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1.
A mathematical model is proposed for estimating daily contaminant intake by multiplying three variables related to consumption, from three independent consumption surveys. With lead as an example, the product of the three variables typified the mean and increasing intakes among infants 0–5 months, children 6–23 months and children 2–5 yr of age. Limitations implicit to the approach and the variables were discussed. Daily mean lead intake increased between the three respective age groups, 15, 59, and 82 g lead. When intake was expressed on a body weight basis (g lead/kg BW), the rate of daily lead exposure for children 6 to 23 months (6.1) and 2 to 5 yr (5.6) of age was similar but both were higher than the rate for the 0–5 month infant (2.7 g kg-1 BW). The 90th percentile daily dietary lead intake for 0–5 month infants was double their mean intake and for children 6 months to 5 yr was one and a half times their corresponding mean intakes. Food sources which contributed to the daily lead intake of the infant differed from those for the two groups of older children.  相似文献   

2.
Substantial amounts of NOx (146 000 t/y) and total hydrocarbons (294 000 t/y) are released to the marine atmosphere by the large number of oil and gas operations over Federal waters of the Gulf of Mexico (GOM). Under appropriate meteorological conditions these emissions react to form ozone (0–54 g/m3 over-water) which can affect the marine environment. Using a dry deposition model, this work examines the amount of ozone derived from oil and gas offshore operations and deposited in the sea surface of the Gulf of Mexico, and assesses its impact on the neuston of the sea-surface microlayer. Surface integrated estimates of ozone deposited from oil and gas operations over the sea surface ranges from 400 kg to 1800 kg which results in sea surface concentrations of 15 g/m3. This estimate and the actual toxic ozone levels suggest no acute, toxic impacts to the neuston. However, indirect effects may occur through changes to the pelagic foodwebs and organic carbon pathways. Another potential pathway for ozone impacting the environment is through the production of bromate. Based on the concentrations and time scales (11–139 days) only sublethal effects appear to occur, but uncertainties associated with this assessment need to be further studied. From an ecological perspective, the environmental impacts and risks of NOx and VOC discharges from offshore platforms need to be assessed for neuston and other components of the marine ecosystem.  相似文献   

3.
The treated water at the outlet oftreatment plants and representative servicereservoirs of Mumbai city have been evaluatedfor trihalomethane formation potential in1995–1996. Chloroform, dichlorobromomethane,chlorodibromomethane and bromoform have beenmonitored during monsoon, winter and summer.The levels of chloroform are found above theregulated WHO guideline value of 200 g L-1 in final water during postmonsoon atGhatkopar (226 g L-1), Malbar (210.3 g L-1) and Tulsi (231.26 g L-1).  相似文献   

4.
Distribution of heavy metals in plants and fish of the Yamuna river (India)   总被引:2,自引:0,他引:2  
The distribution of cadmium (Cd), cobalt (Co), chromium (Cr), copper (Cu), iron (Fe), manganese (Mn), nickel (Ni), lead (Pb) and zinc (Zn) in the plants and fish of Yamuna river from Delhi to Allahabad, a distance of about 840 km, at five sampling stations was determined in the year 1981. The results have shown wide variations in the heavy metal levels from one sampling station to the other. The concentrations of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, and Zn in the plants (Eicchornia crassipes) were found to be 0.02–0.12, 2.7–21.3, 4.6–64.8, 9.8–114.0, 193.0–1835.0, 380.0–1443.0, 4.4–83.0, 4.8–30.2, and 22.1–356.5 g g-1 respectively whereas in the fish (Heteropnuestes fossilis) were found to be ND-0.40, 2.3–13.7, 3.7–26.9, 8.33–58.1, 278.3–1108.0, 81.3–213.8, 2.8–32.7, 1.4–12.8 and 101.8–364.8 gg-1 respectively on dry weight basis.  相似文献   

5.
Residues of organochlorines and organophosphates were determined by gas chromatography in water and sediment from 26 locations in 17 major rivers, 7 natural springs and 13 wells across Jamaica. Samples were collected on only one occasion between May and July, 1994. Residues of endosulfan were detected in all but three rivers; -endosulfan in 15 samples of sediment (0.9–108.1, mean = 28.93, S.E. = 7.198 g kg-1) and 13 of water (0.01–0.35, mean = 0.11, S.E. = 0.035 g L-1), -endosulfan in 5 sediment (15.29–49.35, mean = 30.56, S.E. = 7.132 g kg-1) and 12 water (0.05–0.31, mean = 0.14, S.E. = 0.031 g L-1) samples, and endosulfan sulphate in waters of three rivers (0.003–0.244 g L-1). Chlorpyrifos was present in 9 sediment (0.423-135.2, mean = 18.38, S.E. = 10.699 g kg-1) and two water (0.001–0.022 g L-1) samples, diazinon and ethoprophos in the sediment of one river each. Mean levels (g L-1) of and isomers and sulphate of endosulfan were 0.16 (S.E. = 0.057), 0.12 (S.E. = 0.036) and 0.15 (S.E. = 0.089), respectively, in four of the seven springs and 0.23 (S.E. = 0.052), 0.11 (S.E. = 0.029) and 0.26 (S.E. = 0.088), respectively, in seven of the thirteen wells monitored.  相似文献   

6.
Studies on marine sediments are extremely important since they act as ultimate sink of anthropogenic pollutants. The present study was conducted near Mumbai city of India to understand andassess the behaviour and fluxes of trace and toxic elements increek sediment. Seven sediment core samples were collected andanalysed for trace and toxic elements such as Fe, Cu, Pb, Zn, Rb and Sr in different sections of the core using EDXRF technique. The fluxes of the elements in each section of the core were calculated using the mass sedimentation rates derivedfrom 210Pb dating technique and the sediment density at each location. The estimated depositional fluxes of Fe, Rb and Sr in Zone-1 and Zone-3 are in the ranges of 0.4–0.5% cm-2yr-1; 4–6 g cm-2 yr-1 and 10–20 g cm-2 yr-1 respectively, where as they were about 3–4 times higher in zone-2 for the same elements. The depositionalfluxes of elements Cu (40–60 g cm-2 yr-1), Zn (35–43 g cm-2 yr-1) and Pb (6–12 g cm-2 yr-1) were also found to be higher in zone-2 compared tozone-1 and zone-3 which can be attributed to the release from thenewly developed chemical zone of Thane-Belapur industrial belt.  相似文献   

7.
The concentration of trace metals (Cd, Cu, Pb and Zn) in a total of 144 samples of grass, soil and lower animal (earthworm, Lybrodrilus violaceous) were collected and analysed for their metallic content. Levels of cadmium ranged from 0.01–0.07 g g–1; 0.01–0.12 g g–1 and from trace–0.05 g g–1 dry weight for plant, soil and animal samples respectively. Mean concentration of copper ranged 0.10–1.48 g g–1; 0.10–2.90 g g–1 and 0.01–0.08 g g–1 for samples in similar order as above. The levels of Pb varied from 0.01–0.14 g g–1; 0.02–0.23 g g–1 and from trace–0.07 g g–1 while that of Zn ranged from 0.19–1.80 g g–1; 0.51–3.35 g g–1and 0.01–0.08 g g–1 also in the same order of samples as mentioned above. Levels of metals in soil samples were higher than the background levels with the exception of Zn but lower than European Union (EU) limits. The results generally revealed the presence of metals in plant and animal samples and metal dynamics up the food chain is highly possible. Acceptable recoveries of the spiking experiment validate the experimental protocol.  相似文献   

8.
The nature of atmospheric aerosols at Gurushikar, Mt. Abu, Rajasthan where a gamma ray telescope is to be installed, was investigated. Air particulate samples collected on filters were used to estimate the total suspended particulate matter (TSPM) and its elemental composition. The TSPM varied from 31 to 103 g/m3 during January to March 1994. The heighest loads were observed during the months of May and June (80–100 g/m3) and lowest during October (20–60 g/m3). The dust was also examined for size, shape and nature of the mineral matter. The particle sizes varied from 100 m to 5 m. The course particles (>50 m) are irregular shaped quartz grains. Some of the medium size (=50 m) particles were spherical and were highly conducting. These particles were rich in iron content. Correlation coefficients among various elements in the dust showed that it is made up of mainly two components-wind blown ground dust and particulate arising out of wood and coal burning.  相似文献   

9.
The concentrations of cadmium, chromium, copper, iron, lead, manganese, nickel, and zinc in water and bed sediments of river Gomti have been studied in a fairly long stretch of 500 km from Neemsar to Jaunpur. Grab samples of water (October 2002–March 2003) and bed sediments (December 2002 and March 2003) were collected from 10 different locations following the standard methods. The river water and sediment samples were processed and analyzed for heavy metals viz., Cd, Cr, Cu, Fe, Pb, Mn, Ni, and Zn, and using ICP-AES. The heavy metals found in the river water were in the range: Cd (0.0001–0.0005 mg/L); Cr (0.0015–0.0688 mg/L); Cu (0.0013–0.0.0043 mg/L); Fe (0.0791–0.3190 mg/L); Mn (0.0038–0.0.0973 mg/L); Ni (0.0066–0.011 mg/L); Pb (0.0158–0.0276 mg/L); and Zn (0.0144–0.0298 mg/L) respectively. In the sediments the same were found in the range: Cd (0.70–7.90 g/g); Cr (6.105–20.595 g/g); Cu (3.735–35.68 g/g); Fe (5051.485–8291.485 g/g); Mn (134.915–320.45 g/g); Ni (13.905–37.370 g/g); Pb (21.25–92.15 g/g); and Zn (15.72–99.35 g/g) of dry weight respectively. Some physico-chemical parameters viz., pH, total solids, total dissolved solids, total suspended solids, dissolved oxygen, biological oxygen demand, chemical oxygen demand, hardness etc. were estimated as these have direct or indirect influence on the incidence, transport and speciation of the heavy metals. Based on the geoaccumulation indices, the Gomti river sediments from Neemsar to Jaunpur are considered to be unpolluted with respect to Cr, Cu, Fe, Mn, and Zn. It is unpolluted to moderately polluted with Pb. In case of Cd it varies from moderately polluted to highly polluted. As far as Ni is concerned the sediment is very highly polluted at Barabanki and Jaunpur D/s. No correlation was found between enrichment factor and geoaccumulation index.  相似文献   

10.
This study examined the levels of seven heavy metals (namelyzinc, copper, cadmium, chromium, lead, manganese and iron) andtheir associations with magnetic properties in playground dustof Hong Kong. Results showed that the playground dust containedhigh concentrations of Zn (mean = 1883 g g-1), Cu(mean = 143 g g-1) and Cr (mean = 263 g g-1).Qualitative examination of dust samples under microscope indicated local traffic as one of the important pollutant sources. Magnetic measurements indicated that these anthropogenicpollutants mainly consisted of coarse-grained multidomain (MD) ferrimagnetic minerals. Superparamagnetic (SP), stable single domain (SSD) ferrimagnetic grains and non-ferrimagnetic mineralswere present in relatively small amounts. Significant correlations between heavy metals and various magnetic parametersindicated a strong affinity of heavy metals to magnetic minerals hence pointed out the potential of magnetic properties for simpleand rapid proxy indications of heavy metal pollution in playground dust.  相似文献   

11.
Air particulate samples collected during 1995–96 ata background site situated on the east coast of Thar Desert inRajsthan State of India were analysed for atmospheric dustloads (Suspended Particulate Matter) and elemental composition.The values of SPM ranged from 9 g M-3 to 97g M-3 with an average of 43 g M-3 except a fewepisodic values, which were 3 to 5 times higher than the averageduring summer months. The results for elemental composition ofthe particulate samples showed that the concentrations ofanthropogenic toxic trace elements viz. Br, Cr, Pb, Sb, Se and Znare lower by a factor of 2 to 10 as compared to urban areas. Thehigh enrichment factors for anthropogenic elements viz. Br, Pb,Sb and Zn show an input from coal/wood fuel burning andvehicular pollution at the sampling site. The depletion of Si inSPM samples shows long distance transport of dust to the samplingsite.  相似文献   

12.
Cadmium (Cd) and lead (Pb) concentrations in different cigarette brands sold and/or produced in Jordan were determined by graphite furnace atomic absorption spectrometry (GF-AAS). Average levels of Cd and Pb in different cigarette brands in Jordan were 2.64 and 2.67 g g– 1 (DW), respectively. The results obtained in this study estimate the average quantity of Cd inhaled from smoking one packet of 20 cigarettes to be in the range of 3.65–7.30 g. Results suggest that the quantity of Pb inhaled of smoking one packet of 20 cigarettes, is estimated to be 0.74–2.22 g. The concentrations of Cd and Pb in cigarettes were significantly different between cigarette brands tested. Our results were compared with other worldwide studies.  相似文献   

13.
Monitoring of the New Calabar River water was conductedmonthly for a period of one year to ascertain seasonalinfluences and industrial effluent discharges on the organicpollution status of the river. Dissolved oxygen (DO) levelsranged between 3.4 and 9.1 mg/l and 4.4–9.0 mg/l for therainy and dry seasons respectively. Total dissolved solids(TDS) levels ranged between 6.5 and 4013.9 mg/l for the rainyseason and 4.32–619.5 mg/l for the dry season. The ranges forthe organic pollutant parameters were: biochemical oxygendemand, 0.25–4.20 mg/l and 0.15–4.95 mg/l; COD, 10–1000mg/l and 15–100 mg/l; oil and grease, 0.00001–5000 g/l and0.00001–800 g/l; anionic surfactants, 2.0–30 gMBAS/l and 0.1–2.0 g MBAS/l for the rainy and dryseasons respectively. The ranges for the same parameters forthe industrial effluent were: DO, 2.1–3.9 mg/l and 6.5–10.8mg/l; BCD, 0.35–1.4 mg/l and 2.3–2.7 mg/l; COD, 508 mg/l and20–576 mg/l; oil and grase, 0.07–50 g/l and0.048–25.0 g/l; and anionic surfactants, 4.0–7.3g MBAS/l and 0,2–17.0 g MBAS/l for the rainyand dry seasons respectively. These results indicate thatseasonal changes as well as industrial effluent dischargesinfluenced the organic load of the river.  相似文献   

14.
Electro Thermal Atomic Absorption Spectrophotometry (ET-AAS), is used for the determination of chromium (Cr) in a variety of environmental matrices. The detection limit for the estimation of Cr is 2 pg absolute for a volume injection of 20 l. The precision of the method is established by analysing Cr from a synthetic mixture containing various elements in different qualities (0.5–10 ppm) and is found to be within ± 8%. The reliability of estimation is further assessed through the analysis of Standard Reference Materials (SRMs) of soil, hay, milk powder and lake sediment obtained from IAEA.The total intake of Cr through air, water and food works out to be 54 g/day for the adult population of Mumbai city. The dietary intake through food is the major contributor to the total intake of Cr. The concentration of Cr in atmospheric air and drinking water collected from different suburbs showed geometric mean concentrations of 0.09 g/m3 and 0.3 g/l, respectively. The daily intake of Cr, though lower, is closer to the lower bound of the recommended value of 50–200 g/day.  相似文献   

15.
Carbaryl insecticide was applied by ground spray to plants in urban areas to control a serious insect pest the glassy-winged sharpshooter, Homalodisca coagulata (Say), newly introduced inCalifornia. To assure there are no adverse impacts to human health and the environment from the carbaryl applications, carbaryl was monitored in tank mixtures, air, surface water, foliage and backyard fruits and vegetables.Results from the five urban areas – Porterville, Fresno, Rancho Cordova, Brentwood and Chico – showed there were no significanthuman exposures or impacts on the environment. Spray tank concentrations ranged from 0.1–0.32%. Carbaryl concentrationsin air ranged from none detected to 1.12 g m-3, well below the interim health screening level in air of 51.7 g m-3. There were three detections of carbaryl in surface water nearapplication sites: 0.125 ppb (parts per billion) from a water treatment basin; 6.94 ppb from a gold fish pond; and 1737 ppbin a rain runoff sample collected from a drain adjacent to a sprayed site. The foliar dislodgeable residues ranged from 1.54–7.12 g cm-2, comparable to levels reported forsafe reentry of 2.4 to 5.6 g cm-2 for citrus. Carbarylconcentrations in fruits and vegetables ranged from no detectableamounts to 7.56 ppm, which were below the U.S.EPA tolerance, allowable residue of 10 ppm.  相似文献   

16.
Ozone concentrations were measured in Zagreb at four sites from May 1999 to April 2001 in order to categorize the air quality with respect to ozone. In the summer of 2000, the ozone measurements were also extended to four sites in the suburbs of Zagreb. Methods of active and passive sampling with nitrite ion as a reagent were used. In the northern part of the town ozone was analyzed by an automatic device. Automatic device measurements in the years 1999 and 2000 showed that hourly averages of ozone concentrations did not exceed the Croatian recommended value of the 98th percentile (180 g m–3). Over the two-year period, 24-h averages occasionally exceed 110 g m–3 in city center and in the northern part of the town. Regardless of these isolated examples, ozone was well within acceptable concentrations. Ozone concentrations measured in summer 2000 were higher in the suburbs of Zagreb than in the city. The 98th percentile values higher than 110 g m–3 were recorded at three sites.  相似文献   

17.
We determined concentrations of selected trace elements inlivers, kidneys and blood samples from common eiders (Somateria mollissima borealis) from the eastern Canadianarctic during 1997 and 1998. Concentrations of totalmercury and organic mercury were generally low in the liversof these birds (less than 6 and 4 g g–1 dry wt,respectively). Selenium ranged between 11–47 g g–1 inlivers. Renal cadmium concentrations were among the highestever published for this species (range: 47–281 g g–1). The regressions of log-transformed concentrations ofthese trace elements in blood samples on those in liver orkidney were significant (all P-values < 0.05) andpositive. However, except for organic mercury (RM 2 = 0.83), the co-efficients of determination were low tomoderate (range of R 2: 0.26–0.52), suggesting poorto moderate predictive capability. Furthermore, therelationships between total mercury in blood and liverchanged between 1997 and 1998, suggesting that it would notbe possible to predict consistently, concentrations ofmercury in blood from those in liver based on samples takenin one year. Blood samples can be used to determineconcentrations of these trace elements in common eiders (andprobably other sea duck species as well). The use of bloodsamples is especially warranted when it is undesirable tokill the animal such as when working with rare or endangeredsea duck species or when the objective is to relate traceelement exposure to annual survival rates. However, thepredictive equations developed here should not be used topredict expected concentrations in one type of tissue fromthose in the other.  相似文献   

18.
The ocelot (Felis pardalis) isan endangered neotropical cat distributed within asmall range in the Lower Rio Grande Valley (LRGV), inTexas, U.S.A. Studies of the impacts of environmentalcontaminants in wild cats are few. Approximately onefourth of the estimated population (about 100) ofocelots in the LRGV was sampled to evaluate theimpacts of chlorinated pesticides, polychlorinatedbiphenyls, and trace elements on the population. Hairwas collected from 32 ocelots trapped between 1986–1992,and blood was collected from 20 ocelots trappedbetween 1993–1997. A few blood samples were obtainedfrom individuals recaptured two or three times. Tissue samples from 4 road-killed ocelots were alsoanalyzed. DDE, PCBs, and Hg were some of the mostcommon contaminants detected in hair and blood. MeanHg levels in hair ranged from 0.5 to 1.25 g g-1 dw,Se from 1.5 to 3.48 g g-1 dw, and Pb from 0.56 to26.8 g g-1 dw. Mean DDE concentrations in plasma ranged from 0.005 g g-1 ww to 0.153 g g-1 ww, and PCBs ranged from 0.006 g g-1 ww to 0.092 g g-1 ww. Mean Hg levels in red blood cells rangedfrom 0.056 g g-1 dw to 0.25 g g-1 dw. Concentrations of DDE, PCBs, or Hg, did not increasesignificantly with age, although the highestconcentrations of DDE and Hg were found in olderanimals. Overall, concentrations of DDE, PCBs, and Hgwere low and at levels that currently do not pose anythreat to health or survival of the ocelot. This isfurther supported by good reproduction of the ocelotin the LRGV, where adult females averaged about 1.5kittens/litter. Thus, it seems that the current majorthreat to recovery of the ocelot in the LRGV may behabitat loss, although potential impacts of newgeneration pesticides, such as organophosphorus andcarbamate insecticides need further study.  相似文献   

19.
An investigation was carried out to monitor Pb and Cd contamination in grazing land located near a highway. Environmental media at different distances fromhighway (soil, grass, water, cow's forage, fertilizer,manure and milk samples) were collected from three samplinglocations. Soil and grass were characterized by high metalmobility (soil with Pb: 5.25±0.71–14.59±1.17 mgkg-1, dry mass and Cd: 0.038–0.33±0.04 mg kg-1, dry mass and grass with Pb: 0.76±0.05–6.62±0.18 mg kg-1, dry mass and Cd: 0.17±0.01–0.73±0.09 mg kg-1, dry mass). One-way analysis of variane (ANOVA) was applied to find out the correlation between metal (total and bioavailable) concentrationsin the soil and the distance from roadside. In most cases, the finding showed that plants growing nearer to the highway are usually exposed to more heavy metal accumulations than those awayfrom the highway. In addition, a correlation was established between plant available metal concentrations and plant metaluptake concentrations.Analysis of fertilizer and manure showed considerable amountof metals (fertilizer with Pb: 1.53±0.06 mg kg-1 andCd: 0.038 mg kg-1 and manure with Pb: 2.55–3.34 mgkg-1 and Cd: 0.14–0.31 mg kg-1). Long termsimultaneous application of fertilizer and manure on thecommercial farm showed higher metal accumulation in the soiland plants than those of co-operative farm Considerableconcentrations of metals (Pb: 1.60–2.94 mg kg-1 andCd: 0.025–0.19 mg kg-1) were observed in fodder. The finding clearly demonstrated that there are seasonalvariation in total daily metal intake by individual cow (Pb:109.37 mg day-1 (dry), 273.47 mg day-1 (rainy) andCd: 2.02 mg day-1 (dry), 19.62 mg day-1 (rainy)).The provisional tolerable weekly intake of heavy metals incows is 390 g Pb and 28 g Cd per kg bodyweight in the rainy season and 156 g Pb and 2 gCd per kg body weight in the dry season. The levels of metals (Pb: 0.014 mg L-1 and Cd: not detectable) and bio-transferfactor (10-5–10-4) in raw milk were found to be well below the Codex Alimentarius Commissions Draft (1997). Ouranalysis revealed that improvements on farm management give significant reduction in elevated levels of Pb and Cdin soil and plants, and however leads to minimize the amountof Pb and Cd in consumed milk.  相似文献   

20.
More than 2000 blood samples were collected at random from full-time middle school teachers in 9 cities of China and analyzed for lead concentration with strict quality assurance procedures. Questionnaries about the smoking habits, alcohol consumption, residence condition, and fuel used at home were filled out by each person, and information about traffic, and lead concentration in different areas of the environment was also collected as far as possible. The result showed that the geometric mean of blood lead levels of teachers in different cities was ranging between 59–82 g l–1 among them the lowest levels were found in Nanjing and the highest in Shanghai. The difference between the lowest and the highest value was only 23 g l–1. Comparing with the results of WHO/UNEP and CEC projects. The overall geometric average blood level in China is lower than in all the other countries except Japan. It indicates that the lead pollution in the general environment of China was not as severe as in the participating countries of WHO/UNEP and CEC projects. This may be attributed by the following factors: The less automobile triffic, the larger proportion of non-leaded gasoline used and the less canned food consumption. Factors influencing the lead levels in blood were also analyzed and the normal value (95% upper limit) of blood lead was assessed to be 160 g l–1.  相似文献   

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