Combustion and emission characteristics of a direct injection CI engine when operated on Marotti oil methyl ester and blends of Marotti oil methyl ester and diesel

This paper presents a feasibility study of Marotti oil biodiesel as an alternative to diesel fuel for a compression ignition engine. Marotti oil is inedible and available mainly in the state of Kerala. The oil is extracted from Marotti seeds. However, the high viscosity, poor volatility and cold flow characteristics of many vegetable oils in general, and Marotti oil in particular, can cause problems such as injector coking, severe engine deposits, filter gumming, piston ring sticking and thickening of lubrication from long-term use in diesel engines. These problems can be eliminated or minimised by transesterification of the vegetable oils to form monoesters. Although transesterification improves the fuel properties of vegetable oil, the viscosity and volatility of biodiesel are still worse than for petroleum diesel fuel. Subsequently, Marotti oil was converted into its methyl ester by the process of transesterification. The methyl ester was blended with diesel in various proportions to obtain different blends of Marotti oil with diesel. The performance, emission and combustion characteristics of Marotti methyl ester and its blends with diesel were studied and the results were compared with the base line data generated for diesel operation. Experiments were conducted using an injection timing of 23° before top dead centre (BTDC) and an injection pressure of 205 bar at various power outputs and at a constant rated speed of 1500 rpm. The engine manufacturer specifies an injection timing of 23° BTDC and injection pressure of 205 bar for the standard diesel fuel operation. The heat release rates, maximum rate of pressure rise, ignition delay and combustion duration for these fuel combinations were obtained.

From the results obtained, it was observed that the biodiesel produced from Marotti oil and its blends with diesel have slightly reduced brake thermal efficiency and increased smoke, hydrocarbon, carbon monoxide and reduced NO _x emissions compared with diesel-only operation. The investigation showed that the B20 biodiesel blend of Marotti oil with diesel produced better performance in terms of higher brake thermal efficiency, lower specific fuel consumption and comparatively lower emissions compared to the other blend ratios considered.     

Performance studies of a low heat rejection engine operated on non-volatile vegetable oils with exhaust gas recirculation

During recent decades, considerable effort has been expended world-wide to reduce dependency on petroleum fuels for power generation and transportation through the search for suitable alternative fuels that are environmentally friendly. In this respect, vegetable oils are a promising alternative to diesel fuel. However, the high viscosity, poor volatility and cold flow characteristics of vegetable oils can cause some problems such as injector coking, severe engine deposits, filter gumming and piston ring sticking and thickening of lubrication from long-term use in diesel engines. These problems can be eliminated or minimised by transesterification of the vegetable oils to form monoesters. Although transesterification improves the fuel properties of vegetable oil, the viscosity and volatility of biodiesel are still worse than those of petroleum diesel fuel. The performance of a diesel engine with such biodiesel operation can be improved further with the concept of the low heat rejection (LHR) engine. In the LHR engine, combustion surfaces on the pistons, cylinder walls and valves can be coated with ceramic materials. The objective of this study was to apply the LHR engine concept for improving engine performance when either honge biodiesel, known as honge oil methyl ester (HOME), or neem biodiesel, known as neem oil methyl ester (NOME) oils was used as an alternative fuel. For this purpose, experiments were conducted on a single cylinder, four-stroke, direct injection, water-cooled compression ignition engine using diesel, HOME and NOME oils at different injection timings of 19, 23 and 27° before top dead centre (BTDC) with and without the induction of exhaust gas recirculation (EGR). The percentage of EGR was varied from 5 to 20% in steps of 5%. The results showed that specific fuel consumption and brake thermal efficiency were improved for both of the biodiesel fuels in the LHR engine. An EGR of 10% resulted in better performance with trade-off between oxides of nitrogen and hydrocarbons/carbon monoxide emissions and hence 10% EGR is taken as the best of the range from 5 to 20%. However, readings with other EGR ratios are not reported.     

Combustion and emission characteristics of a direct injection,compression‐ignition engine when operated on Honge oil,HOME and blends of HOME and diesel

This paper reports the results of research conducted to study the fuel properties of Honge oil and blends of its ester and the subsequent testing of these oils in a four‐stroke, single cylinder, water‐cooled, direct injection, compression‐ignition (CI) engine. Experiments were conducted with injection timings of 19, 23 and 27° BTDC at various loads and at a constant rated speed of 1500?rev?min^?1. The performance and emission characteristics of Honge oil and Honge oil methyl ester (HOME) blended with diesel, to produce blends designated B20, B40 and B80, were studied. The heat release rates, maximum rate of pressure rise, ignition delay, and combustion duration for these fuel combinations were determined.     

Combustion characteristics of a four-stroke CI engine operated on Honge and Jatropha oil methyl ester–ethanol blends when directly injected and dual fuelled with CNG induction

The demand for petroleum products in India has been increasing at a rate higher than the increase of domestic availability. At the same time, there is continuous pressure on emission control through periodically tightened regulations particularly in metropolitan cities. In the wake of this situation, there is an urgent need to promote the use of alternative fuels as substitutes for high-speed diesel. Dual-fuel mode of operation employing compressed natural gas (CNG) and plant oils such as Honge and Jatropha oils and their esters is an attractive option as our country has a large agriculture base that can be a feedstock to this fuel technology which can ease the burden on the economy by curtailing fuel imports. This paper presents the results of investigations carried out in studying the behaviour of Honge and Jatropha oil methyl esters and their blends with 15% ethanol and subsequent testing of these oils in a four-stroke, single-cylinder, water-cooled, direct-injection compression ignition engine in dual-fuel mode with CNG induction.     

Dividivi tannins: an ecological product for water-based drilling fluids

Modified tannins are used as deflocculant additives in the formulation of water-based drilling fluids (WBDF) for drilling operations in any scenario. Due to their high heavy metals content, these additives are toxic and hazardous for any environmental scenario. Deflocculant efficiency of unmodified tannins (UDT) extracted from fruit pods of “dividivi” (Caesalpinia coriaria) as an additive for WBDF was assessed. Raw materials for UDT elaboration come from the rural and sustainable exploitation of natural occurring dividivi trees, growing in dry tropical forests in Anzoátegui state (Orinoco Oil Belt, eastern Venezuela). The tannins extract, in the form of dividivi fruit powder, contains 47.0 % of total tannins (hydrolyzable tannins plus condensed tannins), of which 67.4 % corresponds to hydrolyzable tannins. Dividivi tannins in WBDF showed nine (9) times deflocculant efficiency than heavy metals commercial modified tannins. Moreover, commercial modified tannins do not improve their deflocculant efficiency with increased tannin content. Ecotoxicological studies were carried out for WBDF formulations with UDT, using freshwater microalgae Scenedesmus dimorphus as chronic toxicity bioindicator. Toxicity bioassays performed with these microalgae did not show significant effects on its population growth. The EC₅₀ values resulted in over 100,000 mg L^?1, and these formulations were therefore considered non-toxic. Values of LC₅₀ obtained this time with Poecilia reticulata, as acute toxicity bioindicator are around 100,000 mg L^?1, with no significant effects on population mortality. Thus, WBDF formulated with UDT can be considered non-toxic formulations for populations of this freshwater fish. From the social perspective, the use of UDT in WBDF fosters organized communities economical activities based on the maintenance of a sustainable supply chain for processing fruits in a quantity enough to obtain three thousand seven hundred fifty kilograms (3750 Kg). The UDT so obtained was used as deflocculant in four (4) oil wells producing excellent performance and relevant savings compared with commercial modified tannin.     

Studies on process optimization of biodiesel production from waste cooking and palm oil

This work investigated the optimisation of biodiesel production from waste cooking oil (WCO) and palm oil using a two-step transesterification process for WCO and base catalysed transesterification for palm oil. Transesterification reactions were carried out to investigate the effects of prepared catalyst CaO, methanol/WCO and methanol/palm oil ratio and temperature on the yield of biodiesel. A series of experiments were conducted to determine the best conditions for biodiesel production, using methanol/oil ratio between 4:1 and 11:1 and contact time varying between 2 and 4 h. Biodiesel yield of around 90 and 70% was obtained for palm and waste cooking oil at the methanol/oil ratios of 6:1 and 8:1 at temperature of 60 °C for reaction time of 4 h using prepared CaO as catalyst. The physicochemical properties of palm and WCO biodiesel were carried out using standard methods, while the fatty acid profile was determined using gas chromatography. The investigation concludes that biodiesel obtained from palm and waste cooking oil was within the specified limit.     

Thermal barrier coated diesel engine running on biodiesel: a review

Thermal barrier coated diesel engine, also known as low heat rejection (LHR) engine have offered the promise of reducing heat rejection to the engine coolant and increase the combustion temperature which results in increase of thermal efficiency, decrease of fuel consumption and emission rate of the engine. Biodiesel derived from the vegetable oils are a promising alternative fuel for diesel fuel. The viscosity of vegetable oil after transestrification is still higher than that of diesel fuel. The various researchers have reported that the energy of the biodiesel could be released more efficiently with the concept of LHR engine. In the case of LHR engine running on different biodiesel blends, almost all experimental studies has predicted improved performance. This paper analyses and discussed the operating conditions under which the experimental studies are carried out and the factors which affect thermal efficiency and exhaust emissions in LHR engine.     

Effect of injection timing,injector opening pressure and nozzle geometry on the performance of a compression ignition engine operated on non-edible oil methyl esters from different sources

Increasing cost of fossil fuels, environmental threats from exhaust emissions and their depleting nature have generated intense international interest in developing renewable and alternative fuels for internal combustion engines. This study investigates the suitability of different non-edible-derived biodiesels such as cottonseed oil methyl ester (COME), honne oil methyl ester (HnOME) and honge oil methyl ester (HOME) to four-stroke, single-cylinder compression ignition (CI) engine. Engine tests were conducted to study the effect of fuel injection timing (IT), fuel injector opening pressure (IOP) and injector nozzle geometry on the performance, combustion and emission characteristics of COME, HnOME and HOME in the modified CI engine. IT was varied from 19° to 27° before top dead centre (bTDC) in steps of 4° bTDC; IOP was varied from 205 to 240 bar in steps of 10 bar. Nozzle injectors of three to five holes, each of 0.3 mm size, were selected for the study. It was concluded that a retarded IT of 19° bTDC increased IOP of 230 bar, and four-hole nozzle injector of 0.3 mm size resulted in overall better engine performance with increased brake thermal efficiency and reduced hydrocarbon and carbon monoxide smoke emissions for the fuels tested.     

Improved oxidative stability of biodiesel via alternative processing methods using cottonseed oil

Biodiesel from waste cooking oil (WCO) requires antioxidants to meet oxidation stability specifications set forth in ASTM D6751 or EN 14214. In contrast, unrefined cottonseed oil (CSO), containing tocopherols and gossypol, produces biodiesel of higher oxidation stability. However, only a portion of these CSO endogenous antioxidants are suspected to be retained in biodiesel. Because the economics of biodiesel manufacturing rely upon inexpensive sources of triglycerides, emphasis was placed on developing improved alternative processing methods where WCO was the main source of methyl esters (WCOME) and CSO was used as a supplemental source of triglycerides and antioxidants in a 4:1 ratio. This study compared four processing methods for their ability to produce biodiesel of increased oxidative stability prepared from a 4:1 ratio of WCO:CSO. Two novel processing methods developed for this study utilise solvent properties of fatty acid methyl esters and glycerol to avoid additional chemical inventory for biodiesel processors. This study concludes that the two new processing methods resulted in biodiesel that had statistically significant improved oxidation stability when compared to two common industrial processing methods. Another significant finding is that high-shear homogenisation during transesterification reduced reaction time from the published one hour to 16 minutes.     

Oil spill source identification by infrared,gas chromatographic,and trace metal analyses

Tests on several oil spills and their reference, unweathered oils, indicated that trace metals in oils such as V, Ni, Fe, and Mg are not appreciably influenced by weathering and that the use of characteristics trace-metal indicators can offer potential fingerprints for oil pollutants.     

Life improvement programme of producer gas–biodiesel operated dual fuel engines

Biomass fuels have attracted an increase in interest due to the alarming rise in global greenhouse gases and the rapid rise of petroleum prices. Energy security on a sustainable basis can come only with the responsible use of home-sourced resources and not from imported fossil fuels such as coal or crude petroleum products. Partial combustion of biomass in the downdraft gasifier generates producer gas that can be used as the sole fuel or as a supplementary fuel for internal combustion engines. A dual fuel mode of operation, in which producer gas is used as a supplementary inducted fuel along with injected pilot fuels of Honge or Jatropha biodiesels, can be a promising alternative to diesel only usage. Two different carburettors were designed and fabricated to facilitate gas entry at 45° and 90° to the engine cylinder. The engine was experimentally optimised using Honge or Jatropha biodiesels–producer gas combinations with respect to maximum pilot fuel savings in the dual fuel mode operation, optimum air and gas mixing with different tested carburettors. The performance, combustion and emission characteristics of these dual fuel combinations were compared at different load conditions. The results showed that biodiesels of Honge or Jatropha oils–Producer gas combinations with carburettor of 90° gas entry resulted in better performance.     

Effect of mixing chamber venturi,injection timing,compression ratio and EGR on the performance of dual-fuel engine operated with HOME and CNG

Stringent environmental policies and the ever increasing demand for energy have triggered interest in novel combustion technologies that use alternative fuels as energy sources. Of these, pilot-ignited compressed natural gas (CNG) engines that employ small biodiesel pilot to ignite a premixed natural gas–air mixture have received considerable attention. This paper discusses the effect of mixing chamber venturi, injection timing, compression ratio and exhaust gas recirculation (EGR) on the performance of dual-fuel engine operated on biodiesel derived from honge oil and is called honge oil methyl ester (HOME) and CNG. The proposed study mainly focuses on the manifold induction of CNG along with HOME injection. However, CNG can also be injected using port or direct gas injector (Lakshmanan and Nagarajan 2010, Energy 35, pp. 3172–3178). The future study will involve these methods of CNG injection. From this study, it is concluded that an advanced injection timing and an increased compression ratio resulted in increased brake thermal efficiency and reduced smoke, hydrocarbons and carbon monoxide emissions. However, nitrogen oxides (NO _x ) emission increased significantly. The increased NO _x emission was effectively reduced with EGR method. A mixing chamber venturi of 3 mm size, injection timing of 27° before top dead centre (BTDC), compression ratio of 17.5 and 10% EGR were found to be optimum for the modified compression ignition engine that was operated on CNG–HOME dual-fuel mode.     

The economics of handling refinery sludges

Methods of handling sludges generated from normal refinery operations are evaluated to determine the costs of alternative disposal methodologies. Sludges generated from several areas in the refinery are classified as (1) sludges from which oils may be recovered; (2) other oily sludges from which oils cannot be recovered; and (3) biological sludges. Methodologies for handling these sludges are reviewed based on previous experience. The economics of handling a representative combination of biological and oily sludges from the refinery are evaluated considering three disposal options: Alternative I in which the sludge would be dewatered using pressure filtration followed by landfill disposal of the sludge cake; Alteration II in which vacuum filtration was employed for sludge dewatering followed by sludge disposal in a landfill; and Alternative III in which the sludges were disposed of by landfarming. Costs are presented for centrifugation of oily sludges and incineration as a final disposal alternative.     

Energy rating methodology for light-duty vehicles: geographical impact

The aim of this paper was to describe a new energy dependency score methodology and its consequent application to cars sold in twelve regions: Europe (EU-28) and eleven specific countries worldwide (Australia, Brazil, China, India, Japan, Norway, Portugal, Russia, Saudi Arabia, South Africa and USA). This methodology was developed as a potential tool to inform consumers of their choice impact on the country’s economy. This methodology is based on primary energy assessments and origins for each energy pathway associated with a gasoline-, diesel-, natural gas (used for H₂ production)- or electricity (balanced with country electricity mix)-powered vehicle. An energy dependency index was attributed to the best-case (100 % endogenous production) and worst-case (0 % endogenous production) scenarios and consequently weighted with vehicle fuel consumption. This enabled obtaining an energy dependency index (10–0). This index could be assigned to an environmental and social index to provide a sustainability index and therefore complement a road vehicle environmental rating system, providing a combined index rating. Internal combustion engine vehicles and hybrid vehicles (that have oil products as energy source) rate the lowest for almost all locations, with the exception of regions that are energy independent (Norway, Saudi Arabia or Russia). Electric vehicles rank higher when comparing to the other technologies analyzed for all locations in this study. The plug-in hybrid electric vehicle shows generally a rank in an intermediate place, except for Japan where it scores lower than all other technologies.     

Comparative study on effect of blending,thermal barrier coating (LHR) and injector nozzle geometry on biodiesel-fuelled engines

Increased petroleum prices, increased threat to the environment from exhaust emissions and global warming have generated intense international interest in developing renewable and alternative non-petroleum fuels for internal combustion engines. Evolving suitable technology for addressing energy crisis creates a continued investigation into the search for sustainable and clean-burning renewable fuels. This work investigates suitability of different non-edible-derived biodiesels such as cotton seed oil methyl ester (COME), Honne oil methyl ester (HnOME) and Rubber seed oil methyl ester (RuOME) to four stroke, single cylinder compression ignition (CI) engine. Engine tests were conducted to study the effect of fuel blending, thermal barrier coating (TBC) or Low Heat Rejection (LHR) and injector nozzle geometry on the performance, combustion and emission characteristics of COME, HnOME and RuOME in the modified CI engine. Blends of biodiesels with diesel were varied from 20 to 80% in steps of 20%. Two thermal barrier coatings of partially stabilized zirconium (PSZ) and aluminium oxide (Al₂O₃) were provided on the engine to make it fully adiabatic. Nozzle injectors of 3, 4 and 5 holes, with size of orifice varied from 0.2 to 0.3 mm size were selected for the study. It was concluded that B20 biodiesel blend, PSZ-coated engine and four hole nozzle injector of 0.2 mm size resulted in overall better engine performance with increased brake thermal efficiency (BTE) and reduced HC, CO, smoke emissions for the fuel combinations tested. Combustion analysis to study the effect of biodiesel blends, LHR coatings, injector nozzle geometry on the performance of the biodiesel-fuelled engine has been presented to give more insight into the behaviour of operation.     

Sustainable polymer composites: immiscible blends prepared by extrusion of poly(trimethylene terephthalate) and polyamide6,10 with high bio-based content

Components for binary polymer blends were sought to produce an immiscible blend of improved renewable character and with good structural properties. The poly(trimethylene terephthalate) and polyamide6,10 system was selected based on the molecular structure of the molecules and the bio-based origin of the feedstocks. A preliminary study of three compositions in this system demonstrated the similar thermal properties of the two polymers as measured by differential scanning calorimetry (DSC) and the ability of these polymers to be processed together in conventional extrusion equipment to produce blends with micrometer-scale domains. Dispersed phases were observed by electron microscopy near the end members. Available viscosity data and the appearance of columnar blends at the 50/50 composition suggest the possibility of co-continuous blends in close proximity to this composition.     

Blends of karanja and jatropha biodiesels for diesel engine applications

Over a number of years, the work of exploring different biodiesels as an alternative to diesel fuel has been carried out worldwide. Not much focus on the use of combination of different biodiesels and their behaviour in diesel engines has been reported. This work is an attempt in this direction, which reports on the use of combination of biodiesels derived from jatropha and karanja oils. Jatropha oil methyl ester (JOME) and honge oil methyl ester (HOME) represent the respective biodiesels derived from these non-edible oils. Experiments were conducted on a four-stroke, single-cylinder diesel engine using these biodiesel combinations in order to check their feasibility as alternative fuels to diesel. Initially, experiments were conducted on each biodiesel and their blends with diesel and engine parameters were optimised in terms of injection pressure and injection timing. Advancing the injection timing improved the overall performance of the engine fuelled with JOME while retarding the injection timing favoured the HOME. Both biodiesels performed better with an injector opening pressure of 230 bar. Finally, experiments were conducted with the combination of both biodiesels with different blend ratios. It was observed that increasing the JOME content in the biodiesels blend improved the performance with reduced emissions of smoke, hydrocarbons and carbon monoxide emissions. However NO _x emission increased.     

Increased functionality of methyl oleate using alkene metathesis

A series of alkene cross-metathesis reactions were performed using a homogeneous ruthenium-based catalyst. Using this technology, a variety of functional groups can be incorporated into the bio-based starting material, methyl oleate. Trans-stilbene, styrene, methyl cinnamate and hexen-3-ol have all been shown to give desirable products. Using this technology, aromatics, alcohols or additional esters can be incorporated into the products. For example, the cross-metathesis reaction of methyl oleate with methyl cinnamate by the second-generation Grubbs catalyst showed 70% conversion of methyl oleate into products where half of the observed products contain an aromatic group and over one-third of the products contain an α,β-unsaturated methyl ester. This promising green route is versatile, and with an appropriate selection of starting materials, it is applicable to the synthesis of polymer precursors, industrial fluids or any other application where the upgrade of natural oils is necessary.     

Performance,combustion and emission characteristics of a single-cylinder,four-stroke,direct injection diesel engine operated on a dual-fuel mode using Honge oil methyl ester and producer gas derived from biomass feedstock of different origin

Renewable and alternative fuels have numerous advantages compared with fossil fuels, as they are renewable and biodegradable, and provide food and energy security and foreign exchange savings besides addressing environmental concerns and socio-economic issues. In this context, present work was carried out to investigate the feasibility of alternative and renewable fuels derived from biomass feedstock of different origin for engine applications. The present study was also extended to study the effect of producer gas composition derived from different biomass feedstock on the performance, combustion and emission characteristics of a single-cylinder, four-stroke, direct injection stationary diesel engine operated on a dual-fuel mode using Honge oil methyl ester (HOME) and producer gas induction. The performance of the engine was evaluated with a constant injection timing of 27° before top dead centre, an injection pressure of 205 bar for the diesel–producer gas combination and 230 bar for the HOME–producer gas combination and a compression ratio of 17.5. The results showed that the performance of the dual-fuel engine varies with the composition of the producer gas and depends on the type of biomass feedstock used in the gasifier. Experimental investigations on the dual-fuel engine showed that brake thermal efficiency values for the engine operated using HOME–producer gas derived from babul, neem and honge woods were found to be 17.2, 14.3 and 11.56% respectively, compared to 23.8% for diesel–producer gas operation at 80% load. However, the results showed better engine performance with lower exhaust emission levels for the operation of HOME–producer gas derived from the ordinary or babul wood compared with the operation of that derived from the neem and Honge woods. In view of this, present study reveals that use of alternative and renewable fuels for dual fuel engine can be considered as an immediate solution for the development of rural areas and emergency use in the event of severe diesel fuel shortage.     

Review of pollutants in petroleum refinery wastewaters and effect upon aquatic organisms

In the past decade, the number of organic chemical contaminants identified in oil refinery wastewaters has risen from less than 20 to over 300. This increase in knowledge was made possible by advances in gas chromatography-mass spectrometry instrumentation and new techniques to maximize resolution of capillary chromatography. The types of compounds identified in refinery wastewaters are similar to those identified in crude oils; i.e., aliphatic, aromatic, alkyl aromatic, polynuclear aromatic hydrocarbons, and some hydrocarbons containing nitrogen, sulfur, and oxygen. The contaminants in oil refinery wastewaters acutely lethal to aquatic organisms can be removed by biological treatment systems. However, biological treatment systems may not be capable of removing all deleterious contaminants. Long-term fathead minnow bioassays of biologically treated refinery wastewaters resulted in 10%–50% mortality after 14–16 days of exposure. The lethal effects were eliminated by sequential treatment with dual media filtration-activated carbon adsorption.