Experimental investigation of solar-powered desiccant cooling system by using composite desiccant “CaCl<Subscript>2</Subscript>/jute”

A solar-powered composite desiccant cooling system has been experimentally investigated. It consists of evacuated tube solar water heater, composite desiccant bed heat exchanger (CDBHE), direct evaporative cooling unit and cooling tower. The composite desiccant material has been synthesized by using iron mesh and jute layer impregnated with calcium chloride solution, and this composite desiccant is placed in shell- and tube-type heat exchanger to make CDBHE. In this desiccant cooling system, the evacuated tube solar water heater is used to produce required hot water for regeneration of composite desiccant material. A cooling tower is used to produce cooling water which is pumped into CDBHE during dehumidification process to remove heat of adsorption. Direct evaporative cooling unit is used to cool the outlet process air of CDBHE. It has been found that the average dehumidification rate increases by 54.1 % when using circulating cooling water. The COP_th of desiccant cooling system has been found to be 0.46 with a cooling capacity of 353.8 W.     

Energy and exergy analysis of a PCM-based solar powered winter air conditioning using desiccant wheel during nocturnal

In this paper, heating and humidification of air for space have been carried out by using a phase change material (PCM)-based solar-powered desiccant wheel air conditioning (SPDWAC) in winter. The analysis of the setup has been done at different air flow rates. At low and high air flow rates, system has mean thermal coefficient of performance of 0.121 and 0.172, respectively, and mean exergy efficiency of 0.0787 and 0.0846, respectively. The mean thermal coefficient of performance of the system at high air flow rate (127.23 kg h-1) is 1.42 times the low air flow rate (63.62 kg h-1) and average exergy efficiency of the system at high air flow rate is 1.07 times the low air flow rate. It is observed that with an increase in air flow rate, efficiency of the evacuated tube solar air collector (ETSAC) increases. The average efficiency of the ETSAC at high air flow rate is 15.60%. The maximum average energy efficiency (17.80%) and exergy efficiency (17.08%) of the PCM storage system have been obtained at high air flow rate. The overall performance of the system showed that the use of PCM storage is feasible to run the system in winter during the hours of darkness.     

Experimental analysis of thermal performance of evacuated tube and flat-plate solar air collectors at different air flow rates

The thermal performances of an evacuated tube collector (ETC) and flat-plate solar air collector (FPC) are experimentally investigated at different air flow rates. To investigate the performance of the ETC and FPC, experimental set-ups were fabricated. Air was used as a working fluid and tested at the same climatic conditions. The ETC had 15 evacuated tubes with a surface area of 1.66 m². The experimental set-up consisted of a header with a hollow pipe (square pipe) in the centre through which the air flowed. The flat-plate collector had a surface area of 1.35 m². The FPC had a black painted absorber sheet which divides the collector into two sections. The air flowed through the upper and the lower sections parallel to the collector to minimize the overall heat loss. The temperature of the outlet air depends on several factors along with the airflow rate and the intensity of the solar radiation. It was found that during the day at high flow rates, the efficiency of the ETC varies from 0.12 to 0.5, and for the flat plate it was from 0.29 to 0.68. The maximum temperature of the air was 56.7°C for the ETC and 25.7°C for the FPC.     

Performance of a hybrid solar collector system in days with stable and less stable radiative regime

The aim of this work is to analyse the performance of a solar energy collector system for water and air heating in real working conditions. Two coupled mathematical models have been developed. One of them describes the thermal behaviour of the Hybrid Solar Collector (HSC) and the second one describes the simultaneous operation of the HSC and of a fully mixed water storage tank. The dependence of the performance of the HSC system on the following three parameters has been studied: (1) water and air mass flow rate; (2) water pipe diameter and air channel height; (3) water storage tank volume. The mathematical models were used to evaluate the HSC system performance during 29 different days, covering all four seasons. A higher water flow rate generally enhances the thermal efficiency of the HSC system, but the enhancement became significantly smaller at higher air flow rates. Positive but small values are recommended for the difference between the fluid temperature at solar collectors exit and the water temperature in the tank. The thermal efficiency of the HSC system is higher on nearly clear sky and decreases in case the amount of clouds on the sky increases.     

Solar-driven technology for freshwater production from atmospheric air by using the composite desiccant material “CaCl<Subscript>2</Subscript>/floral foam”

In this communication, experiments have been performed to check the capability of the newly formed composite desiccant material (CaCl₂/floral) for the extraction of freshwater from atmospheric air. Three numbers of solar glass desiccant box type system (SGDBS) with a captured area of 0.36 m² each, have been used. The design parameters for the water production are height of glass from desiccant bed at 0.22 m, inclination in angle as 30°, the effective thickness of glass as 3 mm and number of glazing as single. The maximum yield by the new composite desiccant material is 0.35 ml/cm³/day. The efficiency of the system SGDBS with 37 % concentration of CaCl₂ is 76.44 %.     

Comparative study of solar-powered water production from atmospheric air using different desiccant materials

In this paper, experiments have been performed in order to determine the quantity of water produced from the atmospheric air using different desiccant materials named Silica gel, Activated alumina and Molecular sieve 13 X. On the bases of experimental results, a correlation is derived among the different temperatures and water production using Central Composite Design (CCD) of Response Surface Methodology. A newly designed solar glass desiccant box type system (SGDBS), three in number, has been used. Design parameters for the production of water has been taken as depth of material from the glass is 0.22 m, inclination in angle as 30°, effective thickness of glass as 3 mm and number of glazing as single. It has been found experimentally that the maximum quantity of water produced by Silica gel, Activated alumina and Molecular sieve 13 X is 160, 20 and 35 ml/kg/day, respectively. Whereas theoretically, value of water produced by the Silica gel, Activated alumina and Molecular sieve 13 X is 600, 28 and 60 ml/kg/day, respectively.     

Performance analysis of solar water heating system in Centre for DNA Fingerprinting and Diagnostics (CDFD), Southern region of India

In the present study, a natural circulation thermosyphon flat plate solar water heater has been tested at the CDFD, Hyderabad (17.37°N, 78.43°E) Andhra Pradesh, India. Experimental data were noted on a sunny day. Dynamic response of the system to variations in solar insulation was studied and analyzed. T _inlet °C and T _outlet °C temperatures were recorded. The performance of the system can be improved by using aluminum tape inserts into the collector fins. The objective of the present study is to evaluate the performance of flat plate collector with and without inserts (aluminum strip of 1 mm thick, 3 mm width and 203 mm length). It is expected that with the same collector with the same flow rate, higher efficiency can be obtained by inserting the tapes inside the collector copper fins (9 mm). Thus, the cost of the system can be further bringing down by enhancing the collector efficiency.     

Comparative experimental analysis of the effect of convective heat losses on the performance of parabolic dish water heater

This paper reveals comparative experimental analysis of the effect of variation of natural and forced convection heat losses on the performance of prototype parabolic dish water heater with coated and non-coated receivers. With the above-described system, hot water needs in domestic applications can be fulfilled instantly. A parabolic dish collector was used for instant water heating. Design of solar parabolic dish collector consists of truncated cone-shaped helical coiled receiver made up of copper at focal point. Instantaneous efficiency of 63% and 48% has been achieved with coated and non-coated receivers. This prototype has been evaluated for its performance with water flow rate of 0.0076 kg/s during the months of April and May 2010 at Shivaji University, Kolhapur, Maharashtra, India (latitude: 16.42° North, longitude: 74.13° West).     

An experimental and a numerical study of horizontal earth-air heat exchanger in a hot climate

Earth-air heat exchangers (EAHE) are devices used in the geothermal technique in order to reduce energy consumption in buildings. In this study, a simulation was conducted through the computational fluid dynamics platform FLUENT 6.3 for the prediction of thermal performance of the EAHE that describes the variation of the air temperature inside the tube. For this, it was necessary to design the heat exchanger while respecting the design and the actual dimensions of the experimental set-up, and stating that the temperature of the wall of the horizontal tube of the exchanger is equal to that of ground at 3 m depth. It should be noted that in assessing the temperature along the two sections vertical (input and output) of the exchanger, opting for a function (UDF) the user define function. Finally, noting a good agreement between both experimental and numerical study, and showing that a significant reduction in temperature at the outlet of the exchanger to a difference of 20 °C, confirming the effectiveness of the heat exchanger.     

Evaluation of decoloration potential of <Emphasis Type="Italic">Xanthium Strumarium</Emphasis> seed hull for adsorption of Direct red 81 in aqueous solution

An unmodified natural adsorbent, Xanthium Strumarium, was explored for its decoloration potential for treatment of textile effluents. Batch mode experimentation was carried out to optimize several process parameters with the well characterized adsorbent. For proper assessment of optimized pathway of adsorption, adsorption isotherms were implemented to the experimental data using nonlinear method. Apart from coefficients of determination, three error analysis methods standard error (S.E.), Chi-square (χ²) statistic and residual mean square error were additionally used to determine the best fitted isothermal model for the system. Freundlich model was creditably fitted to the adsorption data with minimum errors and high R ² values. The adsorption capacity obtained was 14.7, 15.2 and 18.7 mg g^?1 at 30, 40 and 50 °C, respectively. Overall adsorption process was endothermic with positive enthalpy and entropy values. Kinetic study revealed adsorption to be a two stage process initially controlled by film diffusion followed by pseudosecond order as the rate administering step during adsorption. About 95 % decoloration was achieved in 60 min. High decoloration tendency of the opted adsorbent proved that it is an effective and cheap adsorbent for treatment of coloured effluents providing a good alternative to activated carbon.     

Phosphate removal by activated carbon–silica nanoparticles composite,kaolin, and olive cake

This work aimed to utilize four low-cost materials, namely activated carbon (AC), activated carbon–nanoparticle composite, kaolin, and olive cake, for phosphate removal. Batch mode tests were used to evaluate the performance of the adsorbents. The parameters affecting the adsorption process such as pH, initial concentration, mixing time, dosage, and temperature were studied. The obtained results showed that the removal efficiency of the adsorbents followed the order of: activated carbon–nanosilica > activated carbon > kaolin > olive cake. The addition of silica nanoparticles significantly enhanced the removal efficiency of activated carbon by 18.1% reaching a removal efficiency of 98% at 15wt% nanosilica loading. The adsorption isotherm data fitted well with Langmuir and Redlich–Peterson models with a correlation coefficient of >0.98, which indicates a monolayer homogenous adsorption. The fitness of the kinetic models was ranked as: pseudo-second-order > pseudo-first-order > intraparticle model. The calculated values of ΔH° = 23.4 kJ/mole, ΔS° = 0.11 kJ/mole, and ΔG = ?7.4 to ?11.8 kJ/mole indicated the endothermic and spontaneous nature of adsorption. The positive value of activation energy (17.66 kJ/mole) and the very low value of the sticking probability (2.4 × 10^?4) suggest high indefinite sticking of the phosphate ions to the adsorbent surface. The removal efficiency increased with time, dosage, and temperature, while it decreased with the increase in the initial concentration at an optimum pH of 7. The obtained results buttressed the benefit of using silica nanoparticles to enhance activated carbon capacity for phosphate removal, while kaolin and olive cake provided lower removal.     

Experimental investigation of dust pollutants and the impact of environmental parameters on PV performance: an experimental study

The accumulation of dust pollution on the photovoltaic (PV) module can have a significant effect on the productivity and efficiency of PV systems in different locations in the world. Dust which accumulated over time on the PV module and is based on weather conditions led to the reduction in the effectiveness of solar cells. The aim of this research was to experimentally investigate the effect of the natural dust and the effects of environmental parameters on PV performance. The experiments were conducted to propose a model for the current, voltage, power and efficiency and to simulate the effect of environmental parameters on PV performance. The natural dust investigated consisted of different compounds: SiO₂ (45.53 %), CaO (24.62 %), Al₂O₃ (10.83 %), Fe₂O₃ (10.46 %), MgO (6.33 %), K₂O (0.87 %), TiO₂ (0.45 %), SO₃ (0.24 %), MnO₂ (0.21), Cr₂O₃ (0.23 %), SrO (0.13 %) and NiO (0.09 %). It was found that the most accurate correlation is a polynomial from seventh degree for current, voltage, power and efficiency, fourth degree for solar radiation and temperature, cubic degree for humidity and wind velocity. The coefficients of general model are 0.6343, 0.0110, 0.0 and 0.0001 for PV module, respectively, with 0.0011 fitting factor. The proposed model has been validated using models in the literature.     

Energy and exergy analysis of solar hybrid adsorption refrigeration system

In this paper, performance of a solar hybrid adsorption refrigeration (AR) system is investigated experimentally. Such a system was built and tested under the conditions at National Institute of Technology Calicut, Kerala, India. The hybrid system has been designed for heating 50 l of water from 25 to 90°C as well as cooling 10 l of water from 25 to 10°C. The experimental results demonstrate that the refrigerator has a cooling capacity of 47–78 W with a cycle coefficient of performance (COP) of 0.19 and maximum possible COP of 0.45. In exergy analysis of the system, the irreversibility and exergetic efficiency of each component of the system have been calculated. The exergy analysis reveals that the main source of irreversibility is the adsorbent bed of the AR system, emphasising that the input heat energy is not utilised efficiently due to material constraints. The exergetic efficiencies of condenser, expansion device, evaporator and adsorbent bed are found as 42.3%, 79.8%, 54.7% and 11%, respectively.     

Viability of solar photovoltaics as an electricity generation source for Jordan

Viability of solar photovoltaics as an electricity generation source for Jordan was assessed utilising a proposed 5 MW grid‐connected solar photovoltaic power plant. Long‐term (1994–2003) monthly average daily global solar radiation and sunshine duration data for 24 locations – distributed all over the country – were studied and analysed to assess the distribution of radiation and sunshine duration over Jordan, and formed an input to the RetScreen Software for evaluation and analysis of the proposed plant's electricity production and economic feasibility. It was found that depending on the geographical location, the global solar radiation on horizontal surface varied between 1.51 and 2.46 MWh/m²/year with an overall mean value of 2.01 MWh/m²/year for Jordan. The sunshine duration was found to vary, according to the location, between 8.47 and 9.68 hours/day, with a mean value of 9.07 hours/day and about 3311 sunshine hours annually for Jordan. The annual electricity production of the proposed plant varied depending on the location between 6.886 and 11.919 GWh/year, with a mean value of 9.46 GWh/year. The specific yield varied between 340.9 and 196.9 kWh/m², while the mean value was 270.59 kWh/m². Analysis of the annual electricity production of the plant, the specific yield, besides the economic indicators, i.e. internal rate of return, simple payback period, years to positive cash flow, net present value, annual life cycle saving, benefit/cost ratio, and cost of energy – for all sites – showed that Tafila and Karak are the most suitable sites for the solar photovoltaic power plant's development and Wadi Yabis is the worst. The results also showed that an average of 7414.9 tons of greenhouse gases can be avoided annually utilising the proposed plant for electricity generation at any part of Jordan.     

Solar photovoltaic investments and economic growth in EU: Are we able to evaluate the nexus?

A core question in energy economics may be stated as follows: Is the cost–benefit analysis being correctly applied when we encourage investments in renewables, as an alternative to the traditional energy sources? The relationship between energy consumption and economic growth has been extensively treated within economics literature. Yet, literature on the nexus between specific energy sources and GDP is almost inexistent. In this article, we intend to explore the relationship between a certain type of renewable generation technology (solar PV) and GDP. The present and above all the planned energy mix might differ widely from one country to another. Thus, the analysis by source of energy generation becomes a helpful instrument for policy-making. Using a fixed effects panel data methodology and a sample of eighteen EU countries, we find that a 1 % increase in solar PV installed capacity and in electricity production from renewable sources has a positive impact on GDP of 0.0248 and 0.0061 %, respectively. We also conclude that a 1 % growth on greenhouse gas emissions positively affects GDP by 0.3106 %. Further evidence reveals that, in terms of country-specific analysis, Germany, France, Italy and the UK have the most significant estimations for fixed effects. In fact, Germany is a solar PV technology producer, France has a very active nuclear sector, with little pressure for both renewables development and CO₂ reductions, Italy had in this period a strong governmental support to this sector, and the UK has a strong connection between the solar PV and the industry sectors.     

The influence of air temperature on the perception of body odor

Ambient temperature may influence both the emission and the perception of human odor. This paper studies how human odor is perceived at different temperatures. The intensity of human odor in an auditorium was judged by an odor panel in an adjacent space. The ventilation rate of the occupied auditorium was 5–17 L/sec person. A continuous sample of odorous air was exhausted from the auditorium through a glass tube to an odor test station. One-half of the air flow was heated 1–7 K, and the other half was unheated. The odor panel was asked to compare the odor intensity of the two air flows. The air flow judged to have the strongest odor was stepwise dilluted with clean air (air temperature difference maintained). The dilution required to provide the same odor intensity in the two air flows was estimated. At air temperatures 23–32 °C no significant influence of temperature on perceived intensity of body odor was found. The ventillation requirement in auditoria and similar spaces is likely to be independent of the temperature level, provided that the occupants are kept thermally neutral or cooler, so that little or no perspiration occurs.     

Temperature calibration formula for activated charcoal radon collectors

Radon adsorption by activated charcoal collectors such as PicoRad radon detectors is known to be largely affected by temperature and relative humidity. Quantitative models are, however, still needed for accurate radon estimation in a variable environment. Here we introduce a temperature calibration formula based on the gas adsorption theory to evaluate the radon concentration in air from the average temperature, collection time, and liquid scintillation count rate. On the basis of calibration experiments done by using the 25 m³ radon chamber available at the National Institute of Radiological Sciences in Japan, we found that the radon adsorption efficiency may vary up to a factor of two for temperatures typical of indoor conditions. We expect our results to be useful for establishing standardized protocols for optimized radon assessment in dwellings and workplaces.     

How changes in diet and trade patterns have shaped the N cycle at the national scale: Spain (1961–2009)

During the last five decades (1961–2009), Spain has experienced a considerable expansion in the nutrient cycle of its agricultural sector and, in particular, a threefold increase in anthropogenic reactive nitrogen inputs, from 536 Gg N year^?1 in 1961–1965 to 1673 Gg N year^?1 in 2005–2009. Import of feed (soybean, cereals, and cakes) from America and Europe to supply a growing livestock population constitutes the largest share of this increase, along with intensification of synthetic fertilizer use. While in the early 1960s, Spain was nearly self-sufficient in terms of food and feed supply, the net import of agricultural products presently equals domestic crop production, when expressed in terms of nitrogen content (ca. 650 Gg N year^?1). The most important driver of this shift appears to be the rapid change in domestic consumption patterns, which evolved from a typical Mediterranean diet to an animal-protein-rich diet similar to the North European and American diets. Besides livestock production mostly for national consumption, the Spanish agricultural system has specialized in vegetal products with low N content such as olive oil, wine, vegetables, and citrus fruit, which are for the most part exported. The nitrogen load exported outside the Spanish borders by rivers is very low (6.5 % of the total net N input). As a result of the high import and low export of reactive nitrogen, the Spanish mainland is suffering from considerable pollution by local emissions of reactive nitrogen forms to air and water.     

Assessment of hydrothermally modified fly ash for the treatment of methylene blue dye in the textile industry wastewater

Dyes and pigments are one of the major water pollutants and if not discharged properly cause ecological disturbance. Considering this, the current study investigates the application of thermal power plant by-product, i.e., fly ash for the elimination of a hazardous methylene blue dye from its synthetic aqueous solution. Experiments were conducted in batch mode to study the effect of pH, temperature, adsorbent dose and contact time. Highest dye removal (94.3%) was achieved at pH 10 using adsorbent dose of 10 g/L in 90 min of contact time at 40 °C. However, for cost-effective operation at neutral pH and room temperature (30 °C), it yields 89.3% dye removal having similar dose and contact time. Equilibrium isotherms for adsorption were analyzed by Langmuir and Freundlich, Temkin and Dubinin–Radushkevich isotherm equations. The results revealed that the best fit model of adsorption closely followed Langmuir adsorption. Based on adsorption isotherm models, thermodynamics parameters ΔG, ΔH and ΔS were calculated. The negative value of ΔG and ΔH revealed that adsorption process was exothermic, spontaneous and physical. The present work suggests that through simple process hydrothermally modified fly ash has the potential to be used as cost-effective and efficient adsorbent for the treatment of wastewater from textile industries.     

Fuel efficiency enhancement of modified diesel engine operated in dual fuel mode using renewable and sustainable fuels

ABSTRACT

Renewable and sustainable fuels for diesel engine applications provide energy protection, overseas exchange saving and address atmospheric and socio-economic concerns. This study presents the investigational work carried out on a single cylinder, four-stroke, direct injection diesel engine operated in dual fuel (DF) mode using renewable and sustainable fuels. In the first phase, a Y-shaped mixing chamber or venture was developed with varied angle facility for gas entry at 30°, 45° and 60°, respectively, to enable homogeneous air and gas mixing. Further effect of different gas and air mixture entry on the DF engine performance was studied. In the next phase of the work, hydrogen flow rate influence on the combustion and emission characteristics of a compression ignition (CI) engine operated in DF mode using diesel, neem oil methyl ester (NeOME) and producer gas has been investigated. During experimentation, hydrogen was mixed in different proportions varied from 3 to 12 l/min (lpm) in step of 3 lpm along with air-producer gas and the mixtures were directly inducted into engine cylinder during suction stroke. Experimental investigation showed that 45° Y-shaped mixing chamber resulted in improved performance with acceptable emission levels. Further, it is observed that investigation showed that at maximum operating conditions and hydrogen flow rate of 9 lpm, Diesel–producer gas and NeOME–producer gas combination showed increased thermal efficiency by 13.2% and 3.8%, respectively, compared to the DF operation without hydrogen addition. Further, it is noticed that hydrogen-enriched producer gas lowers the power derating by 5–10% and increases nitric oxide (NO_x) emissions. However, increased hydrogen addition beyond the 12 lpm leads to sever knocking.

Abbreviations: NeOME: Neem oil methyl ester; BTE: brake thermal efficiency; CI: compression ignition; ITE: indicated thermal efficiency; PG: producer gas; CA: crank angle; K: Kelvin; BP: brake power; IP: indicated power; H₂: hydrogen; HC: unburnt hydrocarbon; CO: carbon dioxide; CO₂: carbon dioxide; NO_x: nitric oxide; HRR: heat release rate; %: percentage; PPM: parts per million; CMFIS: conventional mechanical fuel injection system.