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1.
以花生壳活性炭对RO浓水进行吸附处理,利用傅立叶红外光谱(FTIR)和荧光光谱(EEM)研究花生壳活性炭对不同pH的RO浓水的吸附特性.结果表明,花生壳活性炭对溶解性有机碳(DOC)的吸附遵循准二级吸附动力学方程,特别是碱性条件下,DOC的吸附量随着pH的升高而降低.而且pH越高,达到吸附平衡的时间越长.通过FTIR光谱分析发现,活性炭的芳香结构吸收峰在吸附后红移至1630 cm-1,表明被吸附的有机物在该处有明显的特征吸收峰,而C—O和O—H官能团的吸收峰则因为钙离子等物质的吸附而显著降低.由EEM光谱分析可知,RO浓水的荧光物质主要由腐殖酸类腐殖质和富里酸类腐殖质组成,其荧光强度与DOC之间具有较好的线性相关性.  相似文献   

2.
斑马鱼幼鱼运动行为测试评价饮用水安全   总被引:1,自引:1,他引:0  
饮用水安全直接关乎人类的健康与安全,当前迫切需要全新的毒性测试方法对饮用水的潜在人类健康风险进行全面、准确和灵敏的评估和预警。本研究以反渗透技术(RO)取代常用的固相萃取,分别浓缩饮用水厂的进厂水、出厂水和管网水进行毒性试验水样的前处理。反渗透技术前处理方法可以避免传统固相萃取方法中使用的有机溶剂对行为学测试体系的干扰。RO浓缩后的饮用水对斑马鱼胚胎进行持续暴露,采用Viewpoint行为测试软件量化分析出生后第6天(6 dpf)斑马鱼幼鱼的运动行为,选择运动距离和转向行为作为测试终点,分析进厂水、出厂水及管网水的潜在毒性及可能变化。结果表明,暴露在进厂水的幼鱼出现了明显的行为变化,尤其在较高浓度(20倍浓缩)暴露时,运动距离相比对照组显著减少,同时伴有剧烈的转向等异常行为;管网水对斑马鱼幼鱼行为存在一定程度的影响,而出厂水对幼鱼的运动行为没有显著影响。研究结果反映出当前饮用水厂深度处理工艺可以有效降低进厂水的潜在毒性和健康风险,但是经供水管网输送后,其水质可能发生了改变,导致管网水可能存在潜在的毒性。本研究所采用的反渗透技术前处理技术及斑马鱼幼鱼的运动行为学测试方法,可用于未来建立评估饮用水水质安全的早期预警系统。  相似文献   

3.
水环境中残留的抗生素对生态环境和人体健康存在潜在危害.近年来,国内外关于抗生素污染特征研究多集中于地表水和污水处理厂等水环境中,而同时针对水源水、出厂水等供水体系抗生素风险情况的研究相对较少.本文利用固相萃取-超高效液相色谱-串联质谱法调查了南方某地区氯霉素(CAP)、四环素(TC)、土霉素(OTC)、诺氟沙星(NOR)、脱水红霉素(ERY-H2O)、罗红霉素(ROX)、阿莫西林(AMOX)、青霉素G(PEN-G)和头孢拉定(CFD)等9种抗生素的含量水平,揭示该地区供水系统中抗生素的污染现状和分布特征.同时,本文分别采用风险商值法(RQ)和蒙特卡罗法评价了9种抗生素在水源水中的生态风险和在出厂水对人体健康风险.结果表明,该地区水源水脱水红霉素含量较高,浓度在200—600 ng·L-1间,出厂水中脱水红霉素含量水平比水源水低.而其余8种抗生素在水源水和出厂水中均含量较低.风险评价结果显示:所有被测抗生素风险RQ值均小于1,说明该地区水源水、出厂水抗生素风险危害处于较低水平.但不同水源水和出厂水最大风险指标均指向脱水红霉素,说明脱水红霉素是该地区主要的风险抗生素之一.  相似文献   

4.
以黄浦江上游水源地为例,利用1999年上海水资源普查数据及2000年初成像的上海市1∶50 000彩红外航空像片,采用G IS空间分析技术、灰色关联分析技术,划分土地利用样带,设计水质改善指数,探讨平原河网地区水环境质量对土地利用结构的响应,以及水源水质对土地利用变化驱动力的响应。结果表明,黄浦江上游水环境质量受到土地利用格局及上游来水的综合影响,各样带工业用地比例与水质改善指数呈极显著负相关(P<0.01),松浦大桥取水口水质与上游来水水质以及水源地当地的工业发展、人口密度等土地利用变化驱动力具有很好的关联性。建议在开展平原河网地区水源保护工作中,应在关注上游来水状况的同时,从土地利用及其社会经济驱动两方面控制水文敏感区域土地开发强度,构筑水源地圈层土地利用格局。  相似文献   

5.
以原代培养的大鼠睾丸细胞为体外毒性试验靶细胞,采用支持细胞、生精细胞、间质细胞的形态、细胞活力、胞外乳酸脱氢酶(LDH)活力、细胞早期凋亡坏死率和间质细胞睾酮分泌量5种检测指标评价了X市和L市水源水中有机提取物的生殖毒性,并筛选了对痕量有机污染物敏感的生殖毒性指标.研究结果表明,两市水源水中有机提取物皆可引起支持细胞、间质细胞和生精细胞形态的变化,相比较而言,对生精细胞的影响更严重.X市水源水有机提取物对3种生殖细胞胞外LDH活力没有显著影响(p>0.05);而在L市水源水中有机提取物的暴露下,支持细胞和间质细胞胞外LDH活力显著增强(p<0.01).X市水源水中有机提取物可使间质细胞睾酮分泌量显著减少(p<0.01);而L市水源水有机提取物对间质细胞睾酮分泌量无明显影响(p>0.05).两市水源水有机提取物均能不同程度地诱发大鼠睾丸细胞损伤,生精细胞对环境毒物是比较敏感的细胞,细胞形态、活力、LDH活力、凋亡坏死率、睾酮分泌量等生殖毒理学检测指标可用于饮用水源地水质的评价.  相似文献   

6.
戴丹超  马旭洲  张勇  周桢 《环境化学》2019,38(11):2573-2582
为研究宜兴滆湖地区河蟹生态养殖池塘对水环境的影响,于2017年5—10月对江苏省宜兴市高塍镇滆湖渔场3个河蟹生态养殖池塘和水源进行水质监测,并采用灰色关联分析法对水质进行评价,结果表明,整个养殖期间池塘T、DO和pH与水源差异较小,TN、NH_3-N、NO~-_2-N和NO~-_3-N总体低于水源,TP、PO■-P和COD_(Mn)总体高于水源,池塘对水体的净化效果主要体现在对各种形式含氮化合物的吸收转化.池塘和水源水质等级在Ⅲ类以上的频率分别为76.7%和50%,主要超标指标均为TN、TP和COD_(Mn).池塘和水源的水质排序结果表明,养殖前中期池塘水质大体优于水源,后期及起捕后劣于水源,若将养殖尾水不经处理直接排放到水源,最终汇入滆湖,会对滆湖水体造成污染.高温季节及时割去伊乐藻冠层和适当降低放养密度,可能是优化宜兴滆湖地区河蟹生态养殖模式、提高生态效益的两个方向.  相似文献   

7.
反渗透(Reverse Osmosis,RO)因出水水质好、运行成本低等优势常用于垃圾渗滤液的处理,但产生的RO浓缩液具有COD高、色度高、盐分高、难降解等特点,其处理存在效果差、能耗和成本均较高等问题.本工作采用氧化钌/氧化铱涂层电极(RuO2/IrO2-Ti)的钛网为阳极,以304不锈钢电极为阴极,设计制作了6通道的电化学反应器,通过电化学氧化处理RO浓缩液,研究考查了电流密度、循环流速、比电极面积等参数对COD去除效果的影响,分析了电化学氧化去除难降解有机物并同时脱盐的过程机理与能耗.结果表明,在电流密度32.89 mA·cm-2,循环流速0.46 cm·s-1,比电极面积65.10 m2·m-3的条件下,电化学氧化处理RO浓缩液3 h,COD去除率可达68.0%,TOC去除率可达40.6%,脱盐率可达72.1%,去除单位质量COD能耗仅为常规的板状电极电化学反应器的25.5%.本工作可为垃圾渗滤液RO浓缩液的预处理提供新思路.  相似文献   

8.
贾延  马旭洲  张文博  戴丹超  刘宇 《环境化学》2020,39(6):1544-1554
为探究中华绒螯蟹幼蟹蜕壳期间池塘水环境的变化特征,于2018年5月7日至10月13日,对上海松江泖港地区幼蟹生态养殖池塘和水源进行水质监测.结果表明,大眼幼体经160 d养殖,蜕壳11次成长为幼蟹,T均值为27.0±2.9℃,总有效积温为3085.3℃·d;随蜕壳次数增加,有效积温增长趋势贴近指数函数y=42.166e~(0.2644)~x,R~2=0.9629;累计有效积温增长趋势贴近二次函数y=33.059x~2-98.244x+160.05,R~2=0.9992.幼蟹池溶解氧(DO)在养殖前期优于水源,NH~+_4-N、NO~-_2-N、NO~-_3-N总体优于水源,PO_4~(3-)-P在高温季节优于水源,COD_(Mn)在整个养殖阶段均较水源差.除TN、TP、COD_(Mn)有不同程度超标外,幼蟹池和水源其它水质因子基本符合渔业水质标准和地表水环境质量标准的Ⅲ级标准.  相似文献   

9.
为探讨利用我国本土植物进行水质综合评价和指示的可行性,试验研究了我国特有的浮萍属植物——稀脉萍(Lemna paucicostata)对不同来源水(自来水、雨水为唯一来源的池塘水、接纳多种排放废水的湖水及垃圾填埋场渗滤液)水质的综合评价和指示效果.结果表明,1)就不同来源水而言,随着水质的下降(自来水、池塘水、湖水、渗滤液),稀脉萍叶状体和群体7d相对增殖率(相对于对照)均逐渐降低;2)就某一污水而言,随着水质的下降(渗滤液稀释4096~128倍),稀脉萍叶状体7d相对增殖率逐渐降低,而群体相对增殖率没有明显变化规律.以上结果提示,稀脉萍对水质具有一定的评价和指示作用,其叶状体相对增殖率可应用于水质的生物学监测和综合评价.  相似文献   

10.
以北京市3条具有不同功能的代表性河流(清河:纳污排洪;京密引水渠:供水水源;小月河:景观用水)作为研究对象,分析测定了33个水质指标,采用内梅罗指数法与大型蚤急性毒性测试法对3条河流的水质与毒性状况进行了评价,同时运用主成分分析法对毒性产生的原因和影响水质的因素进行了初步探讨.结果表明,1)3条河流已受到不同程度的污染,水质和毒性状况均不容乐观.作为纳污排洪的清河大部分采样点水质较差,生物毒性极高;作为景观用水的小月河水质一般,具有一定的生物毒性;作为供水水源的京密引水渠水质一般,但毒性较低.2)水样生物毒性与Cl-、Ca、K、Li、Mn、Na、Cr、Ni等指标有关;内梅罗水质指数与NO2-、Cl-、K、Na、Ni等指标有关.3)某些指标(如NO2-)超标会对水质分级产生较大影响,但对生物毒性贡献不大,而低浓度的重金属,不会对水质分级产生贡献,却会对生物的生理活动产生影响,综合化学指标和毒性指标共同评价水质更为合理.  相似文献   

11.
为防控长江上游重大突发水污染事件的发生,收集整理长江宜宾至泸州江段沿江水环境污染源及受体基础资料,构建水环境潜在污染风险分级评价体系。采用地统计学理论和地理信息系统(Geographic Information System,GIS)相结合的方法开展突发水污染风险分区评价研究,以揭示研究区江段突发水污染风险空间分布差异性。结果表明,污染源或受体热点分布主要集中在城镇化、工业化较快的地区,如宜宾市叙州区污染源最多,泸州市龙马潭区高风险污染源最密集,宜宾县和南溪县高敏感受体数量最多;其他区域污染源或受体分布较为均衡,未形成明显的冷点区域。水环境潜在污染高风险区集中分布在龙马潭区江段和江阳区江段,须提高该区域对潜在污染的风险管理能力,以降低污染事故发生的可能性。  相似文献   

12.
The objectives were to investigate the potential remedial measures for reverse osmosis (RO) rejected water through constructed wetlands (CWs) with low-cost materials in the media established in chronic kidney disease of unknown etiology (CKDu) prevalent area in Sri Lanka. A pilot-scale surface and subsurface water CWs were established at the Medawachchiya community-based RO water supply unit. Locally available soil, calicut tile and biochar were used in proportions of 81, 16.5 and 2.5% (w/w), respectively, as filter materials in the subsurface. Vetiver grass and Scirpus grossus were selected for subsurface wetland while water lettuce and water hyacinth were chosen for free water surface CWs. Results showed that the CKDu sensitive parameters; total dissolved solids, hardness, total alkalinity and fluoride were reduced considerably (20–85%) and most met desirable levels of stipulated ambient standards. Biochar seemed to play a major role in removing fluoride from the system which may be due to the existing and adsorbed K+, Ca+2, Mg+2, etc. on the biochar surface via chemisorption. The least reduction was observed for alkalinity. This study indicated potential purification of aforesaid ions in water which are considerably present in RO rejection. Therefore, the invented bio-geo constructed wetland can be considered as a sustainable, economical and effective option for reducing high concentrations of CKDu sensitive parameters in RO rejected water before discharging into the inland waters.  相似文献   

13.
• The boron concentration in diluted DS can satisfy the irrigation water standard. • The boron concentration in diluted DS equaled that in two-pass RO permeate. • FDFO process SEC was slightly lower than the 2nd pass RO SEC. • FDFO has potential as an alternative to 2nd pass RO for irrigation water production. Agriculture is the largest consumer of freshwater. Desalinated seawater is an important alternative water source for sustainable irrigation. However, some issues of the current desalination technology hinder its use for agriculture irrigation, including low boron removal and high energy consumption. This study systematically explored the feasibility of employing fertilizer drawn forward osmosis (FDFO) as an alternative to 2nd pass reverse osmosis (RO) by considering the boron removal performance and specific energy consumption (SEC). Different operating conditions were investigated, such as the boron and NaCl concentrations in feed solution (FS), draw solution (DS) concentration, pH, the volume ratio of FS to DS, membrane orientation, flow rate, and operating temperature. The results indicated that a low boron concentration in FS and high pH DS (pH= 11.0) decreased the boron solute flux, and led to low final boron concentration in the DS. The other operating conditions had negligible influence on the final DS boron concentration. Also, a lower flow rate and higher specific water flux with certain permeate water volumes were conducive to reducing the SEC of the FDFO process. Overall, our study paves a new way of using FDFO in irrigation, which avoids the phytotoxicity and human health risk of boron. The results show the potential of FDFO as an alternative to 2nd pass RO for irrigation water production.  相似文献   

14.
The concentrations of polycyclic aromatic hydrocarbons (PAH), total carbon (TC), total organic carbon (TOC), total nitrogen (TN) and dissolved inorganic nitrogen (DIN) in water and sediments of Lake Baikal and its tributaries were measured. It was found that according to existing water and sediment quality standards limiting permissible PAH concentrations, both surface waters and sediments in Lake Baikal watershed can be considered as unpolluted with PAHs compounds. Nevertheless, the spatial distribution of PAH concentrations in lake water indicates the existence of some point PAH sources in and around the lake. These sources were natural oil seeps and communal facilities such as residential coal-fired and oil-fired boilers. It was observed that concentrations of PAHs in both water and sediments are controlled by organic matter content and organic matter mineralisation degree, as indicated by PAH-to-carbon and nitrogen-to-carbon ratios respectively. It was found that PAH/TOC and PAH/TC ratios characterise PAH loading on water and sediments respectively, whereas DIN/TOC and TN/TC ratios characterise self-purification of water and sediments respectively. It was proved that PAH/TOC and DIN/TOC ratios can be used as tracers to evaluate the PAH contributions from tributaries to Lake Baikal.  相似文献   

15.
A trace elements study of various samples from the Keana brines field, middle Benue Trough was carried-out to determine the extent to which Pb–Zn–S and BaSO4 mineralisations have affected the quality of the brines and the waters in the area. Different sample media such as well-water, pond water, brine spring pool water, stream water, stream sediments etc. were analysed. Geochemical results show that Cu, Zn, Pb, As and S are concentrated in the waters (0.3, 0.36, 0.05, 0.07 and 1 1.5 ppm respectively). These elements are more concentrated in both the spring and pond waters, suggesting that the spring water could have acted as the transport medium for these elements released from deep-seated sources. Transitions elements (Ti, V, Cr, Fe, Co, Ni and Sr) are concentrated in the waters. Compared to the World Health Organization (WHO) admissible limits, the well waters present very high concentrations in Cd (0.56 ppm) and Sb (0.40 ppm) (200× and 70× WHO admissible values respectively). There is a preferential concentration of transition elements (Ti, V, Fe, Co and Ni) in the sediments (41.38, 362, 52.21, 269 and 54 ppm respectively) than in the waters (0.70, 0.05, 5.6, 0.04 and 0.02 ppm respectively). Similarly, Cu, Zn, Pb and As are concentrated in the sediments (44, 72, 41 and 14 ppm respectively). The concentrations of transition elements (Ti, V, Cr, Fe, Co and Ni) in the refined salt were highly elevated (784, 363, 283, 105, 59.2 and 42.6 ppm respectively) (7000–10,000× well water). Similarly, the concentrations of As, Pb, Br and Sr in the refined salt were also alarming (11.6, 16.4, 16.4 and 122 ppm respectively), (1000, 700, 3000 and 20,000× well water values respectively). S on the other hand is absent. One of the striking features is the absence of I, Cd, Sb and Se in the refined salt crystals which were detected in the waters and the brines. Compared to WHO admissible values, the refined salt crystal concentrations for Ni (426 ppm) and Cr (283 ppm) were also very high (2000× WHO values respectively) and to a lesser extent Cu (26.9 ppm) and Zn (21.7 ppm) (12 and 7× WHO values respectively).  相似文献   

16.
• Optimal growth of Chlorella in inland saline-alkaline water was achieved by blue LED. • Lipids of Chlorella sp. HQ were mainly composed of C16:0 and C18:2 under various LEDs. • The BiodieselAnalyzer© software was used to evaluate the Chlorella biodiesel quality. Chlorella sp. HQ was a high-quality feedstock for biodiesel production. Inland saline-alkaline water can be used for the low-cost cultivation of microalgae, but whether algal biomass under various light sources has the potential to produce biodiesel remains to be developed. Herein, the influence of different light-emitting diode (LEDs) light colors (blue, red, white, mixed blue-red, and mixed blue-white LED) on the growth performance, lipid accumulation, and fatty acid composition of Chlorella sp. HQ cultivated in inland saline-alkaline water was investigated. The highest algal density was obtained under blue LEDs at the end of cultivation, reaching 1.93±0.03 × 107 cells/mL. White LEDs can improve biomass yield, total lipid yield, and triacylglycerol yield per algal cell. The main fatty acid components of Chlorella from inland saline-alkaline water were palmitic acid and linoleic acid. The BiodieselAnalyzer© software was used to predict algal biodiesel quality by estimating different quality parameters. The cetane number, kinematic viscosity, and density of Chlorella biodiesel were 51.714–67.69, 3.583–3.845 mm2/s, and 0.834–0.863 g/cm3, respectively. This further proved that the Chlorella biomass obtained from inland saline-alkaline water has the potential to be used as a high-quality biodiesel feedstock.  相似文献   

17.
Humic acids (HA) didn’t cause obvious reverse osmosis (RO) membrane fouling in 45 h. Osmotic pressure (NaCl) affected slightly the RO membrane fouling behavior of HA. Ca2+ promoted aggregation of HA molecules and thus aggravated RO membrane fouling. Ozonation eliminated the effect of Ca2+ on the RO membrane fouling behavior of HA. The change of the structure of HA was related to its membrane fouling behavior. Humic acid has been considered as one of the most significant sources in feed water causing organic fouling of reverse osmosis (RO) membranes, but the relationship between the fouling behavior of humic acid and the change of its molecular structure has not been well developed yet. In this study, the RO membrane fouling behavior of humic acid was studied systematically with ozonation as a pretreatment method to control RO membrane fouling. Furthermore, the effect of ozone on the structure of humic acid was also explored to reveal the mechanisms. Humic acid alone (10–90 mg/L, in deionized water) was found not to cause obvious RO membrane fouling in 45-h operation. However, the presence of Ca2+ aggravated significantly the RO membrane fouling caused by humic acid, with significant flux reduction and denser fouling layer on RO membrane, as it was observed by scanning electron microscope (SEM) and atomic force microscope (AFM). However, after the pretreatment by ozone, the influence of Ca2+ was almost eliminated. Further analysis revealed that the addition of Ca2+ increased the particle size of humic acid solution significantly, while ozonation reduced the SUVA254, particle size and molecular weight of the complexes of humic acid and Ca2+ (HA-Ca2+ complexes). According to these results and literature, the bridge effect of Ca2+ aggregating humic acid molecules and the cleavage effect of ozone breaking HA-Ca2+ complexes were summarized. The change of the structure of humic acid under the effect of Ca2+ and ozone is closely related to the change of its membrane fouling behavior.  相似文献   

18.
• Mesoporous silica nanoparticle was modified with 4-triethoxysilylaniline. • AMSN-based TFN-RO membranes were prepared for seawater desalination. • Water transport capability of the AMSN was limited by polyamide. • Polyamide still plays a key role in permeability of the TFN RO membranes. Mesoporous silica nanoparticles (MSN), with higher water permeability than NaA zeolite, were used to fabricate thin-film nanocomposite (TFN) reverse osmosis (RO) membranes. However, only aminoalkyl-modified MSN and low-pressure (less than 2.1 MPa) RO membrane were investigated. In this study, aminophenyl-modified MSN (AMSN) were synthesized and used to fabricate high-pressure (5.52 MPa) RO membranes. With the increasing of AMSN dosage, the crosslinking degree of the aromatic polyamide decreased, while the hydrophilicity of the membranes increased. The membrane morphology was maintained to show a ridge-and-valley structure, with only a slight increase in membrane surface roughness. At the optimum conditions (AMSN dosage of 0.25 g/L), when compared with the pure polyamide RO membrane, the water flux of the TFN RO membrane (55.67 L/m2/h) was increased by about 21.6%, while NaCl rejection (98.97%) was slightly decreased by only 0.29%. However, the water flux of the membranes was much lower than expected. We considered that the enhancement of RO membrane permeability is attributed to the reduction of the effective thickness of the PA layer.  相似文献   

19.
High-pressure membrane process is one of the cost-effective technologies for the treatment of groundwater containing excessive dissolved solids. This paper reports a pilot study in treating a typical groundwater in Huaibei Plain containing excessive sodium, sulfate and fluoride ions. Three membrane systems were set up and two brands of reverse osmosis (RO), four low-pressure RO (LPRO) and one tight nanofiltration (NF) membranes were tested under this pilot study. An apparent recovery rate at about 75% was adopted. Cartridge filtration, in combination with dosing antiscalent, was not sufficient to reduce the fouling potential of the raw water. All RO and LPRO systems (except for the two severely affected by membrane fouling) demonstrated similar rejection ratios of the conductivity (~98.5%), sodium (~98.5%) and fluoride (~99%). Membrane fouling substantially reduced the rejection performance of the fouled membranes. The tight NF membrane also had a good rejection on conductivity (95%), sodium (94%) and fluoride (95%). All membranes rejected sulfate ion almost completely (more than 99%). The electricity consumptions for the RO, LPRO and NF systems were 1.74, 1.10 and 0.72 kWh?m-3 treated water, respectively. The estimated treatment costs by using typical RO, LPRO and tight NF membrane systems were 1.21, 0.98 and 0.96 CNY?m-3 finished water, respectively. A treatment process consisting of either LPRO or tight NF facilities following multi-media filtration was suggested.  相似文献   

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