Air Pollution Administrative Trends—the Canadian Scene

A re-organized local agency for the administration of an air pollution by-law in a group of adjoining municipalities now employs professional staff together with laboratories for air quality analyses, source testing, and applied research and new ideas in the development of improved fuel-burning and control equipment. The agency functions to prevent new sources of pollution, to disseminate information and advice and to provide leadership in the community. Its administrative activities include the use of consultants and outside research organizations for special problems and subjects of a political or controversial nature. However, to deal with the rare and complex contaminants which may be harmful to health now necessitates some assistance from the higher governments. The practices discussed have been employed for several years with general success in the Municipality, following closely the recommendations of a Select Committee of the Legislative Assembly of the Province which traveled and held hearings 1955 to 1957 in the major cities of the U.S.A. and Canada.     

Air quality modeling in the South Coast Air Basin of California: what do the numbers really mean?

This study evaluates air quality model sensitivity to input and to model components. Simulations are performed using the California Institute of Technology (CIT) airshed model. Results show the impacts on ozone (O3) concentration in the South Coast Air Basin (SCAB) of California because of changes in: (1) input data, including meteorological conditions (temperature, UV radiation, mixing height, and wind speed), boundary conditions, and initial conditions (ICs); and (2) model components, including advection solver and chemical mechanism. O3 concentrations are strongly affected by meteorological conditions and, in particular, by temperature. ICs also affect O3 concentrations, especially in the first 2 days of simulation. On the other hand, boundary conditions do not significantly affect the absolute peak O3 concentration, although they do affect concentrations near the inflow boundaries. Moreover, predicted O3 concentrations are impacted considerably by the chemical mechanism. In addition, dispersion of pollutants is affected by the advection routine used to calculate its transport. Comparison among CIT, California Photochemical Grid Model (CALGRID), and Urban Airshed Model air quality models suggests that differences in O3 predictions are mainly caused by the different chemical mechanisms used. Additionally, advection solvers contribute to the differences observed among model predictions. Uncertainty in predicted peak O3 concentration suggests that air quality evaluation should not be based solely on this single value but also on trends predicted by air quality models using a number of chemical mechanisms and with an advection solver that is mass conservative.     

Comments On “Particulate Pollutants in the Air of the United States”

This study was undertaken to identify seasonal and source effects on the par-ticulate contaminants of the New York City atmosphere and ultimately to relate the concentrations of these contaminants to the tissue concentrations in residents of New York City. Continual weekly samples of particulates have been collected at three stations in the New York area on 8 by 10 in. glass fiber filters at a flow rate of 20 cfm.

The sample is ashed with a Tracerlab Low Temperature Asher and leached with nitric acid. Metals analyzed by the Atomic Absorption method include Pb, V, Cd, Cr, Cu, Mn, Ni, and Zn. Lead-210, total particulate, and benzene and acetone soluble organic material are also determined.

The data have been related to various meteorological parameters over a one year period to define significant seasonal and source influences, as well as site to site variations. Very significant inverse correlations to temperature are obtained for suspended particulates, vanadium, and nickel at both Manhattan and Bronx sites. Particulates show a less significant inverse correlation to temperature In lower Manhattan. Oil-fired space heating sources appear to account for as much as 50% of the particulates in the Bronx at the peak demand period.

Lead, copper, and cadmium show a general inverse correlation to average wind speed, and a direct correlation to temperature. The latter is most likely due to an inverse relation between wind speed and temperature. The heating season input for particulates, vanadium, and nickel is so great as to overcome most of the dilution effect due to winds. The other elements having more constant nonseasonal inputs, definitely reflect the effects of the wind.

The most significant site effect occurs with cadmium, which has a concentration in lower Manhattan three times that of the Bronx over a period of six to seven months in the summer and fall. The differences observed for cadmium and particulates may be explained by emission source factors which have not as yet been studied.     

What Do the Hydrocarbons from Trees Contribute to Air Pollution?

Plant species release appreciable quantities of volatile organic substances to the atmosphere. The major compounds emitted are monoterpenes (C₁₀) like α-pinene, β-pinene, and limonene and the hemiterpene (C5) isoprene. The rate of emission of isoprene is light dependent and ranges between 0.04 to 2.4 ppb/cm²/min/l for oak, cottonwood, and eucalyptus foliage. The rate of emission of a- and/3-pinene and limonene is dependent on the rate of transpiration, structural integrity of the oil cells and resin glands, and temperature of the foliage. Rates of emission for conifer foliage range from 0.4 to 3.5 ppb/g/min/l. An inventory of North American forest regions for the frequency of occurrence of these chemicals released by different tree species showed that 15% was the lowest value for a specific forest-type that emitted terpenes to the atmosphere. More commonly 100% of the trees of a given forest-type emitted terpenes to the atmosphere. An average of 70% is typical of the United States forested regions as a whole. The annual contribution of forest hydrocarbon emissions to the air pollution problem on a global basis is reflected in the 175 × 10⁶ tons of reactive hydrocarbons from tree foliage sources compared to the 27 × 10⁶ tons from man’s activities; in other words, there is a 6.2-fold greater emission level from natural sources than from man made sources. The fate of these gaseous olefins in the atmosphere is undetermined.     

Air quality measurements—From rubber bands to tapping the rainbow

It is axiomatic that good measurements are integral to good public policy for environmental protection. The generalized term for “measurements” includes sampling and quantitation, data integrity, documentation, network design, sponsorship, operations, archiving, and accessing for applications. Each of these components has evolved and advanced over the last 200 years as knowledge of atmospheric chemistry and physics has matured. Air quality was first detected by what people could see and smell in contaminated air. Gaseous pollutants were found to react with certain materials or chemicals, changing the color of dissolved reagents such that their light absorption at selected wavelengths could be related to both the pollutant chemistry and its concentration. Airborne particles have challenged the development of a variety of sensory devices and laboratory assays for characterization of their enormous range of physical and chemical properties. Advanced electronics made possible the sampling, concentration, and detection of gases and particles, both in situ and in laboratory analysis of collected samples. Accurate and precise measurements by these methods have made possible advanced air quality management practices that led to decreasing concentrations over time. New technologies are leading to smaller and cheaper measurement systems that can further expand and enhance current air pollution monitoring networks.

Implications: Ambient air quality measurement systems have a large influence on air quality management by determining compliance, tracking trends, elucidating pollutant transport and transformation, and relating concentrations to adverse effects. These systems consist of more than just instrumentation, and involve extensive support efforts for siting, maintenance, calibration, auditing, data validation, data management and access, and data interpretation. These requirements have largely been attained for criteria pollutants regulated by National Ambient Air Quality Standards, but they are rarely attained for nonroutine measurements and research studies.     

Air pollution “holiday effect” resulting from the Chinese New Year

Our study was an attempt to conduct a comprehensive and systematical examination of the holiday effect, defined as the difference in air pollutant concentrations between holiday and non-holiday periods. This holiday effect can be applied to other countries with similar national or cultural holidays. Hourly and daily surface measurements of six major air pollutants from thirteen air quality monitoring stations of the Taiwan Environmental Protection Administration during the Chinese New Year (CNY) and non-Chinese New Year (NCNY) periods were used. We documented evidence of a “holiday effect”, where air pollutant concentrations were significantly different between holidays (CNY) and non-holidays (NCNY), in the Taipei metropolitan area over the past thirteen years (1994–2006).The concentrations of NO_x, CO, NMHC, SO₂ and PM₁₀ were lower in the CNY than in the NCNY period, while the variation in the concentration of O₃ was reversed, which was mainly due to the NO titration effect. Similar differences in these six air pollutants between the CNY and NCNY periods were also found in the diurnal cycle and in the interannual variation. For the diurnal cycle, a common traffic-related double-peak variation was observed in the NCNY period, but not in the CNY period. Impacts of dust storms were also observed, especially on SO₂ and PM₁₀ in the CNY period. In the 13-year period of 1994–2006, decreasing trends of NO_x and CO in the NCNY period implied a possible reduction of local emissions. Increasing trends of SO₂ and PM₁₀ in the CNY period, on the other hand, indicated a possible enhancement of long-range transport. These two mechanisms weakened the holiday effect.     

Nitrogen Trioxide: Key Intermediate in the Chemistry of Polluted Air?

It is proposed that peroxyacetyl nitrate and its homologues are formed in polluted air via hydrogen abstraction from the corresponding aldehyde by nitrogen trioxide, followed by (a relatively fast) combination of the resulting acyl radical with oxygen and NO₂. This mechanism provides a simple explanation for the formation of nitric acid, HNO3, as well. Nitrogen trioxide should be able to abstract hydrogen atoms from hydrocarbons, since the H-ONO₂ bond strength is about 100 kcal/mole.     

Air Quality Technical Information Exchange To the People’s Republic of China

Editor’s note: Donald F. Adams was Past President of the Air Pollution Control Association in 1983 when he led a delegation of air quality experts to the People’s Republic of China for a technical information exchange. Professor Adams has provided an informative (and humorous) report of this technical exchange and we are pleased to share it with the readers of JAPCA.     

Air pollution exposure—the (in)visible risk factor for respiratory diseases

Environmental Science and Pollution Research - There is increasing interest in understanding the role of air pollution as one of the greatest threats to human health worldwide. Nine of 10...     

The State’s Role in the Development of Local Air Pollution Control Programs

This paper examines the history of air pollution control in the State of New Jersey, particularly, how it relates to the development of the state-local governmental relationship, and to the coordination of their respective control efforts. It also describes the methodology for developing local control programs. The information presented in the paper is directed to those individuals who may be able to analogize the experience in New Jersey to situations developing in their own jurisdictions.     

Air–water exchange fluxes of polycyclic aromatic hydrocarbons in the tropical coast,Taiwan

Air–water exchange fluxes of polycyclic aromatic hydrocarbons (PAHs) were simultaneously measured in air and water samples from two sites on the Kenting coast, located at the southern tip of Taiwan, from January to December 2010. There was no significant difference in the total PAH (t-PAH) concentrations in both gas and dissolved phases between these two sites due to the less local input which also coincided to the low levels of t-PAH concentration; the gas and dissolved phases averaged 1.29 ± 0.59 ng m^?3 and 2.17 ± 1.19 ng L^?1 respectively. The direction and magnitude of the daily flux of PAHs were significantly influenced by wind speed and dissolved PAH concentrations. Individual PAH flux ranged from 627 ng m^?2 d^?1 volatilization of phenanthrene during the rainy season with storm–water discharges raising dissolved phase concentration, to 67 ng m^?2 d^?1 absorption of fluoranthene during high wind speed periods. Due to PAH annual fluxes through air–water exchange, Kenting seawater is a source of low molecular weight PAHs and a reservoir of high molecular weight PAHs. Estimated annual volatilization fluxes ranged from 7.3 μg m^?2 yr^?1 for pyrene to 50 μg m^?2 yr^?1 for phenanthrene and the absorption fluxes ranged from ?2.6 μg m^?2 yr^?1 for chrysene to ?3.5 μg m^?2 yr^?1 for fluoranthene.     

What Price Air Quality the Cost of New Jersey’s Inspection/Maintenance Program

Selection of acceptable sites for industrial facilities, especially hazardous waste management facilities, can be made using a relatively new technique referred to as “fuzzy set analysis.” The methodology presented is applicable to multiple alternative decision making, when criteria are of unequal importance, and is based on the concept of establishing a subjective value for each alternative according to each criterion, and then raising the subjective value to a power commensurate with the relative importance of the criterion. This exponential weight is calculated on the basis of a preferential analysis of criteria comparisons. Apart from the ranking of the alternatives, fuzzy set analysis provides a quantitative representation of the community opinion of the order of importance of the criteria, regardless of the sites being considered. Based on the importance factors averaged from a cross section of the community, public concern could also be ranked.     

Planning and Coordination in the New Jersey — New York — Connecticut Air Quality Control Region

On April 16, 1970, the States of New Jersey, New York, and Connecticut designated the Interstate Sanitation Commission as the official Planning and Coordinating Agency for the Federally-designated New Jersey-New York-Connecticut Air Quality Control Region (a seventeen-county tri-state area). The Commission is the first such agency to function in this capacity.     

Pennsylvania’s Compuiterized Air Monitoring System

The Pennsylvania Air Pollution Commission has developed a regulatory program based upon the control of local air pollution problems and reduction of pollutant levels in air basins. The geographical boundaries of 10 air basins have been established. The Commission’s air basin regulations will provide for the reduction of over-all pollutant levels and for emergency procedures in the event of adverse meteorological conditions. The paper discusses the format and objectives of the program.

In order to effectively enforce the air basin regulations and maintain the necessary surveillance of the state’s air quality, a "computerized real time on-line integrated air monitoring-data handling system" has been designed. The system will incorporate a network to constantly monitor the air in each air basin.The primary objectives of the system are: 1. Constant surveillance of air pollution in the air basins.

2. Provide information on air pollution potential alerts.

3. Aid in further development of air quality criteria and regulations.

The air monitoring network is estimated to include approximately 25 remote stations. Each remote will contain air pollution and meteorological sampling equipment and hardware to telemeter to a central station. The data will be transmitted over leased telephone lines. The central station in Harrisburg will contain the necessary hardware to receive and process data, calculate and display results and permit supervisory control of the network. Output options will include immediate display of edited data, command and alarm information, and presentation of statistical results.

Although the air monitoring system is one of the principle ingredients of the program, the air basin concept encompasses other component systems designed to knit together the entire air pollution control program in Pennsylvania.