水体底泥对污染物的吸附-解吸机理的研究

水体底泥污染已经成为世界范围内的一个重要的环境问题,其污染物主要通过大气沉降、废水排放、雨水淋溶冲刷等进入水体,最后沉积到底泥中并逐渐富集,使底泥受到严重污染。吸附-解吸是底泥污染的重要过程,为了控制水体底泥污染,对底泥对各种污染物的吸附-解吸机理及其影响因素的研究显得极其重要。本文总结了底泥中氮、磷和重金属等的吸附-解吸的影响因素及机理,对今后水体底泥污染方面的研究具有重要意义。     

底泥的氮、磷释放及其微生物影响的研究

氮和磷在自然界的循环已经引起了人们的关注,一方面因为氮和磷是生态系统中必不可少的营养元素,另一方面过剩的氮和磷会导致水域的富营养化 ,从而使生态平衡遭受破坏.本文综述了水体沉积物中氮和磷受微生物作用进行释放的影响,以及国内外的研究历史和现状.总结了氮磷微生物代谢的特点,并阐述了与传统认识相区别的最新发现和思想.本文试图从理论上说明微生物的氮磷释放机理,通过生物化学和分子动力的角度解释了细菌对氮磷的吸收和释放,即质子动势理论和Pho调控理论.目前,这一领域研究的热点是为了特殊的使用用途对于高效微生物的分离鉴别和组合培养,和对氮磷代谢的影响因素.     

磁性粉煤灰对磷吸附特性的影响

在含磁性物质（Fe、Co、Ni）的介质中，加入适量的化肥和其它添加物质，经一定磁场强度磁化后制成的具有剩磁和矫顽力的新型肥料，定名为磁化肥料，现已获得国家发明专利。目前提供大量磁性物质的主要载体是火力发电厂排放的粉煤灰。粉煤灰和磁性粉煤灰对主要农作物的增产效果和对土壤的理化性质的影响有不少报道［‘－‘1，但对磷吸附特性的影响则未见报道。因此，我们应用tang－muir等温吸附方程研究了粉煤灰和磁性粉煤灰（并与江汉平原主要土壤黄棕壤、潮土作对照比较）对磷酸盐的吸附特性，探讨了粉煤灰和磷酸根离子之间的相互作用，…     

沈阳市新开河底泥对水体黑臭的关键影响因子研究

对新开河沿河11个点位的底泥进行取样监测,并对监测数据进行分析,筛选底泥中对水体黑臭造成影响的关键因子.结果显示,底泥污染是黑臭水体的重要污染源之一,底泥的含水率是底泥处置的关键考虑因素;重金属和砷是底泥资源化利用的关键因子;总氮、总磷和有机质之间关系密切且有较好的同源性.     

内源磷的释放作用及影响因素研究进展

水体的富营养化已成为目前环境研究中的焦点问题,磷在湖泊中的浓度高低是衡量湖泊富营养化水平的重要指标,是水生态系统基本营养盐之一,并且是淡水湖泊的最主要限制性营养因子。在外源磷得到有效的控制之后,内源磷的污染仍然能够保持湖泊的富营养化状态,此时内源磷的控制就成为了难点和重点。在底泥中的结合态磷,主要是以无机磷和有机磷的形式存在,有机磷与微生物活性密切相关,无机磷则主要与底泥存在的环境联系紧密。湖泊底泥内源磷释放受到一系列物理、化学、生物过程的控制,其影响因素主要包括扰动、氧化还原电位、pH值等,是多种因子综合作用的结果,同时,扰动引起的底泥再悬浮对内源磷有吸附固定作用。故底泥内源磷的释放机理有待进一步探索,在多种影响因素作用下,进一步研究底泥再悬浮对磷的吸附释放作用,从而明确内源磷的主要来源及吸附释放过程,为内源磷的控制提供理论依据,进而控制水体富营养化。     

pH值对黄河兰州段底泥中总磷释放的影响

分析了不同pH值对黄河兰州段底泥总磷（TP）释放特性的影响。结果表明：底泥中的总磷在酸性范围内呈现负释放状态,且pH值越小＂,负释放强度越大＂;在碱性范围内,pH值越大,总磷释放量越大。当pH值为4和6时,水体中的总磷在第1 d都是下降,呈现出负释放的状态;pH值为4时,在第4 d负释放量达到最大值,而pH值为6时到实验结束时负释放量依然在增大。当pH值为10、11、12时,总磷呈现出明显的正释放状态,且在第2 d,总磷的释放量达到最大值。实验数据说明在碱性条件下,底泥中的磷对水质可能产生不良的影响。本次实验对黄河水质的监测以及治理有一定的参考价值。     

富营养化水体中底泥释磷的影响因素及其释放机理

磷是湖泊富营养化的主要限制因子,本文综述了沉积物中磷的赋存形态,释放机理及其影响因素.内源磷的赋存形态主要分为铝磷、铁磷、钙磷及有机磷.磷释放受pH值、溶解氧、生物、温度、扰动5种因素影响.对富营养水体内源磷释放的影响因素及其机理进行研究可为富营养化水体的治理提供理论依据.     

氧化塘底泥对作物生长影响的研究

本文通过农田试验 ,得出氧化塘底泥可以改良土壤结构、增加有机质含量、微生物数量、提高作物产量的结论。因此 ,底泥可以作为一种有机肥应用于农业。     

洗涤剂中的磷对环境的影响及对策的探讨

本文介绍了关于洗涤剂中磷对环境影响的两种典型观点和解决的办法,并从经济和环境的角度进行全面的分析,得出合理的结论和建议。     

黄河以北地区输水干线底泥对调水水质的影响

通过对南水北调东线一期工程的黄河以北地区输水干线底泥污染现状的调查和污染物浸出性实验,分析了输水干线底泥可能对调水水质产生的潜在风险,并根据水质目标要求进行了风险预测分析,最后提出了相应的保障措施和建议。     

不同pH条件下沉积磷释放到水体中化学行为的模拟研究

通过室内模拟湖泊沉积物在不同pH条件下,研究释放到水体中各种磷形态的迁移转化行为,结果表明：碱性条件和酸性条件下,水体磷的时空变化由于其释放机制的不同,其迁移转化行为各不相同,同时,pH值的变化对水体中各种磷的相互转化没有明显的作用,各种磷形态的浓度变化,在很大程度上取决于水体中总磷的浓度。研究结果对认识沉积磷在环境条件变化时,磷在沉积物和水体体系中的迁移转化有重要的意义。     

3种人工湿地填料对磷的动态吸附特征

以河沙、页岩、石灰石等3种重庆常见基质为人工湿地填料,探讨了磷负荷和有机负荷对基质动态除磷效果的影响。结果表明,在同等磷负荷和有机负荷情况下,3种填料的去除效果依次为石灰岩（河沙（页岩;有机负荷对各填料除磷有重要的影响,随着有机负荷的增加,填料除磷率均有不同程度的降低。有机负荷对石灰岩除磷的影响较大,对河沙除磷的影响相对较小。     

Effect of Environmental Setting on Sediment, Nitrogen, and Phosphorus Concentrations in Albemarle-Pamlico Drainage Basin, North Carolina and Virginia, USA

/ Environmental settings were defined, through an overlay process, as areas of coincidence between categories of three mapped variablesMland use, surficial geology, and soil drainage characteristics. Expert judgment was used in selecting factors thought to influence sediment and nutrient concentrations in the Albemarle-Pamlico drainage area. This study's findings support the hypothesis that environmental settings defined using these three variables can explain variations in the concentration of certain sediment and nutrient constituents. This finding underscores the importance of developing watershed management plans that account for differences associated with the mosaic of natural and anthropogenic factors that define a basin's environmental setting. At least in the case of sediment and nutrients in the Albemarle-Pamlico region, a watershed management plan that focuses only on anthropogenic factors, such as point-source discharges, and does not account for natural characteristics of a watershed and the influences of these characteristics on water quality, may lead to water-quality goals that are over- or underprotective of key environmental features and to a misallocation of the resources available for environmental protection.KEY WORDS: Environmental setting; Water quality; Watershed management; Nutrients; Sediment     

长江经济带总磷污染状况与对策建议

长江经济带是我国重要的战略区域,加强长江经济带生态环境保护是我国的重大战略部署,在推进我国"五位一体"总体布局建设中具有重要地位,是体现习近平总书记"共抓大保护,不搞大开发"的重要精髓。目前,总磷已成为长江经济带水体首要污染指标,总磷超Ⅲ类的断面比例达到18.3%,主要的一级支流中,沱江、清水江、岷江、乌江总磷平均浓度在地表水Ⅲ类水质标准上下浮动,污染相对较重;长江经济带总磷污染主要受工业、城镇生活、农业等污染源影响,主要涉及四川、贵州、湖北、湖南、重庆等地区;同时结合总磷污染特征分析,提出了涉磷工业企业治理、磷矿管理、城镇生活污水治理、畜禽养殖防治、规范监测方法等治理措施,为长江经济带总磷污染防控提供技术支撑和决策依据。     

Recent Changes of Sediment Yield in the Upper Yangtze, China

/ Reservoir sedimentation is one of the many environmental problems associated with the Three Gorges Project in China. The rate and characteristics of sedimentation that directly affect the operating life of the reservoir are closely related to soil erosion and sediment transport dynamics in the upstream catchment and to the ability to manage the throughput of sediment-laden waters. The recent changes in sediment yield were examined using gauging data from 187 stations of varying sizes from less than 100 km2 to larger than 1,000,000 km2 in the Upper Yangtze basin between 1956 and 1987. Whereas many previous studies have concentrated on the trends in the main channel of the Yangtze, the distributed pattern of changes across the whole catchment is complex. Results from time series analysis indicate ten stations, mainly located in the Dadu and Wu tributaries (with a total incremental catchment area of 78,963 km2) have shown increasing trajectories of sediment yield, and six stations, located in the upper Jialing and Tuo tributaries (with a total incremental area of 27,816 km2) have experienced decreasing trajectories. By dividing the time series into three components, it is possible to map significant decadal changes in sediment yields that can be related to phases of deforestation and the construction of water conservancy projects. Most of the observed decreases in sediment yield are associated with large reservoir schemes on tributary rivers. The lack of evidence for increasing sediment input to the Three Gorges area masks a considerable variation in sediment conveyance and storage within the Upper Yangtze catchment.KEY WORDS: Sediment yield; Reservoir sedimentation; Three Gorges Project; Time series analysis; China     

钢渣吸附除磷性能的试验研究

研究了钢渣的吸附除磷效果并进行机理探讨。结果表明：钢渣采用0．5g,即可在25℃下、2个小时内,将100ml的磷浓度为10mg／L（以磷计）的模拟含磷废水的磷浓度降至0．5mg／L以下,达到磷的国家一级排放标准;钢渣吸附平衡时问为2小时;钢渣吸附除磷的机理主要是沉淀、吸附（表面络合反应）,并辅以静电作用。     

黄河河口磷酸盐的缓冲作用探讨

河口区,磷酸盐浓度在很宽的盐度范围变化很小,甚至不变,对此提出悬浮物和沉积物对磷有缓冲作用。我们认为解吸吸附反应是其缓冲机制,从而进行了大量的模拟实验,并加以系统的分析。     

汾河底泥耗氧速率测试

以汾河运城段几个县界断面底泥和水质为实验目标,采用实验室测定方法,分别对在平水期、枯水期的底泥耗氧(SOD)速率进行测试,并对测试条件进行优化,对结果进行分析。研究表明,无论枯水期还是平水期,SOD总体变化趋势与河流水质污染(化学需氧量、氨氮)趋势基本一致。     

Assessment of Coarse Sediment Mobility in the Black Canyon of the Gunnison River,Colorado

The Gunnison River in the Black Canyon of the Gunnison National Park (BCNP) near Montrose, Colorado is a mixed gravel and bedrock river with ephemeral side tributaries. Flow rates are controlled immediately upstream by a diversion tunnel and three reservoirs. The management of the hydraulic control structures has decreased low-frequency, high-stage flows, which are the dominant geomorphic force in bedrock channel systems. We developed a simple model to estimate the extent of sediment mobilization at a given flow in the BCNP and to evaluate changes in the extent and frequency of sediment mobilization for flow regimes before and after flow regulation in 1966. Our methodology provides a screening process for identifying and prioritizing areas in terms of sediment mobility criteria when more precise systematic field data are unavailable. The model uses the ratio between reach-averaged bed shear stress and critical shear stress to estimate when a particular grain size is mobilized for a given reach. We used aerial photography from 1992, digital elevation models, and field surveys to identify individual reaches and estimate reach-averaged hydraulic geometry. Pebble counts of talus and debris fan deposits were used to estimate regional colluvial grain-size distributions. Our results show that the frequency of flows mobilizing river bank sediment along a majority of the Gunnison River in the BCNP has significantly declined since 1966. The model results correspond well to those obtained from more detailed, site-specific field studies carried out by other investigators. Decreases in the frequency of significant sediment-mobilizing flows were more pronounced for regions within the BCNP where the channel gradient is lower. Implications of these results for management include increased risk of encroachment of vegetation on the active channel and long-term channel narrowing by colluvial deposits. It must be recognized that our methodology represents a screening of regional differences in sediment mobility. More precise estimates of hydraulic and sediment parameters would likely be required for dictating quantitative management objectives within the context of sediment mobility and sensitivity to changes in the flow regime.