BOD测试的动力学研究

一、引 言 污水含有社会产生的各种水载废物,除生活性质的外,常含有工业废水。污水的化学成份复杂,它的特性取决于可以测定的一些通用参数,其中最重要的是污水与氧的结合力,它随污水中存在的可氧化物质的性质和数量而变化。通常用污水的需氧量作为测定污水与氧的结合力的根据,大小用污水中存在的可氧化物质氧化所需要的氧的数量表示。污水治理的目标就是使污水的需氧量降     

德意志联邦共和国环境研究报告书

一、环境保护的出发点 在历史发展的各个阶段,人类都在以各种各样的方法影响着它周围的环境。由于工业社会的高速发展,自然平衡的形式在数量以及范围上所遭到的猛烈侵犯而造成的世界范围的重大危险正在威胁着人类。对不可更新的原料的需求量的提高以及工业化和城市化都在使生物     

广东区域酸雨污染模拟研究

运用数值模拟方法，使用一年365日的风速资料、12个月的降水资料和环境监测资料以及年平均的污染源资料，对广东地区的酸雨污染进行了较细致的分析。结果认为，以日为基础的累积计算，对于提高模拟酸雨污染的能力是很有帮助的。广东省的酸雨污染主要是由自身排放的污染物造成，外来的污染是次要的，在广东边界地区发现受到外省污染的显著痕迹。     

生态区划的原则及其特征

由于社会经济的发展和人口的急剧增加,使得全球和区域性的生态环境问题日益尖锐,从而严重地阻碍了经济的进一步发展。如何协调发展与环境保护之间的矛盾,维护区域经济的可持续发展,是当前亟待解决的问题。这就要求对区域生态环境问题的形成机制及其演变规律进行细致地研究,进而划分不同的区域,提出生态环境的整治方案,这正是生态区划的研究内容。本文对生态区划的目的、原则和依据、划分的指标体系、生态区划的要素及特征进行了详细的论述,同时指出在我国经济发展的今天进行生态区划的必要性和迫切性。     

煤气废水的可处理性

加利福尼亚(州)的得克萨斯研究中心进行了关于煤的气化中试工厂废水的采样和废水可处理性的研究。这些研究是为评定废水和开发废水回收系统的设计资料进行的。废水的一些分析是在现场进行的。另外的化学分析和可处理性的研究是在Westwood, New Jersey实验室进行的。 所处理的废水包括循环气体的直接冷却水和淋洗水,它们是从得克萨斯气化器在溶     

地下水水质评价的逻辑斯谛曲线模型

为检验已订的地下水水质评价标准的合理性，解决各单项水质指标的评估结果的不相容性问题，提高水质等级模型的分辨率，提出了一种新的水质评价模型－逻辑斯谛曲线模型，它的水质等级是连续的实数值。根据LOG模型的参数值可以分析各水质指标值对水质等级的影响程度，据此检验原订水质等级标准的合理性。并给出了基于实码遗传算法的LOG建模的实施方案。实例研究的结果说明，该方案是可行、有效且通用的，在环境质量综合评价中具有广泛的应用价值。     

水资源的持续开发和利用

随着人品的增长和经济的发展,越来越多的国家正面临着严重的水危机、水质的恶化和水生态系统的破坏使许多国家的淡水供应出现危机,所以水资源必须得到保护和合理的开发。本文探讨了全球水资源的短缺及其原因,并提出了解决水资源短缺的途径。     

运河(杭州段)水体自净规律的实验室模拟

天然水体本身具有一定的自净能力,在一定的限度内,河流可以通过一系列复杂的物理、化学及生物作用净化水体中的污染物(?)从而维持其正常的生态平衡。进入河流的(?)染物一旦超过了其自净能力的范围,河流的这种正常的平衡就被破坏,水体逐渐恶化。为了合理利用水环境的自净能力,实现水体的良性循环,必须掌握水体净化所具有的特定规律。水体自净过程的两个突出表现是污染物的     

氨存在时二氧化硫在大气中的氧化

三年来每天进行SO_2和NH_3的浓度测量,根据每天的测量数据得到的月平均值显示出两种季节性的循环:冬季SO_2的浓度高,NH_3的浓度低;夏季则SO_2的浓度低,NH_3的浓度高。 用Junge和Ryan的NH_3—SO_2液态水模型在野外测量时计算的NH_3和SO_2浓度与观测的结果非常一致。 像Junge和Ryan模型指出的那样,夏季如果NH_3的浓度高,被氧化的SO_2的百分率就高,在此期间光化学反应产生的游离基使得SO_2的气相氧化更加强烈。 通过1972～1973年间硫酸盐的野外测量得到的SO_2氧化百分率与应用NH_3—SO_2液态水体系计算的结果的比较,证实了此模型应用于威尼斯环境的正确性。     

苏联生态环境的保护与研究

绪言 生态环境是指以人类为中心的生物存在与活动的空间,一切与生物有交互作用和关系的环境。生态环境研究的基本含义就是:用生态学和环境料学的观点和基本原理,来研究人类活动与人类赖以生存和发展的环境因素之间的相互关系及其发展演化的机理和规律。生态环境概念的提出,是人们对环境问题认识进一步深化的必然结果。生态环境研究的开展,标志着环境料学的研究工作已进入一个新阶段,它是进行生态建设的基础,是为建设一个经济、社会、环境三者协调、持续发展的人工复合生态大系统而探索科学规律、以便更好的指导人类的活动。生态环境研究的特点在于它的综合性,它需要宏观与微观相结合。 全球性的大生态环境的研究是当前环境科研工作的一个大趋势,是联合国环境规划署成立15年来工作积累的一个新要求,是我国环境科研工作的一个新起点。为此,中科院于198G年10月成立了中国科学院生态环境研究中心。     

Laboratory study on leachability of five herbicides in South Australian soils

Abstract

Norflurazon, oxadiazon, oxyfluorfen, trifluralin and simazine are herbicides widely used in the vineyards of the Barossa Valley, South Australia. The leaching behaviour of norflurazon, oxadiazon, oxyfluorfen and trifluralin was investigated on four key soils in the Barossa Valley. Leaching potential on packed soil columns and actual mobility using intact soil columns were investigated. On the packed soil columns, norflurazon was the most leachable herbicide. More of the herbicides were detected in the leachates from the sandy soils (Mountadam and Nuriootpa) than from the clayey soils (Lyndoch and Tanunda). Organic matter is generally low in soils in the Barossa region. Porosity and saturated conductivity significantly affect herbicide movement and in the sandy Mountadam and Nuriootpa soils, the water flux is greater than for the higher clay content Lyndoch and Tanunda soils. Increasing the time interval between herbicide application and the incidence of “rainfall”; reduced the amounts of herbicides found in the leachates. The use of intact soil columns and including simazine for comparison showed that both norflurazon and simazine were present in the leachates. Simazine was the first herbicide to appear in leachates. Sectioning of the intact soil columns after leaching clearly demonstrated that norflurazon and simazine reached the bottom of the soil columns for all soils studied. Greater amounts of norflurazon were retained in the soil columns compared with simazine. The other herbicides were mostly retained in the initial sections of the soil columns.     

Source identification of copper, lead, nickel, and zinc loading in wastewater reclamation plant influents from corrosion of brass in plumbing fixtures

A natural experiment indicated that a link between the presence and concentration of four elements, copper, lead, nickel, and zinc in the influent to two wastewater reclamation plants to the presence and concentrations of the same four elements in the tap water of residential properties. There were 36 populations of results that were assessed for the normality of their distribution, the difference in their median concentrations, the similarity in the ratios of their median concentrations, and the correlations of the concentrations. The results of this study suggest that brass corrosion is the major source of these four elements in the water reclamation plants influent and that there are two distinct populations of brass sources, those in the early stages of dezincification where the release of the non-copper elements is dominant and those in the later stages where the release of copper dominates and the type of brass that is corroding.     

完全一体化结构的带式污泥浓缩压滤机

通过对带式浓缩压滤机设计和以往的工程实践,从机械结构设计角度分析和对比了完全一体化带式浓缩压滤机与传统意义上的(搭接式)带式浓缩压滤机结构特点,并且提供了完全一体化带式浓缩压滤机的设计参数。     

Cytotoxic and genotoxic effects of metal(oid)s bioactivated in rocket leaves (Eruca vesicaria subsp. sativa Miller)

Rocket is an important source of essential elements. However, it may also accumulate toxic elements such as metal(oids). The objectives of the present work were (i) to study the uptake of arsenic, lead, cadmium and zinc in rocket grown in contaminated soils, (ii) to establish the genotoxic and cytotoxic activities of this vegetable material, and (iii) to study the modulator role of the glucosinolate and metal contents in the genotoxic/cytotoxic activities. Lead, cadmium and zinc leaf concentrations in our study were over the concentrations allowed by the statutory limit set for metal(oid) contents in vegetables. The accessions were non genotoxic at the different concentrations studied, although one of the accessions showed the highest mutation rates doubling those of negative control. The cytotoxicity assays with HL60 human leukaemia cells showed that the tumouricide activities of rocket leaves decreased with the increasing of metal(oid) concentrations and also with the decreasing of glucosinolate concentrations in their tissues. An interaction between metal(oid)s and glucosinolate degradation products contained in rocket leaves is suggested as the main modulator agents of the biological activity of the plants grown in metal-contaminated soils.     

The occurrence of antihistamines in sewage waters and in recipient rivers

Background, aim and scope  Each year, large quantities of pharmaceuticals are consumed worldwide for the treatment and prevention of human and animal diseases. Although the drugs and the metabolites observed in the wastewaters and in the environment are present at concentrations several orders of magnitude lower than the concentrations required to exert their effects in humans or animals, their long-term impact on the environment is commonly not known. In this study, the occurrence of six antihistamines, which are used for the relief of allergic reactions such as hay fever, was determined in sewage treatment plants wastewaters and in recipient river waters. Materials and methods  The occurrence of the antihistamines cetirizine, acrivastine, fexofenadine, loratadine, desloratadine and ebastine in sewage treatment plants wastewaters and in recipient river waters was studied. The analytical procedure consisted of solid-phase extraction of the water samples followed by liquid chromatography separation and detection by a triple-quadrupole mass spectrometer in the multiple reaction mode. Results  Cetirizine, acrivastine and fexofenadine were detected in both influent and effluent wastewater samples at concentration levels ranging from about 80 to 220 ng/L, while loratadine, desloratadine and ebastine could not be detected in any samples. During sewage treatment, the concentration of the antihistamines dropped by an average of 16–36%. Furthermore, elevated concentrations of antihistamines were observed in samples collected during the season of most intensive plant pollen production, i.e. in May. In the river water samples, the relative pattern of occurrence of cetirizine, acrivastine and fexofenadine was similar to that in the wastewater samples; although the concentration of the compounds was substantially lower (4–11 ng/L). The highest concentrations of the studied drugs were observed near the discharging point of the sewage treatment plant. Discussion  The highest concentrations of antihistamines in STP wastewaters correlate with the outbreak of allergic reaction caused by high amounts of plant pollens in the air. The analysis results of the river water samples show that the antihistamines are carried far away from the effluent discharge points. They may account for a part of the mix of pharmaceuticals and of pharmaceutical metabolites that occur downstream of STPs. Conclusions  Antihistamines are poorly degraded/eliminated under the biological treatment processes applied in the wastewater treatment plants and, consequently, they are continuously being discharged along with other drugs to the aquatic environment. Recommendations and perspectives  As a huge quantity and variety of drugs and their metabolites are continuously discharged to rivers and the sea, the compounds should be considered as contaminants that may possess risks to the aquatic ecosystem. Further studies are urgently needed on the environmental fate of the antihistamines and other pharmaceuticals in the aquatic environment. These studies should be concerned with the stability of the compounds, their transformation reactions and the identity of the transformation products, the distribution of drugs and their uptake and effects in organisms. On the basis of these studies, the possible environmental hazards of pharmaceuticals may be assessed.     

Anaerobic digestion of linear alkyl benzene sulfonates: biodegradation kinetics and metabolite analysis

In the present work the effect of the alkyl chain length and the position of the sulfophenyl substituent of the linear alkylbenzene sulfonates (LAS) on their anaerobic biodegradability have been investigated. Degradation kinetics of the linear alkyl benzene sulfonates homologues, 2C₁₀LAS, 2C₁₂LAS and 2C₁₄LAS, have been studied. It has been also investigated the effect of the isomer type on the degradation rate of the LAS molecule through the comparative study of the 2C₁₀LAS and 5C₁₀LAS isomers. Batch anaerobic biodegradation tests were performed using sludge from the anaerobic digester of a wastewater treatment plant as microorganisms source. Ultimate biodegradation was evaluated from the biogas production whereas primary biodegradation was determined by specific analysis of the surfactant. LAS homologues and isomers showed a negligible primary biodegradation under anaerobic conditions. Furthermore, analysis of sulfophenyl carboxilates (SPC) by LC–MS indicated a low and constant level of these LAS degradation metabolites over the test period. These data are consistent with a minimal transformation of the LAS parent molecule in the anaerobic digesters. On the other hand, the addition of the shortest alkyl chain length homologues, decyl and dodecylbenzene sulfonates, reduces the biogas production whereas the most hydrophobic homologue, the tetradecylbenzene sulfonate, enhances the biogas production. This LAS homologue seems to increase the availability of organic compounds sorbed on the anaerobic sludge promoting their biodegradation.     

Effect of expandable clays and cometabolism on PAH biodegradability

Pyrene and phenanthrene degradation was examined in both single and binary slurry systems for three different natural soils. It was found that the amount of total expandable clays (smectite and vermiculite) was in a good agreement with the achieved rate and extent of biodegradation. For instance, the intrinsic phenanthrene biodegradation rate was 626 microg/L/day for the soil with the largest expandable clay and 3203 microg/L/day for the soil with the least. Similarly, the smallest total pyrene biodegradation (65%) was found for the soil rich in expandable clays, compared to an 82% pyrene reduction in the soil that had the lowest amount. Mass transfer limitation after compound sorption to the clays was more pronounced for the more hydrophobic pyrene. In the presence of phenanthrene, total pyrene biodegradation increased by 2 to 7% due to cometabolism, while the total phenanthrene biodegradation was only enhanced by 0.5 to 5% in the binary system. This research demonstrated that expandable clays might govern the substrate availability to microorganisms and microbial accessibility to substrates. Therefore, the contribution of organic matter and expandable clays to sorption, desorption and biodegradation should be taken equally into account in order to better understand complex bioremediation issues.     

Experimental research on recolonisation with <Emphasis Type="Italic">Anemone nemorosa</Emphasis> of the beech forests of the Ruhr district (Germany) floristically impoverished by air pollution

BACKGROUND, AIM, AND SCOPE: High SO(2) concentrations as have been observed over decades in the Ruhr district lead to a remarkable reduction of leaf area in the majority of the characteristic broad-leafed herbs of the Central European beech forests even after only a few months of experimental fumigation. Thus, it is no wonder in the time of high SO(2) pollution, e.g., in the town of Herne (centre of the Ruhr district), that there was not a single beech forest hosting, for instance, Viola reichenbachiana or Anemone nemorosa. As air quality has improved very much over some decades in the Ruhr district, one can expect a recolonisation of the beech forests by the species of former time characteristic for the herb layer. However, one has to consider that only the air pollution was reduced, while soil acidification and contamination with heavy metals and PAH are, on the short run, irreversible. That is why experiments were carried out, considering the question as to whether recolonisation of the forests of the Ruhr district by the aforementioned species is possible and why such a recolonisation up to now has not occurred. MATERIALS AND METHODS: The experiments were carried out in a beech forest situated in the centre of the Ruhr district in the City of Herne. The wood anemone (A. nemorosa) was chosen as test plant because of its high frequency in beech forests on loess soils outside the Ruhr district, and its absence in beech forests in the Ruhr district. The experiments with A. nemorosa were carried out in three variants with different soils: (a): soil of the local forests (R); (b): soil of the local forests whose soot layer was removed (r); (c): imported soil from a clean air region far away from the Ruhr district (Odenwald). RESULTS: Survival of rhizomes of A. nemorosa is possible for some years in the soils of the Ruhr district; however, the establishment of a population could not be achieved. The results obtained by the imported soil show that it is no longer air pollution, but the soil which prevents the establishment of a population. Sexual reproduction is rather impossible because of the thick litter layer with which all of the Ruhr district's beech forests are covered. DISCUSSION: With respect to the unfavourable chemistry of the soil of the Ruhr district and in consideration of the unfavourable attributes of the soot layer, the author expected the following order of the development of shoot numbers: O > r > R. However, the result is: O > R > r. In contrast to the expected result, the soot layer has no negative but slightly positive effects on the implanted rhizomes. A possible explanation is that the soot layer, which is situated immediately below the top soil, prevents the top soil from drying up and thus even protects the rhizomes from desiccation. Also, the possibility has to be considered that the soot layer functions as a nutrient storage area. CONCLUSIONS: At present, a survival of the rhizomes of A. nemorosa in the soils of the Ruhr district is temporarily possible but does not lead to the establishment of a permanent population. This only can be achieved by additional sexual reproduction. However, the thick litter layer present in all beech forests of the Ruhr district prevents the establishment of seedlings, i.e., it does not allow sexual reproduction to contribute to the population. The soot layer situated below the litter layer represents a second hindrance for germination. Other than seedlings, rhizomes are not negatively affected by the soot layer but even a slight stabilisation has to be stated. As a reason for this slightly positive effect, a protection of the upper mineral soil from desiccation by the hydrophob soot layer has to be considered. Secondly, the soot layer may serve as a nutrient storage which is of particular importance in acid soils, because acidification generally leads to a leeching of nutrients. To answer these questions, detailed further research is necessary. RECOMMENDATIONS AND PERSPECTIVES: In order to restore the formerly rich herbaceous layer of the forests of the Ruhr district, experiments (removal of the litter layer; liming; ploughing) should be carried out at broad-scale to solve the question of how the strong negative effects of the established thick raw humus layer can be reduced or even be avoided. When the problem of the humus layer is solved, the beech forests of the Ruhr district today highly impoverished in species will become a vivid ecosystem, rich in flowering herbaceous species and thus much more attractive for the people of the Ruhr district than at present.     

INFLUENCE OF SOIL ORGANIC MATTER ON THE LEACHING OF POLYCYCLIC AROMATIC HYDROCARBONS IN SOIL

Polycyclic aromatic hydrocarbons (PAHs) are one of the main classes of contaminants in the terrestrial environment. Aside from total organic carbon, the ratio among the different organic matter fractions [dissolved organic matter, fulvic acid (FA), humic acid (HA) and humin] can also affect the mobility of these hydrocarbons in soils. In this study the effect of the whole organic carbon pool has been compared with that of HA and FA on the translocation of four PAHs (biphenyl, fluorene, phenanthrene and pyrene) in soil columns. Oxidized and untreated soil columns with and without HA or FA, were prepared, spilled with hydrocarbons and leached with a 0.01 M CaCl₂ solution. The influence of HA and FA on PAH translocation was investigated through determinations of the PAH contents and total organic carbon (TOC) in the layers of the columns. All molecules were moved vertically by the percolating solutions, their concentrations decreasing with depths. The non-oxidized soil tended to retain more PAHs (96%) than the oxidized one (60%), confirming that organic matter plays an important role in controlling PAH leaching. The whole organic matter pool reduced the translocation of pollutants downward the profile. The addition of HA enhanced this behaviour, by increasing the PAH retention in the top layers (7.55 mg and 4.00 mg in the top two layers, respectively) while FA increased their mobility (only 2.30 and 2.90 mg of PAHs were found in the top layers) and favoured leaching. In fact, in the presence of HA alone, the higher amounts of PAHs retained at the surface and the good correlation (r²=0.936) between TOC and hydrocarbon distribution can be attributed to a parallel distribution of PAHs and HA, while in the presence of FA, the higher mobility of PAHs can be attributed to the high mobility of the humic material, as expected by its extensive hydrophilic characteristics.     

TiO2薄膜气相光催化氧化低浓度三氯甲烷和三氯乙烯的研究

自行设计了气固相光催化实验系统,以铝材为担载体,TCM和TCE为模拟污染物,在常温、常压下,对辐射光源、气体相对湿度、污染物反应浓度等因素对TCM和TCE的光催化降解反应的影响进行了研究.结果表明,在研究所采用的实验条件下,辐射光源采用254 nm时的降解效率要比采用365 nm时高10%左右;气体相对湿度为40%时光催化降解效率最高;随着污染物反应浓度的增加,TCM的降解效率降低,而TCE的降解效率增加.初步的反应动力学研究结果表明,TCM和TCE在二氧化钛表面的光催化降解反应可采用Langmuir-Hinshelwood动力学方程来表征.