涪陵地区农田径流水体中三氮含量及分布特征

本文在涪陵地区大面积和定点采集了农田径流水样品，测定了径流水体中的三氮含量。探讨了径流水体三氮随产流时间的变化，分析了干旱时间，水体流动等因素对三氮含量的影响。结果表明，干旱时间，径流水体流动对三氮含量有一定的影响。经统计分析，涪陵地区农田径流水体中的ＮＨ３－Ｎ，ＮＯ３＾－－Ｎ，ＮＯ２＾－－Ｎ和Ｔ－Ｎ含量分别为０．８４０，０．９７０，０．１０７和２．０７ｍｇ／ｌ。     

中药川附子痕量砷的测定

本文报道了以ＨＮＯ３ － ＨＣｌＯ４ 混酸消化、Ｈ２ＳＯ４ － ＫＩ－ Ｔｅ（ Ⅳ） 体系极谱法测定中药川附子中的砷。该方法使样品消化过程的砷损失大为减少并简化了分析过程。样品中砷含量在０－２ ～０－６μｇ·ｇ－ １ ,回收率８４ ％ ～１０８ ％ 。     

AAS与ICP—AES间接测定天然水中硫酸盐

本文以ＳＯ４＾２－与过量Ｂａ＾２＋形成ＢａＳＯ４沉淀反应为基础，较详细地讨论了反应条件，从而拟定了用ＡＡＳ和ＩＣＰ－ＡＥＳ间接测定天然水中ＳＯ４＾２－的方法、确定了方法的精密度，ＡＡＳ法的ＲＳＤ％为１．５，ＩＣＰ－ＡＥＳ法为３．２， 两种方法对比分析的结果接近，误差为１．０％（相对）。用于天然水中ＳＯ４＾２－的测定，获得满意的结果。     

美国降低燃用低反应性煤电站锅炉氮氧化物排放经验

介绍美国ＮＥＰ（Ｎｅｗ Ｅｎｇｌａｎｄ Ｐｏｗｅｒ）电力公司所属Ｓａｌｅｍ Ｈａｒｂｏｒｅ热电厂ＮＯ．１炉（８７ＭＷ）及ＮＯ．３炉（１５５ＭＷ）燃用低反应性煤时装用新型“低害”（低污染）燃烧器结合使用沿炉膛高度不同标高处注入尿素溶液（ＨＮ３）的ＳＮＣＲ（非选择性催化还原）系统和两段（级）燃烧技术经验，使ＮＯｘ排放浓度达到美国麻省州环保部有害气体允许排放标准（３８０ｍｇ／ｍ＾３，当Ｏ２＝６％时）。     

示差脉冲阳极溶出伏安法测定中药川附子痕量铅镉

本文报道了以ＨＮＯ３－ＨＣｌＯ４湿法消化、醋酸盐介质法差脉冲阳极溶出伏安法测定中药川附子中的铅镉。样品中铅镉含量分别在０．２－０．４μｇ．ｇ＾－１、０．０３－０．１６μｇ．ｇ＾－１,回收率９０－１１０％。     

纳氏试剂光度法测定废水中氨氮的问题讨论

应用纳氏试剂比色法测定废水中的氨氮时,水样显色后稳定时间短,影响测定结果的准确性,针对这一问题进行了实验研究。实验中对主要影响因素Ｉ－和ＯＨ－的浓度变化进行了条件实验,结果表明选用所配的Ⅲ型纳氏试剂（ＫＩ含量为７．５ｇ）,可获得稳定的有色胶体,也可采用Ⅰ型纳氏试剂（ＫＩ含量为７．０ｇ）、在中和硼酸后再多加２ｍＬＮａＯＨ（１ｍｏｌ／Ｌ）,也可获得稳定的有色胶体。     

PRA浓度和显色温度对West—Gaeke法测定SO2的回归斜率和空白值的影响

试验研究表明，Ｗｅｓｔ－Ｇａｅｋｅ法制定大气ＳＯ２，空白试验值不仅随显色温度增高而增高，而且随ＰＲＡ浓度增高而增高。尤其，在２０±２℃时，ＰＲＡ浓度＞０．０１６％时，校准曲线斜率比方法规定值偏高；称取ＰＲＡ０．１００ｇ提纯后使用，在３０℃时，回归斜率比方法规定值偏低。本文提出了对方法的补充意见。     

离子色谱法测定钻井废水中的S~(2-)

川东气田生产过程中产生的废水含有硫化物,且色度深、浊度大。为测定废水中的Ｓ２－含量,实验探索了将Ｓ２－氧化成ＳＯ２－４后用离子色谱测定的方法。进行了Ｓ２－的转化率实验,结果表明：Ｓ２－含量在０～２．７ｍｇ／Ｌ范围内可以被完全氧化成ＳＯ２－４,转化率为９８．８％～１０８．０％。同时进行了该方法的精密度和准确度实验,并与碘量法进行了对比,对同一标样和实际样品的测定两种方法的结果吻合较好,该方法测定钻井废水中的Ｓ２－含量,可以避免色度、浊度的干扰,且简便、灵敏、准确     

利用高炉渣开发硅肥

最近几年宝钢集团与上海市有关科研部门合作 ,利用高炉渣开发新型肥料 -硅肥 ,这将使宝钢高炉渣的开发利用再向前发展一步 ,也将对上海地区的农业生产做出一份有益的贡献。１硅肥的增产机理硅肥是一种以含氧化硅（ＳｉＯ２）和氧化钙（ＣａＯ）为主的矿物质肥料 ,它是水稻等作物生长不可缺少的营养元素之一。自５０年代以来 ,日本、韩国、东南亚等许多国家对硅肥在农业上的推广应用进行了富有成效的研究开发。硅肥现被国际土壤学界确认为继氮（Ｎ）、磷（Ｐ２Ｏ５）、钾（Ｋ２Ｏ）之后第四大元素肥料。如水稻生产过程中要吸收大量的硅 ,有２…     

节省投资的利用水膜式除尘器文丘里凝聚器降低电厂锅炉SOx排放技术

介绍俄国近年试成利用在锅炉上广泛应用的水膜式除尘器文丘里凝聚器直接喷注碱液反应剂吸收烟气ＳＯ２技术。在“反应剂／二氧化硫重量比为０．５至０．６时,文氏管的脱硫效率达４０％”。该项具有投资省,系统简,运行维护易、适用性强等优点,我国现有在数量大,分布广装用水膜式除尘器的中、小型锅炉降低ＳＯ２排放有参考价值。     

Losses of surface runoff, total solids, and nitrogen during bermudagrass establishment on levee embankments

Nutrient and sediment runoff from newly constructed levee embankments pose a threat to water quality during soft armor vegetation establishment. Research was initiated in 2008 and 2009 to evaluate the effect of bermudagrass ( L.) coverage and N source on nutrient and sediment runoff from levee embankments during establishment. Bermudagrass plots were seeded at 195.3 kg pure live seed ha and fertilized at 50 kg N ha using a water-soluble N source, urea or NH-NO, or slow-release N source, S-coated urea (SCU) or urea formaldehyde (UF), with controls unfertilized. Vegetative cover percentage, time until the onset of runoff, runoff volume, and total solids (TS), NO-N, and NH-N concentrations were measured from simulated and natural rainfall events for 70 d in 2008 and 56 d in 2009. Bermudagrass at 90% grass cover delayed the onset of runoff an additional 441 to 538 s and reduced runoff volumes 74 to 84% of that exhibited at 10% grass cover. Nitrogen fertilizers did not accelerate bermudagrass growth sufficiently, however, to reduce TS loading compared with unfertilized bermudagrass in either year of the study. The application of urea and SCU resulted in cumulative N losses of 2.45 and 3.13 kg ha compared with 1.59 kg ha from the unfertilized bermudagrass in 2008, and 1.73 kg ha from NH-NO vs. 0.24 kg ha from controls in 2009. Only UF increased bermudagrass establishment without increasing cumulative N losses compared with unfertilized bermudagrass. Therefore, the benefit of greater erosion and runoff resistance expected from N-accelerated vegetative growth did not occur but had the unintended consequence of higher N losses when water-soluble N and SCU fertilizers were applied.     

Land application of domestic effluent onto four soil types: plant uptake and nutrient leaching

Land application has become a widely applied method for treating wastewater. However, it is not always clear which soil-plant systems should be used, or why. The objectives of our study were to determine if four contrasting soils, from which the pasture is regularly cut and removed, varied in their ability to assimilate nutrients from secondary-treated domestic effluent under high hydraulic loadings, in comparison with unirrigated, fertilized pasture. Grassed intact soil cores (500 mm in diameter by 700 mm in depth) were irrigated (50 mm wk(-1)) with secondary-treated domestic effluent for two years. Soils included a well-drained Allophanic Soil (Typic Hapludand), a poorly drained Gley Soil (Typic Endoaquept), a well-drained Pumice Soil formed from rhyolitic tephra (Typic Udivitrand), and a well-drained Recent Soil formed in a sand dune (Typic Udipsamment). Effluent-irrigated soils received between 746 and 815 kg N ha(-1) and 283 and 331 kg P ha(-1) over two years of irrigation, and unirrigated treatments received 200 kg N ha(-1) and 100 kg P ha(-1) of dissolved inorganic fertilizer over the same period. Applying effluent significantly increased plant uptake of N and P from all soil types. For the effluent-irrigated soils plant N uptake ranged from 186 to 437 kg N ha(-1) yr(-1), while plant P uptake ranged from 40 to 88 kg P ha(-1) yr(-1) for the effluent-irrigated soils. Applying effluent significantly increased N leaching losses from Gley and Recent Soils, and after two years ranged from 17 to 184 kg N ha(-1) depending on soil type. Effluent irrigation only increased P leaching from the Gley Soil. All P leaching losses were less than 49 kg P ha(-1) after two years. The N and P leached from effluent treatments were mainly in organic form (69-87% organic N and 35-65% unreactive P). Greater N and P leaching losses from the irrigated Gley Soil were attributed to preferential flow that reduced contact between the effluent and the soil matrix. Increased N leaching from the Recent Soil was the result of increased leaching of native soil organic N due to the higher hydraulic loading from the effluent irrigation.     

Role of rainfall intensity and hydrology in nutrient transport via surface runoff

Loss of soil nutrients in runoff accelerates eutrophication of surface waters. This study evaluated P and N in surface runoff in relation to rainfall intensity and hydrology for two soils along a single hillslope. Experiments were initiated on 1- by 2-m plots at foot-slope (6%) and mid-slope (30%) positions within an alfalfa (Medicago sativa L.)-orchardgrass (Dactylis glomerata L.) field. Rain simulations (2.9 and 7.0 cm h(-1)) were conducted under wet (spring) and dry (late-summer) conditions. Elevated, antecedent soil moisture at the foot-slope during the spring resulted in less rain required to generate runoff and greater runoff volumes, compared with runoff from the well-drained mid-slope in spring and at both landscape positions in late summer. Phosphorus in runoff was primarily in dissolved reactive form (DRP averaged 71% of total P), with DRP concentrations from the two soils corresponding with soil test P levels. Nitrogen in runoff was mainly nitrate (NO3-N averaged 77% of total N). Site hydrology, not chemistry, was primarily responsible for variations in mass N and P losses with landscape position. Larger runoff volumes from the foot-slope produced higher losses of total P (0.08 kg ha(-1)) and N (1.35 kg ha(-1)) than did runoff from the mid-slope (0.05 total P kg ha(-1); 0.48 kg N ha(-1)), particularly under wet, spring-time conditions. Nutrient losses were significantly greater under the high intensity rainfall due to larger runoff volumes. Results affirm the critical source area concept for both N and P: both nutrient availability and hydrology in combination control nutrient loss.     

Fertilizer source effect on ground and surface water quality in drainage from turfgrass

Nutrients in surface and ground water can affect human and aquatic organisms that rely on water for consumption and habitat. A mass-balance field study was conducted over two years (July 2000-May 2001) to determine the effect of nutrient source on turfgrass runoff and leachate. Treatments were arranged in an incomplete randomized block design on a slope of 7 to 9% of Arkport sandy loam (coarseloamy, mixed, active, mesic Lamellic Hapludalf) and seeded with Kentucky bluegrass (Poa pratensis L.) and perennial ryegrass (Lolium perenne L.). Three natural organic (dairy and swine compost and a biosolid) and two synthetic organic nutrient sources (readily available urea and controlled-release N source sulfur-coated urea) were applied at rates of 50 and 100 kg N ha(-1) per application (200 kg ha(-1) yr(-1)). Runoff water collected from 33 storms and composite monthly leachate samples collected with ion exchange resins were analyzed for nitrate (NO3- -N), phosphate (PO4(3-) -P), and ammonium (NH4+ -N). Nutrient concentrations and losses in both runoff and leachate were highest for the 20-wk period following turfgrass seeding. The NO3- -N and NH4+ -N losses declined significantly once turfgrass cover was established, but PO4(3-) -P levels increased in Year 2. Turf's ability to reduce nutrient runoff and leachate was related to overall plant growth and shoot density. The use of natural organics resulted in greater P loss on a percent applied P basis, while the more soluble synthetic organics resulted in greater N loss.     

Growth of alfalfa in sludge-amended soils and inoculated with rhizobia produced in sludge

The efficiency of rhizobial inoculants produced in wastewater sludge used as a growth medium and as a carrier was compared with that of inoculants produced in yeast mannitol broth (YMB) medium and by using peat as a carrier. Alfalfa (Medicago sativa L.) plants were inoculated with solid and liquid Sinorhizobium meliloti inoculants and grown in pots containing two soil types (Kamouraska clay soil and Saint-André sandy soil). The effect of various levels of sludge amendment (60 and 120 kg N/ha) and nitrogen fertilizer (60 kg N/ ha) was also studied. The sludge-based inoculants showed the same symbiotic efficiency (nodulation and plant yield) as YMB-based inoculants. The inoculation increased the nodulation indexes from 4-6 to 8-12, and the rhizobial number from 10(3) (uninoculated soils) to 10(6)-10(7) cells/g in inoculated soils. However, the shoot dry weights and the nitrogen contents were not increased significantly by the inoculation. Applying sludge as an amendment enhanced the rhizobial number in soils from 10(3) to 10(4) cells/g and improved significantly the plant growth (shoot dry weights and nitrogen contents). This improvement increased with sludge rate and with the cut (three cuts). Compared with sludge, N fertilizer gave lower plant yields. The nodulation was not affected by sludge and N-fertilizer application. The texture and physico-chemical properties of soil were found to affect the yield and nitrogen content of the plants. In this study, macroelements and heavy metals were at acceptable levels and were not considered to be negative factors.     

Use of wastewater and compost extracts as nutrient sources for growing nursery and turfgrass species

Nutrient salts present in liquid by-products following waste treatment are lost resources if not effectively recycled, and can cause environmental problems if improperly disposed. This research compared the growth response and mineral nutrient status of two nursery and two turfgrass species, hydroponically supplied with nutritive by-product extracts derived from anaerobically digested municipal solid waste (MSW) and aerobically composted organic wastes from the mushroom and MSW industries. Forsythia (Forsythia x intermedia 'Lynwood') and weigela (Weigela florida 'Red Prince'), and creeping bentgrass (Agrostis palustris Huds.) and Kentucky bluegrass (Poa pratensis L.), were grown in nutrient solutions/extracts prepared from: (i) half-strength Hoagland's #2 solution (HH; control), (ii) Plant Products liquid fertilizer (PP; g kg(-1): 180 N; 39 P; 224 K), (iii) spent mushroom compost (SMC), (iv) MSW compost (GMC), and (v) intra-process wastewater from the anaerobic digestion of MSW (ADW). Additional nutrient solutions (SMC-A, GMC-A, and ADW-A) were prepared by amending the original solutions with N, P, and/or K to concentrations in HH (mg L(-1): 105 N; 15 P; 118 K). Plants receiving the SMC-A extract grew best or at least as well as those in HH, PP, and the amended GMC-A and ADW-A solutions. This study indicated that, with proper amendments of N, P, K and other nutrients, water-soluble constituents derived from organic waste treatment have potential for use as supplemental nutrient sources for plant production.     

Runoff losses of phosphorus and nitrogen imported in sod or composted manure for turf establishment

Nutrient loading on impaired watersheds can be reduced through export of sod grown with manure and export of composted manure for turf production on other watersheds. Effects of the sod and manure exports on receiving watersheds were evaluated through monitoring of total dissolved phosphorus (TDP) and N concentrations and losses in runoff from establishing turf. Three replications of seven treatments were established on an 8.5% slope of a Booneville soil (loamy-skeletal, mixed, superactive Pachic Argicryolls). Three treatments comprised imported 'Tifway' bermudagrass [Cynodon dactylon (L.) Pers. x C. transvaalensis Burtt-Davy) sod grown with composted dairy manure (382 or 191 kg P ha(-1)) or fertilizer (50 kg P ha(-1)). Three treatments were sprigged with Tifway and top-dressed with either composted manure (92 or 184 kg P ha(-1)) or fertilizer (100 kg P ha(-1)). The control was established bermudagrass [Cynodon dactylon (L.) Pers. var. Guymon]. During eight fall rain events, mean TDP concentration in runoff (7.8 mg L(-1)) from sprigged Tifway top-dressed with manure (84 kg P ha(-1)) was 1.6 times greater than sod imported with 129 kg manure P ha(-1). During the first fall event, mass losses of TDP (232 mg m(-2)) and total Kjeldahl nitrogen (TKN) (317 mg m(-2)) from sprigged treatments top-dressed with manure or fertilizer were nearly three times greater than manure-grown sod. Percentages of manure P lost as TDP in runoff from imported sod were 33% of percentages lost from sprigged treatments top-dressed with manure. Sod grown with manure P rates of 190 kg P ha(-1) can be imported without increasing runoff losses of TDP compared with conventional fertilization of establishing turfgrass.     

Vetiver (Vetiveria zizanioides) responses to fertilization and salinity under irrigation conditions

Vetiver (Vetiveria zizanioides) has not been widely introduced in arid and semi-arid regions where irrigation, fertilization, and salinity are important factors in plant growth. The main objective of this study was to determine the response of vetiver to fertilization (fertigation) and salinity and their interactions under irrigated conditions. The experiment was conducted in a greenhouse in 10-L pots. Combined effects of three nutrients concentrations and three salinity levels of electrical conductivity (EC) 1, 3 and 6 dS/m in the irrigation water on growth and transpiration of vetiver plants and the content of different elements in their foliage were studied. Similar contents of 3.7 g/kg Na, 5.77 g/kg Ca and 2.55 g/kg Mg were found in the foliage of all the plants irrigated with the different fertilizer and salinity levels. Concentrations of 59 mg/L N and 36.1 mg/L K in the irrigation water were sufficient for vetiver plants needs at the different salinity levels tested. The salinity threshold (the maximum EC in the soil solution that does not cause a significant yield reduction) for vetiver was between 3 and 6 dS/m. A concentration of 15.2 mg/L P in the irrigation water was the optimum value for vetiver growth in the three salinity levels, resulting in an average content of 5.95 g/kg P in plant foliage. It is suggested that vetiver is sensitive to excess P (>8.66 g/kg). Increasing EC in the irrigation water to 6 dS/m decreased plant foliage biomass mainly due to an increase in the osmotic potential of the irrigation water and high Cl⁻ concentration in the foliage.     

Changes in soil nitrogen and phosphorus under different broiler production systems

In a field study, soils of four conventional free-range and organic broiler runs were analyzed for N and P concentrations in the years 2000 and 2001. Zones of different use intensity by broilers were identified on the free runs and mean zonal nutrient contents were compared with each other. Intensity of use by birds and spatial distribution of soil nutrient concentrations were found to be related to each other. Fecal N input by broilers resulted in accumulation of soil mineral nitrogen (N(min)) contents down to a 90-cm sampling depth. In highly frequented "hot spots," plant requirement as defined by the German "N-Basis-Sollwert" (110 kg/ha N(min)) for grassland was exceeded in all four cases. This implies an increased environmental risk of ammonia volatilization and nitrate leaching. Fecal P input by broilers resulted in accumulation of plant-available and thus mobile soil P (phosphorus extracted with calcium-acetate-lactate [P(CAL)] and phosphorus extracted with water [P(w)]) in the most intensely used zones. In these areas, soil P contents exceeded 90 mg/kg P(CAL) (upper limit of soil test P defined in Germany for optimum plant yield) by as much as 217 mg/kg, which indicates an enhanced risk of P loss from the soil via runoff or leaching. The conclusion might be drawn that, with regard to nutrient loss from free-run soils, intensive indoor production in a closed system may be more environmentally neutral than conventional free-range or organic production. However, to put this into perspective, the scope of the environmental risk connected with spatially limited point accumulation of nutrients should be considered. Furthermore, an environmental evaluation must also account for the fate and environmental effects of the broiler litter produced inside the broiler house.     

Nitrous oxide fluxes in turfgrass: effects of nitrogen fertilization rates and types

Urban ecosystems are rapidly expanding and their effects on atmospheric nitrous oxide (N2O) inventories are unknown. Our objectives were to: (i) measure the magnitude, seasonal patterns, and annual emissions of N2O in turfgrass; (ii) evaluate effects of fertilization with a high and low rate of urea N; and (iii) evaluate effects of urea and ammonium sulfate on N2O emissions in turfgrass. Nitrogen fertilizers were applied to turfgrass: (i) urea, high rate (UH; 250 kg N ha(-1) yr(-1)); (ii) urea, low rate (UL; 50 kg N ha(-1) yr(-1)); and (iii) ammonium sulfate, high rate (AS; 250 kg N ha(-1) y(-1)); high N rates were applied in five split applications. Soil fluxes of N2O were measured weekly for 1 yr using static surface chambers and analyzing N2O by gas chromatography. Fluxes of N2O ranged from -22 microg N2O-N m(-2) h(-1) during winter to 407 microg N2O-N m(-2) h(-1) after fall fertilization. Nitrogen fertilization increased N2O emissions by up to 15 times within 3 d, although the amount of increase differed after each fertilization. Increases were greater when significant precipitation occurred within 3 d after fertilization. Cumulative annual emissions of N2O-N were 1.65 kg ha(-1) in UH, 1.60 kg ha(-1) in AS, and 1.01 kg ha(-1) in UL. Thus, annual N2O emissions increased 63% in turfgrass fertilized at the high compared with the low rate of urea, but no significant effects were observed between the two fertilizer types. Results suggest that N fertilization rates may be managed to mitigate N2O emissions in turfgrass ecosystems.