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1.
A field measurement campaign was conducted near a major road in southern Finland from September 15 to October 30, 1995. The concentrations of NO, NO2 and O3 were measured simultaneously at three locations, at three heights (3.5, 6 and 10 m) on both sides of the road. Traffic densities and relevant meteorological parameters were also measured on-site. We have compared measured concentration data with the predictions of the road network dispersion model CAR-FMI, used in combination with a meteorological pre-processing model MPP-FMI. In comparison with corresponding results presented previously in the literature, the agreement of measured and predicted datasets was good, as measured using various statistical parameters. For all data (N=587), the index of agreement (IA) was 0.83, 0.82 and 0.89 for the measurements of NOx, NO2 and O3, respectively. The IA is a statistical measure of the correlation of the predicted and measured time series of concentrations. However, the modelling system overpredicts NOx concentrations with a fractional bias FB=+13%, and O3 concentrations with FB=+8%, while for NO2 concentrations FB=−2%. We also analyzed the difference between model predictions and measured data in terms of meteorological parameters. Model performance clearly deteriorated as the wind direction approached a direction parallel to the road, and for the lowest wind speeds. The range of variability concerning atmospheric stability, ambient temperature and the amount of solar radiation was modest during the measurement campaign. As expected, no clear dependencies of model performance were therefore detected in terms of these parameters. The experimental dataset is available for the evaluation of other roadside dispersion models.  相似文献   

2.
In 1997, a measuring campaign was conducted in a street canyon (Runeberg St.) in Helsinki. Hourly mean concentrations of CO, NOx, NO2 and O3 were measured at street and roof levels, the latter in order to determine the urban background concentrations. The relevant hourly meteorological parameters were measured at roof level; these included wind speed and direction, temperature and solar radiation. Hourly street level measurements and on-site electronic traffic counts were conducted throughout the whole of 1997; roof level measurements were conducted for approximately two months, from 3 March to 30 April in 1997. CO and NOx emissions from traffic were computed using measured hourly traffic volumes and evaluated emission factors. The Operational Street Pollution Model (OSPM) was used to calculate the street concentrations and the results were compared with the measurements. The overall agreement between measured and predicted concentrations was good for CO and NOx (fractional bias were −4.2 and +4.5%, respectively), but the model overpredicted the measured NO2 concentrations (fractional bias was +22%). The agreement between the measured and predicted values was also analysed in terms of its dependence on wind speed and direction; the latter analysis was performed separately for two categories of wind velocity. The model qualitatively reproduces the observed behaviour very well. The database, which contains all measured and predicted data, is available for further testing of other street canyon dispersion models. The dataset contains a larger proportion of low wind speed cases, compared with other available street canyon measurement datasets.  相似文献   

3.
The dispersion model, ADMS-Urban, alongside the statistical modelling technique, generalized additive modelling, have been used to predict hourly NOx and nitrogen dioxide (NO2) concentrations at a busy street canyon location and the results compared with measurements. Generalized additive models (GAMs) were constructed for NO2 and NOx concentrations using input data required to run ADMS-Urban. Bivariate polar plots have been produced from the wind flow (speed and direction) and pollution data (measured and predicted concentrations) to provide further information regarding the complex wind-pollutant interactions in an urban street canyon. The predictions made with the GAMs show excellent agreement with measured concentrations at this location, reproducing both the magnitude of NOx and NO2 concentrations and also the wind speed-wind direction dependence of pollutant sources within the canyon. However, the predictions made with ADMS-Urban under-estimated the measured NOx by 11% and NO2 by 21% and there are clear differences in the bivariate polar plots. Several sensitivity tests were carried out with ADMS-Urban in an attempt to produce predictions in closer agreement to those measured at Gillygate. Increasing the primary NO2 fraction in ADMS-Urban (from 10% to 20%) had a considerable effect on the predictions made with this model, increasing NO2 predictions by ∼20%. However, the bivariate plots still showed major differences to those of the measurements. This work illustrates that generalized additive modelling is a useful tool for investigating complex wind-pollutant interactions within a street canyon.  相似文献   

4.
We have developed a modelling system for predicting the traffic volumes, emissions from stationary and vehicular sources, and atmospheric dispersion of pollution in an urban area. This paper describes a comparison of the NOx and NO2 concentrations predicted using this modelling system with the results of an urban air quality monitoring network. We performed a statistical analysis to determine the agreement between predicted and measured hourly time series of concentrations at four permanently located and three mobile monitoring stations in the Helsinki Metropolitan Area in 1996–1997 (at a total of ten urban and suburban measurement locations). At the stations considered, the so-called index of agreement values of the predicted and measured time series of the NO2 concentrations vary between 0.65 and 0.82, while the fractional bias values range from −0.29 to +0.26. In comparison with corresponding results presented in the literature, the agreement between the measured and predicted datasets is good, as indicated by these statistical parameters. The seasonal variations of the NO2 concentrations were analysed in terms of the relevant meteorological parameters. We also analysed the difference between model predictions and measured data diagnostically, in terms of meteorological parameters, including wind speed and direction (the latter separately for two wind speed classes), atmospheric stability and ambient temperature, at two monitoring stations in central Helsinki. The modelling system tends to overpredict the measured NO2 concentrations both at the highest (u⩾6 m s−1) and at the lowest wind speeds (u<2 m s−1). For higher wind speeds, the modelling system overpredicts the measured NO2 concentrations in certain wind direction intervals; specific ranges were found for both monitoring stations considered. The modelling system tends to underpredict the measured concentrations in convective atmospheric conditions, and overpredict in stable conditions. The possible physico-chemical reasons for these differences are discussed.  相似文献   

5.
The pollutant dispersion behavior from the vehicular exhaust plume has a direct impact on human health, particularly to the drivers, bicyclists, motorcyclists, pedestrians, people working nearby and vehicle passengers. A two-dimensional pollutant dispersion numerical model was developed based on the joint-scalar probability density function (PDF) approach coupled with a kε turbulence model to simulate the initial dispersion process of nitrogen oxides, temperature and flow velocity distributions from a vehicular exhaust plume. A Monte Carlo algorithm was used to solve the PDF transport equations in order to obtain the dispersion distribution of nitrogen oxides concentration. The model was then validated by a series of sensitivity experimental studies in order to assess the effects of vehicular exhaust tailpipe velocities, wind speeds and chemistry on the initial dispersion of NO and NO2 mass concentrations from the vehicular exhaust plume. The results show that the mass concentrations of nitrogen oxides decrease along the centerline of the vehicular exhaust plume in the downstream distance. The dispersion process can be enhanced when the vehicular exhaust tailpipe velocity is much larger than the wind speed. The oxidation reaction of NO plays an important role when the wind speed is large and the vehicular exhaust exit velocity is small, which leads to chemical reduction of NO, and the formation and accumulation of NO2 in the exhaust plume. It is also found that the effect of vehicular exhaust-induced turbulence in the vicinity of the exhaust tailpipe exit is more dominant than the effect of wind turbulence, while the wind turbulence gradually shows a significant role for the dispersion of nitrogen oxides along with the development of exhaust plume. The range of dispersion of nitrogen oxides in the radial direction is increased along with the development of vehicular exhaust plume.  相似文献   

6.
Possible effects of climate change on air quality are studied for two urban sites in the UK, London and Glasgow. Hourly meteorological data were obtained from climate simulations for two periods representing the current climate and a plausible late 21st century climate. Of the meteorological quantities relevant to air quality, significant changes were found in temperature, specific humidity, wind speed, wind direction, cloud cover, solar radiation, surface sensible heat flux and precipitation. Using these data, dispersion estimates were made for a variety of single sources and some significant changes in environmental impact were found in the future climate. In addition, estimates for future background concentrations of NOx, NO2, ozone and PM10 upwind of London and Glasgow were made using the meteorological data in a statistical model. These showed falls in NOx and increases in ozone for London, while a fall in NO2 was the largest percentage change for Glasgow. Other changes were small. With these background estimates, annual-average concentrations of NOx, NO2, ozone and PM10 were estimated within the two urban areas. For London, results averaged over a number of sites showed a fall in NOx and a rise in ozone, but only small changes in NO2 and PM10. For Glasgow, the changes in all four chemical species were small. Large-scale background ozone values from a global chemical transport model are also presented. These show a decrease in background ozone due to climate change. To assess the net impact of both large scale and local processes will require models which treat all relevant scales.  相似文献   

7.
The emission factors of NOx, VOC and CO of a road tunnel study performed in September 1993 in the Gubrist tunnel, close to Zürich (Switzerland) are compared with results of emission calculations based on recent results of dynamometric test measurements. The emission calculations are carried out with a traffic emission model taking into account the detailed composition of the vehicle fleet in the tunnel, the average speed and the gradient of the road and the special aerodynamics in a tunnel. With the exception of NOx emission factors for heavy duty vehicles no evidence for a discrepancy between the results of the tunnel study and the emission modeling was found. The measured emission factors of individual hydrocarbons of light duty vehicles were in good agreement with the expectations for most components.  相似文献   

8.
Under the 11th Five Year Plan (FYP, 2006–2010) for national environmental protection by the Chinese government, the overarching goal for sulfur dioxide (SO2) controls is to achieve a total national emissions level of SO2 in 2010 10% lower than the level in 2005. A similar nitrogen oxides (NOx) emissions control plan is currently under development and could be enforced during the 12th FYP (2011–2015). In this study, the U.S. Environmental Protection Agency (U.S.EPA)’s Community Multi-Scale Air Quality (Models-3/CMAQ) modeling system was applied to assess the air quality improvement that would result from the targeted SO2 and NOx emission controls in China. Four emission scenarios — the base year 2005, the 2010 Business-As-Usual (BAU) scenario, the 2010 SO2 control scenario, and the 2010 NOx control scenario—were constructed and simulated to assess the air quality change from the national control plan. The Fifth-Generation NCAR/Penn State Mesoscale Model (MM5) was applied to generate the meteorological fields for the CMAQ simulations. In this Part I paper, the model performance for the simulated meteorology was evaluated against observations for the base case in terms of temperature, wind speed, wind direction, and precipitation. It is shown that MM5 model gives an overall good performance for these meteorological variables. The generated meteorological fields are acceptable for using in the CMAQ modeling.  相似文献   

9.
We used a dispersion model to analyze measurements made during a field study conducted by the U.S. EPA in July–August 2006, to estimate the impact of traffic emissions on air quality at distances of tens of meters from an eight-lane highway located in Raleigh, NC. The air quality measurements consisted of long path optical measurements of NO at distances of 7 and 17 m from the edge of the highway. Sonic anemometers were used to measure wind speed and turbulent velocities at 6 and 20 m from the highway. Traffic flow rates were monitored using traffic surveillance cameras. The dispersion model [Venkatram, A., 2004. On estimating emissions through horizontal fluxes. Atmospheric Environment 38, 2439–2446] explained over 60% of the variance of the observed path averaged NO concentrations, and over 90% of the observed concentrations were within a factor of two of the model estimates.Sensitivity tests conducted with the model indicated that the traffic flow rate made the largest contribution to the variance of the observed NO concentrations. The meteorological variable that had the largest impact on the near road NO concentrations was the standard deviation of the vertical velocity fluctuations, σw. Wind speed had a relatively minor effect on concentrations. Furthermore, as long as the wind direction was within ±45° from the normal to the road, wind direction had little impact on near road concentrations. The measurements did not allow us to draw conclusions on the impact of traffic-induced turbulence on dispersion. The analysis of air quality and meteorological observations resulted in plausible estimates of on-road emission factors for NO.  相似文献   

10.
The threshold values of indicator species and ratios delineating the transition between NOx and VOC sensitivity of ozone formation are assumed to be universal by various investigators. However, our previous studies suggested that threshold values might vary according to the locations and conditions. In this study, threshold values derived from various model simulations at two different locations (the area of Switzerland by UAM Model and San Joaquin Valley of Central California by SAQM Model) are examined using a new approach for defining NOx and VOC sensitive regimes. Possible definitions for the distinction of NOx and VOC sensitive ozone production regimes are given. The dependence of the threshold values for indicators and indicator ratios such as NOy, O3/NOz, HCHO/NOy, and H2O2/HNO3 on the definition of NOx and VOC sensitivity is discussed. Then the variations of threshold values under low emission conditions and in two different days are examined in both areas to check whether the models respond consistently to changes in environmental conditions. In both cases, threshold values are shifted similarly when emissions are reduced. Changes in the wind fields and aging of the photochemical oxidants seem to cause the day-to-day variation of the threshold values. O3/NOz and HCHO/NOy indicators are predicted to be unsatisfactory to separate the NOx and VOC sensitive regimes. Although NOy and H2O2/HNO3 provide a good separation of the two regimes, threshold values are affected by changes in the environmental conditions studied in this work.  相似文献   

11.
We analyse the air quality data measured at a green area of Buenos Aires City (Argentina) during 38 days in winter. We study the relationships between ambient concentrations of nitric oxide (NO), nitrogen dioxide (NO2), ozone (O3) and nitrogen oxides (NOx=NO+NO2). The variation of the level of oxidant (OX=O3+NO2) with the NOx is obtained. It can be seen that the level of OX at a given location is made up of two contributions: one independent and another dependent on the NOx concentration. The first one can be considered as a regional contribution, equivalent to the background O3 concentration and the second one as a local contribution that depends on the level of primary pollution. Local oxidant sources may include direct NO2 emissions, the reaction of NO with O2 at high-NOx levels, and the emission of species that promote the conversion of NO to NO2. The final category of emissions may include the nitrous acid (HONO) that is emitted directly in vehicle exhaust. Finally, we present a diurnal variation of the local as well as regional contributions and the dependence of the last one on wind direction.  相似文献   

12.
Weekly and seasonal variations of surface ozone and their precursors – nitrogen oxides, carbon monoxide-associated with meteorological parameters (wind direction, temperature, solar radiation) – are reported. Measurements were performed continuously during 2006 at two sampling stations located in the metropolitan area of Porto Alegre, Brazil. Results have shown that O3 concentrations remained almost constant between weekdays. Levels of NOx precursors decreased especially on Sundays, due to lighter traffic. The seasonal variation has shown a maximum O3 concentration during summer and spring while NOx and NO2 have maxima at the colder months. The daily cycle of highest ozone concentrations reveals a lower nightly level and an inverse relation between O3 and NOx, evidencing the photochemical formation of O3. There are seasonal variation and source heterogeneity.  相似文献   

13.
Several studies have investigated the health of children attending schools located near busy roads. In this study, we have measured personal exposure to traffic-related pollutants in children to validate exposure classification based on school location. Personal exposure to PM2.5, soot, NOx and NO2 was measured during four 48-h periods. The study involved 54 children attending four different schools, two of which were located within 100 m of a major road (one ring road and one freeway) and the other two were located at a background location in the city of Utrecht, The Netherlands. Outdoor monitoring was conducted at all school sites, during the personal measurements. A questionnaire was administered on time activity patterns and indoor sources at home. The outdoor concentration of soot was 74% higher at the freeway school compared to its matched background school. Personal exposure to soot was 30% higher. For NOx the outdoor concentration was 52% higher at the freeway school compared to its background school. The personal concentration of NOx was 37% higher for children attending the freeway school. Differences were smaller and insignificant for PM2.5 and NO2. No elevated personal exposure to air pollutants was found for the children attending the school near the ring road. We conclude that the school's proximity to a freeway can be used as a valid estimate of exposure in epidemiological studies on the effects of the traffic-related air pollutants soot and NOx in children.  相似文献   

14.
Abstract

An atmospheric dispersion model was developed for the environmental impact assessment of thermal power plants in Japan, and a method for evaluating topographical effects using this model was proposed. The atmospheric dispersion model consists of an airflow model with a turbulence closure model based on the algebraic Reynolds stress model and a Lagrangian particle dispersion model (LPDM). The evaluation of the maximum concentration of air pollutants such as SO2, NOx, and suspended particulate matter is usually considered of primary importance for environmental impact assessment. Three indices were therefore estimated by the atmospheric dispersion model: the ratios (α and β, respectively) of the maximum concentration and the distance of the point of the maximum concentration from the source over topography to the respective values over a flat plane, and the relative concentration distribution [γ(x)] along the ground surface projection of the plume axis normalized by the maximum concentration over a flat plane. The atmospheric dispersion model was applied to the topography around a power plant with a maximum elevation of more than 1000 m. The values of α and β evaluated by the atmospheric dispersion model varied between 1 and 3 and between 1 and 0.4, respectively, depending on the topographical features. These results and the calculated distributions of γ(x) were highly similar to the results of the wind tunnel experiment. Therefore, when the slope of a hill or mountain is similar to the topography considered in this study, it is possible to evaluate topographical effects on exhaust gas dispersion with reasonable accuracy using the atmospheric dispersion model as well as wind tunnel experiments.  相似文献   

15.
The CALINE4 roadway dispersion model has been applied to concentrations of NOx and NO2 measured near Gandy Boulevard in Tampa, FL (USA) during May 2002. A NOx emission factor of 0.86 gr mi−1 was estimated by treating NO+NO2 (NOx) as a conserved species and minimizing the differences between measured and calculated NOx concentrations. This emission factor was then used to calculate NO2 concentrations using the NO/NO2 transformation reactions built into CALINE4. A comparison of measured and calculated NO2 concentrations indicates that for ambient O3 concentrations less than 40 ppb the model under-predicts the chemical transformation of NO. The enhanced transformation of NO may be due to reactions of NO with oxidants such as peroxy radicals that are present either in the atmosphere or in vehicle exhaust.  相似文献   

16.
An analysis of air quality data from 1970-1975 in the Los Angeles (LA) Basin has been made with emphasis on factors relevant to high hourly NO2 concentrations, (NO2). Detailed analysis of CO and SO2 air quality and the (NO x )/(CO) and (CO)/(SO2) ratios reveals that high (NO2) result mainly from vehicular sources; contributions from stationary sources to these high (NO2) of greater than 10% occur rarely. Meteorological conditions (very low early-morning inversion base height and low wind speed) favoring the formation of high (NO2) restrict the impact of elevated point NO x sources on the ground level (NO2) during the early to mid-morning hours. The overnight leftover NO x during high NO2 days is shown to originate largely from local sources near the monitoring sites. A regression analysis using NO2, NO x and HC data from downtown LA shows that a 50% reduction in (NO x ) reduces high (NO2) by 40-45%; a 50% reduction in (HC) reduces high (NO2) by 5-10%. The present analysis supports assumptions used in an earlier generalized rollback model that related NO x emissions to high 1-h average (NO2) observed at downtown LA.  相似文献   

17.
Research over the past ten years has created a more detailed and coherent view of the relation between O3 and its major anthropogenic precursors, volatile organic compounds (VOC) and oxides of nitrogen (NOx). This article presents a review of insights derived from photochemical models and field measurements. The ozone–precursor relationship can be understood in terms of a fundamental split into a NOx-senstive and VOC-sensitive (or NOx-saturated) chemical regimes. These regimes are associated with the chemistry of odd hydrogen radicals and appear in different forms in studies of urbanized regions, power plant plumes and the remote troposphere. Factors that affect the split into NOx-sensitive and VOC-sensitive chemistry include: VOC/NOx ratios, VOC reactivity, biogenic hydrocarbons, photochemical aging, and rates of meteorological dispersion. Analyses of ozone–NOx–VOC sensitivity from 3D photochemical models show a consistent pattern, but predictions for the impact of reduced NOx and VOC in indivdual locations are often very uncertain. This uncertainty can be identified by comparing predictions from different model scenarios that reflect uncertainties in meteorology, anthropogenic and biogenic emissions. Several observation-based approaches have been proposed that seek to evaluate ozone–NOx–VOC sensitivity directly from ambient measurements (including ambient VOC, reactive nitrogen, and peroxides). Observation-based approaches have also been used to evaluate emission rates, ozone production efficiency, and removal rates of chemically active species. Use of these methods in combination with models can significantly reduce the uncertainty associated with model predictions.  相似文献   

18.
We have developed a model for evaluating the mass-based concentrations of urban particulate matter. The basic model assumption is that local vehicular traffic is responsible for a substantial fraction of the street-level concentrations of both PM10 and NOx, either due to primary emissions or resuspension from street surfaces. The modelling system utilises the data from an air quality monitoring network in the Helsinki Metropolitan Area. We have determined linear relationships between the measured urban PM10 data against those of NOx in various urban surroundings, based on continuously measured hourly concentration values. The data was obtained from two stations in central Helsinki and one suburban station in the Helsinki Metropolitan Area during a period of 3 yr, from 1996 to 1998. The model also includes a treatment of the regional background concentrations, and resuspended particulate matter. The model performance was evaluated against the measured PM10 data from the above-mentioned three stations and from two other stations, using data that was measured in 1999. We used two alternative model versions, one based on separate correlation parameters (PM10 vs. NOx) for each station, and another based on parameters averaged over the stations considered. We analysed the agreement between the measured and predicted hourly concentration time series, utilising the values of the fractional bias (FB) and the so-called index of agreement (IA). As expected, the model predicts relatively well the yearly mean concentrations of PM10: the FB values range from −0.05 to +0.09. Model performance is also relatively good when predicting the yearly mean values that are classified separately for each hour of the day: the corresponding IA values range from 0.85 to 0.96. However, model performance is substantially worse in predicting the hourly time series of the year: the IA values using the station-specific parameters range from 0.46 to 0.65. The model was applied in evaluating the yearly average spatial concentration distribution of PM10 in central Helsinki, based on the corresponding modelled NOx concentrations. With re-evaluation of a few parameters that can be determined empirically, the model could be evaluated, and most probably applied, in other urban areas as well.  相似文献   

19.
The “Stockholm Trial” involved a road pricing system to improve the air quality and reduce traffic congestion. The test period of the trial was January 3–July 31, 2006. Vehicles travelling into and out of the charge cordon were charged for every passage during weekdays. The amount due varied during the day and was highest during rush hours (20 SEK = 2.2 EUR, maximum 60 SEK per day). Based on measured and modelled changes in road traffic it was estimated that this system resulted in a 15% reduction in total road use within the charged cordon. Total traffic emissions in this area of NOx and PM10 fell by 8.5% and 13%, respectively. Air quality dispersion modelling was applied to assess the effect of the emission reductions on ambient concentrations and population exposure. For the situations with and without the trial, meteorological conditions and other emissions than from road traffic were kept the same. The calculations show that, with a permanent congestion tax system like the Stockholm Trial, the annual average NOx concentrations would be lower by up to 12% along the most densely trafficked streets. PM10 concentrations would be up to 7% lower. The limit values for both PM10 and NO2 would still be exceeded along the most densely trafficked streets. The total population exposure of NOx in Greater Stockholm (35 × 35 km with 1.44 million people) is estimated to decrease with a rather modest 0.23 μg m?3. However, based on a long-term epidemiological study, that found an increased mortality risk of 8% per 10 μg m?3 NOx, it is estimated that 27 premature deaths would be avoided every year. According to life-table analysis this would correspond to 206 years of life gained over 10 years per 100 000 people following the trial if the effects on exposures would persist. The effect on mortality is attributed to road traffic emissions (likely vehicle exhaust particles); NOx is merely regarded as an indicator of traffic exposure. This is only the tip of the ice-berg since reductions are expected in both respiratory and cardiovascular morbidity. This study demonstrates the importance of not only assessing the effects on air quality limit values, but also to make quantitative estimates of health impacts, in order to justify actions to reduce air pollution.  相似文献   

20.
选择石家庄市区代表性路段作为研究对象,对其交通环境空气中NOx的污染水平进行现状监测。基于Matlab软件建立拟合模型,对下一时期的NOx污染趋势进行预测。结果表明,石家庄市交通环境中NOx小时浓度介于0.047~0.237 mg/m3之间,呈早晚高,且下午明显低于上午的日变化规律;NOx日均浓度介于0.076~0.211 mg/m3之间,其浓度与车流量呈明显的正相关性。利用matlab软件建立的ARMA模型能够较好地预测道路交通环境空气中NOx的浓度变化趋势。  相似文献   

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