我国油田产出水再利用技术现状及展望

随着我国油气田勘探开发力度加大和新环保法的实施,油田开采过程中耗水量大和污水处理问题是我国油气田企业面临的共同难题。从污水余热回收、污水回注、压裂液重复利用、钻井废水再利用四个方面,介绍了国内油田产出水再利用技术研究进展与应用现状,指出目前存在的污水余热再利用应用范围不广、回注污水利用不合理、化工原料未回收利用等主要问题。并通过文献调研,展望了油田污水再利用技术的发展方向,指出需从污染源头防控入手,研发更加经济环保的液体配方,并深入研究从污水中取热、取水及取化工原料的循环再利用技术,因地制宜制定相应的水质及污水配伍性实验评价标准,实现从源头至末端治理相结合的油田污水清洁生产。     

居住区生活污水资源化的探讨

城镇居住区的生活污水资源化越来越受到关注,掌握其水质水量变化趋势对收集、处理和资源化利用十分必要。分别以北方某城市、南方某城市、东部某城市的典型居住区为例,开展了水质水量调查。研究表明,居住区的水量变化规律有很强的地区差异性,且与当地的生活习惯有很大关系。北方地区的污水各项污染物浓度平均比南方地区高10%。主要污染物的浓度与用水量有一定相关性,除去夜间的洗浴时间,在用水高峰期尤其是清晨期间浓度较高。     

Developing a sustainable energy strategy for a water utility. Part II: A review of potential technologies and approaches

Environmental legislation is increasing the amounts of bought-in electricity required for sewage treatment, and generating larger volumes of sewage sludge to be treated and disposed of. Concurrently, concerns over global warming and food safety from sewage sludge recycling on agricultural land is augmenting the costs of conventional sewage and sludge treatment technologies and practices. This paper reviews some emerging technologies and practices that may assist in mitigating these problems in the future. In addition, a number of potential renewable energy technologies available to water companies are reviewed. Results suggest that through the take-up of new technologies, current and future water quality standards could be delivered in a more sustainable way. However, this series of papers also highlights that institutional and political conflicts may have inadvertently failed to recognise the wider effects of improving water quality and lessened the financial support necessary for their widespread take-up. It is also suggested that through the use of a Strategic Environmental Assessment (SEA) approach, stakeholders could gain a better understanding of the broader environmental effects of achieving certain water quality standards and develop policy and long-term investment strategies accordingly. However, to fulfill the information requirements of an SEA, an appropriate appraisal tool that considers many of these factors in unison is required, and a possible technique is suggested.     

稠油采出含聚污水微生物处理研究

随着海外河油田聚合物驱采油技术大面积应用,含聚合物(聚丙烯酰胺)污水大量产出。针对含聚污水黏度大、含油多、乳化稳定,采用传统的污水处理方法及设施难以达到油田注水水质标准的问题,在对海外河油田含聚污水水质分析和微生物处理可行性分析的基础上,进行了微生物处理实验,实验表明:经生化处理的污水满足SY/T 5329-2012《碎屑岩油藏注水水质指标及分析方法》。     

CHANGING A GREAT CITY IN EASTERN EUROPE — CRACOW: ENVIRONMENTAL CHANGES1

ABSTRACT: The main factor in the location of medieval Cracow was drainage. In the 700-year history of the City, there were numerous changes in water conditions, particularly in channel network, runoff, ground water level, and ice phenomena. The most dangerous threat to surface water and ground water in Cracow in the last decades has been from industrial and municipal sewage. Currently there are no rivers that meet Drinking Water Quality standards in Cracow. The quality of the ground water has declined because of infiltration of contaminated river water, water from sewage disposal ponds, and pollution from the atmosphere and soil. Cracow does not have enough waste water plants to meet its needs. Most municipal and industrial sewage has not been treated or has been treated only partially. Because of considerable contamination of surface and ground waters in Cracow, more than half of the city's fresh water is pumped about 50 kilometers from a reservoir on the Raba River. A Polish government declaration of April 4, 1989, recognized Cracow as an area of particular protection, and directed that a number of actions be undertaken for the protection of environmental quality.     

欧盟游泳场水质监管现状及对我国游泳场水质管理的建议

欧洲国家对游泳场水质的管理由来已久,管理经验丰富,而我国对游泳场水质的管理刚刚起步,仍然存在很多不足。针对目前我国由于监督管理以及某些地区的经营不善出现的一系列游泳场水质问题,本文介绍了欧盟成员国的游泳场水质质量监测管理现状,分别从游泳场水质管理立法、游泳场水质监测方法、游泳场水质评估和等级划分,以及欧盟国家游泳场未来发展趋势等方面,对欧盟国家游泳场水质管理的发展情况进行了分析总结。借鉴欧盟发达国家游泳场的水质管理经验对我国游泳场水质进行监测和管理非常重要,最后提出完善我国游泳场水质管理的一些建议,如建立游泳场水质监测日志,制作游泳场水质信息系统,加强游泳场水质监测技术研究等。希望借助欧盟国家的游泳场管理经验,促进我国游泳场水质管理的进一步发展和完善。     

我国城镇污水处理厂水质监管问题及对策研究

介绍了目前我国城镇污水处理厂的发展现状以及将其作为污染源纳入监管的背景;从进水水质监管、出水水质监管和对污水处理厂内部运营管理监管的角度,结合对部分地区行政管理部门、污水处理厂的调研,分析了污水处理厂出水水质不达标的主要原因;针对我国的实际情况并借鉴国外经验,从政府部门的监管职能、政企的合作、监管技术和末端污染控制方面,给出了加强污水处理厂运行监管效果的对策。     

Eco-Compensation in Multi-District River Networks in North Jiangsu, China

Eco-compensation is a multi-disciplinary topic. There is no consensus on the issue of river eco-compensation across districts. Although policies regarding river eco-compensation have been issued in China since 2008, due to the high cost, eco-compensation has not been well implemented in the Taihu pilot region. Therefore, a simplified method based solely on water quality (both water quality and water volume included in the Taihu method) was proposed for North Jiangsu province (NJP). However, the formula was flawed and it led to payments being too low. Three problems need to be solved: (1) how to specify the eco-compensation areas; (2) how to test a reasonable eco-compensation model and (3) how to determine the compensation criterion. Solving these issues is already a priority. In this paper, three potential solutions surrounding eco-compensation are discussed: (1) three principles for selecting the representative eco-compensation areas are suggested; (2) the compensation calculation method based on contaminant flux above the ultra standard is revised and (3) a compensation criterion model based on the treatment costs of sewage is proposed. In the NJP case in 2009, the average eco-compensation criterion for chemical oxygen demand (COD) is 2,000 Chinese Yuan (CNY) per ton and ammonia nitrogen (NH₄–N) and total phosphorus (TP) are 8,000 CNY and 80,000 CNY per ton, respectively. Five districts needed to be compensated. The payments in the revised scheme were 4.15–586 million CNY, which were 16–48 times greater than that in the draft method. The new method can provide an important template for managers when drafting river eco-compensation schemes.     

稠油污水回用锅炉处理工艺的应用

新疆油田公司稠油污水处理普遍采用成熟的离子调整旋流反应水处理技术,污水处理后达到回用锅炉水质标准SY/T 0097-2000《稠油油田采出水用于蒸汽发生器给水处理设计规范》,供给油田专用高压注汽锅炉用水。采用相同技术建成的采油一厂稠油处理站污水回用锅炉处理工艺投用后,处理后污水回用锅炉,减少了含油污水的外排,充分利用了稠油污水的热能,取得了良好的经济和社会效益。     

烟台市水环境污染与经济发展的关系研究

对烟台市2001～2017年水环境质量与经济发展的系列数据进行收集、整理及分析后,建立以环境库兹涅茨曲线(EKC)及其相关理论为基础的烟台市人均GDP与烟台市水环境污染指标的计量模型.对结果进行分析后发现:烟台市工业污水排放量对数值与人均GDP对数值间关系呈倒"N"形曲线,烟台市城乡居民生活污水排放量与人均GDP间关系...     

沱江流域水资源的保护与利用

本文研究了沱江流域水资源的开发利用问题。由于流域内水资源贫乏和开发利用程度较高,枯水期中下游区无法保证水资源的需要。随着工业的发展,沱江水质污染将日趋严重致使枯水期有限的水资源变成不能使用的污水。因此,本文较详细地研究了沱江水质保护规划。在水目标、水污染控制最优方案、总量控制标准、流域水质保护区划等方面进行了探讨,文中从水量和水质两方面着手,根据系统工程原理求得解决水资源问题的最佳方案。     

Methods of Compliance Evaluation for Ocean Outfall Design and Analysis

Sewage discharge from an ocean outfall is subject to water quality standards, which are often stated in probabilistic terms. Monte Carlo simulation (MCS) has been used in the past to evaluate the ability of a designed outfall to meet water quality standards or compliance guidelines associated with sewage discharges. In this study, simpler and less computer-intensive probabilistic methods are considered. The probabilistic methods evaluated are the popular mean first-order second-moment (MFOSM) and the advance first-order second-moment (AFOSM) methods. Available data from the Spaniard's Bay Outfall located on the east coast of Newfoundland, Canada, were used as inputs for a case study. Both methods were compared with results given by MCS. It was found that AFOSM gave a good approximation of the failure probability for total coliform concentration at points remote from the outfall. However, MFOSM was found to be better when considering only the initial dilutions between the discharge point and the surface. Reasons for the different results may be the difference in complexity of the performance function in both cases. This study does not recommend the use of AFOSM for failure analysis in ocean outfall design and analysis because the analysis requires computational efforts similar to MCS. With the advancement of computer technology, simulation techniques, available software, and its flexibility in handling complex situations, MCS is still the best choice for failure analysis of ocean outfalls when data or estimates on the parameters involved are available or can be assumed.     

Quantitative catchment profiling to apportion faecal indicator organism budgets for the Ribble system, the UK's sentinel drainage basin for Water Framework Directive research

Under the EU Water Framework Directive (WFD) 20/60/EC and the US Federal Water Pollution Control Act 2002 management of water quality within river drainage basins has shifted from traditional point-source control to a holistic approach whereby the overall contribution of point and diffuse sources of pollutants has to be considered. Consequently, there is a requirement to undertake source-apportionment studies of pollutant fluxes within catchments. The inclusion of the Bathing Water Directive (BWD), under the list of 'protected areas' in the WFD places a requirement to control sources of faecal indicator organisms within catchments in order to achieve the objectives of both the BWD (and its revision - 2006/7/EC) and the WFD. This study was therefore initiated to quantify catchment-derived fluxes of faecal indicator compliance parameters originating from both point and diffuse sources. The Ribble drainage basin is the single UK sentinel WFD research catchment and discharges to the south of the Fylde coast, which includes a number of high profile, historically non-compliant, bathing waters. Faecal indicator concentrations (faecal coliform concentrations are reported herein) were measured at 41 riverine locations, the 15 largest wastewater treatment works (WwTWs) and 15 combined sewer overflows (CSOs) across the Ribble basin over a 44-day period during the 2002 bathing season. The sampling programme included targeting rainfall-induced high flow events and sample results were categorised as either base flow or high flow. At the riverine sites, geometric mean faecal coliform concentrations showed statistically significant elevation at high flow compared to base flow. The resultant faecal coliform flux estimates revealed that over 90% of the total organism load to the Ribble Estuary was discharged by sewage related sources during high flow events. These sewage sources were largely related to the urban areas to the south and east of the Ribble basin, with over half the load associated with the relatively small subcatchment of the River Douglas. The majority of this load was attributed to two WwTWs that discharge through a common outfall close to the tidal limit of this catchment. Budgets adjusted to accommodate the impact of proposed UV disinfection of these effluents showed that the load from these sources would be reduced significantly during base flow conditions. However, during high flow events loads would still remain high due to the operation of storm sewage overflows from stormwater retention tanks. The study identified untreated storm sewage spills from urban infrastructure and WwTW stormwater retention tanks as the dominant component of the high flow flux of faecal indicators to receiving waters of the Fylde coast and the associated bathing waters.     

长庆气田甲醇污水水质特点分析

长庆气田天然气开采加工过程中产生的甲醇污水水质复杂,区域差异大,只有正确认识甲醇污水水质特点,才能有针对性地进行甲醇污水处理工艺设计及运行管理,确保系统平稳、安全运行。文章分析了靖边气田、榆林气田、苏里格气田甲醇污水水质特点,对以上气田水质进行综合比较。应根据含醇污水水质特点,随着水质的变化进行相应的工艺调整。     

彩南污水处理技术改进研究及应用

针对彩南油田原有水处理技术不能满足工艺要求的现状,对水质净化工艺技术进行改进研究。确定预催化—强化絮凝净水的技术路线,并选定了最优药剂体系、加药量和加药位置;结合以往污水处理经验和现场实际情况,在预催化—强化絮凝净水技术基础上自行研发了新型污水反应器,对斜板沉降罐进出水系统、沉降罐收油槽、调储罐、污泥沉降池和杀菌技术进行了改进。通过现场实际运行,处理后含油污水水质达到Q/SY XJ0039—2001《彩南油田注水水质标准》。     

协定水污染物间接排放标准的法律问题探究

以协商的方式确定水污染物间接排放标准的规定打破了人们对标准确定性、强制性的传统认识。协定标准的优势在于充分利用污水处理厂的污水处理能力,减轻企业的污水处理负担,使企业可以集中力量搞生产。协定标准具有灵活性和优越性,应充分利用。通过对协定标准概念和重要性的分析,指出协定标准存在效力不确定、缺少对协定范围的限制等问题,造成协定标准在实践中通常被忽视或者滥用。并从明确协定标准的范围、加强排污企业的管理和协定标准的监督等方面,进一步提出了限制和完善水污染物间接排放标准的建议。     

济宁南四湖水质富营养化评价及防治对策研究

以2012年南四湖水质监测数据为依据,采用修正的卡森指数法（TSIM）对南四湖水质进行评价。结果表明,修正卡森指数的评价结果为TSIM=56．04,南四湖已达到富营养化的标准。根据评价结果,从工业废水、生活污水排放、底质、农业生产、渔业养殖的影响方面分析了水体富营养化的原因,从减少外源污染物、应用生物措施和发展健康水产养殖模式三个方面提出了南四湖水体富营养化的防治对策。     

A CLOSED WATER REUSE SYSTEM FOR POWER PLANT COOLING AND DIGESTER HEATING1

ABSTRACT: A model consisting of closed water reuse and productive use of various types of wastes for energy generation is presented. The sewage after treatment would be used as the cooling water for power plants, and the condenser discharge therefrom be used as heating water for sludge digesters. The water is then purified for municipal water supply for continuous use. The advantages of this system are that water resources and energy are conserved while various types of wastes including waste heat are controlled. With a preliminary system analysis, it appears that the design for power plant based on the total heating value of wastes and digester capacity based on sewage sludge generation is feasible in terms of acquisition and full utilization of various types of wastes as generated in a single metropolitan area. The system as shown in this design is in balance among various factors such as the generation rate of municipal refuse, municipal sewage, waste heat in the condenser discharge, and raw sewage sludge.     

Policy, Principle, and Practice in Industrial Pollution Control: Views from the Regulatory Interface

There has been much criticism of the system for the control of industrial pollution, but not much is known about the views of the regulators and the industry. The objective of this study was to explore the attitudes at this regulatory interface towards the current and proposed regulatory system and make recommendations for improvements. The methodology involved a questionnaire survey sent to over 700 key personnel. Statistical analysis revealed similarities and significant differences between the views of industry and the regulator on the effectiveness of the current regime. Weaknesses related to the derivation and enforcement of standards were identified. The Environmental Quality Standards system was acknowledged to be flawed by both operators and regulators who agreed it should be improved by the expansion of listed chemicals, the introduction of sediment environmental quality standards and direct toxicity assessment of effluents. This paper concludes that these measures should be incorporated into the regulatory system, together with more rigorous enforcement of environmental performance standards including serious sanctions for non-compliance. In the longer term, a reappraisal of the regulatory system is required in order to establish an appropriate framework to ensure that environmental policy commitments are implemented.     

AN ANALYSIS OF COLIFORM BACTERIA IN THE UPPER ILLINOIS WATERWAY1

ABSTRACT: During the summer of 1971 about 150 water samples were examined for total and fecal coliform bacteria in the Upper Illinois Waterway at 19 river stations. The data per station were found to be normal geometric distributed. Bacteria densities changed with sampling dates and generally decreased with water movement downstream. Several sewage treatment effluents made marked pulses along the bacterial die-off curves. The observed fecal coliform results were evaluated in terms of the Illinois Pollution Control Board's standards. The FC:TC ratio on the waterway for each station were presented. Using Chick's Law, coliforms death rates were estimated. Efforts to correlate observed total and fecal densities with temperature, flow, algal densities, dissolved oxygen, and 5-day biochemical oxygen demand were not successful. (KEY TERMS: algae; biochemical oxygen demand; coliform bacteria; dissolved oxygen; flow; stream survey; temperature; water pollution; water quality standards)