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1.
ABSTRACT

The Arizona inspection and maintenance (I/M) program provides one of the first opportunities to examine the costs and effectiveness of vehicle emission repair. This paper examines various aspects of emission reductions, fuel economy improvements, and repair costs, drawing data from over 80,000 vehicles that failed the I/M test in Arizona between 1995 and the first half of 1996. We summarize the wealth of data on repair from the Arizona program and highlight its limitations. Because missing or incomplete cost information has been a serious shortcoming for the evaluation of I/M programs, we develop a method for estimating repair costs when they are not reported. We find surprising evidence that almost one quarter of all vehicles that take the I/M test are never observed to pass the test. Using a statistical analysis, we provide some information about the differences between the vehicles that pass and those that do not. Older, more polluting vehicles are much more likely never to pass the I/M test, and their expected repair costs are much higher than those for newer cars.

This paper summarizes the evidence on costs and emission reductions in the Arizona program, comparing costs and emissions reductions between cars and trucks. Finally, we examine the potential for more cost-effective repair, first through an analysis of tightening I/M cut points and then by calculating the cost savings of achieving different emission reduction goals when the most cost-effective repairs are made first.  相似文献   

2.
A one-year-long experiment in which two different tracers were simultaneously released from two different locations was used to test various hybrid receptor modeling techniques to estimate the tracer emissions using the measured air concentrations and a meteorological model. Air concentrations were measured over an 8-hour averaging time at three sites 14 to 40 km downwind. When the model was used to estimate emissions at only one tracer source, 6 percent of the short-term (8-h) emission estimates were within a factor of 2 of the actual emissions. Temporal averaging of the 8-h data enhanced the precision of the estimate such that after 10 days 42 percent of the estimates were within a factor of 2 and after six months all of them (each source-receptor pair) were within a factor of 2. To test the ability of the model to separate two sources, both tracer sources were combined, and a multiple linear regression technique was used to determine the emissions from each source from a time series of air concentration measurements representing the sum of both tracers. In general, 50 percent of the short-term estimates were within a factor of 10, 25 percent were biased low, and in another 25 percent the regression technique failed. The bias and failures are attributed to low or no correlation between measured air concentrations and model calculated dispersion factors. In the regression method increased temporal averaging did not consistently improve the emission estimate since the ability of the model to distinguish emissions between sources was diminished with increased averaging time. However, including progressively longer time periods (more data) into the regression or spatially averaging the data over all the receptors was found to be the most effective method to improve the estimated emissions. At best about 75 percent of the estimated monthly emission data were within a factor of 10 of the measured values. This suggests that the usefulness of meteorological models and statistical methods to address questions of source attribution requires many data points to reduce the uncertainty in the emission estimates.  相似文献   

3.
This paper is directed to those concerned with estimating releases to the air of volatile compounds from equipment component leaks. We compared emission rates for equipment component leaks using EPA’s Average Emission Factor Method, Leak/No-Leak Emission Factor Method, and Stratified Emission Factor Method. The latter two methods may be used if there are concentration measurements about the components. An organic vapor analyzer was applied with the appropriate response factor to measure the concentrations around each equipment component using EPA Method 21. We analyzed this data to determine mass emission rates. Results show that the Average Emission Factor Method substantially overstates the emission rates calculated using these other two methods. We conclude that use of Method 21 concentration measurements with the Leak/No Leak or Stratified Emission Factor Method may increase the accuracy and reduce significantly the estimated releases to the air of volatile compounds from equipment component leaks for many facilities.  相似文献   

4.
Studies of roof monitor emissions are conducted for two reasons: (1) to obtain design data necessary to engineer control systems to meet existing regulations, and (2) to determine projected control costs which can influence present day proposals for process change. Heated wire anemometers and rotating vane anemometers have been selected for velocity measurements, and high-volume air samplers have been selected to collect the particulate sample. Evaluation of other types of velocity sensing devices are described in the paper.

Roof monitor studies must be preceded by a preliminary survey to allow the project engineer to determine the test sampling locations and specific methodology necessary for the given study, and to allow the engineer to determine the type of safety equipment, scaffolds, and power requirements necessary to complete the study.

Field tests are conducted by operating a number of high-volume air samplers simultaneously while at the same time measuring the velocity of the gas through the monitor opening. Curves of particulate concentration and velocity as a function of monitor length are constructed. The concentration and velocity curves are then integrated together and the resultant curve is multiplied by the monitor width to determine a curve of mass emission rate as a function of monitor length. The total mass emission rate is represented by the area under the mass emission rate curve.

Procedures for calibrating the anemometers and correcting for the effect of power fluctuation on the high-volume sampler operation are described. Data evaluation procedures and discussion of test error are also described.

A study can cost between 10 and 20 thousand dollars, including the cost of manpower and the cost of scaffolds, power, cables, etc. It can take four months or more to conduct a study, from the preliminary survey phase through the report phase.  相似文献   

5.
Abstract

Manure storage tanks and animals in barns are important agricultural sources of methane. To examine the possibility of using an inverse dispersion technique based on a backward Lagrangian Stochastic (bLS) model to quantify methane (CH4) emissions from multiple on-farm sources, a series of tests were carried out with four possible source configurations and three controlled area sources. The simulated configurations were: (C1) three spatially separate ground-level sources, (C2) three spatially separate sources with wind-flow disturbance, (C3) three adjacent ground-level sources to simulate a group of adjacent sources with different emission rates, and (C4) a configuration with a ground level and two elevated sources. For multiple ground-level sources without flow obstructions (C1 and C3), we can use the condition number (k, the ratio of the uncertainty in the calculated emission rate to the uncertainty in the predicted ratio of concentration to emission rate) to evaluate the applicability of this inverse dispersion technique and a preliminary threshold of k < 10 is recommended. For multiple sources with wind disturbance (C2) or an even more complex configuration including ground level and elevated sources (C4), a low k is not sufficient to provide reasonable discrete and total emission rates. The effect of flow obstructions can be neglected as long as the distance between the source and the measurement location is greater than approximately 10 times the height of the flow obstructions. This study shows that the bLS model has the potential to provide accurate discrete emission rates from multiple on-farm emissions of gases provided that certain conditions are met.  相似文献   

6.
Hamilton, Ontario is an industrial city with a population of 300,000 which is situated at the western end of Lake Ontario. Canada’s two largest iron and steel mills are located here; the city historically has had relatively poor air quality, which has improved markedly in the last 25 years. Concern about the health effects of current air quality recently led us to carry out an epidemiological study of the effects of air pollution on the respiratory health of over 3500 school children. Respiratory health was measured by pulmonary function testing of each child, and by an assessment of each child’s respiratory symptoms via a questionnaire administered to the parents. Previous studies had shown that other environmental factors (e.g. parental smoking, parental cough, socioeconomic level, housing, and gas cooking) might also affect respiratory health, and thus “confound” any potential relationships between health and air pollution. The questionnaire also collected information on many of these confounding factors. For the purposes of initial analysis, the city was divided Into five areas in which differences In air quality were expected. In general, factors which have been associated with poor respiratory health were observed to be more prevalent in areas of poorer air quality.  相似文献   

7.
The body of information presented in this paper is directed toward those individuals involved with handling hazardous materials, whether in actual use of such chemicals, or in monitoring atmospheric emissions. Although specifically relating experience in the design and testing of phosgene emission control equipment, it attempts to establish general guidelines for effectively dealing with emissions of hazardous materials. An approach for handling chemical pollutants having no established air quality emission standards is developed. The paper presents a technique for establishing process emissions at acceptably low levels to insure the health and safety of the general population as well as that of the process workers themselves. Methods, suitable for measuring phosgene at these low levels, have been investigated, and problems associated with such an investigation are discussed. While complete theoretical scrubber design criteria are beyond the scope of this paper, many of the "real world" problems which affected scrubber performance are presented. Finally, the practical aspects of process emissions control are illustrated by actual results from the system test.  相似文献   

8.
Abstract

This paper presents an experimental study of calcium bisulfite oxidation, a key step in the wet limestone-gypsum flue gas desulfurization (FGD) process, in the presence of catalysts (e.g., cobalt ions and a mixture of ferrous and cobalt ions). A fundamental approach is followed, by reproducing a simplified synthetic FGD liquor in which both catalyst ions, alone or mixed together, are present. A laboratory-scale apparatus is used, in which sulfurous solution is contacted with a gas phase at a fixed oxygen partial pressure (21.3 kPa) and at different temperature levels (25, 45, and 55 °C). The experimental results are analyzed using the theory of gas-liquid mass transfer with chemical reaction, showing that the slow reaction regime is explored and the transition from the kinetic to the diffusional subregime is identified. The experimental results are compared with those obtained in the presence of other catalytic species (manganese and ferrous ions), showing that cobalt is effective in catalyzing the oxidation of calcium bisulfite to sulfate, but to a minor extent with respect to iron and manganese.  相似文献   

9.
ABSTRACT

A large chamber test method for measuring indoor air emissions from office equipment was developed, evaluated, and revised based on the initial testing of four dry-process photocopiers. Because all chambers may not necessarily produce similar results (e.g., due to differences in sink effects, temperature and humidity control, air exchange, pollutant monitoring, and measurement biases), a preliminary four-laboratory evaluation of the revised test method was conducted. To minimize variability, the evaluation used a single dry-process photocopier that was shipped to each of the four laboratories along with supplies (i.e., toner and paper).

The results of this preliminary four-laboratory evaluation demonstrate that the test method was used successfully in the different chambers to measure emissions from dry-process photocopiers. Differences in chamber design and construction appeared to have had minimal effect on the results for the volatile organic compounds (VOCs). Perhaps more important than the chamber itself is the sample analysis as identified by duplicate samples that were analyzed by a different laboratory. Percent relative standard deviation (%RSD) was used to provide a simplistic view of interlaboratory precision for this evaluation. Excluding problems with suspected analytical bias observed from one of the laboratories, the precision was excellent for the VOCs with RSDs of less than 10% in most cases. Less precision was observed among the laboratories for aldehydes/ketones (RSD of 23.2% for formaldehyde). The precision for ozone emission rates among three of the laboratories was excellent (RSD of 7.9%), but emission rates measured at the fourth laboratory were much higher.  相似文献   

10.
A decentralized emission inventories are prepared for road transport sector of India in order to design and implement suitable technologies and policies for appropriate mitigation measures. Globalization and liberalization policies of the government in 90's have increased the number of road vehicles nearly 92.6% from 1980–1981 to 2003–2004. These vehicles mainly consume non-renewable fossil fuels, and are a major contributor of green house gases, particularly CO2 emission. This paper focuses on the statewise road transport emissions (CO2, CH4, CO, NOx, N2O, SO2, PM and HC), using region specific mass emission factors for each type of vehicles. The country level emissions (CO2, CH4, CO, NOx, N2O, SO2 and NMVOC) are calculated for railways, shipping and airway, based on fuel types. In India, transport sector emits an estimated 258.10 Tg of CO2, of which 94.5% was contributed by road transport (2003–2004). Among all the states and Union Territories, Maharashtra's contribution is the largest, 28.85 Tg (11.8%) of CO2, followed by Tamil Nadu 26.41 Tg (10.8%), Gujarat 23.31 Tg (9.6%), Uttar Pradesh 17.42 Tg (7.1%), Rajasthan 15.17 Tg (6.22%) and, Karnataka 15.09 Tg (6.19%). These six states account for 51.8% of the CO2 emissions from road transport.  相似文献   

11.
Emission measurement programmes were carried out at industrial plants in several regions of Germany to determine the fine dust in the waste gases; the PM10, PM2.5 and PM1.0 fractions were sampled using a cascade impactor technique. The installations tested included plants used for: combustion (brown coal, heavy fuel oil, wood), cement production, glass production, asphalt mixing, and processing plants for natural stones and sand, ceramics, metallurgy, chemical production, spray painting, wood processing/chip drying, poultry farming and waste treatment. In addition waste gas samples were taken from small-scale combustion units, like domestic stoves, firing lignite briquettes or wood.In total 303 individual measurement results were obtained during 106 different measurement campaigns. In the study it was found that in more than 70% of the individual emission measurement results from industrial plants and domestic stoves the PM10 portion amounted to more than 90% and the PM2.5 portion between 50% and 90% of the total PM (particulate matter) emission. For thermal industrial processes the PM1.0 portion constituted between 20% and 60% of the total PM emission.Typical particle size distributions for different processes were presented as cumulative frequency distributions and as frequency distributions. The particle size distributions determined for the different plant types show interesting similarities and differences depending on whether the processes are thermal, mechanical, chemical or mixed. Consequently, for the groups of plant investigated, a major finding of this study has been that the particle size distribution is a characteristic of the industrial process. Attempts to correlate particle size distributions of different plants to different gas cleaning technologies did not lead to usable results.  相似文献   

12.
Abstract

Emissions inventories of fine particulate matter (PM2.5) were compared with estimates of emissions based on data emerging from U.S. Environment Protection Agency Particulate Matter Supersites and other field programs. Six source categories for PM2.5 emissions were reviewed: on-road mobile sources, nonroad mobile sources, cooking, biomass combustion, fugitive dust, and stationary sources. Ammonia emissions from all of the source categories were also examined. Regional emissions inventories of PM in the exhaust from on-road and nonroad sources were generally consistent with ambient observations, though uncertainties in some emission factors were twice as large as the emission factors. In contrast, emissions inventories of road dust were up to an order of magnitude larger than ambient observations, and estimated brake wear and tire dust emissions were half as large as ambient observations in urban areas. Although comprehensive nationwide emissions inventories of PM2.5 from cooking sources and biomass burning are not yet available, observational data in urban areas suggest that cooking sources account for approximately 5–20% of total primary emissions (excluding dust), and biomass burning sources are highly dependent on region. Finally, relatively few observational data were available to assess the accuracy of emission estimates for stationary sources. Overall, the uncertainties in primary emissions for PM2.5 are substantial. Similar uncertainties exist for ammonia emissions. Because of these uncertainties, the design of PM2.5 control strategies should be based on inventories that have been refined by a combination of bottom-up and top-down methods.  相似文献   

13.
The Arizona inspection and maintenance (I/M) program provides one of the first opportunities to examine the costs and effectiveness of vehicle emission repair. This paper examines various aspects of emission reductions, fuel economy improvements, and repair costs, drawing data from over 80,000 vehicles that failed the I/M test in Arizona between 1995 and the first half of 1996. We summarize the wealth of data on repair from the Arizona program and highlight its limitations. Because missing or incomplete cost information has been a serious shortcoming for the evaluation of I/M programs, we develop a method for estimating repair costs when they are not reported. We find surprising evidence that almost one quarter of all vehicles that take the I/M test are never observed to pass the test. Using a statistical analysis, we provide some information about the differences between the vehicles that pass and those that do not. Older, more polluting vehicles are much more likely never to pass the I/M test, and their expected repair costs are much higher than those for newer cars. This paper summarizes the evidence on costs and emission reductions in the Arizona program, comparing costs and emissions reductions between cars and trucks. Finally, we examine the potential for more cost-effective repair, first through an analysis of tightening I/M cut points and then by calculating the cost savings of achieving different emission reduction goals when the most cost-effective repairs are made first.  相似文献   

14.
ABSTRACT

From 2004 to 2009, aiming to better understand implications for its smelters, Rio Tinto Alcan conducted a detailed study of PM2.5 and PM10 (particulate matter [PM] ≤ 2.5 and 10 μm in aerodynamic diameter, respectively) in its facilities. This involved a two-level study: part 1, emission quantification; and part 2, assessment of aluminum smelter contribution to the surrounding environment. In the first part, U.S. Environmental Protection Agency Other Test Method (OTM) OTM27 and OTM28 are assessed as relevant and efficient methods for measuring fine particle emissions from aluminum smelter stacks. Rio Tinto Alcan has also developed a safe and robust method called CYCLEX to measure PM2.5 and condensable particulate matter (CPM) at the roof vents of potrooms. This work aims to determine the PM2.5 emission coefficients of 17, 55, and 417 g·t?1 of aluminum produced (including CPM) in anode baking furnace exhaust (fume treatment center), at potroom scrubber stacks (gas treatment centers), and at potroom roof vents, respectively. Results indicate that roof vents are the primary PM2.5 emitters (85% of all smelter emissions) and that 71% of all smelter PM2.5 comes from CPM. In the second part, preliminary inorganic speciation studies are conducted by scanning electron microscopy–energy-dispersive X-ray analysis and by isotopic ratios to track smelter emissions to their surrounding environment. This paper releases the first speciation results for an aluminum smelter, and the preliminary isotopic ratio study indicates a 3% impact in terms of PM2.5 emissions for a representative smelter in an urban area.

IMPLICATIONS Aluminum smelters tend to continuously improve their competitiveness by incrementally increasing production. In this context, assessing the effect of major contaminants is overriding, and ambient air modeling is often the preferred way to do so. Fine particles fit this category, and the primary aluminum industry needs to accurately know their emission factors to obtain representative modeling. Moreover, not all aluminum smelters have a method to measure PM2.5 at roof vents, the primary emission outlets. Therefore, this paper describes the first-rate PM2.5 measurement methods for aluminum smelter roof vents without down-comers. It also provides insight for environmental managers for tracking PM2.5 emissions in plant surroundings.  相似文献   

15.
Abstract

Heavy-duty diesel vehicle idling consumes fuel and reduces atmospheric quality, but its restriction cannot simply be proscribed, because cab heat or air-conditioning provides essential driver comfort. A comprehensive tailpipe emissions database to describe idling impacts is not yet available. This paper presents a substantial data set that incorporates results from the West Virginia University transient engine test cell, the E-55/59 Study and the Gasoline/Diesel PM Split Study. It covered 75 heavy-duty diesel engines and trucks, which were divided into two groups: vehicles with mechanical fuel injection (MFI) and vehicles with electronic fuel injection (EFI). Idle emissions of CO, hydrocarbon (HC), oxides of nitrogen (NOx), particulate matter (PM), and carbon dioxide (CO2) have been reported. Idle CO2 emissions allowed the projection of fuel consumption during idling. Test-to-test variations were observed for repeat idle tests on the same vehicle because of measurement variation, accessory loads, and ambient conditions. Vehicles fitted with EFI, on average, emitted [~20 g/hr of CO, 6 g/hr of HC, 86 g/hr of NOx, 1 g/hr of PM, and 4636 g/hr of CO2 during idle. MFI equipped vehicles emitted ~35 g/hr of CO, 23 g/hr of HC, 48 g/hr of NOx, 4 g/hr of PM, and 4484 g/hr of CO2, on average, during idle. Vehicles with EFI emitted less idleCO, HC, and PM, which could be attributed to the efficient combustion and superior fuel atomization in EFI systems. Idle NOx, however, increased with EFI, which corresponds with the advancing of timing to improve idle combustion. Fuel injection management did not have any effect on CO2 and, hence, fuel consumption. Use of air conditioning without increasing engine speed increased idle CO2, NOx, PM, HC, and fuel consumption by 25% on average. When the engine speed was elevated from 600 to 1100 revolutions per minute, CO2 and NOx emissions and fuel consumption increased by >150%, whereas PM and HC emissions increased by ~100% and 70%, respectively. Six Detroit Diesel Corp. (DDC) Series 60 engines in engine test cell were found to emit less CO, NOx, and PM emissions and consumed fuel at only 75%of the level found in the chassis dynamometer data. This is because fan and compressor loads were absent in the engine test cell.  相似文献   

16.
Abstract

The In-Plume Emission Test Stand (IPETS) characterizes gaseous and particulate matter (PM) emissions from combustion sources in real time. Carbon dioxide (CO2), carbon monoxide (CO), nitric oxide (NO), nitrogen dioxide (NO2), and other gases are quantified with a closed-path Fourier transform infrared spectrometer (FTIR). Particle concentrations, chemical composition, and other particle properties are characterized with an electrical low-pressure impactor (ELPI), a light-scattering particle detector, an optical particle counter, and filter samples amenable to different laboratory analysis. IPETS measurements of fuel-based emission factors for a diesel generator are compared with those from a Mobile Emissions Laboratory (MEL). IPETS emission factors ranged from 0.3 to 11.8, 0.2 to 3.7, and 22.2 to 32.8 g/kg fuel for CO, NO2, and NO, respectively. IPETS PM emission factors ranged from 0.4 to 1.4, 0.3 to 1.8, 0.3 to 2.2, and 1 to 3.4 g/kg fuel for filter, photoacoustic, nephelometer, and impactor measurements, respectively. Observed linear regression statistics for IPETS versus MEL concentrations were as follows: CO slope = 1.1, r2 = 0.99; NO slope = 1.1, r2 = 0.92; and NO2 slope = 0.8, r2 = 0.96. IPETS versus MEL PM regression statistics were: filter slope = 1.3, r2 = 0.80; ELPI slope = 1.7, r2 = 0.87; light-scattering slope = 2.7, r2 = 0.92; and photoacoustic slope = 2.1, r2 = 0.91. Lower temperatures in the dilution air (~25 °C for IPETS vs. ~50 °C for MEL) may result in greater condensation of semi-volatile compounds on existing particles, thereby explaining the 30% difference for filters. The other PM measurement devices are highly correlated with the filter, but their factory-default PM calibration factors do not represent the size and optical properties of diesel exhaust. They must be normalized to a simultaneous filter measurement.  相似文献   

17.
Abstract

Consumer products can emit significant quantities of terpenes, which can react with ozone (O3). Resulting byproducts include compounds with low vapor pressures that contribute to the growth of secondary organic aerosols (SOAs). The focus of this study was to evaluate the potential for SOA growth, in the presence of O3, following the use of a lime-scented liquid air freshener, a pine-scented solid air freshener, a lemon-scented general-purpose cleaner, a wood floor cleaner, and a perfume. Two chamber experiments were performed for each of these five terpene-containing agents, one at an elevated O3 concentration and the other at a lower O3 concentration. Particle number and mass concentrations increased and O3 concentrations decreased during each experiment. Experiments with terpene-based air fresheners produced the highest increases in particle number and mass concentrations. The results of this study clearly demonstrate that homogeneous reactions between O3 and terpenes from various consumer products can lead to increases in fine particle mass concentrations when these products are used indoors. Particle increases can occur during periods of elevated outdoor O3 concentrations or indoor O3 generation, coupled with elevated terpene releases. Human exposure to fine particles can be reduced by minimizing indoor terpene concentrations or O3 concentrations.  相似文献   

18.
A procedure for the assessment of emissions of nitrogen (N) species (ammonia, nitrous oxide, nitric oxide, di-nitrogen) from the manure management system is developed, which treats N pools and flows including emissions strictly according to conservation of mass criteria. As all relevant flows in the husbandry of mammals are depicted, the methodology is considered a Tier 3 approach in IPCC terminology or a detailed methodology in UN ECE terminology. The importance of accounting for all N species is illustrated by comparing emission estimates obtained using this approach with those obtained from the application the present detailed/Tier 2 methodology.  相似文献   

19.
Abstract

Grass, and particularly cut grass, recently has been shown to emit significant amounts of volatile organic compounds (VOCs) into the atmosphere. Some components of these emissions are highly reactive and may contribute to photochemical smog in urban areas. A simple model for estimating the VOC emissions from grass and for grass cutting that allows these processes to be included in urban/regional emissions inventories is presented here. Using previous work and recent literature values, estimates are made of these biogenic volatile organic compound (BVOC) emissions for two typical urban airsheds, those including the cities of Sydney and Melbourne in Australia. Grass and cut grass could contribute ~2% for Sydney and 3% for Melbourne of the total VOCs emitted into these urban atmospheres annually. These contributions could rise to 4 and 5%, respectively, during the weekends of the summer growing season and, thus, could contribute to weekday/weekend ozone differences. It is recommended that the emissions of BVOCs from grass and cut grass be included in urban and global emissions inventories so that more accurate predictions of smog chemistry can be determined.  相似文献   

20.
Environmental Science and Pollution Research - The motivation for the current study stem from the United Nations Sustainable Development Goals (UN-SDGs) such as access to clean (SDG-7) and...  相似文献   

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