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鉴于氰化物所具有的明显的毒性和电镀、炼焦、造气及其他化工等含氰废水对环境水体的污染,水中微量氰化物的监测一直是人们所重视的项目。 水中微量氰化物的测定方法报导颇多。尤其近年来,采用仪器分析手段,诸如气相 相似文献
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在反复实验的基础上建立了运用Bran+Luebbe AutoAnalyzer 3流动注射分析仪快速测定地表水中总氰化物的分析方法。结果表明,该方法与传统的分光光度法相比,具有自动进样、分析速度快、测定成本低等优点。与经典的分析方法相对照,结果无显著性差异,能够满足大批量地表水监测的要求。在测试系统中引入了恒温槽,进一步提高了测试的精密度和准确度。 相似文献
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电混凝处理电镀综合废水 总被引:4,自引:0,他引:4
采用电混凝法处理酸性电镀综合废水,首先研究了不同电流密度对总氰化物、重金属和化学需氧量(COD)去除率的影响。实验结果表明,电混凝可有效去除酸性电镀综合废水中的氰化物与重金属。随着电流密度的增大,总氰化物与重金属的去除率逐渐提高。当电流密度为10mA/cm2时,废水中残留的总氰化物、Cu2+、Ni2+、Cr6+和Zn2+ 的浓度分别为23.0、25.0、4.5、0.2和0.2mg/L。为了进一步提高去除率,在电化学体系中添加H2O2,随着H2O2投量的增大,总氰化物、重金属、COD去除率不断提高。当H2O2投量为3mL/L时,处理过废水中残留总氰化物、Cu2+、Ni2+、Cr6+、Zn2+和COD的浓度分别为0.2、2.0、3.0、1.5、0.1和220mg/L。 相似文献
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二氧化氯销毁氰化物的应用研究 总被引:1,自引:0,他引:1
在弱碱性条件下,二氧化氯消毒剂将氰化物氧化成无毒的氰酸盐(OCN)、二氧化碳和氮气。研究了影响二氧化氯销毁氰化物的几种因素:pH在8—11的范围内,不影响二氧化氯对氰化物的销毁率;在所试验的反应温度(0-40℃)内,温度对反应速率表现出有限的影响;二氧化氯与氰离子的最佳质量比为2:1;当氰离子最高使用浓度小于0.5g/L时,废水中氰离子浓度达一级以上的排放标准。 相似文献
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对异烟酸-吡唑啉酮光度法测定水和废水中氰化物的方法进行了改进。在不改变其它步骤的前提下,以去离子水代替二甲基甲酰胺所配制的吡唑啉酮溶液及异烟酸溶液作为显色剂。试验结果表明,改进后的新方法精密度RSD〈5%,加标回收率为92.0%~105.0%,通过电镀废水和标准样品的比对试验表明,改进后的方法与标准方法对同一样品的测定结果无显著性差异,满足监测分析要求。 相似文献
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氰化物(总氰)标准样的分析结果往往会明显低于它的实际真值。这除了与在蒸馏过程中有少量的氰化氢挥发有关外,还与蒸馏时取样量的多少(即氰化物含量的高低)有关。通过对一已知浓度的总氰化物标准样的分析,发现氰化物蒸馏时的取样量对其测定结果有一定的影响。将同一浓度(1毫升=0.486微克)的总氰化物标准样,分成不同体积,按《水和废水监测分析方法》(第三版)中的总氰化物蒸馏步骤同时进行蒸馏,然后取馏出液,用“异烟酸——吡唑啉酮比色法”进行分析,其各自测定结果见表。 相似文献
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金矿开采引起砷污染的初步研究及治理措施 总被引:1,自引:0,他引:1
砷伴生于许多有色金属之中,随着含砷矿床的开采,导致砷由地层深处转至地表,改变了它们迁移的地球化学条件,容易释放到周围环境中。以辽宁某金矿为例,调查并阐述了金矿开采过程中的砷释放,以及尾矿渣的堆放,随废水排放造成对周围河流的砷污染情况,提出了适合金矿床开采的砷污染治理方法。 相似文献
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Masanabo Ntombenhle Orimolade Benjamin Idris Azeez O. Nkambule Thabo T. I. Mamba Bhekie B. Feleni Usisipho 《Environmental science and pollution research international》2023,30(6):14062-14090
Environmental Science and Pollution Research - Globally, ibuprofen is the third most consumed drug and its presence in the environment is a concern because little is known about its adverse effects... 相似文献
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Wang Yinghui Chen Yuantao Zhao Meng Zhang Lili Zhou Changyou Wang Haiyang 《Environmental science and pollution research international》2022,29(59):88882-88893
Environmental Science and Pollution Research - Radioactive iodine in nuclear waste is increasingly harmful to the human body and the environment because of its strong radioactivity, high fluidity,... 相似文献
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Mercury policy and regulations for coal-fired power plants 总被引:1,自引:1,他引:0
Rallo M Lopez-Anton MA Contreras ML Maroto-Valer MM 《Environmental science and pollution research international》2012,19(4):1084-1096
Introduction
Mercury is a high-priority regulatory concern because of its persistence and bioaccumulation in the environment and evidence of its having serious adverse effects on the neurological development of children. 相似文献15.
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Ming Fang Chak K. Chan Xiaohong Yao 《Atmospheric environment (Oxford, England : 1994)》2009,43(1):79-86
As the world gets ready to begin the second decade of the twenty-first century, global climate change has been recognized as a real threat to civilization as we know it. The rapid and successful economic growth of developing nations, particularly China and India, is contributing to climate change. The route to initial economic success in China followed that of the developed nations through the development of industries. Unfortunately, China's environmental protection efforts have not been the same as in developed countries because China is vastly different culturally, socially, economically and, especially, politically from developed nations. When China started to deal with environmental concerns in the late 1970s, it took advantage of the experiences of other countries in establishing environmental standards and regulations, but it did not have a model to follow when it came to implementing these standards and regulations because of the abovementioned differences. Economically, China is transitioning from an agricultural base into an industrial base; however, even now, 60% of the population remains farmers. China has been and still is heavily dependent upon coal for energy, resulting in serious atmospheric particulate pollution. While growing efforts have been expended on the environment, at this juncture of its economic development, China would be well served to revisit the traditional “develop first and clean up later” approach and to find a balance between development and protecting the environment. Against this backdrop, a reflective look of the effort to manage air quality from 1949–2008 (with an emphasis on the past 30 years) in China is presented in this paper. The environmental component of the 2008 Olympic Games is examined as a special example to illustrate the current measures being used to improve air quality in China. 相似文献
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Bartels-Rausch T Krysztofiak G Bernhard A Schläppi M Schwikowski M Ammann M 《Chemosphere》2011,82(2):199-203
Reduction of divalent mercury and subsequent emission to the atmosphere has been identified as loss process from surface snow, but its mechanism and importance are still unclear. The amount of mercury that stays in the snow pack until spring is of significance, because during snow melt it may be released to the aquatic environment and enter the food web. Better knowledge of its fate in snow might further assist the interpretation of ice core data as paleo-archive. Experiments were performed under well-controlled laboratory conditions in a coated wall flow tube at atmospheric pressure and irradiated with light between 300 nm and 420 nm. Our results show that the presence of benzophenone and of oxalic acid significantly enhances the release of mercury from the ice film during irradiation, whereas humic acid is less potent to promote the reduction. Further it was found that oxygen or chloride, and acidic conditions lowered the photolytically induced mercury release in the presence of benzophenone, while the release got larger with increasing temperatures. 相似文献
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Endosulfan, one of the major pesticides used in cotton-growing, is of environmental concern because of its toxicity to fish and its apparent persistence in the environment. This study examines the distribution and degradation pathways for endosulfan in an aquatic system and the processes by which it is removed. In the alkaline waters of the cotton region, hydrolysis is the dominant degradation process. By this mechanism alone, the expected half-lives for the alpha- and beta-endosulfan isomers were found to be 3.6 days and 1.7 days, respectively. Partitioning studies showed, however, that the major proportion of endosulfan would associate with the sediments (log Koc(alpha) 3.6 and log Koc(beta) 4.3). Field studies confirmed the presence of high concentrations in sediments. Microcosm experiments showed that loss of endosulfan was slower than predicted from hydrolysis rates. Models are presented to explain how desorption from sediment limits the loss of endosulfan from a system. 相似文献
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Phosphorus recovery from wastewater has become a necessity for sustainable development because phosphorus is a non-renewable
essential resource, and its discharge into the environment causes serious negative impacts. There are no economic incentives
for the implementation of phosphorus recovery technologies because the selling price of rock phosphate is lower than phosphorus
recovered from sewage. The methodologies used to determine the feasibility of such projects are usually focused on internal
costs without considering environmental externalities. This article shows a methodology to assess the economic feasibility
of wastewater phosphorus recovery projects that takes into account internal and external impacts. The shadow price of phosphorus
is estimated using the directional distance function to measure the environmental benefits obtained by preventing the discharge
of phosphorus into the environment. The economic feasibility analysis taking into account the environmental benefits shows
that the phosphorus recovery is viable not only from sustainable development but also from an economic point of view. 相似文献
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Designing green plasticizers: influence of molecular geometry on biodegradation and plasticization properties 总被引:1,自引:0,他引:1
The plasticizer di (2-ethylhexyl) phthalate (DEHP) and its metabolites are considered ubiquitous contaminants, which have a range of implications on the environment and human health. This work considered several alternative compounds with structural features similar to DEHP. This added to the understanding of why DEHP is so poorly biodegraded once it enters the environment. These alternative compounds were based on 2-ethylhexyl diesters of maleic acid (cis-isomer), fumaric acid (trans-isomer) and succinic acid (saturated analogue). The rates of biodegradation by the common soil bacterium Rhodococcus rhodocrous were shown to be dependent on the structure of the central unit derived from the diacid used to make the ester. The diacid components of DEHP and the maleate both had a cis orientation and they were the two that were slow to biodegrade. Plasticizing properties were also compared and, because the ester of the saturated succinic acid was degraded quickly and also had good plasticizing properties, it was concluded that the succinic esters of straight chain alcohols would make the best green plasticizers. The maleate ester had excellent plasticizing properties but this is mitigated by a significant resistance to biodegradation. 相似文献