Harbor remediation project in 2006. This natural depression is used as a subaqueous confined disposal facility (CDF). Calculation of the volume of disposed sediments in the CDF is based on elevation change, derived from two high-resolution bathymetric datasets obtained in 2004, i.e. before the onset of the remediation project, and in April 2008. Seismic profiles across the CDF have been used to estimate the settlement of the original seabed, caused by loading-induced dewatering and compaction of the seabed sediments under the disposed masses.Detailed bathymetry and backscatter data demonstrate the lateral spread of disposed sediments within a well-confined area covering ca. 195,000 m². The sea bottom within this area is distinctly softer than the surrounding seabed as shown by very low acoustic backscatter amplitude, signifying a very loose surface character of the disposed sediments. The thickness of the disposed sediments reaches 6 m the deepest part of the original depression. The volume calculation of the disposed sediments in the CDF, based solely on bathymetry data, gives a value of ca. 310,000–320,000 m³. Settlement of the original seabed as a result of loading has been estimated to be 30 cm at 5 m thickness of the disposed sediments. Under the condition that the settlement rate is linearly correlated to the thickness of disposed sediments, the settlement corrected volume of disposed sediments is ca. 330,000–340,000 m³. Presented results demonstrate high accuracy and good reproducibility of acoustic seafloor data, and indicate a great potential of such methods as monitoring tools in environmental projects that involve dredging and subaqueous disposal.     

160 h of chemical-looping combustion in a 10 kW reactor system with a NiO-based oxygen carrier

Chemical-looping combustion, CLC, is a technology with inherent separation of the greenhouse gas CO₂. The technique uses an oxygen carrier made up of particulate metal oxide to transfer oxygen from combustion air to fuel. In this work, an oxygen carrier consisting of 60% NiO and 40% NiAl₂O₄ was used in a 10 kW CLC reactor system for 160 h of operation with fuel. The first 3 h of fuel operation excepted, the test series was accomplished with the same batch of oxygen carrier particles. The fuel used in the experiments was natural gas, and a fuel conversion to CO₂ of approximately 99% was accomplished. Combustion conditions were very stable during the test period, except for the operation at sub-stoichiometric conditions. It was shown that the methane fraction in the fuel reactor exit gas was dependent upon the rate of solids circulation, with higher circulation leading to more unconverted methane. The carbon monoxide fraction was found to follow the thermodynamical equilibrium for all investigated fuel reactor temperatures, 660–950 °C. Thermal analysis of the fuel reactor at stable conditions enabled calculation of the particle circulation which was found to be approximately 4 kg/s, MW. The loss of fines, i.e. the amount of elutriated oxygen carrier particles with diameter <45 μm, decreased during the entire test period. After 160 h of operation the fractional loss of fines was 0.00022 h⁻¹, corresponding to a particle life time of 4500 h.     

Utilization of pulp and paper industrial wastes to remove heavy metals from metal finishing wastewater

Two pulp and paper industrial wastes, lime mud (LM) and recovery boiler ash (RB), have low moisture contents, low heavy metal contaminations and contain various carbonate compounds which contribute to a high pH. Metal finishing wastewater (MF-WW) has a low pH, high levels of TDS and high contaminations from Cr, Cu, Pb and Zn. The heavy metals from MF-WW were removed by sorption and precipitation mechanisms. LM gave better results in removing heavy metals from MF-WW than RB. At a reaction time of 45 min, the maximum removal efficiencies for Cr (93%) and Cu (99%) were obtained at 110 g L⁻¹ of LM, but at 80 g L⁻¹ for Pb (96%) and Zn (99%). Treatment with LM gives a higher sludge volume than with RB. However, the leachability of heavy metals from LM is lower. Leachability of heavy metals in the sediment for all selected treatment conditions is within government standards.