Groundwater contamination by microbiological and chemical substances released from hospital wastewater: Health risk assessment for drinking water consumers

Contamination of natural aquatic ecosystems by hospital wastewater is a major environmental and human health issue. Disinfectants, pharmaceuticals, radionuclides and solvents are widely used in hospitals for medical purposes and research. After application, some of these substances combine with hospital effluents and, in industrialised countries, reach the municipal sewer network. In certain developing countries, hospitals usually discharge their wastewater into septic tanks equipped with diffusion wells. The discharge of chemical compounds from hospital activities into the natural environment can lead to the pollution of water resources and risks for human health. The aim of this article is to present: (i) the steps of a procedure intended to evaluate risks to human health linked to hospital effluents discharged into a septic tank equipped with a diffusion well; and (ii) the results of its application on the effluents of a hospital in Port-au-Prince. The procedure is based on a scenario that describes the discharge of hospital effluents, via septic tanks, into a karstic formation where water resources are used for human consumption. COD, Chloroform, dichlomethane, dibromochloromethane, dichlorobromomethane and bromoform contents were measured. Furthermore, the presence of heavy metals (chrome, nickel and lead) and faecal coliforms were studied. Maximum concentrations were 700 NPP/100 ml for faecal coliforms and 112 mg/L for COD. A risk of infection of 10^? 5 infection per year was calculated. Major chemical risks, particularly for children, relating to Pb(II), Cr(III), Cr(VI) and Ni(II) contained in the ground water were also characterised. Certain aspects of the scenario studied require improvement, especially those relating to the characterisation of drugs in groundwater and the detection of other microbiological indicators such as protozoa, enterococcus and viruses.     

A quantitative water resource planning and management model for an industrial park level

This paper introduces an integrated water management model at the industrial park level. It suggests four approaches to water management: first, direct water reuse among users; second, water reuse among users by blending with freshwater; third, water reuse between users and a wastewater treatment plant; and fourth, groundwater recharge by reclaimed wastewater or other feasible applications in order to optimize the overall water efficiency. The model results in a comprehensive management methodology for optimizing water resources within an industrial park, seeking potential water reuse among industries, and incorporating the size and cost of reclaimed wastewater delivery systems. A case study is employed to test the model’s feasibility. An economic analysis of the optimized water use network is also carried out, showing the potential water and cost savings.     

Energy analysis for onsite and offsite suburban wastewater

The environmental consequence of meeting the planet’s energy requirements has shown that biological degradation of organic constituent from wastewater does not only produces biogas. It also produces flammable methane that has 21 times more global warming potential or greenhouse effect than carbon dioxide. This becomes a loss of potential renewable energy when it is flared. This study investigates recoverable energy from cassava wastewater and effect of unrecovered onsite (not from treatment plant) wastewater energy. Sludge from both onsite untreated and offsite treated wastewater from a cassava processing station in a sub urban community of Nigeria was analyzed. The result shows that the offsite treatment has a methane potential of 27.428 m³/day compared to the onsite methane emission potential with 17.807 m³/day. The onsite 17.807 m³/day of methane is equivalent to 0.126 kgCH₄/year of emitted methane base on industrial procedure standards by the IPCC (2006) guidelines for national greenhouse gas inventories. An additional 54.03% of methane will be recovered if the onsite emissions were to be captured . At an emission efficiency of 0.025 kgCH₄/kg COD, the untreated wastewater indicates a potential contribution to the greenhouse effect. A mathematical model analysis was presented for ease in determining the amount of methane emitted from the untreated wastewater. This study support suggested methodologies and previous work comparing anaerobic offsite methane potential and untreated wastewater methane emission potentials along with its greenhouse effects.     

Determination of non-steroidal anti-inflammatory drug (NSAIDs) residues in water samples

Pharmacologically active substances used to treat human and animal illnesses can enter the aquatic environment via effluents from wastewater treatment plants or in the case of veterinary drugs directly through liquid manure discharge. Some of these substances enter the environment either as the parent compound or as active/inactive metabolites. Due to their pharmacological activity, their determination and understanding their behavior and fate in the environment are important. The scope of this paper was to develop an analytical procedure to determine common pharmaceutical residues in wastewaters. Pharmacologically active substances were chosen according to their wide spread application in Slovenia and Central Europe and are members of analgesics, e.g., non-steroidal anti-inflammatory drugs: ibuprofen, naproxen, ketoprofen and diclofenac. Selected compounds were isolated from synthetic water using a novel SPE sorbent Strata X. Due to the non-volatile nature of these compounds they were first silylised prior to gas chromatographic-mass spectrometric detection. The developed procedure was tested with synthetic wastewaters and their extraction efficiency (>84%) and method limits of detection (2-6 ng L(-1)) were determined. Our procedure has been adopted and optimised for "real" water samples and applied to eleven drinking and ten river water samples from Slovenia. The results showed no traces of NSAIDs in all potable water samples and low-range contamination (ng L(-1)) of Slovene rivers. These results show that NSAIDs contamination of Slovene waters is comparable with published results of water contamination in Central Europe.     

八种不同工艺组合人工湿地系统除磷效果研究

传统的人工湿地系统除磷效能的提高方式主要集中在基质填料的选择、湿地植物的筛选等方面,本试验从调整湿地的组合工艺着手探索提高磷去除效率的优化组合,在为期两年的研究中考察了推流床-下行流-上行流、下行流-上行流-推流床、好氧塘-下行流、下行流-兼性塘、推流床-下行流、下行流-上行流、推流床等8种不同工艺组合人工湿地系统对富营养化湖泊水体中磷的去除规律,比较了这些湿地组合所构建的生物学效应。试验结果显示,如果采用塘系统作组合单元在湿地系统中前置比较理想,而在不同的季节,不同水力负荷下的冲击试验结果表明,复合垂直流湿地系统可以常年保持稳定的、较高的磷去除能力,而且对水力变化具有更好的耐受性能。复合垂直流湿地作为一种新型的人工湿地系统工艺组合具有较好的理论价值和应用前景.     

Identifying implementation gaps in water recycling policy of Beijing municipality

ABSTRACT

Due to its dry climate, growing population, and overexploited groundwater, China’s capital is plagued by water scarcity. Since the late 1980s, Beijing has adopted water reuse solutions to bring relief; today, however, the intentions of these reuse policies are often not reflected in practice. Three significant implementation gaps exist: lack of use of installed decentralized reuse systems, limited understanding of the operation of decentralized treatment plants by operators, and inadequate service of centralized reuse treatment systems. By understanding the cause, impact, and severity of these gaps, Beijing’s policymakers can work to meet existing needs via a range of municipal and national policy-driven actions.

AbbrevationBWA Beijing Water AuthorityCECEPChina Energy Conservation and Environmental Protection GroupCNY Chinese yuanIPEInstitute of Public and Environmental AffairsENGOEnvironmental non-governmental organizationMACMunicipal Action CommitteeMEEMinistry of Ecological Environment MEP Ministry of Environmental ProtectionMEPBMunicipal Bureau of Environmental ProtectionMNRMinistry of Natural ResourcesOECDOrganization for Economic Cooperation and DevelopmentO&MOperation and maintenanceSNWTPSouth-North Water Transfer ProjectSOEState-Owned Enterprise     

Reuse of mining wastewater in agricultural activities in Jordan

A pilot study was completed in the Al-Abyad area near phosphate mining activity in Jordan. Six plots of 50 m² each were planted with two types of plant species (Zea mays spp. and Medicago lupulina spp.) and irrigated using three types of water (fresh groundwater, mine wastewater, and hydride water consisting of 50% fresh and 50% mine wastewater) to investigate the suitability of utilizing mine wastewater for food production in the area. Water, soil and plant sampling was completed for each plot over different time intervals and analyzed for heavy metal (Cr⁺⁶, Ni⁺², Zn⁺² and Pb⁺²) in addition to major ionic composition of the water used for irrigation. Crop yield was estimated at the end of the experiment. Plots irrigated with mine wastewater showed slightly higher heavy metals concentrations and soil salinity during the experiment period was higher for plots irrigated with mine wastewater compared to plots irrigated with fresh water, and it was uniform through the upper 45 cm of the soil profile due to the high amount of irrigation water used during the experiment. Crop yield was inversely proportional to salinity as an increase of salinity by 2-folds resulted in reducing yield by almost 50%. However, no risk of heavy metals contamination was found in plants and soil. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue.     

Environmental challenge vis a vis opportunity: the case of water hyacinth

Water hyacinth (Eichhornia crassipes) is a noxious weed that has attracted worldwide attention due to its fast spread and congested growth, which lead to serious problems in navigation, irrigation, and power generation. On the other hand, when looked from a resource angle, it appears to be a valuable resource with several unique properties. As a result, research activity concerning control (especially biological control) and utilization (especially wastewater treatment or phytoremediation) of water hyacinth has boomed up in the last few decades. Investigations on biogas/compost production from water hyacinth have also come up very well mainly from few research groups in India. This review presents a comprehensive view of the research related to water hyacinth with special emphasis on the recent investigations on water hyacinth control and utilization technologies conducted in the last 2-3 decades. Based on these significant research achievements, now it is desirable to identify a management strategy so that the excessive growth can be controlled and the plant can be used in beneficial ways. In the rural areas, water hyacinth could be used in an integrated manner for decentralized wastewater treatment systems coupled to biogas and compost production from the resulting biomass. There is a need to work out the techno-economic viability of such integrated model systems.     

Photodegradation characteristics of PPCPs in water with UV treatment

The degradation characteristics of PPCPs commonly found in surface water under UV treatment were examined for 30 kinds of PPCPs using a UV/Lamp1 that emits light at a wavelength of 254 nm and a UV/Lamp2 that emits light at 254 nm and 185 nm in pure water. When a UV dose of some 230 mJ/cm² was introduced to the 30 PPCPs, photodegradation rates of about > 3% (theophylline) to 100% (diclofenac) and about > 15% (clarithromycin) to 100% (diclofenac) were observed for UV/Lamp1 and UV/Lamp2, respectively. This study also showed that UV/Lamp2, which photolyzes water molecules and generates OH radicals, is more effective for PPCP removal than UV/lamp1. It was postulated that the degradation rates of sulfamethoxazole, sulfamonomethoxine, sulfadimethoxine and sulfadimidine, all, including sulfamethoxazole, derived from sulfanilamide, under UV/Lamp1 resulted mainly from the bond-breaking reactions occurring between –SO₂– and its side atoms, the C–S bond and the N–H bond. Some PPCPs with amide bonds, such as cyclophosphamide and DEET, were highly resistant to photodegradation by UV/Lamp1. AOPs (Advanced oxidation processes) such as the UV/H₂O₂ or UV/O₃ processes should therefore be considered for their potential to remove these substances effectively.     

Human health effects of residual carbon nanotubes and traditional water treatment chemicals in drinking water

The volume of industrial and domestic wastewater is increasing significantly year by year with the change in the lifestyle based on mass consumption and mass disposal brought about by the dramatic development of economies and industries. Therefore, effective advanced wastewater treatment is required because wastewater contains a variety of constituents such as particles, organic materials, and emulsion depending on the resource. However, residual chemicals that remain during the treatment of wastewaters form a variety of known and unknown by-products through reactions between the chemicals and some pollutants. Chronic exposure to these by-products or residual chemicals through the ingestion of drinking water, inhalation and dermal contact during regular indoor activities (e.g., showering, bathing, cooking) may pose cancer and non-cancer risks to human health. For example, residual aluminium salts in treated water may cause Alzheimer's disease (AD). As for carbon nanotubes (CNTs), despite their potential impacts on human health and the environment having been receiving more and more attention in the recent past, existing information on the toxicity of CNTs in drinking water is limited with many open questions. Furthermore, though general topics on the human health impacts of traditional water treatment chemicals have been studied, no comparative analysis has been done. Therefore, a qualitative comparison of the human health effects of both residual CNTs and traditional water treatment chemicals is given in this paper. In addition, it is also important to cover and compare the human health effects of CNTs to those of traditional water treatment chemicals together in one review because they are both used for water treatment and purification.     

Impact and cost of measures to reduce nutrient emissions from wastewater and storm water treatment in the German Elbe river basin

As a leading nutrient emitter, wastewater infrastructure harbors significant technical potentials to reduce the water-polluting emissions of phosphorus and nitrogen into the Elbe river basin. From the viewpoint of the central infrastructure, the effluent threshold value of urban wastewater treatment plants could be lowered further by advanced use of denitrification and membrane filtration, and storm water overflows of wastewater and contaminated rainwater from sewers could be treated in retention soil filters. In addition, small-scale wastewater treatment plants, infiltration and reducing or unsealing impervious surfaces could be used as decentralized elements of wastewater or storm water treatment. It can be shown that if the most advanced measures were applied in all wastewater-relevant areas, up to 60% of the phosphorus and 37% of the nitrogen emissions could be avoided. Alongside central wastewater treatment plants, small-scale treatment plants prove to be the most effective and cost-efficient option. To achieve an ecologically acceptable state of the Elbe, however, it may be necessary to employ more costly measures as well.     

Physical model study of thermal and chemical pollution in the Shuaiba offshore area of Kuwait

The cooling and process waters of the industrial plants located in the Shuaiba Industrial Area in Kuwait are supplied by a complex system of seawater outlets and intakes. Discharge of heated water from the industrial plants is considered a major problem since it may recirculate directly through the intake towers, and the cooling water withdrawn may be at a higher temperature than is desirable. Higher cooling water temperature reduces the efficiency of industrial plants and causes thermal pollution, which adversely affects the water of the Arabian Gulf. In addition, the discharged process water may cause chemical pollution in the offshore area.An undistorted physical model with a scale of 1:50 was constructed and tested with the basic objectives of determining the temperature field in the Shuaiba offshore area identifying possible recirculation patterns and temperature increase at the intake, examining the flow and mixing characteristics of chemical effluents discharged, and investigated alternative remedial measures.The model test results showed that, in line with the field tests, the temperature of the sea water at the intakes was about 1.7–2.5°C higher than the ambient temperature. When heated water from the larger outlets was allowed to discharge into a channel running parallel to the shoreline and curved to stay parallel to the outside of the southern breakwater of the Shuaiba harbor, the temperature increase at the intakes was limited to 0.8–1.0°C and tests showed that the concentration of conservative chemical pollutants at the intakes was reduced by about 50%.     

Influence of silts on the growth,reproduction and chlorophyll fluorescence of <Emphasis Type="Italic">Potamogeton crispus</Emphasis> in turbid water

Turions of Potamogeton crispus were planted in several turbid waters. Some parameters of growth, reproduction and chlorophyll fluorescence were measured. The results were as follows: (1) Sprouting rates in all groups reached to 100.0% on the 17^th day. (2) The parameters of the growth (stem and leaf) and chlorophyll fluorescence (Φ_PSII, qP and qN) in 120 and 150NTU waters were inhibited heavily 60 days later, and their survival time was only 140 days. However, the plants in 30 to 90NTU waters could grow near water surface, their survival time was about 190 days. (3) After 150 days, the saturating irradiance intensity and rETR_max of the leaves in 30 to 90NTU waters markedly decreased with an increase in the amount of attached silts, and the number and fresh mass of turions (propagula) in 60 and 90NTU waters were significantly lower than the control. In summary, P. crispus in 0.7-metre-deep turbid water with suspended silts (not more than 90NTU) could sprout and grow normally, and produce the turions.     

Estimation of sources of total phosphorus in a river basin and assessment of alternatives for river pollution reduction

The methodology of material flow analysis is presented and applied to developing a phosphorus balance in a river basin and evaluating different scenarios for pollution reduction. The method is based on the balance principle: inputs and outputs of each phosphorus-related subsystems were balanced. The application of the methodology strategies was illustrated by means of a case study of the Krka River, Slovenia. The results showed that besides effluents from wastewater treatment plants, agriculture contributed significantly to the total annual phosphorus load. After establishing the present levels of phosphorus balance, different scenarios were considered: different stages of wastewater treatment as well as management of agricultural activities. The present emission of phosphorus is estimated to be 81.8 tons/year; after implementation of measures, it would be 48.6 tons/year, a total reduction of 40%. Besides reduction of point sources by means of wastewater collection and implementation of nutrient removal technology, managing agricultural phosphorus to protect water quality should become a major challenge in the Krka river basin.     

Phytoaccumulation of heavy metals by aquatic plants

Three aquatic plants were examined for their ability to remove heavy metals from contaminated water: parrot feather (Myriophylhum aquaticum), creeping primrose (Ludwigina palustris), and water mint (Mentha aquatic). The plants were obtained from a Solar Aquatic System treating municipal wastewater. All the three plants were able to remove Fe, Zn, Cu, and Hg from the contaminated water. The average removal efficiency for the three plant species was 99.8%, 76.7%, 41.62%, and 33.9% of Hg, Fe, Cu, and Zn, respectively. The removal rates of zinc and copper were constant (0.48 mg/l/day for Zn and 0.11 mg/l/day for Cu), whereas those of iron and mercury were dependent on the concentration of these elements in the contaminated water and ranged from 7.00 to 0.41 mg/l/day for Fe and 0.0787 to 0.0002 mg/l/day for Hg. Parrot feather showed greater tolerance to toxicity followed by water mint and creeping primrose. The growth of creeping primrose was significantly affected by heavy metal toxicity. The selectivity of heavy metals for the three plant species was the same (Hg>Fe>Cu>Zn). The mass balance preformed on the system showed that about 60.45-82.61% of the zinc and 38.96-60.75% of the copper were removed by precipitation as zinc phosphate and copper phosphate, respectively.     

Assessing and selecting interventions for river water quality improvement within the context of population growth and urbanization: a case study of the Cau River basin in Vietnam

In this study, a multi-criteria methodology is proposed to identify and prioritize interventions for water quality improvement with the aid of computer simulation models. The methodology can be used to elaborate and compare future socio-economic development scenarios to select the best interventions based on three criteria: (1) ideas of experts and stakeholders about the importance of scenarios, (2) impacts of each scenario on surface water quality in watershed, and (3) benefit–cost analysis for each scenario. A score is computed for each scenario based on a weighted sum technique which enables to take into consideration different level of importance for the three criteria. The methodology is applied to Cau River basin in Vietnam, with the aid of a computer tool, to assess interventions for river water quality improvement within the context of population growth and urbanization. The results show that fast future population growth in upstream has significant impacts. In 2020, an increase of 116 % of the population in Bac Kan town can lead to an increase of 120 and 135 % in BOD₅ and NH₄ ⁺ median concentrations, respectively, with the implementation of a treatment plant for 10,000 people in Bac Kan town. Therefore, the increase of the domestic wastewater treatment plant’s capacity in Bac Kan town, at least twice as the projection of local government, is necessary. These results will help decision makers to select the best interventions for Cau River basin management.     

Phytoremediation of aquaculture wastewater for water recycling and production of fish feed

Five plants were examined for their ability to remove nutrients from aquaculture wastewater and suitability as fish feed: alfalfa, white clover, oat, fall rye, barley. The seeds were first germinated in water in a hydroponic system, and the plants were fed wastewater from Tilapia production facility. Clover and alfalfa seeds were infected with fungus shortly after germination, and their roots were completely destroyed by day 14. Oat, rye and barley had the fastest growth and showed greater tolerance to fungal disease compared with alfalfa and clover. Although substantial amounts of soluble and insoluble substances were released by the seeds during the germination period, the plants were able to remove all the pollutants in wastewater and significant portions of those released substances. The total reductions in total solids, COD, NO3-N, NO2-N, phosphate and potassium ranged from 54.7% to 91.0%, 56.0% to 91.5%, 82.9% to 98.1%, 95.9% to 99.5%, 54.5% to 93.6% and 99.6% to 99.8%, respectively. Oat, barley and rye grow well in this type of hydroponic system and can be used as a fish feed after being supplemented with fat, Ca, Na, Mn and Fe. Oil seeds and the chlorides of these elements could be added to these plants when formulating the fish feed. For a continuous operation, a two-unit system could be configured to allow for one week germination and one week cleaning and startup in one unit while the other unit is in operation.     

Cleaning the river Damodar (India): impact of COVID-19 lockdown on water quality and future rejuvenation strategies

Globally, it is established that the partial lockdown system assists to improve the health of the total environment due to inadequate anthropogenic actions in different economic sectors. The ample research on fitness of environment has been proved that the strict imposition of lockdown was the blessings of environment. The river Damodar has historical significance and lifeline for huge population of Jharkhand and West Bengal state of India but in the recent years the water quality has been deteriorated due to untreated industrial effluents and urban sewage. The main objective of this study is to examine the water quality of river Damodar during and prelockdown phase for domestic use and restoration of river ecosystem. A total of eleven (11) effluent discharge sites were selected in prelockdown and during lockdown phase. A new approach of water quality assessment, i.e., water pollution index (WPI) has been applied in this study. WPI is weightage free, unbiased method to analysis of water quality. The result shows that the physical, chemical and heavy elements were found beyond the standard limit in prelockdown period. The cation and anion were arranged in an order of Na²⁺ ?>?K⁺ ?>?Ca²⁺ ?>?Mg²⁺ and Cl^??>?So₄^??>?No₃^??>?F^? in both the sessions. WPI of prelockdown showed that about 100% water samples are of highly polluted. WPI of lockdown period showed that around 90.90% samples improved to ‘good quality’ and 9.10% of samples are of ‘moderately polluted.’ Hypothesis testing by ‘t’ test proved that there was a significant difference (ρ?=?0.05%) in values of each parameter between two periods. Null hypothesis was rejected and indicated the improvement of river water quality statistically. Spatial mapping using Arc GIS 10.4 interpolation (IDW) helps to understand spatial intensity of pollution load in two periods. This research study should be helpful for further management and spatial diagnosis of water resource of river Damodar.

     

Dairy wastewater treatment using water treatment sludge as coagulant: a novel treatment approach

The dairy industry is among the most polluting industries as it produces large volume of wastewater that may adversely affect the environment if discharged untreated. Dairy wastewater is characterized by high COD, BOD and nutrient levels. In this study, water treatment sludge was used as a coagulant for the treatment of synthetic dairy wastewater in the pH range of 4–10. Turbidity, COD, BOD, TSS and TDS removals from the synthetic dairy wastewater were found to be around 93, 65, 67, 84 and 85%, respectively, at the optimum conditions. Water treatment sludge was found to perform even better than other conventional coagulants used for the same. Results showed that it has the potential to substitute the conventional coagulants partially or fully in the primary treatment of dairy wastewater. The utilization of water treatment sludge at dairy wastewater treatment plants would provide sustainable sludge management and cost-effective dairy wastewater treatment.     

Collection characteristics of a double stage scrubber to eliminate the paint mist from a spray booth

A 4.5 m³/min laboratory paint spray booth was built adopting a double-stage scrubber with heavy oil as the scrubbing liquid. The relationship between the collection efficiency E and the pressure drop ΔP was studied using a cylindrical paper tilter and a Digital Dust Counter. Experimental results indicated that the collection efficiency in this system is in accordance with the collection efficiency equation based on the theory of inertial impaction. With water used as the scrubbing liquid, the factor K is about 0.5 for single-stage scrubbing, while it is 0.6 for double-stage scrubbing. At a pressure drop of 60 mm of H₂O, heavy oil used as the scrubbing liquid gained about 2.0% more in collection efficiency than water. The zigzag baffler equipped for removing heavy oil mist was also effective for the paint mist collector, and 99.1% of E was gained at a pressure drop of 135 mm H₂O.