利用氮、氧稳定同位素识别地下水硝酸盐污染源研究进展

氮污染特别是地下水硝酸盐污染已成为一个相当普遍而重要的环境问题。地下水硝酸盐污染与人类健康和环境安全密切相关。为控制地下水硝酸盐污染,最根本的解决办法就是找到硝酸盐的来源,减少硝态氮向地下水的输送。由于不同来源的硝酸盐具有不同的氮、氧同位素组成,人们利用NO3-中δ15N和δ18O开展了硝酸盐污染源识别研究。本文综述了利用氮、氧同位素识别地下水硝酸盐污染源及定量硝酸盐污染源输入的研究进展及目前存在的问题,并提出几个值得重视的研究方向。     

The Role of Headwater Wetlands in Altering Streamflow and Chemistry in a Maine,USA Catchment1

Morley, Terry R., Andrew S. Reeve, and Aram J.K. Calhoun, 2011. The Role of Headwater Wetlands in Altering Streamflow and Chemistry in a Maine, USA Catchment. Journal of the American Water Resources Association (JAWRA) 1‐13. DOI: 10.1111/j.1752‐1688.2011.00519.x Abstract: Headwater wetlands, including hillside seeps, may contribute to downstream systems disproportionately to their relatively small size. We quantified the hydrology and chemistry of headwater wetlands in a central Maine, USA, catchment from 2003 to 2005 to determine their role in maintaining headwater streamflow and in affecting stream chemistry. A few of these headwater wetlands, commonly referred to as “seeps,” were characterized by relatively high groundwater discharge. During summer base flow, seeps were the primary source of surface water to the stream, contributing between 40 and 80% of stream water. Comparisons of groundwater and surface water dominant ion chemistry revealed only slight differences at the bedrock interface; however, significant changes occurred at the shallow groundwater‐surface water interface where we found decreases in total and individual cation concentrations with decreasing depth. Seep outflows significantly increased total cation and calcium concentrations in streams. Outflows at two seeps produced relatively high nitrate concentrations (88 ± 15 and 93 ± 15 μg/l respectively), yet did not correspond to higher nitrate in stream water below seep outflows (2 ± 1 μg/l). We demonstrate that small wetlands (< 1,335 m²) can contribute to headwater stream processes by linking groundwater and surface‐water systems, increasing the duration and magnitude of stream discharge, and by affecting stream chemistry, particularly during periods of base flow.     

A GEOGRAPHIC INFORMATION SYSTEM PROCEDURE TO QUANTIFY DRAINAGE-BASIN CHARACTERISTICS1

ABSTRACT: The Basin Characteristics System (BCS) has been developed to quantify characteristics of a drainage basin. The first of four main BCS processing steps creates four geographic information system (GIS) digital maps representing the drainage divide, the drainage network, elevation contours, and the basin length. The drainage divide and basin length are manually digitized from 1:250,000-scale topographic maps. The drainage network is extracted using GIS software from 1:100,000-scale digital line graph data. The elevation contours are generated using GIS software from 1:250,000-scale digital elevation model data. The second and third steps use software developed to assign attributes to specific features in three of the four digital maps and analyze the four maps to quantify 24 morphometric basin characteristics. The fourth step quantifies two climatic characteristics from digitized State maps of precipitation data. Compared to manual methods of measurement, the BCS provides a reduction in the time required to quantify the 26 basin characteristics. Comparison tests indicate the BCS measurements are not significantly different from manual topographic-map measurements for 11 of 12 primary drainage-basin characteristics. Tests indicate the BCS significantly underestimates basin slope. Comparison-measurement differences for basin slope, main channel slope, and basin relief appear to be due to limitations in the digital elevation model data.     

Effects of Groundwater-Flow Paths On Nitrate Concentrations Across Two Riparian Forest Corridors1

Speiran, Gary K., 2010. Effects of Groundwater-Flow Paths on Nitrate Concentrations Across Two Riparian Forest Corridors. Journal of the American Water Resources Association (JAWRA) 46(2):246-260. DOI: 10.1111/j.1752-1688.2010.00427.x Abstract: Groundwater levels, apparent age, and chemistry from field sites and groundwater-flow modeling of hypothetical aquifers collectively indicate that groundwater-flow paths contribute to differences in nitrate concentrations across riparian corridors. At sites in Virginia (one coastal and one Piedmont), lowland forested wetlands separate upland fields from nearby surface waters (an estuary and a stream). At the coastal site, nitrate concentrations near the water table decreased from more than 10 mg/l beneath fields to 2 mg/l beneath a riparian forest buffer because recharge through the buffer forced water with concentrations greater than 5 mg/l to flow deeper beneath the buffer. Diurnal changes in groundwater levels up to 0.25 meters at the coastal site reflect flow from the water table into unsaturated soil where roots remove water and nitrate dissolved in it. Decreases in aquifer thickness caused by declines in the water table and decreases in horizontal hydraulic gradients from the uplands to the wetlands indicate that more than 95% of the groundwater discharged to the wetlands. Such discharge through organic soil can reduce nitrate concentrations by denitrification. Model simulations are consistent with field results, showing downward flow approaching toe slopes and surface waters to which groundwater discharges. These effects show the importance of buffer placement over use of fixed-width, streamside buffers to control nitrate concentrations.     

Estimating Watershed Level Nonagricultural Pesticide Use From Golf Courses Using Geospatial Methods1

Abstract: Limited information exists on pesticide use for nonagricultural purposes, making it difficult to estimate pesticide loadings from nonagricultural sources to surface water and to conduct environmental risk assessments. A method was developed to estimate the amount of pesticide use on recreational turf grasses, specifically golf course turf grasses, for watersheds located throughout the conterminous United States (U.S.). The approach estimates pesticide use: (1) based on the area of recreational turf grasses (used as a surrogate for turf associated with golf courses) within the watershed, which was derived from maps of land cover, and (2) from data on the location and average treatable area of golf courses. The area of golf course turf grasses determined from these two methods was used to calculate the percentage of each watershed planted in golf course turf grass (percent crop area, or PCA). Turf‐grass PCAs derived from the two methods were used with recommended application rates provided on pesticide labels to estimate total pesticide use on recreational turf within 1,606 watersheds associated with surface‐water sources of drinking water. These pesticide use estimates made from label rates and PCAs were compared to use estimates from industry sales data on the amount of each pesticide sold for use within the watershed. The PCAs derived from the land‐cover data had an average value of 0.4% of a watershed with minimum of 0.01% and a maximum of 9.8%, whereas the PCA values that are based on the number of golf courses in a watershed had an average of 0.3% of a watershed with a minimum of <0.01% and a maximum of 14.2%. Both the land‐cover method and the number of golf courses method produced similar PCA distributions, suggesting that either technique may be used to provide a PCA estimate for recreational turf. The average and maximum PCAs generally correlated to watershed size, with the highest PCAs estimated for small watersheds. Using watershed specific PCAs, combined with label rates, resulted in greater than two orders of magnitude over‐estimation of the pesticide use compared to estimates from sales data.     

A Quantitative Method for Delineating Regions: An Example for the Western Corn Belt Plains Ecoregion of the USA

/ A method was developed to systematically delineate boundaries forecological classification of regions. The process entailed the use ofsmall-scale digital data to quantify spatial concordance among environmentalattribute data sets. The data sets were grouped into spatially related themesusing cluster analysis and multidimensional scaling. Selected data sets werethen used either individually or collectively to divide the study area intosubregions that exhibited different environmental attributes. The method wasapplied to a previously defined ecological unit, the western Corn Belt of thecentral United States. The results showed that the portion of the study areawith intensive corn and soybean production was identifiable using each of thethree input data sets selected for partitioning (soil associations; AVHRRremote-sensing imagery; and a combined data set of landform, forest, andsoils data). The classification of other portions of the study area washighly dependent on the type and scale of the input data. The systematicmethodology used here offers advantages over other methods for identifyingecological regions in that the results from the systematic approach can bereproduced, the boundaries between ecological units can be revised based onnew or more accurate data, important ecological processes are explicitlychosen to delineate boundaries, and transition zones between regions can bequantified.KEY WORDS: Ecoregions; Spatial analysis; Corn Belt; Iowa; GIS;Regionalization     

Analytical Solutions to the Linearized Boussinesq Equation for Assessing the Effects of Recharge on Aquifer Discharge1

Boggs, Kevin G., Robert W. Van Kirk, Gary S. Johnson, Jerry P. Fairley, and P. Steve Porter, 2010. Analytical Solutions to the Linearized Boussinesq Equation for Assessing the Effects of Recharge on Aquifer Discharge. Journal of the American Water Resources Association (JAWRA) 46(6):1116–1132. DOI: 10.1111/j.1752-1688.2010.00479.x Abstract: There is a need to develop a general understanding of how variations in aquifer recharge are reflected in discharge. Analytical solutions to the linearized Boussinesq equation governing flow in an unconfined aquifer provide a unified mathematical framework to quantify relationships among lag time, attenuation and distance between aquifer recharge and discharge and the effect of an up-gradient no-flow boundary. We applied this framework to three types of recharge: (1) instantaneous, (2) periodic, and (3) constant rate for a finite duration. When the temporal scale of recharge exceeds the diffusive aquifer time scale, recharge will be reflected in discharge quickly and with little attenuation. When aquifer time scale is large, most recharge events are shorter in scale than that of the aquifer, resulting in large attenuation. Attenuation is more sensitive to boundary effects than lag time, and boundary effects increase as recharge time scale increases. Boundary effects can often be ignored when the recharge source is farther than 1/3 of the domain length away from the no-flow boundary. We illustrate analytical results with application to the economically critical Eastern Snake River Plain Aquifer in Idaho. In this aquifer, detectable annual and decadal cycles in discharge can result from recharge no farther than 20 and 60 km away from the discharge point, respectively. The effects of more distant, long-term recharge can be detected only after a time lag of several decades.     

GROUNDWATER ZONING IN WATER RESOURCES MANAGEMENT1

In today's society the planned management of groundwater resources has played an increasingly greater role. One means of insuring the protection of groundwater quantity and quality is a regional zoning of groundwater resources. Regional zoning means to classify a given region with regard to hydrogeological characteristics and to evaluate and determine the possible use of each zone. The necessary assumption is the appropriate knowledge of geological structure (compiled in a geological map) and of hydrogeological conditions (compiled in a hydrogeological map). The basis for subdivision is a hydrogeological unit distinguished and delineated on the basis of lithological, stratigraphical, structural, and hydrogeological characteristics. It should have its own distinct hydrological system. The hydrogeological region is the basic unit. Regions may be grouped into larger units: hydrogeological provinces and realms. The subdivision of regions into hydrogeological zones, or subzones when applicable, forms the basis for a groundwater development plan.     

INTERPRETATION OF THE DUAL PROGRAM FOR OPTIMAL GROUNDWATER HYDRAULIC CONTROL1

ABSTRACT: Optimization formulations for hydraulic control that take the form of linear programs possess a corresponding dual linear program. The economic and physical interpretations of the dual linear program are examined for formulations in which hydraulic head in groundwater systems is constiained. In each case it is shown that the dual linear program has a physically meaningful interpretation. For a hydraulic gradient control formulation used for remedial analysis it is shown that the dual variable can be interpreted as the remedial benefit due to each gradient control constraint. The dual linear program maximizes the remedial benefit. The value of the dual variable can be used to compute such useful properties as the total remedial benefit of pumping at a specific location. For a formulation that optimizes aquifer yield while constraining drawdown the dual variable can be used to measure the total cost of drawdown capacity consumption per unit of pumping at a specific location. The dual program minimizes the cost of drawdown capacity consumption. By examining the meaning of the dual linear program an alternate statement of the problem under study is revealed. Quantities arising from the dual program add to the value of the optimization approach. Significant new information can be derived from existing linear optimization formulations with minimal additional computational effort.