火电厂水平衡优化研究

通过对火电厂水系统供水、需水特性的分析，建立了水系统优化的数学模型，对不同供水、需水条件下的火电厂水系统水平衡进行了优化。模型的优化结果对火电厂水系统的设计和运行管理有一定指导作用。     

徐州电厂正压浓相气力输灰系统

详细介绍了徐州发电厂5号炉正压浓相气力输灰系统的结构及其特点。自该系统投运以来，运行情况良好。各项技术经济指标均达到了设计要求。     

PLC在除尘系统自控上的应用

本文介绍了ＰＬＣ在电炉除尘控制系统中应用的一个实例，采用ＰＬＣ后将提高电炉尘系统的整体性，可靠性，维护性，降低运行成本。     

二矿选煤厂煤泥水处理系统工艺研究与改造

二矿选煤厂跳汰洗选系统自1992年7月投产以来，煤泥水处理运行就极不正常，各工艺环节指标一直未能达到设计要求，直接影响洗精煤的质、数量指标的提高。从1992年至2000年间经历了高频筛代替园盘过滤机等一系列技术改造，虽取得一定效果，均不十分理想。洗水浓度仍是影响二矿选煤厂洗精煤达产的最大障碍。截至2000年底，二矿洗精煤产量一直在60—70万吨左右徘徊，而且质量指标稳定性差。因此，我厂与唐山煤科院协作对二矿选煤厂煤泥水处理系统进行了研究及工艺改造。工程于2000年10月31日开工，于2001年元月18日竣工投产，运行一年来，效果十分明显。     

烟气排放连续监测系统在420t/h燃煤锅炉上的应用

铜陵发电厂在1台420t／h燃煤锅炉上应用烟气排放连续监测系统(CEMS)，对锅炉烟气SO2、NOx、颗粒物及相关烟气参数进行在线监测。该系统工作可靠，安装简便，无需专人值守，运行维护量较小，性能指标通过了环境监测部门的标定测试，达到了国家环保总局行业标准的要求。同时，该系统具有实时数据传送功能，提高了环境监测工作的信息化管理水平。     

上海五钢（集团）有限公司第三炼钢分厂100t电炉除尘系统介绍

上钢五厂１００ｔ电炉除尘系统采用第二孔＋密闭罩和屋顶罩切除＋ＬＦ炉的排烟方式，长袋低压脉冲除尘器净化工艺，除尘系统于１９９７年３月建成，目前运行情况良好。     

布袋式除尘器在电厂输煤系统上的应用

针对胜利电厂皮带输煤系统粉尘浓度高、污染环境、影响职工身体健康的问题，用布袋式除尘器替代原有的静电除尘器，并对布袋除尘器辅助系统进行了多处改进和完善，提高了运行的可靠性。投运后粉尘质量浓度由原来的18．3mg／m^3降低至1．68mg／m^3，除尘效率达到了98％以上。     

影响脱硫系统运行经济性的因素及改进措施

分析了原烟气成分、脱硫剂石灰石等对脱硫系统运行经济性的影响,探讨循环泵组合投运和工艺参数控制对运行经济性的影响规律,提出改进湿法脱硫系统运行经济性的措施,为脱硫装置的节能、经济运行提供参考。     

湿壁塔烟气脱硫系统的研究

燃煤锅炉的烟气脱硫(FGD)技术，是当今世界上减少二氧化硫排放的主要技术措施。在FGD技术中石灰石-湿法烟气脱硫(WFGD)是占主导地位的方式方法。传统的石灰石湿脱硫通常采用气液逆流式、鼓泡式、气液冲击式、文丘里式等气液接触方式的系统，这些系统在运行中存在阻力较大，耗能高，易结垢或脱硫效果不理想等缺点。针对这种特点，我们设计了一种以管状或栅板为填料的并流式湿壁塔脱硫系统，研究结果表明，这种系统不仅具有较低的系统阻力，同时系统还拥有较高的脱硫率。     

干式洗涤系统在化工环保中的应用

文中介绍了使用于化工厂废弃物焚烧炉烟道气处理的干式洗涤系统,讨论了该系统的主要部件和设计参数,并对干式洗涤系统的投资和运行费用与传统的湿式系统进行了比较。     

Distribution of Cd,Ck, Pb and Zn in Soil and Vegetation Compartments in Stands of Five Boreal Tree Species in N.E. Sweden

Concentrations and total quantity of cadmium (Cd), cupper (Cu),lead (Pb) and zink (Zn) were determined in biomass and soil compartments in a replicated tree species experiment with 27-yr-old stands growing on former farmland in N.E. Sweden. Sequentialextractions of soil samples were performed in order to estimate the exchangeable and an organically bound fraction of each element. The tree species included were Picea abies (L.)H. Karst., Pinus sylvestris L., Pinus contorta Dougl., Larix sibirica Ledeb., and Betula pendula Roth.Tree species influenced the rate of removal of Cu, Pb and Zn incase of stemwood harvesting, and of Cd, Cu and Zn in the case ofwhole-tree harvesting. B. pendula and P. abies had higher quantities and average concentrations of Zn in the biomass. For all species, >50% of the Zn in the stems was found in the bark. P. abies and L. sibirica had higher quantities of Cu in the biomass than the other species.P. abies and P. contorta had high quantities of Cd inthe biomass in relation to the other species. Branches and stembark contained high concentrations of Cd and Pb in relation to foliage and stemwood. Dead branches had especially high concentrations of Pb. The high accumulation rate of Zn in thebiomass of B. pendula was related to a low exchangeable amount of Zn in the A horizon. In the superficial centimeters ofthe A horizon, a depletion similar to that found for Zn was detected for Cu, whereas for Cd and Pb, no correlations were found between quantities of elements in the trees and element pools in the soil.     

Starch-plastic materials—Preparation,physical properties,and biodegradability (a review of recent USDA research)

Recent starch-plastic research at the National Center for Agricultural Utilization Research is reviewed and related worldwide efforts are noted. Properties of starch that influence its formulation and performance in plastics are discussed. Methods are given for preparation of starch-poly(methyl acrylate) graft copolymer, starch-poly(ethylene-co-acrylic acid), and starch-poly(ethylene-co-acrylic acid)-polyethylene plastics. Their physical properties are discussed, as is degradability by enzymes or amylolytic organisms from soil, ponds, and streams.The mention of firm names or trade products does not imply that they are endorsed or recommended by the U.S. Department of Agriculture over other firms or similar products not mentioned.     

Application of Cellulose Microfibrils in Polymer Nanocomposites

Cellulose microfibrils obtained by the acid hydrolysis of cellulose fibers were added at low concentrations (2–10% w/w) to polymer gels and films as reinforcing agents. Significant changes in mechanical properties, especially maximum load and tensile strength, were obtained for fibrils derived from several cellulosic sources, including cotton, softwood, and bacterial cellulose. For extruded starch plastics, the addition of cotton-derived microfibrils at 10.3% (w/w) concentration increased Young’s modulus by 5-fold relative to a control sample with no cellulose reinforcement. Preliminary data suggests that shear alignment significantly improves tensile strength. Addition of microfibrils does not always change mechanical properties in a predictable direction. Whereas tensile strength and modulus were shown to increase during addition of microfibrils to an extruded starch thermoplastic and a cast latex film, these parameters decreased when microfibrils were added to a starch–pectin blend, implying that complex interactions are involved in the application of these reinforcing agents.     

四氮唑废水处理工艺设计

高浓度、高盐分的四氮唑生产废水通过三效蒸发浓缩,馏出液经铁炭氧微电解和混凝预处理,再采用水解酸化一接触氧化一反应二沉主体组合工艺进行处理。研究了该工艺所需构筑物和设备的设计与选型。该工艺在正常运行条件下,处理后出水pH6～9,COD 302mg／L,BOD5 108mg／L,SS30mg／L,色度36倍,水质达到GB8978--1996（污水综合排放标准》三级标准。     

Bioassessment of silvicultural impacts in streams and wetlands of the Eastern United States

Bioassessment is a useful tool to determine the impact of logging practices on the biological integrity of streams and wetlands. Measuring biota directly has an intuitive appeal for impact assessment, and biota can be superior indicators to physical or chemical characteristics because they can reflect cumulative impacts over time. Logging can affect stream and wetland biota by increasing sedimentation rates, altering hydrologic, thermal, and chemical regimes, and changing the base of food webs. Biotic impacts of logging on streams compared to wetlands probably differ, and in this paper we review some of those differences. In streams, invertebrates, fishes, amphibians, algae, and macrophytes have been used as indicators of logging impacts. In wetlands, bioassessment is just beginning to be used, and plants and birds are the most promising indicator taxa. Various best management practices (BMPs) have been developed to reduce the impacts of logging on stream and wetland biota, and we review quantitative studies that have evaluated the efficacy of some of these techniques in streams and wetlands in the eastern United States. Remarkably few studies that address the overall efficacy of BMPs in limiting biotic changes in streams and wetlands after BMP implementation have been published in scientific journals, although some work exists in reports or is unpublished. We review these works, and compile conclusions about BMP efficacy for biota from this body of research.     

Characterization of air emissions and residual ash from open burning of electronic wastes during simulated rudimentary recycling operations

Air emissions and residual ash samples were collected and analyzed during experiments of open, uncontrolled combustion of electronic waste (e-waste), simulating practices associated with rudimentary e-waste recycling operations. Circuit boards and insulated wires were handled separately to simulate processes associated with metal recovery. The average emissions of polychlorinated dibenzodioxins and dibenzofurans (PCDD/PCDFs) were 92 ng toxic equivalency (TEQ)/kg [n = 2, relative standard deviation (RSD) = 98%] and 11 900 ng TEQ/kg (n = 3, RSD = 50%) of the initial mass of the circuit boards and insulated wire, respectively. The value for the insulated wire is about 100 times higher than that for backyard barrel burning of domestic waste. The emission concentrations of polybrominated dibenzodioxins and dibenzofurans (PBDD/PBDFs) from the combustion of circuit boards were 100 times higher than for their polychlorinated counterparts. Particulate matter (PM) sampling of the fly ash emissions indicated PM emission factors of approximately 15 and 17 g/kg of the initial mass for the circuit boards and insulated wire, respectively. Fly ash samples from both types of e-waste contained considerable amounts of several metallic elements and halogens; lead concentrations were more than 200 times the United States regulatory limits for municipal waste combustors and 20 times those for secondary lead smelters. Leaching tests of the residual bottom ash showed that lead concentrations exceeded U.S. Environmental Protection Agency landfill limits, designating this ash as a hazardous waste.     

Does Soil Acidification Affect Spruce Needle Chemical Composition and Tree Growth?

In 1994, a large survey of soil chemistry was undertaken in thecounty of Värmland in central Sweden (Lundström et al., 1998).The southern part of the county was affected by soilacidification whereas there were no such indications in thenorthern part. To investigate the influence of soil chemistryon the trees at the specific sites, the survey was continued byan analysis of needle chemistry (Norway spruce) which wasundertaken at 150 of the 180 sites, and of tree growth at 65 ofthe 180 sites. Growth was expressed as a ratio between expectedgrowth, estimated with a national, empirical growth model, andthe growth observed in the field. In statistical analyses,using rank correlation, PCA and PLS, there were only weakindications of an influence of soil chemistry on needlechemistry and on tree growth. A moderate correlation betweennitrogen and sulphur in needles was found, which wasinterpreted as an effect of deposition and of processes in thetree canopy. No obvious regional pattern of the growth ratiowas found, in contrast to the clear pattern of soilacidification. The statistical analysis could not with anycertainty point out any of the soil chemistry variables asespecially important for the tree growth ratio.     

Solubility and Potential Mobility of Heavy Metals in Two Contaminated Urban Soils from Stockholm,Sweden

The solubility and potential mobility of heavy metals (Cd, Cu,Hg, Pb and Zn) in two urban soils were studied by sequential andleaching extractions (rainwater). Compared to rural (arable) soils on similar parent material, the urban soils were highlycontaminated with Hg and Pb and to a lesser extent also with Cd,Cu and Zn. Metal concentrations in rainwater leachates were related to sequential extractions and metal levels reported fromStockholm groundwater. Cadmium and Zn in the soils were mainly recovered in easily extractable fractions, whereas Cu and Pb were complex bound. Concentrations of Pb in the residual fractionwere between two- and eightfold those in arable soils, indicatingthat the sequential extraction scheme did not reflect the solidphases affected by anthropogenic inputs. Cadmium and Zn conc. inthe rainwater leachates were within the range detected in Stockholm groundwater, while Cu and Pb conc. were higher, whichsuggests that Cu and Pb released from the surface soil were immobilised in deeper soil layers. In a soil highly contaminatedwith Hg, the Hg conc. in the leachate was above the median concentration, but still 50 times lower than the max concentration found in groundwater, indicating the possibilityof other sources. In conclusion, it proved difficult to quantitatively predict the mobility of metals in soils by sequential extractions.     

Biodegradation of Injection Molded Starch-Poly (3-hydroxybutyrate-co-3-hydroxyvalerate) Blends in a Natural Compost Environment

Injection molded specimens were prepared by blending poly (hydroxybutyrate-co-valerate) (PHBV) with cornstarch. Blended formulations incorporated 30% or 50% starch in the presence or absence of poly-(ethylene oxide) (PEO), which enhances the adherence of starch granules to PHBV. These formulations were evaluated for their biodegradability in natural compost by measuring changes in physical and chemical properties over a period of 125 days. The degradation of plastic material, as evidenced by weight loss and deterioration in tensile properties, correlated with the amount of starch present in the blends (neat PHBV < 30% starch < 50% starch). Incorporation of PEO into starch-PHBV blends had little or no effect on the rate of weight loss. Starch in blends degraded faster than PHBV and it accelerated PHBV degradation. Also, PHBV did not retard starch degradation. After 125 days of exposure to compost, neat PHBV lost 7% of its weight (0.056% weight loss/day), while the PHBV component of a 50% starch blend lost 41% of its weight (0.328% weight loss/day). PHB and PHV moieties within the copolymer degraded at similar rates, regardless of the presence of starch, as determined by ¹H-NMR spectroscopy. GPC analyses revealed that, while the number average molecular weight (Mn) of PHBV in all exposed samples decreased, there was no significant difference in this decrease between neat PHBV as opposed to PHBV blended with starch. SEM showed homogeneously distributed starch granules embedded in a PHBV matrix, typical of a filler material. Starch granules were rapidly depleted during exposure to compost, increasing the surface area of the PHBV matrix.     

Effects of Nitrogen Deposition on Bryophyte Species Composition of Calcareous Grasslands

Regular additions of NH₄NO₃ (35–140 kg N ha⁻¹ yr⁻¹) and (NH₄)₂SO₄ (140 kg N ha⁻¹ yr⁻¹) to a calcareous grassland in northern England over a period of 12 years have resulted in a decline in the frequency of the indigenous bryophyte species and the establishment of non-indigenous calcifuge species, with implications for the structure and composition of this calcareous bryophyte community. The lowest NH₄NO₃ additions of 35 kg N ha⁻¹ yr⁻¹ produced significant declines in frequency of Hypnum cupressiforme, Campylium chrysophyllum, and Calliergon cuspidatum. Significant reductions in frequency at higher NH₄NO₃ application rates were recorded for Pseudoscleropodium purum, Ctenidum molluscum, and Dicranum scoparium. The highest NH₄NO₃ and (NH₄)₂SO₄ additions provided conditions conducive for the establishment of two typical calcifuges – Polytrichum spp. and Campylopus introflexus, respectively. Substrate-surface pH measurements showed a dose-related reduction in pH with increasing NH₄NO₃ deposition rates of 1.6 pH units between the control and highest deposition rate, and a further significant fall in pH, of >1 pH unit, between the NH₄NO₃ and (NH₄)₂SO₄ treatments. These results suggest that indigenous bryophyte composition may be at risk from nitrogen deposition rates of 35 kg N ha⁻¹ yr⁻¹ or less. These effects are of particular concern for rare or endangered species of low frequency.