Multifunctional metal-organic frameworks in oil spills and associated organic pollutant remediation

The release of toxic organic compounds into the environment in an event of oil spillage is a global menace due to the potential impacts on the ecosystem. Several approaches have been employed for oil spills clean-up, with adsorption technique proven to be more promising for the total reclamation of a polluted site. Of the several adsorbents so far reported, adsorbent-based porous materials have gained attention for the reduction/total removal of different compounds in environmental remediation applications. The superior potential of mesoporous materials based on metal–organic frameworks (MOFs) against conventional adsorbents is due to their intriguing and enhanced properties. Therefore, this review presents recent development in MOF composites; methods of preparation; and their practical applications towards remediating oil spill, organic pollutants, and toxic gases in different environmental media, as well as potential materials in the possible deployment in reclaiming the polluted Niger Delta due to unabated oil spillage and gas flaring.

     

Econometric modelling, estimation and policy analysis of oil spill processes

This paper explores approaches to model specification suitable for empirical investigation of a stochastic oil spill model. We focus on the effects of economic incentive measures on the frequency of oil spills, spill size, and volume of oil spilled. We look into the relationships between parameters that describe the spill generation process and the enforcement effort, using data for the Black and Baltic Seas.     

Droplet charging for wet scrubbers

Water droplet charge/mass of wet scrubbers was measured over the direct charging applied potential range of 0-20 kV, 30-70 pounds per square inch gauge (206.8-482.6 kPa) water pressure, and with spiral, impingement, and whirl nozzles. The measured charge/mass ranged from -0.0005 to 0.2 microcoulomb/gm and was directly related to the applied voltage. The water charge/mass was a function of the spray nozzle, with the smaller orifice lower-flow nozzles having the higher charge/mass.     

Assessment of crude oil biodegradation in arctic seashore sediments: effects of temperature,salinity, and crude oil concentration

The expected increase in offshore oil exploration and production in the Arctic may lead to crude oil spills along arctic shorelines. To evaluate the potential effectiveness of bioremediation to treat such spills, oil spill bioremediation in arctic sediments was simulated in laboratory microcosms containing beach sediments from Barrow (Alaska), spiked with North Slope Crude, and incubated at varying temperatures and salinities. Biodegradation was measured via respiration rates (CO₂ production); volatilization was quantified by gas chromatography/mass spectrophotometry (GC/MS) analysis of hydrocarbons sorbed to activated carbon, and hydrocarbons remaining in the sediment were quantified by GC/flame ionization detector (FID). Higher temperature leads to increased biodegradation by naturally occurring microorganisms, while the release of volatile organic compounds was similar at both temperatures. Increased salinity had a small positive impact on crude oil removal. At higher crude oil dosages, volatilization increased, however CO₂ production did not. While only a small percentage of crude oil was completely biodegraded, a larger percentage was volatilized within 6–9 weeks.     

Compensation for natural resource damages from oil spills: a comparison of US law and international conventions

The basic measure of natural resource damages in USA environmental liability statutes is the cost of restoring the injured resources, plus compensation for the interim loss of resources from the time of injury until their full recovery. In contrast, until 1996, the international Convention Protocols addressing liability for accidental oil spills did not hold the responsible party liable for damages to natural resources, except to compensate for lost profits and earnings of commercial users of the resources. Recent developments, however, suggest that international and USA laws are converging. In the 1996 regulations implementing the natural resource liability provisions of the USA Oil Pollution Act (OPA), natural resource damages are quantified as the costs of a Restoration Plan designed to return resources to baseline and to compensate for interim losses. The 1992 international Convention Protocols, which entered into force in May 1996, include the costs of resource 'reinstatement' measures, though a clear definition of the scope of 'reinstatement', consistent with the restoration concepts in the OPA regulations, could provide an inclusive measure of damages for environmental harm. Furthermore, such a measure would not contravene the policy, previously articulated by the international organisation administering the compensation regime, that only losses quantifiable in financial terms may be claimed.     

Advanced Electrostatic Stimulation of Fabric Filtration

In advanced electrostatic stimulation of fabric filtration (AESFF), a high voltage electrode is placed coaxially inside a filter bag to establish an electric field between the electrode and the bag surface. The electric field alters the dust deposition pattern within the bag, yielding a much lower pressure drop than that found in a conventional bag. Pilot plant results show that AESFF bags can operate with a rate of pressure loss that is 70 percent below that for conventional bags. The presence of the electric field also affects the aging characteristics of the AESFF bags. On the average, the AESFF bags had residual drags that were 10 percent below those of conventional bags. The results show that AESFF baghouses can yield the same pressure drop performance as conventional baghouses while operating at much higher air-to-cloth ratios. An economic analysis evaluated the capital, operating, and maintenance costs for electric utility plants ranging from 200 to 1,000 MW. For AESFF baghouses the capital cost was found to be 25 to 48 percent below that of a conventional baghouse. A lifetime cost analysis predicts a net present value for an AESFF baghouse that is 10 to 30 percent below that of a conventional baghouse.     

加油站气液比检测方法及其影响

气液比(A/L)是加油站油气回收系统的一项重要控制指标,利用A/L测试仪、光离子化VOCs检测仪和油气排放因子测试装置,研究了不同A/L检测连接方式对A/L检测结果、检测人员暴露浓度、油气排放和油气回收效率等的影响。结果表明,不同连接方式和是否预先向检测油桶注油会导致A/L检测结果不一致,如果油桶与流量计不连接,A/L检测值将是实际A/L的1.04倍,当按照A/L=1.00~1.20调整加油枪A/L时,实际A/L将在0.96~1.15之间;按照国标GB20952-2007连接方式检测A/L可以减少检测过程中约80%的加油油气排放,夏季检测人员暴露油气浓度将由451×10-6(体积浓度)下降至91×10-6(体积浓度),油气排放因子将由1 056 mg/L下降至242 mg/L,更可减少因油罐吸入空气造成额外的汽油挥发排放,但不能减少倒油油气排放。     

Causes and Consequences of Backdrafting of Vented Gas Appliances

Abstract

House depressurization occurs when household equipment such as a kitchen or bathroom fan or a fireplace exhausts air from the house and lowers the pressure indoors with respect to the outside. The operation of air handlers for forced-air heating or cooling systems also can have a depressurization effect. This depressurization can hinder the natural draft from vented combustion appliances and lead to backdrafting, which in turn can result in combustion gases spilling into the indoor airspace. Extensive spillage can cause elevated indoor levels of combustion products such as carbon dioxide (CO2) and water vapor, as well as contaminants such as carbon monoxide (CO) and nitrogen dioxide (NO2).

The focus of this paper is to review studies on depressurization- induced backdrafting and spillage from gas-fired, drafthood equipped furnaces and domestic hot water heaters. Qualitative and quantitative techniques that were used in depressurization and backdrafting studies conducted in Canada, Europe, and the United States are analyzed. These studies have shown that exhaust fans operated simultaneously with fireplaces depressurize houses by 3 to 8 Pa on average. The CO indoor concentrations due to spillage, as reported in these studies, generally have been lower than 5 ppm. However, such low CO concentrations do not necessarily imply that a potential problem associated with backdrafting does not exist. Other combustion products, such as NO2, rarely have been measured in prior backdrafting studies.

It can be concluded from the literature review that causes of house depressurization are well understood. However, more comprehensive research is needed to better understand the frequency, duration, and severity of depressurization-induced spillage in a broad cross section of houses. Efforts in this direction have begun recently in the United States through a workshop to define research issues, pilot studies to develop comprehensive measurement protocols, and consensus standard development activities to prepare standardized methods and protocols.     

Modeling dissolution and volatilization of LNAPL sources migrating on the groundwater table

A vertically averaged two-dimensional model was developed to describe areal spreading and migration of light nonaqueous-phase liquids (LNAPLs) introduced into the subsurface by spills or leaks from underground storage tanks. The NAPL transport model was coupled with two-dimensional contaminant transport models to predict contamination of soil gas and groundwater resulting from a LNAPL migrating on the water table. Numerical solutions were obtained by using the finite-difference method. Simulations and sensitivity analyses were conducted with a LNAPL of pure benzene to study LNAPL migration and groundwater contamination. The model was applied to subsurface contamination by jet fuel. Results indicated that LNAPL migration were affected mostly by volatilization. The generation and movement of the dissolved plume was affected by the geology of the site and the free-product plume. Most of the spilled mass remained as a free LNAPL phase 20 years after the spill. The migration of LNAPL for such a long period resulted in the contamination of both groundwater and a large volume of soil.     

Petroleum and hazardous chemical spills in Newark Bay, New Jersey, USA from 1982 to 1991

Newark Bay, New Jersey, is particularly vulnerable to ecological damage from petroleum and chemical spills, as a result of the enclosed nature and shallow depth of the bay, the high frequency of shipping traffic, and the numerous chemical and petroleum transfer terminals located alongs its shores. To evaluate the potential impacts to the natural resources of this coastal estuarine ecosystem, chemical and petroleum accidents reported to the US Coast Guard (USCG) between 1982 and 1991 were compiled to determine the frequency and volume of these incidents in Newark Bay and in each of its major tributaries. Records obtained from the USCG National Response Center's computerized database indicated that more than 1453 accidental incidents, resulting in the release of more than 18 million US gallons of hazardous materials and petroleum products, occurred throughout Newark Bay during this period of time. The bulk of the materials released to the aquatic environment consisted of petroleum products, specifically No. 6 Fuel Oil (103 spills, 12 829 272 US gal) and gasoline (207 spills, 48 816 US gal). The majority of the reported incidents occurred in the Arthur Kill and its tributaries, as well as in the Kill Van Kull and the Passaic River. The results of this study indicated that the accidental discharge of petroleum and hazardous chemicals represents a significant source of chemical pollution in Newark Bay. Based on the frequency of spills and the volume of materials released to the aquatic environment, it is likely that these events are having a deleterious effect on the Newark Bay ecosystem.     

Influence of nozzle type upon the control of the stalkborer using chlorpyrifos and cyfluthrin 1

Abstract

Field experiments were conducted in corn plots during 1988 that were artificially Infested with stalkborers, Papianema nebris (Guenee'). Two atomizers, a flatfan and a flood nozzle chosen for different droplet size distributions were used to apply two insecticides, chlorpyrifos and cyfluthrin at two application rates. Nozzles, insecticides, rates, and associated interactions were evaluated for control of stalkborer in the field. Laboratory studies involved application of insecticides to soil and glass via a spray track for bioassay at field application rates. Image analysis of percent area travelled on water sensitive paper by stalkborers was compared to droplet percent area covered to obtain percent area contacted per insect. Droplet size distributions for each nozzle were obtained using an Aerometrics particle sizing instrument. Significant differences in stalkborer control were attributed to percent area covered by smaller droplets measured by image analysis.     

Design and assessment of a chamber to expose plants to simulated aerosol and rain

Increased reports of contaminants in atmospheric aerosols necessitate the development of exposure systems that can accurately simulate aerosols for research purposes. This study outlines the design, construction, cost, and performance of a simple plexiglass chamber equipped with nozzles for rain and aerosol generation. The chamber occupies approximately 152 cm x 125 cm (height x width) space and can be used to expose six large (625 cm2) plants or twelve smaller (144 cm2) ones. The total cost of the materials used in construction, including nozzles, was less than 700 dollars. Repeated analysis of the quantity and particle size distribution of the simulated aerosol and rain showed them to be highly predictable. By adjusting the volume and/or concentration of the spray, and the position of plants within the chamber, particle sizes typical of environmental aerosols (< or = 20 microm) and rains (0.7 to 1.2 mm) could be applied to experimental plants. This sample, economical system will allow for precise simulations of important aerosols and rain events in the study of their impingement on plants.     

The Detection and Estimation of Part Per Billion Concentrations of Hydrocarbons

The addition of a freeze-out step in liquid nitrogen prior to analysis by gas chromatography with flame ionization detection permits the accurate determination of C₂ and higher hydrocarbons in the part per billion (ppb) range. Concentrations of C₂ and higher hydrocarbons have been measured in commercial cylinders of nitrogen, helium and hydrogen. Using a 150 ml sample of gas, recovery of ppb concentrations is 95 to 100 percent.     

motor vehicle emissions and atmospheric lead concentrations in the los angeles area

This paper is directed to those concerned with the effect of changes in lead consumption by motor vehicles on atmospheric lead concentrations. Atmospheric lead concentrations in the Los Angeles area have been found to be dependent on lead consumption, meteorology, and source-receptor relationships. Mathematical relationships between these variables for selected Los Angeles area sites are derived. Los Angeles County experienced a 50% reduction in annual average atmospheric lead concentrations between 1971 and 1976, which was found to be due to a decrease in vehicular emissions of lead. Seasonal variations in lead concentration were found to be mainly a product of seasonal variations in weather. Projections of atmospheric lead concentrations for the next decade show a continued downtrend, based on regulation of fuel lead content and introduction of additional catalyst equipped vehicles. By the mid-1980's most locations in the Los Angeles area are expected to attain the California and federal ambient air quality standards for lead, 1.5 micrograms per cubic meter, based on a monthly average.     

Simulation of a Hazardous and Noxious Substances (HNS) spill in the marine environment: Lethal and sublethal effects of acrylonitrile to the European seabass

Despite the extensive maritime transportation of Hazardous and Noxious Substances (HNS), there is a current lack of knowledge on the effects posed by HNS spills on the marine biota. Among the HNS identified as priority, acrylonitrile was selected to conduct ecotoxicological assays. We assessed the acute and subletal effects of acrylonitrile in seabass, followed by a recovery phase to simulate the conditions of a spill incident. The work aimed at testing a broad range of biological responses induced by acrylonitrile. Sublethal exposure to the highest two doses increased the fish mortality rate (8.3% and 25% mortality in 0.75 and 2 mg L⁻¹ acrylonitrile concentrations), whereas no mortality were observed in control and 0.15 mg L⁻¹ treatments. Additionally, important alterations at sub-individual level were observed. Acrylonitrile significantly induced the activities of Catalase– CAT and Glutathione S-Transferase – GST; and the levels of DNA damage were significantly increased. Conversely, Superoxide Dismutase– SOD – activity was found to be significantly inhibited and no effects were found on Lipid Peroxidation– LPO and ethoxyresorufin O-deethylase – EROD – activity. Following a 7 d recovery period, the levels of CAT, GST and EROD fell to levels at or below those in the control. In the 2 mg L⁻¹ group, SOD remained at the levels found during exposure phase. This study has gathered essential information on the acute and subletal toxicity of acrylonitrile to seabass. It also demonstrated that 7 d recovery allowed a return of most endpoints to background levels. These data will be useful to assist relevant bodies in preparedness and response to HNS spills.     

Oil spill cleanup using graphene

In this article, we study the use of thermally reduced graphene (TRG) for oil spill cleanup. TRG was synthesized by thermal exfoliation of graphite oxide and characterized by X-ray diffusion, Raman spectroscopy, SEM, TEM, elemental analysis, and Brunauer–Emmett–Teller (BET) surface area measurement. Various aspects of the sorption process have been studied including the sorption capacity, the recovery of the adsorbed oil, and the recyclability of TRG. Our results shows that TRG has a higher sorption capacity than any other carbon-based sorbents, with sorption capacity as high as 131 g of oil per gram TRG. With recovery of the sorbed oil via filtration and reuse of TRG for up to six cycles, 1 g of TRG collectively removes approximately 300 g of crude oil. Moreover, the effects of TRG bulk density, pore volume, and carbon/oxygen ratio and the oil viscosity on the sorption process are also discussed.     

The distribution of particle-phase organic compounds in the atmosphere and their use for source apportionment during the Southern California Children''s Health Study

Atmospheric particulate matter (PM) samples from 12 sites in southern California, collected as part of the Southern California Children's Health Study (SCCHS), were analyzed using gas chromatography/mass spectrometry (GC/MS) techniques. Ninety-four organic compounds were quantified in these samples, including n-alkanes, fatty acids, polycyclic aromatic hydrocarbons (PAH), hopanes, steranes, aromatic diacids, aliphatic diacids, resin acids, methoxyphenols, and levoglucosan. Annual average concentrations of all detected compounds, as well as average concentrations for three seasonal periods, were determined at all 12 sites for the calendar year of 1995. These measurements provide important information about the seasonal and spatial distribution of particle-phase organic compounds in southern California. Also, co-located samples from one site were analyzed to assess precision of measurement. Excellent agreement was observed between annual average concentrations for the broad range of organic compounds measured in this study. Measured concentrations from the 12 sampling sites were used in a previously developed molecular-marker source apportionment model to quantify the primary source contributions to the PM10 organic carbon and mass concentrations at these 12 sites. Source contributions to atmospheric PM from six important air pollution sources were quantified: gasoline-powered motor vehicle exhaust, diesel vehicle exhaust, wood smoke, vegetative detritus, tire wear, and natural gas combustion. Important trends in the seasonal and spatial patterns of the impact of these six sources were observed. In addition, contributions from meat smoke were detected in selected samples.     

Airshed Model Evaluation of Reactivity Adjustment Factors Calculated with the Maximum Incremental Reactivity Scale for Transitional-Low Emission Vehicles

Abstract

The California Air Resources Board recently adopted regulations for light- and medium-duty vehicles that require reductions in the ozone-forming potential or “reactivity,” rather than the mass, of nonmethane organic gas (NMOG) emissions. The regulations allow sale of all alternatively fueled vehicles (AFVs) that meet NMOG exhaust emission standards equivalent in reactivity to those set for vehicles fueled with conventional gasoline. Reactivity adjustment factors (RAFs), the ratio of the reactivity (per gram) of the AFV exhaust to that of the conventionally fueled vehicle (CFV), are used to correct the stringent exhaust emission standards. Complete chemical speciation of the exhaust and conversion of each NMOG species to an appropriate mass of ozone using the maximum incremental reactivity (MIR) scale of Carter determines the RAF. The MIR approach defines reactivity where NMOG control is the most effective strategy in reducing ozone concentrations, and assumes it is not important to define reactivity at other conditions, i.e., where NO_x is the limiting precursor.

This study used the Carnegie/California Institute of Technology airshed model to evaluate whether the RAF-adjusted AFV emissions result in ozone impacts equivalent to those of CFV emissions. A matrix of two ozone episodes in the South Coast Air Basin (SoCAB) of California, two base emission inventories, and exhaust emissions from three alternative fuels that meet the first level of the low emission vehicle standards bounds the expected range of conditions. Although very good agreement was found previously for individual NMOG species,² this study noted deviations of up to ±15 percent from the equal ozone impacts for any vehicle/fuel combination required by the California regulations. These deviations appear to be attributable to differences in spatial and temporal patterns of emissions between vehicle fleets, rather than a problem with the MIR approach. The first formally adopted RAF, a value of 0.41 for 85 percent methanol/15 percent gasoline-fueled vehicles, includes a 10 percent increase based on the airshed modeling. The correction to the RAF is different for other fuels and may be different for air basins other than the SoCAB.     

A Survey of Graduate Education in Hazardous Waste Management

A brief, informal survey questionnaire was sent to 69 universities in the U.S. Forty-two schools responded. Of the 42 respondents, 30 offered one or more courses in hazardous waste management. The average number of courses offered was 1.76 at an average frequency of once per year. Approximately 400 students take the hazardous waste management courses each year. Only four schools provided explicit laboratory training in hazardous waste analysis/treatment. Sixty-nine percent of the respondents have a research program in hazardous waste management. Typical course outlines are presented. Equipment needs for a hazardous waste laboratory are suggested.     

Bacillus thuringiensis field applications: Effect of nozzle type,drop size,and application timing on efficacy against gypsy moth

Abstract

In a series of recent studies, we evaluated the influence of delivery systems, drop size and application timing on the efficacy of aerially applied Bacillus thuringiensis against gypsy moth infestations. Use of different nozzle systems including Micronair, Flat Fan or Twin Jet, did not appear to result in significant differences in Bt coverage efficiency, foliage protection or population reduction. Nor was there any significant difference in population reduction when Bt was applied at two different drop sizes with volume median diameters of 110 and 163 μm. The efficacy of different formulations on larval populations were similar when used against the younger 1st and 2nd instar but differed when treatment was delayed until the population matured to the 3rd and 4th instar stages.