Contamination of groundwater and risk assessment for arsenic exposure in Ha Nam province, Vietnam

The characteristics of arsenic-contaminated groundwater and the potential risks from the groundwater were investigated. Arsenic contamination in groundwater was found in four villages (Vinh Tru, Bo De, Hoa Hau, Nhan Dao) in Ha Nam province in northern Vietnam. Since the groundwater had been used as one of the main drinking water sources in these regions, groundwater and hair samples were collected in the villages. The concentrations of arsenic in the three villages (Vinh Tru, Bo De, Hoa Hau) significantly exceeded the Vietnamese drinking water standard for arsenic (10 microg/L) with average concentrations of 348, 211, and 325 microg/L, respectively. According to the results of the arsenic speciation testing, the predominant arsenic species in the groundwater existed as arsenite [As(III)]. Elevated concentrations of iron, manganese, and ammonium were also found in the groundwater. Although more than 90% of the arsenic was removed by sand filtration systems used in this region, arsenic concentrations of most treated groundwater were still higher than the drinking water standard. A significant positive correlation was found between the arsenic concentrations in the treated groundwater and in female human hair. The risk assessment for arsenic through drinking water pathways shows both potential chronic and carcinogenic risks to the local community. More than 40% of the people consuming treated groundwater are at chronic risk for arsenic exposure.     

High (210)Po atmospheric deposition flux in the subtropical coastal area of Japan

Bulk atmospheric deposition fluxes of (210)Po and (210)Pb were measured at three coastal regions of Japan, the Pacific Ocean coastal area of the Japanese mainland (Odawa Bay), the Chinese continental side of Japanese coastal area (Tsuyazaki), and an isolated island near Okinawa (Akajima). Wet and dry fallout collectors were continuously deployed from September 1997 through August 1998 for periods of 3 to 31 days depending on the frequency of precipitation events. Annual (210)Pb deposition fluxes at Odawa Bay (35 degrees N 139 degrees E), Tsuyazaki (33 degrees N 130 degrees E) and Akajima (26 degrees N 127 degrees E) were 73.3+/-8.0, 197+/-35 and 78.5+/-8.0 Bqm(-2)y(-1), respectively. Higher (210)Pb deposition was observed at the Chinese continental side of Japanese coast than at the Pacific Ocean coastal site. The high (210)Pb atmospheric flux at the Chinese continental side coast was thought to be attributable to (222)Rn-rich air-mass transport from the Chinese continent during the winter monsoon. In contrast, the annual (210)Po deposition fluxes at the three study sites were 13.0+/-2.3 (Odawa Bay), 21.9+/-4.4 (Tsuyazaki) and 58.4+/-7.7 (Akajima)Bqm(-2)y(-1), respectively, indicating unusual high (210)Po deposition at Akajima during winter. Anomalous unsupported (210)Po input was observed during summer 1997, suggesting unknown source of (210)Po at this area.     

A review of the ecological effects of radiofrequency electromagnetic fields (RF-EMF)

ObjectiveThis article presents a systematic review of published scientific studies on the potential ecological effects of radiofrequency electromagnetic fields (RF-EMF) in the range of 10 MHz to 3.6 GHz (from amplitude modulation, AM, to lower band microwave, MW, EMF).MethodsPublications in English were searched in ISI Web of Knowledge and Scholar Google with no restriction on publication date. Five species groups were identified: birds, insects, other vertebrates, other organisms, and plants. Not only clear ecological articles, such as field studies, were taken into consideration, but also biological articles on laboratory studies investigating the effects of RF-EMF with biological endpoints such as fertility, reproduction, behaviour and development, which have a clear ecological significance, were also included.ResultsInformation was collected from 113 studies from original peer-reviewed publications or from relevant existing reviews. A limited amount of ecological field studies was identified. The majority of the studies were conducted in a laboratory setting on birds (embryos or eggs), small rodents and plants. In 65% of the studies, ecological effects of RF-EMF (50% of the animal studies and about 75% of the plant studies) were found both at high as well as at low dosages. No clear dose–effect relationship could be discerned. Studies finding an effect applied higher durations of exposure and focused more on the GSM frequency ranges.ConclusionsIn about two third of the reviewed studies ecological effects of RF-EMF was reported at high as well as at low dosages. The very low dosages are compatible with real field situations, and could be found under environmental conditions. However, a lack of standardisation and a limited number of observations limit the possibility of generalising results from an organism to an ecosystem level. We propose in future studies to conduct more repetitions of observations and explicitly use the available standards for reporting RF-EMF relevant physical parameters in both laboratory and field studies.     

Regional Risk Assessment addressing the impacts of climate change in the coastal area of the Gulf of Gabes (Tunisia)

Sound, cost efficient management strategies in developed coastal zones can be reinforced by a thorough understanding of risks associated with the combination of anthropogenic and natural drivers of change. A Regional Risk Assessment (RRA) methodology was developed for the assessment of the potential impacts of climate change in the Tunisian coastal zone of the Gulf of Gabes. It is based on the use of Multi-Criteria Decision Analysis techniques and Geographic Information Systems and is designed to support the development and prioritization of adaptation strategies. The RRA focuses on sea-level rise and storm surge flooding impacts for human and natural systems, i.e., beaches, wetlands, urban areas, agricultural areas, and terrestrial ecosystems. Results suggest that for both of the studied climate change impacts, i.e., sea-level rise and storm surge flooding, the area potentially exposed is limited to a narrow, low elevation region adjacent to the shoreline. However, the exposed areas showed a high relative risk score, obtained by the integration of exposure and susceptibility factors. Beaches have the lowest relative risk scores, while wetlands and terrestrial ecosystems have the higher relative risk scores. The final outputs of the analysis (i.e., exposure, susceptibility, and risk maps) can support end-users in the establishment of relative priorities for intervention and in the identification of suitable areas for human settlements, infrastructure, and economic activities, thus providing a basis for coastal zoning and land-use planning.     

Causes and ecological effects of resuspended contaminated sediments (RCS) in marine environments

Sediments act as a net sink for anthropogenic contaminants in marine ecosystems and contaminated sediments may have a range of toxicological effects on benthic fauna and associated species. When resuspended, however, particulate-bound contaminants may be remobilised into the water column and become bioavailable to an additional assemblage of species. Such resuspension occurs through a range of natural and anthropogenic processes each of which may be thought of as pulsed disturbances resulting in pulsed exposures to contaminants. Thus, it is important to understand not only the toxicological responses of organisms to resuspended contaminated sediments (RCS), but also the frequency, magnitude and duration of sediment disturbance events. Such information is rarely collected together with toxicological data. Rather, the majority of published studies (> 50% of the articles captured in this review) have taken the form of fixed-duration laboratory-based exposures with individual species. While this research has clearly demonstrated that resuspension of contaminated sediments can liberate sediment-bound contaminants leading to toxicity and bioaccumulation under controlled conditions, the potential for ecological effects in the field is often unclear. Monitoring studies suggest that recurrent natural disturbances such as tides and waves may cause the majority of contaminant release in many environments. However, various processes also act to limit the spatial and temporal scales across which contaminants are remobilised to the most toxic dissolved state. Various natural and anthropogenic disturbances of contaminated sediments have been linked to both community-level and sub-lethal responses in exposed populations of invertebrates and fish in the field. Together these findings suggest that resuspension of contaminated sediments is a frequently recurring ecological threat in contaminated marine habitats. Further consideration of how marine communities respond to temporally variable exposures to RCS is required, as well as research into the relative importance of various disturbances under field conditions.     

Potential for the desalination of a brackish groundwater aquifer under a background of rising sea level via salt intrusion prevention river gates in the coastal area of the Red River Delta,Vietnam

Additional freshwater sources are required in many parts of the world, including the coastal areas of the Red River Delta (RRD), where the groundwater (GW) is generally brackish. Determining a feasible method for desalinating brackish aquifers would help provide additional freshwater sources. However, substantial desalination of brackish aquifers cannot be achieved under the natural conditions of GW flow and precipitation recharge. Although rainfall recharge to the shallow Holocene aquifer has occurred for hundreds of years, the aquifer still remains brackish since the natural hydraulic conditions do not allow a complete mixing between the fresh recharged water and aquifer salinized water or the discharging of the aquifer salinized water. The planned salt intrusion prevention gates in the Red River, Tra Ly River and Hoa River in the RRD coastal area, combined with increased GW abstraction and associated aquifer recharge with fresh river water, could result in the gradual desalination of the shallow Holocene aquifer. These effects would help improve the area’s resilience to freshwater shortages and sea level rises and would allow for the creation of a long-term sustainable water resource development plan to manage the salinization of water resources caused by sea level rises. Finite element (FE) modeling of GW flow, solute transport via GW flow and dynamic programming (DP) have been used to study the potential desalination of brackish aquifers, the magnitude of GW abstraction quantities and the spatial and temporal aspects of desalination. FE modeling of GW flow coupled with DP was utilized to identify the magnitude of sustainable abstraction quantities and the GW flow field, which is required in salt transport models. Multiple sizes of elements and time steps were used to adapt to the unsteady state of GW flow and hydraulic head variables between the elements in the FE meshes in order to ensure reasonable accuracy of numerical modeling. The GW flow and salt transport modeling and DP allowed determining quasi-steady-state GW abstraction rates and aquifer salinity levels for conditions that did and did not include the shallow Holocene unconfined aquifer recharge from rainfall. The aquifer modeled domain which is supposed to serve the pumping well field is 1.5 km². The results showed that the Holocene aquifer may provide a stable abstraction rate of 100 m³/day starting in the 6th year (for the worst-case scenario with zero aquifer recharge from rainfall) to 130 m³/day starting in the 3rd year (for the scenario with aquifer recharge equal to 3% of the rainfall levels). During the first years of GW abstraction, the desalination of the brackish upper Holocene aquifer will mainly occur in the area close to the river, and at the 18th year of abstraction, almost the entire area between the river and line of pumping wells would be desalinized. From the 10th year of abstraction, the abstracted water has a total dissolved solids content lower than 0.5 g/l for the worst-case scenario with zero aquifer recharge from rainfall and lower than 0.42 g/l for the scenario with aquifer recharge equal to 3% of the rainfall. The modeling results indicate the simulated process by which abstraction of groundwater adjacent to the Tra Ly River could desalinize the brackish aquifer via freshwater recharge from the river.     

Effect of environmental conditions on morphological,ecological and geographic characteristics of lichens in coastal habitats

The distribution of morphological, substrate, and latitudinal geographic groups of lichen species has been analyzed in various habitat types on the northwestern coast of the Sea of Japan. The results show that the influence of the sea manifests itself in the presence of halophytes, xerophytic life forms, and species of the suboceanic latitudinal geographic group; soil-plant conditions account for the development of the substrate group of epiphytic lichens, mesophytic life forms, and species of the nemoral latitudinal geographic group.     

The ecological effects of trichloroacetic acid in the environment

Trichloroacetic acid (TCAA) is a member of the family of compounds known as chloroacetic acids, which includes mono-, di- and trichloroacetic acid. The significant property these compounds share is that they are all phytotoxic. TCAA once was widely used as a potent herbicide. However, long after TCAA's use as a herbicide was discontinued, its presence is still detected in the environment in various compartments. Methods for quantifying TCAA in aqueous and solid samples are summarized. Concentrations in various environmental compartments are presented, with a discussion of the possible formation of TCAA through natural processes. Concentrations of TCAA found to be toxic to aquatic and terrestrial organisms in laboratory and field studies were compiled and used to estimate risk quotients for soil and surface waters. TCAA levels in most water bodies not directly affected by point sources appear to be well below toxicity levels for the most sensitive aquatic organisms. Given the phytotoxicity of TCAA, aquatic plants and phytoplankton would be the aquatic species to monitor for potential effects. Given the concentrations of TCAA measured in various soils, there appears to be a risk to terrestrial organisms. Soil uptake of TCAA by plants has been shown to be rapid. Also, combined uptake of TCAA from soil and directly from the atmosphere has been shown. Therefore, risk quotients derived from soil exposure may underestimate the risk TCAA poses to plants. Moreover, TCE and TCA have been shown to be taken up by plants and converted to TCAA, thus leading to an additional exposure route. Mono- and di-chloroacetic acids can co-occur with TCAA in the atmosphere and soil and are more phytotoxic than TCAA. The cumulative effects of TCAA and compounds with similar toxic effects found in air and soil must be considered in subsequent terrestrial ecosystem risk assessments.     

Distribution of U-Th nuclides in the riverine and coastal environments of the tropical southwest coast of India

A reconnaissance study has been made on the distribution of 238U, 234U, 232Th and 230Th in soils, water, suspended particulate matter (SPM) and bottom sediments in the Kali river basin around Kaiga, its estuarine region and the adjacent Arabian Sea to obtain the baseline data of U-Th series nuclides in view of the commissioning of nuclear power reactors at Kaiga, near Karwar, on the southwest coast of India. Drainage basin soils developed over greywackes (the dominant litho-unit upstream) are lower in 238U/Al and 232Th/Al ratios by factors of 3-5 in comparison with those developed over tonalitic gneisses (the dominant litho-unit downstream). The dominance of the former type of soils is reflected in the composition of river-bottom sediments derived from the upstream drainage basin during the monsoon. The 232Th in bottom sediments tends to increase towards the estuarine and coastal areas, presumably due to deposition of heavy minerals and onshore transport of coastal sediments into the estuary. The dissolved U in the Kali river is low (0.001-0.02 microg/l) when compared to the major Indian rivers as the Kali river flows through U-poor greywackes. Thus, the input of dissolved U to the Kali estuary is dominated by sea water. Although there is some evidence for the removal of dissolved U at low salinity during estuarine mixing, its behaviour is conservative in the lower estuary (at higher salinities). The removal rate of dissolved U from the Kali river basin is similar to that reported from other tropical river basins. The U flux from all the west-flowing rivers of Peninsular India is estimated at 26.3 x 10(6) g/yr to the Arabian Sea which is about 2% of the flux from the Himalayan rivers to the Bay of Bengal.     

Vertical distributions of (99)Tc and the (99)Tc/(137)Cs activity ratio in the coastal water off Aomori, Japan

Using a sector-field ICP-MS the vertical distributions of the ⁹⁹Tc concentration and ⁹⁹Tc/¹³⁷Cs activity ratio were measured in the coastal waters off Aomori Prefecture, Japan, where a spent-nuclear-fuel reprocessing plant has begun test operation. The ⁹⁹Tc concentrations in surface water ranged from 1.8 to 2.4 mBq/m³, no greater than the estimated background level. Relatively high ⁹⁹Tc/¹³⁷Cs activity ratios (10-12 × 10⁻⁴) would be caused by the inflow of the high-⁹⁹Tc/¹³⁷Cs water mass from the Japan Sea. There is no observable contamination from the reprocessing plant in the investigated area. The ⁹⁹Tc concentration and the ⁹⁹Tc/¹³⁷Cs activity ratio in water column showed gradual decreases with depth. Our results implied that ⁹⁹Tc behaves in a more conservative manner than ¹³⁷Cs in marine environments.     

Seasonal ecophysiology of an endangered coastal species,the yellow-horned poppy (Glaucium flavum Crantz)

Glaucium flavum Crantz. is a short-lived perennial herb distributed in coastal zones from the Black Sea to southern, western and north-western Europe. Despite its diminishing area of distribution and potential pharmacological value, little is known about the ecophysiological features of this coastal species. We investigated the photosynthetic performance of G. flavum by measuring gas exchange, chlorophyll fluorescence, photosynthetic pigment concentration and leaf water content over the space of a year in a coastal habitat of SW Spain. We also measured the variation in total concentrations of nitrogen, phosphorus, sulphur, potassium, calcium and magnesium, in the leaves and soil, throughout the study period. G. flavum showed a high resistance to summer drought conditions which appeared to be due to the high degree of stomatal control. The potential photochemical efficiency of photosystem II showed minimum values during the winter, indicating that low temperatures can produce negative effects within the photosynthetic apparatus. However, the marked decline in net photosynthesis during the winter seems to be mainly related to a loss of metabolic activity. Although leaf nutrient concentrations were, in general, within the normal ranges, phosphorus availability seems to be limited by the high calcium concentrations detected in the soil of the study site. Our study points out the efficiency of the different physiological adaptations of this rare and endangered coastal species in coping with the strong seasonal variability of the Mediterranean climate.     

Occurrence, distribution and possible sources of organochlorine pesticide residues in tropical coastal environment of India: an overview

Organochlorine pesticides (OCPs) are an important potential component of chemical pollutants used extensively for agriculture and sanitation purposes in India as these are comparatively cheap and effective. These persistent organic compounds such as HCH isomers, DDT and its metabolites are the predominant chemical contaminants found along the Indian coast and thus constitute both alluring and grave areas of scientific research. Our objective in the paper is to provide a comprehensive account of the distribution of organochlorine pesticides in biotic and abiotic compartments of the Indian coastal environment, make some comments on their environmental sources, their movement through the food chain and possible ecotoxicological risk of health in biota including humans. The prevalent HCH, DDT and HCB concentrations differ markedly in eastern and western coast of India reflecting differing agricultural and other usage and their ultimate input into the coastal environment by several rivers and the bioturbation activities of macrozoobenthos (bivalve mollusks, polychaetous annelids, etc.). In several cases, the DDT levels exceeded the effects range-low (ER-L) and could thus cause acute biological impairments, in comparison with the sediment quality guidelines. Contributions of DDT metabolites (DDT, DDD and DDE residues) vary in different Indian coastal regions predominated by pp'-DDT and pp'-DDD. Measured concentrations of HCHs were lower than DDTs that might be due to higher water solubility, vapor pressure and biodegradability of the latter. HCH and DDT residues in fish in India were lower than those in the temperate countries indicating a lower accumulation in tropical fish, which might be related to rapid volatilization of this insecticide in the tropical environment. The concentrations of other chlorinated pesticides (aldrin, dieldrin, eldrin, methoxychlor, endosulfan sulphate) were lower and not generally of great concern.     

Lead and cadmium levels in coastal benthic algae (seaweeds) of Tenerife,Canary Islands

Lead and cadmium levels of some species of brown-algae (Phaeophyta) from the mesolittoral (intertidal area) of the Island of Tenerife (central-eastern Atlantic) were determined by Atomic Absorption Spectrometry. The quality control was carried out using a standard "CRM 279 Ulva lactuca".The mean, minimum and maximum concentrations were 11.21, 2.090 and 81.795 microg/g/dw; and 1.13, 0.190 and 5.130 microg/g/dw for lead and cadmium, respectively. The fact that samples registering the highest cadmium concentrations were the same as those which showed the highest lead level corresponding to a sampling station nearby an urban water outlet could be relevant.     

Key factors determining the ecological niche of the Himalayan marmot, Marmota himalayana Hodgson (1841)

Four key factors determining the ecological niche of the Himalayan marmot, Marmota himalayana Hodgson (1841), in the Central Himalayas (Nepal) have been identified. These are elevation above sea level, temperature, the presence of accumulative formations, and feeding conditions. The Himalayan marmot ecologically differs from all other marmots of the world fauna, and the main difference is that the lower boundary of its range lies very high—3000 m above sea level.     

Interaction of total N-nitroso compounds in environment and in vivo on risk of esophageal cancer in the coastal area, China

Shantou, China, is one of the endemic regions of esophageal cancer (EC) in the coastal areas, but the relationship between the multiple exposures of total N-nitroso compounds (TNOCs) and the high risk of EC to date is unclear. This study is to estimate the potential integrative role of multiple exposures of environmental and endogenous TNOC on the EC risk. We collected randomly the samples of 72 h diet and 24 h urine from 256 healthy male (aged 30-65 years) in the high- and low-risk area for EC, and determined the contents of TNOC and 4 N-nitrosamino acids (NAAs) by a method of chemical fission-Thermal Energy Analyzer (TEA) and gas chromatography--TEA, respectively. We used TNOC and NAAs index to evaluate the integrative effect of multiple TNOC exposures on the EC risk by a logistic model. TNOC intake and urinary TNOC content were higher in the high-risk subjects than that in the low-risk subjects by 1.60 micromol/day and 1.45 micromol/L, respectively. TNOC intake, urinary TNOC content and its interaction were significant factors involved in the higher risk of EC (R(2)=0.685, p=0.000) with predicted Correct Class of 85.6%. The risk of the occurrence of a larger SMR of EC may increase by 4.841-fold for every 1 micromol/day increase in TNOC intake (95% CI 2.370-9.888, p=0.000) and by 4.113-fold for every 1 micromol/L increase in urinary TNOC content (95% CI 2.108-8.023, p=0.000), respectively. The integrally role of multiple exposures of TNOC in environment and in vivo may increase the risk of EC in the coastal areas in eastern Guangdong, China.     

Uncovering causes and effects of desertification using a Leopold matrix in Binh Thuan Province,Vietnam

Vietnam is a coastal country projected to be heavily affected by climate change.Binh Thuan Province is part of the driest region of Vietnam and is prone to desertification.An expert panel participated in developing a Leopold matrix which allowed for identification of desertification impact factors on the province's socioeconomic activities and assessment of the strength of cause-effect relationships in terms of magnitude and importance.Land use planning,surface water,and the length of the dry season are considered the most important causes,with the overall highest scores for both magnitude and importance in the cause-effect relationship.The largest effects of the different factors are perceived on water supply for agriculture and household use.Water availability and land use planning are important remedial action domains,while drought and land cover require monitoring to assess impacts.The indicators of cause and effect can be used in a longer-term general monitoring and assessment framework to combat desertification in the area.     

Measuring sustainable urbanization in China: a case study of the coastal Liaoning area

The global urbanization process poses a serious challenge to achieving sustainable development. The significance of sustainable urbanization has been increasingly appreciated, yet, very little empirical evidence has been provided for this prospect. In this paper, we use the Human Development Index and the ecological footprint to measure the sustainability of the coastal Liaoning area. We then use the quadrant map approach to determine the relationship between sustainability and urbanization. The results show that the coastal area has made progress in sustainable urbanization in the social dimension. Improvement in the environmental dimension has been dynamic. Our results indicate that sustainable urbanization is a dynamic, multi-dimensional progress that requires regular monitoring and reevaluation. This paper also highlights the importance of choosing more complete indicators for measuring the sustainability of urbanization, as no single model or measurement is sufficient for quantifying the different dimensions of sustainability.     

Soil-water distribution coefficients and plant transfer factors for (134)Cs, (85)Sr and (65)Zn under field conditions in tropical Australia

Measurements of soil-to-plant transfer of (134)Cs, (85)Sr and (65)Zn from two tropical red earth soils ('Blain' and 'Tippera') to sorghum and mung crops have been undertaken in the north of Australia. The aim of the study was to identify factors that control bioaccumulation of these radionuclides in tropical regions, for which few previous data are available. Batch sorption experiments were conducted to determine the distribution coefficient (K(d)) of the selected radionuclides at pH values similar to natural pH values, which ranged from about 5.5 to 6.7. In addition, K(d) values were obtained at one pH unit above and below the soil-water equilibrium pH values to determine the effect of pH. The adsorption of Cs showed no pH dependence, but the K(d) values for the Tippera soils (2300-4100 ml/g) exceeded those for the Blain soils (800-1200 ml/g) at equilibrium pH. This was related to the greater clay content of the Tippera soil. Both Sr and Zn were more strongly adsorbed at higher pH values, but the K(d) values showed less dependence on the soil type. Strontium K(d)s were 30-60 ml/g whilst Zn ranged from 160 to 1630 ml/g for the two soils at equilibrium pH. With the possible exception of Sr, there was no evidence for downward movement of radionuclides through the soils during the course of the growing season. There was some evidence of surface movement of labelled soil particles. Soil-to-plant transfer factors varied slightly between the soils. The average results for sorghum were 0.1-0.3 g/g for Cs, 0.4-0.8 g/g for Sr and 18-26 g/g for Zn (dry weight) with the initial values relating to Blain and the following values to Tippera. Similar values were observed for the mung bean samples. The transfer factors for Cs and Sr were not substantially different from the typical values observed in temperate studies. However, Zn transfer factors for plants grown on both these tropical soils were greater than for soils in temperate climates (by more than an order of magnitude). This may be related to trace nutrient deficiency and/or the growth of fungal populations in these soils. The results indicate that transfer factors depend on climatic region together with soil type and chemistry and underline the value of specific bioaccumulation data for radionuclides in tropical soils.     

Effects of ecological factors on size-related traits in the ground beetle Carabus granulatus L. (Coleoptera,Carabidae)

Multivariate analysis of variation in the metric characters in the ground beetle C. granulatus has been performed. It has been shown that the beetle body size increases toward the center of its range, urbanization has a positive effect on all metric traits, but the effect of habitat vegetation has no definite trend. The structure of variation in the metric characters estimated by the principal components method depends on all ecological factors considered: the locality in the geographic range, level of anthropogenic influence, and degree of biotope openness.