Trace metals in the western Mediterranean Sea∗

Data on Cd, Pb and Cu concentrations in seawater referring to five years of field studies on the western Mediterranean Sea are reported in order to present a space and time integrated situation on the levels of these metals. Surface total metal concentrations present rather homogeneous distributions between the different areas considered, including the Tyrrhenian Sea. The metal concentrations in three areas affected by natural and industrial wastes are also discussed. The vertical distribution of the dissolved Cd, Pb and Cu in the Alboran Sea seems to be rather homogeneous, both vertically and among the stations chosen between the Strait of Gibraltar and the Island of Alboran.     

Accumulation, contamination, and seasonal variability of trace metals in the coastal zone – patterns in a seagrass meadow from the Mediterranean

Amongst a plethora of threats to seagrass ecosystems, contamination with heavy metals may well be one of the most significant. We therefore set out to track contamination levels with Cu, Zn, Pb and Cd in the principal autotrophic compartments and sediments of a meadow of Posidonia oceanica in the Gulf of Naples, Mediterranean Sea. With respect to metal levels, leaves and their associated epibiota are certainly not a homogenous compartment, as might perhaps be inferred from the common use of the term “leaf–epiphyte complex” in the literature. Save for Cu, all metal species analysed showed appreciable differences in concentration between seagrass leaves and epibiota. These results give strength to our argument that in ecotoxicological work leaves and epibiota should not be treated as a single unit. Although absolute differences in trace-metal levels among sampling periods varied somewhat with the specific component analysed (i.e. macrophyte organs, epibiota, sediment), an overall trend of markedly higher heavy-metal levels during the winter season is a striking one. Whilst annual cycles in growth dynamics of the seagrasses explain a significant fraction of the temporal variance, seasonality in productivity is a doubtful explanation for similar patterns in non-living sedimentary components; consideration of additional variables therefore seems sensible. As variables with consistent explanatory powers we suggest: (1) seasonal cycles in storm frequency and amplitude which remobilise metals bound in the sediments of the sea floor, and (2) increased precipitation during the cold season which may significantly increase marine metal levels through elevated weathering of rocks and elevated fluvial inputs of anthropogenic contaminant loads. Whereas Cd and Pb concentrations in seagrass leaves from the Gulf of Naples fall within the range for coastal areas subjected to low levels of heavy-metal pollution, Cu and Zn reach levels typical of highly contaminated regions, such as the waters bordering major coastal cities. Any direct comparisons of the pollution status of seagrass beds between different geographic areas are, however, likely to be confounded by the indiscriminate application of the “leaf–epiphyte complex”: the magnitude of the confounding effect depends on the ratio of epibiota/leave biomass, time of sampling, and metal species analysed. Received: 15 May 1997 / Accepted: 2 February 1998     

Trace elements in commercial marine organisms from the Russian part of the Northwest Pacific (2010–2018)

Environmental Chemistry Letters - We report levels of trace elements in commercially harvested species from the Far Eastern seas of Russia from 2010 to 2018. The best studied organisms in this...     

The prevalence of heavy metals in Cladophora glomerata L. from Farahabad Region of Caspian Sea – Iran

The presence of toxic heavy metals in the environment is considered as a risk factor for adverse human and environmental health effects. Farahabad Region is a tourist center in the southern coast of Caspian Sea in Mazandaran Province of Iran. Environmental monitoring of this site is important for public health for individuals visiting and residing in this region. Although numerous biomonitoring data are available globally, very few if any apparent investigations have been conducted in this region. In this study, concentration of three heavy metals chromium (Cr), lead (Pb), and cadmium (Cd) was determined for one year in Cladophora glomerata, the predominant macroalga species present in this region. Detection of heavy metals was performed with atomic absorption spectrophotometer using standard methods. Results showed that the range of Cr metal in various algal samples was 29–55 ppm/g dry weight. The levels of Pb in algal samples (Cladophora) ranged from 2 to 8 ppm/g dry weight. The Cd concentrations in C. glomerata biomass ranged from 1.5 to 8.2 ppm/g dry biomass. In view of potential threats of such high metal concentrations in coastal waters and in algal tissues, it is necessary to adopt conservation measures to ensure public health safety.     

Accumulation trends of metals and a metalloid in the freshwater crayfish Astacus leptodactylus from Lake Yeniçağa (Turkey)

This study aims to determine the extent of metal pollution in Lake Yeniça?a (Bolu, Turkey) by investigating the accumulation trends of five metals (Al, Cu, Fe, Ni and Zn) and a metalloid (As) in gills, exoskeleton, hepatopancreas and abdominal muscles of the freshwater crayfish Astacus leptodactylus. Principal component analysis (PCA), cluster analysis (CA), correlation analysis and analysis of variance (ANOVA) were utilised to determine the accumulation profiles of each element over four seasons. The greatest element accumulation was found to occur in the gills. All elements in exoskeletal tissue displayed positive correlations with each other, a similar trend was also observed in the hepatopancreas samples. Strong (r=0.868) and very strong (r=0.960) positive correlations were found between the accumulations of Al and Fe in gills and the exoskeleton, respectively. Correlations in tissue accumulation rates are discussed in the context of metabolic roles and impacts associated with the elements tested. Elemental compositions of Yeniça?a water and sediment samples were also investigated to determine whether the composition of the surrounding environment matches the metal accumulation trends of tissue samples. We demonstrate that, by the criteria set by the United States Environmental Protection Agency, Lake Yeniça?a is heavily polluted in terms of As and Ni.     

Trace elements in fish and oysters from Sepetiba Bay (Rio de Janeiro – Brazil) determined by total reflection X-ray fluorescence using synchrotron radiation

Trace elements were determined in fish and oysters from Sepetiba Bay, Brazil, by total reflection Xray fluorescence using synchrotron radiation (SRTXRF). Cr, Mn, Fe, Ni, Cu, Zn and Se were determined in fish muscles and organs and in oyster soft tissue. SRTXRF was shown to be a good tool for the analysis of trace elements from biological tissue samples. Overall, the levels of the analysed metals were higher in oysters than in the fish samples. Metals were not uniformly distributed throughout the body of the analysed fish. The detected concentrations of Cr, Zn and Se were very high in some samples, surpassing the maximum limits established by Brazilian legislation.     

Vulnerability associated with “symptoms similar to those of mercury poisoning” in communities from Xingu River,Amazon basin

The Brazilian Amazon is known to be a region with high levels of mercury (Hg) in the environment and studies point to an association between high levels of natural mercury in the mother rock and the vast number of clandestine gold mines. Other studies already report the contamination of fish in this region, as well as high levels of Hg in biological material from environmentally exposed populations. On the other hand, this is one of the least developed regions of the planet and it is necessary to understand the vulnerability factors in these populations that may be intoxicated by this element. The purpose of the present study was to investigate the vulnerability factors in communities from Xingu River—Amazon basin probably exposed to Hg. A cross-selection study in two cities localized in Xingu River was conducted, and the sample contained was 268 individuals. sociodemographic questions, lifestyle, diet habits and health conditions were collated. The majority of the sample was female, between 30 and 59 years old, had less than 3 years of educational level and lived in the local of study more than 240 months. There was regular fish consumption (95.9%), principally carnivorous species (80.5%). The visual problem has a highest prevalence (43.3%) between the health problems and about the symptoms of Hg intoxication, memory loss (42.9%), weakness (35.1%), fatigue (34.3%), mood changes (28.7%) and difficulties in concentration (27.2%) was most reported. The female sex, age over 60, educational level below 3 years of study, did not had flush toilet, smoke and least one chronic non-communicable disease represent higher probability to had symptoms of Hg intoxication. Lack of access to health services, low education level and income evidence the susceptibility of this community to diseases and injuries. The vulnerable groups identified in this study should be a priority in public health and environmental health policies.     

Trace analysis. Determination of the “breakthrough volume”; (B.T.V.) of atmospheric isoprene

This paper presents the first results of a study of B.T.V. on Tenax TA, at various flow rates of sampling, with standard isoprene gaseous mixtures whose concentration ranging from 0.7 ppbV to 4 ppbV was very similar to the concentrations found in natural atmosphere. The method used is based on the exploitation of chromatographic signals obtained from a preconcentration—thermodesorption —analysis cycle carried out on a standard isoprene mixture. The B.T.V. of isoprene on Tenax TA does not show a significant change at very low concentrations of isoprene.     

Gametogenesis, spawning behavior, and early development in the “iceworm”Hesiocaeca methanicola (Polychaeta: Hesionidae) from methane hydrates in the Gulf of Mexico

Gametogenesis, spawning behavior, and early development have been described in the methane-seep polychaete Hesiocaecamethanicola Desbruyères and Toulmond, 1998, the first documentation of the reproductive biology of any cold-seep polychaete species. The worms were collected at the Green Canyon site in the Gulf of Mexico (27°44.77N; 91°13.33W) in August 1997. The gonads are situated in the neuropodia in association with an intraepithelial capillary system. Oogenesis is intraovarian, with oocytes remaining in the ovary until late vitellogenesis when they are released into the coelom for final growth and differentiation. Vitellogenesis involves both autosynthetic and heterosynthetic processes and, along with ovarian structure, suggests a relatively slow process of egg formation. Sperm differentiation is intertesticular until early spermiogenesis, when spermatid tetrads complete development in the coelom. The mature spermatozoon is an ect-aquasperm consisting of a tapering, digitate acrosome, a spherical nucleus, a midpiece containing from six to eight mitochondria and glycogen stores, and two centrioles associated with the flagellum. Both sexes undergo broadcast spawning, but the males spawn exclusively through the anus, a behavior previously unknown in polychaetes. Artificial fertilization resulted in spiral cleavage and development to the trochophore stage. Oocyte size-frequency analysis of adult females indicates a wide range of oocyte sizes and vitellogenic stages, suggesting that asynchronous gametogenesis occurs. Received: 13 July 2000 / Accepted: 29 November 2000     

“Anting” in Blue Jays: evidence in support of a food-preparatory function

Summary.  Anting, the plumage-dipping behavior to which ants (mostly formicines) are commonly subjected by birds (mostly passerines), is shown in tests with hand-raised Blue Jays (Cyanocitta cristata) and the ant Formica exsectoides to be instinctive: the birds displayed typical renditions of the behavior on the first occasion that they encountered ants. Evidence is presented supportive of the view that anting is a strategy by which birds render ants fit for ingestion. Formicine ants are ordinarily protected by their formic acid-containing spray. Being wiped into the bird’s plumage causes them to discharge that spray, without harm to the bird, to the point of almost total emptying of the glandular sac in which the secretion is stored. The ants are therefore essentially secretion-free by the time they are swallowed. Further evidence indicates that it is the ant’s possession of the acid sac that triggers the anting behavior in the bird. If F. exsectoides are surgically deprived of their acid sac, they are eaten by the birds without first being subjected to anting. Data are also presented indicating that the ant’s crop, which is especially capacious in formicines (its contents may amount to over 30% of the formicine’s mass), and which appears to survive the anting procedure intact, constitutes, at least when laden, a valuable component of the trophic package that the bird accesses by anting.     

Dioxin-/Furan-“Verbrennungsprofile” in Abgasen aus Hochtemperaturprozessen

Different mechanisms downstream from high temperature processes lead to the formation of polychlorinated dibenzo(p) dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs). Independent from any concentrations, these mechanisms cause comparable PCDD/F patterns, the percentage proportion of single congeners or homologous groups related to the total of 17 2,3,7,8-Cl-substituted congeners or with respect to the sum of the homologous groups tetra to octa CDD/F. The characteristics of these so-called “combustion profiles” can help to interpret corresponding data from burning and melting facilities, such as municipal waste incinerators, coal power plants, sintering plants, metal finishing facilities, cement kilns, crematoria, hazardous waste incinerators and landfill gas burners     

Analysis of insecticide “Toxaphene”; in fish products

The gaschromatographic determination of Toxaphene in the presence of other chlorinated hydrocarbons with similar retention times is often difficult. The practibility of a new method, based on photodehalogenation of the interfering substances, is shown during the analytical determination of Toxaphene residues in selected environmental samples, especially in fish and fish products. Irradiation of the extracts after clean‐up procedures with wavelengths at 254 nm lead directly to photodechlorination products of interfering substances with shorter retention times and makes it possible to determine the Toxaphene components quantitatively, which are mostly stable under the same experimental conditions.     

Chemical egg defense in Photuris firefly “femmes fatales”

Summary. Female Photuris fireflies contain defensive chemicals of two types. They sequester steroidal pyrones (lucibufagins) from male fireflies of the genus Photinus that they eat, and themselves produce the defensive betaine N-methylquinolinium 2-carboxylate. Chemical analyses of Photuris eggs showed that females that fed on Photinus males endow their eggs with both lucibufagin and the betaine, while those that did not feed on Photinus lay eggs that contain betaine, but virtually no lucibufagin. Photuris females collected in the field during the Photinus flight season laid eggs that invariably contained betaine, but lucibufagin only at times. Predation experiments showed that Photuris eggs are essentially unacceptable to larvae of a coccinellid beetle (Harmonia axyridis) and an ant (Leptothorax longispinosus), but moderately acceptable to an earwig (Forficula auricularia). When applied experimentally to palatable insect eggs, lucibufagin proved deterrent to these three predators, while the betaine proved deterrent to the ant and coccinellid larva only. Both types of defensive compound decreased egg predation in the field. By endowing their eggs with both exogenous and endogenous chemicals, Photuris females are essentially “maximizing their options”– when feeding on Photinus, their eggs are doubly protected, but they are not entirely defenseless when the females are unable to procure lucibufagin. Received 12 August 1999; accepted 27 August 1999     

A comparison of lead exposures in industrial “hot spots” in Jordan and Israel

The aim of this study was to compare two hot spots of lead (Pb) exposure in Israeli and Jordanian occupational settings. The study also sought to assess whether any differences in regulations and legislation regarding occupational health could be identified as a source of exposure disparities. Blood and hair specimens were collected from workers in a battery factory in Jordan and a secondary Pb smelter in Israel and compared. About 33% of the currently exposed group showed blood lead (BPb) levels above the internationally recommended concentration of 40 µg dL^?1. Although the differences of BPb levels between Israel and Jordan were not statistically significant, average levels were lower in Jordan. Beyond the difference in the factory types, disparity in exposure levels might be explained due to a combination of proclivities of factory management, public policies, existing medical surveillance and insurance, as well as cultural differences. Results reveal that despite existing regulations and the growing attention that is dedicated to Pb and metal occupational exposures, there are still hot spots for Pb exposure in Israel and Jordan. The contrasting experience found in the current study raises the possibility that information and technology exchange between the two countries Israel and Jordan, may be beneficial for improving occupational health policy in these two neighboring countries.     

“NEW” resource recovery from wastewater using bioelectrochemical systems: Moving forward with functions

Bioelectrochemical systems (BES) have been extensively studied for resource recovery from wastewater. By taking advantage of interactions between microorganisms and electrodes, BES can accomplish wastewater treatment while simultaneously recovering various resources including nutrients, energy and water (“NEW”). Despite much progress in laboratory studies, BES have not been advanced to practical applications. This paper aims to provide some subjective opinions and a concise discussion of several key challenges in BES-based resource recovery and help identify the potential application niches that may guide further technological development. In addition to further increasing recovery efficiency, it is also important to have more focus on the applications of the recovered resources such as how to use the harvested electricity and gaseous energy and how to separate the recovered nutrients in an energy-efficient way. A change in mindset for energy performance of BES is necessary to understand overall energy production and consumption. Scaling up BES can go through laboratory scale, transitional scale, and then pilot scale. Using functions as driving forces for BES research and development will better guide the investment of efforts.

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Trace metal content in inhalable particulate matter (PM<Subscript>2.5–10</Subscript> and PM<Subscript>2.5</Subscript>) collected from historical mine waste deposits using a laboratory-based approach

Mine wastes and tailings are considered hazardous to human health because of their potential to generate large quantities of highly toxic emissions of particulate matter (PM). Human exposure to As and other trace metals in PM may occur via inhalation of airborne particulates or through ingestion of contaminated dust. This study describes a laboratory-based method for extracting PM_2.5–10 (coarse) and PM_2.5 (fine) particles from As-rich mine waste samples collected from an historical gold mining region in regional, Victoria, Australia. We also report on the trace metal and metalloid content of the coarse and fine fraction, with an emphasis on As as an element of potential concern. Laser diffraction analysis showed that the proportions of coarse and fine particles in the bulk samples ranged between 3.4–26.6 and 0.6–7.6 %, respectively. Arsenic concentrations were greater in the fine fraction (1680–26,100 mg kg^?1) compared with the coarse fraction (1210–22,000 mg kg^?1), and Co, Fe, Mn, Ni, Sb and Zn were found to be present in the fine fraction at levels around twice those occurring in the coarse. These results are of particular concern given that fine particles can accumulate in the human respiratory system. Our study demonstrates that mine wastes may be an important source of metal-enriched PM for mining communities.     

Comments on “turbulent velocity profile in fully-developed open channel flows”

In a recent paper published in this journal, Bonakdari et al. (Environ Fluid Mech 8:1–17, 2008) presented a new formulation of the vertical velocity profile in the central portion of steady fully developed turbulent open-channel flows which is based on an analysis of the Navier–Stokes equations. The predicted mean streamwise velocity profiles presented by the authors represent dip phenomenon (maximum velocity below the free surface). The discusser would like to point out some contradictions and an error in the main demonstration. This error appears in the right-hand side term of the main Eq. 22 (Environ Fluid Mech 8:1–17, 2008) in the parameter α. Our corrected demonstration shows that α is equal to and not to as obtained by the authors (Environ Fluid Mech 8:1–17, 2008). The values of α used by the authors are under-estimated by 1, this difference has a significant effect on velocities and therefore will involve a difference between measured and predicted velocity profiles. Finally, the assumption of at the free surface is in contradiction with predicted velocity profiles.