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1.
A significant improvement in river water quality cannot be expected unless nonpoint-source contaminants are treated in addition to the further treatment of point-source contaminants. If river water is sprayed over a floodplain, the consequent water filtration through the sediment profile can simultaneously remove organic matter and nitrogen in the water through aerobic and denitrifying reactions. This hypothesis was tested using lysimeters constructed from polyvinyl chloride (PVC) pipe (150 cm long, 15 cm in diameter) packed with loamy sand floodplain sediment. Water was applied to the top of the lysimeters at three different flow rates (48, 54, and 68 mm d(-1)). Concentrations of NO3 and dissolved oxygen (DO), chemical oxygen demand (COD), and redox potential (Eh) in the water were measured as functions of depth after the system reached steady states for both water flow and reactions. At the rate of 68.0 mm d(-1), a reducing condition for denitrification developed below the 5-cm depth due to the depletion of O2 by organic matter degradation in the surface oxidizing layer; Eh and DO were below 205 mV and 0.4 mg L(-1), respectively. At a depth of 70 cm, COD and NO3-N concentration decreased to 5.2 and 3.8 mg L(-1) from the respective influent concentrations of 17.1 and 6.2 mg L(-1). Most biodegradable organic matter was removed during flow and further removal of NO3 was limited by the lack of an electron donor (i.e., organic matter). These results indicate that the floodplain filtration technique has great promise for treatment of contaminated river water.  相似文献   

2.
Spatio-temporal variations of biochemical oxygen demand (BOD) and total coliform (TC) in the Han River, Korea, were investigated in terms of concentration-based and mass loading-based approaches. Considering the river water quality criteria regulated by the Ministry of Environment in Korea, the tributaries linked to the mainstream of the Han River were found to be highly contaminated with respect to both BOD and TC and, in fact, most of the tributaries exceeded the maximum water quality criteria. To evaluate the pollution impact of tributaries on the mainstream, the monthly water quality monitoring data for six years (from 1995 to 2000) were collected from the Han River basin, and statistically analyzed using Pearson’s correlation coefficient. The results revealed that mass loading-based approach was superior to the concentration-based approach for effective Han River watershed management. Overall results supported that the mass loading-based approach associated with total maximum daily loads (TMDL) management would be a useful and suitable protocol in watershed management for improving the water quality of the Han River and protecting public health. Therefore, this study supporting TMDL management can be applicable to a wide array of contaminants and watershed settings in Korea.  相似文献   

3.
Abstract: The effect of stream restoration on hyporheic functions has been neglected, although channel rehabilitation projects have a potential to alter stream‐ground‐water interactions. The present study examined the effect of an artificially constructed gravel bar and re‐meandered stream channel on lateral hyporheic exchange flow and chemistry in two lowland N‐rich streams in southern Ontario, Canada. Nitrate concentrations were relatively high, ranging from 0.5 to 1.3 mg N/l in both streams during spring through fall months. However, nitrate concentrations showed a steep decline as stream water entered the gravel bar and the meander bends. Differences between observed and predicted nitrate concentrations based on conservative ion concentration patterns indicated that 40‐100 and 68‐98% of the nitrate entering the hyporheic zone was removed in the gravel bar and meanders, respectively. Rapid depletion of dissolved oxygen concentrations along lateral hyporheic flow paths and denitrifying potentials assayed by the acetylene block technique in hyporheic sediments suggests that denitrification was an important mechanism of nitrate depletion. Despite the high rate of nitrate removal, the flux of stream water laterally entering the constructed gravel bar and meander bends was very small, and hyporheic nitrate removal was <0.015% of the daily stream load during base‐flow periods in summer and fall. The effects of restoration projects on hyporheic zone dynamics are often limited in lowland streams by low channel gradients and fine floodplain sediments with low interstitial flows that restrict the magnitude of the stream‐hyporheic connection.  相似文献   

4.
ABSTRACT: The U.S. Environmental Protection Agency (USEPA) Water Quality Analysis Simulation Program (WASP5) was used to model the transport and sediment/water interactions of metals under low flow, steady state conditions in Tenmile Creek, a mountain stream supplying drinking water to the City of Helena, Montana, impacted by numerous abandoned hard rock mines. The model was calibrated for base flow using data collected by USEPA and validated using data from the U.S. Geological Survey (USGS) for higher flows. It was used to assess metals loadings and losses, exceedances of Montana State water quality standards, metals interactions in stream water and bed sediment, uncertainty in fate and transport processes and model parameters, and effectiveness of remedial alternatives that include leaving contaminated sediment in the stream. Results indicated that during base flow, adits and point sources contribute significant metals loadings to the stream, but that shallow ground water and bed sediment also contribute metals in some key locations. Losses from the water column occur in some areas, primarily due to adsorption and precipitation onto bed sediments. Some uncertainty exists in the metal partition coefficients associated with sediment, significance of precipitation reactions, and in the specific locations of unidentified sources and losses of metals. Standards exceedances are widespread throughout the stream, but the model showed that remediation of point sources and mine waste near water courses can help improve water quality. Model results also indicate, however, that alteration of the water supply scheme and increasing base flow will probably be required to meet all water quality standards.  相似文献   

5.
Recent research and technology have provided promising outcomes to rely on biodiesel as the alternative and conventional source of fuel. The use of renewable sources constitutes the main stream of research. Waste Cooking Oil (WCO) was used for biodiesel production in this study. Lipase enzyme producing fungi Rhizopus oryzae 262 and commercially available pure lipase enzyme were used for comparative study in the production of FAAE. The whole cell biocatalyst and pure enzyme were immobilized using calcium alginate beads. It was prepared by optimizing with different molar ratios of calcium chloride and different percent sodium alginate. Entrapment immobilization was done for whole cell biocatalyst. PE was also immobilized by entrapment for the transesterification reaction. Four different solvents methanol, ethanol, n-propanol, n-butanol were used as the acyl acceptors. The reaction parameters like temperature, molar ratio, reaction time, and amount of enzyme to be used were also optimized for methanol alone. The same parameters were adopted for the other acyl acceptors too. Among the different acyl acceptors, methanol whose reaction parameters were optimized showed maximum conversion of triglycerides to FAAE - 94% with PE and 84% with WCB. On the whole, PE showed better catalytic converting ability with all the acyl acceptor compared to WCB, further study, it was observed that three consecutive and reversible reactions occurred in the interesterification of triglycerides. So, a kinetic model based on Michaelis-Menten equation with competitive substrate inhibition was used to find the maximum reaction rate Vi for the four solvents using pure enzyme and WCB.  相似文献   

6.
ABSTRACT: As part of a study of Redwood National Park in north-western California, an investigation was conducted from June to November 1974 on intragravel dissolved oxygen and sediment in three tributaries to Redwood Creek, a major coastal stream that flows through Redwood National Park. Of concern was whether the intragravel environment of streams in logged and unlogged redwood-forested drainage basins was different. The tributary in the unlogged drainage basin had lower percentages of fine streambed sediment than either of the tributaries in logged drainage basins. Concentration and percentage saturation of dissolved oxygen of intragravel water were highest in the stream in the unlogged drainage basin, intermediate in the stream in the patch-cut drainage basin, and lowest in the stream in the clear-cut drainage basin. The differences in intragravel dissolved-oxygen conditions among the three tributaries are attributed chiefly to differences in their interchange of surface and intragravel water. The larger quantities of fine streambed sediment in the two streams in logged basins may have reduced the permeability of the streambeds and hence their capacity to interchange surface and intragravel water. However, differences in the lithology of the three tributary drainage basins examined may contribute to the differences in the percentage of fine sediments observed among the streams, even in the absence of logging.  相似文献   

7.
ABSTRACT: Karst terrane provides a linkage between surface water and ground water regimes by means of caves, sinkholes and swallets, and sinking streams, and facilitates the inter‐watershed transfer of water and contaminants through these subsurface systems. The goal of this study was to develop procedures to identify the sources of degradation of a creek situated in a complex karst‐water system. The study approach consisted of using dye tracing technique to determine subsurface flow paths through the karst system, a water‐sampling network to identify and characterize pollution sources within the surface watershed and subsurface flow regime, and evaluation of analytical data for several water quality parameters. The results of this study provide an interesting perspective of water and contaminant movement in karst‐water systems and pinpoint the sources of stream contamination for a case study site in southwest Virginia where two springs supply water to a contaminated freshwater stream.  相似文献   

8.
ABSTRACT: The rehabilitation of urban stream channels and riparian areas involves a potentially large number of design alternatives. When substantial modifications are planned, water surface profile models (e.g., HEC-2) provide a means for a thorough and efficient evaluation of many design variations. The rehabilitation of a reach of Paradise Creek, Idaho, utilized the REC-2 model to verify the appropriateness of a new channel geometry and explore the consequences of variable floodplain geometries and excavation depths. The desirability of habitat diversity, coupled with the constraints of minimized earthwork costs and adequate flow capacity, framed the floodplain design question. The final design geometry was iteratively approached using the HEC-2 model to mimic the existing channel capacity. This modeling framework produces as output computed water surface elevations for the design channel and floodplain under any discharge. Hence, the method provides the means for demonstrating that rehabilitation designs will (or will not) cause increases in flood elevations, an assessment that is generally required for project approval.  相似文献   

9.
Reactive barriers are used for in situ treatment of contaminated ground water. Waste green sand, a by-product of gray-iron foundries that contains iron particles and organic carbon, was evaluated in this study as a low-cost reactive material for treating ground water contaminated with the herbicides alachlor [2-chloro-2',6'-diethyl-N-(methoxymethyl)acetanilide] and metolachlor [2-chloro-6'-ethyl-N-(2-methoxy-1-methylethyl)-o-acetoluidide]. Batch and column tests were conducted with 11 green sands to determine transport parameters and reaction rate constants for the herbicides. Similar Fe-normalized rate constants (K(SA)) were obtained from the batch and column tests. The K(SA) values obtained for green sand iron were also found to be comparable with or slightly higher than K(SA) values for Peerless iron, a common reactive medium used in reactive barriers. Partition coefficients ranging between 3.6 and 50.2 L/kg were obtained for alachlor and between 1.0 and 54.8 L/kg for metolachlor, indicating that the organic carbon and clay in green sands can significantly retard the movement of the herbicides. Partition coefficients obtained from the batch and column tests were similar (+/-25%), but the batch tests typically yielded higher partition coefficients for green sands exhibiting greater sorption. Calculations made using transport parameters from the column tests indicate that a 1-m-thick reactive barrier will result in a 10-fold reduction in concentration of alachlor and metolachlor for seepage velocities less than 0.1 m/d provided the green sand contains at least 2% iron. This level of reduction generally is sufficient to reduce alachlor and metolachlor concentrations below maximum contaminant levels in the United States.  相似文献   

10.
Between 1850 and 1970, rivers throughout Sweden were channelized to facilitate timber floating. Floatway structures were installed to streamline banks and disconnect flow to secondary channels, resulting in simplified channel morphologies and more homogenous flow regimes. In recent years, local authorities have begun to restore channelized rivers. In this study, we examined the effects of restoration on riparian plant communities at previously disconnected secondary channels of the Pite River. We detected no increase in riparian diversity at restored sites relative to unrestored (i.e., disconnected) sites, but we did observe significant differences in species composition of both vascular plant and bryophyte communities. Disconnected sites featured greater zonation, with mesic-hydric floodplain species represented in plots closest to the stream and mesic-xeric upland species represented in plots farthest from the stream. In contrast, restored sites were most strongly represented by upland species at all distances relative to the stream. These patterns likely result from the increased water levels in reconnected channels where, prior to restoration, upland plants had expanded toward the stream. Nonetheless, the restored fluvial regime has not brought about the development of characteristic flood-adapted plant communities, probably due to the short time interval (ca. 5 years) since restoration. Previous studies have demonstrated relatively quick responses to similar restoration in single-channel tributaries, but secondary channels may respond differently due to the more buffered hydrologic regimes typically seen in anabranching systems. These findings illustrate how restoration outcomes can vary according to hydrologic, climatic and ecological factors, reinforcing the need for site-specific restoration strategies.  相似文献   

11.
The purpose of this research is to study the temporal and spatial sediment delivery to and within the stream network following a wildfire on a chaparral watershed in Arizona, USA. Methods include interpretation of channel processes (aggradation, degradation) from sequential aerial photographs, field measurements of sediment delivery, and overland flow from ten microwatersheds having different vegetation cover (no vegetation, chaparral cover, and bare with vegetation buffer strips). The response of the watershed to the fire was very complex. The fire reduced the chaparral cover to zero in most locations and severe erosion led to filling of the channels by sediment. With vegetation recovery, sediment delivery from the watershed practically ceased. Vegetation buffer strips were mainly responsible for arresting the sediment delivered from bare hillslopes. Relatively clear water, entering the channels, caused degradation in the tributaries that delivered the sediment into the main stream at El Oso Creek. Due to high water infiltration by immense volumes of sediment deposits in the middle reach, the sediment from the tributaries was deposited as in-channel fans. In contrast, the upper reach of El Oso Creek behaved similarly to the tributaries. It aggraded after the fire and was followed by degradation. The low reach of El Oso Creek is degrading because it is still adjusting base level to the incision of the master stream. Implications of this study are that land managers, concerned to avoid severe erosion and sedimentation following disturbance, should concentrate on the establishment and enhancement of vegetation buffer strips along channel banks.  相似文献   

12.
Since 1994, water-quality constituents have been measured monthly in three adjacent Coastal Plain watersheds in southwestern Georgia. During 1994, rainfall was 650 mm above annual average and the highest flows on record were observed. From November 1998 through November 2000, 19 months had below average rainfall. Lowest flows on record were observed during the summer of 2000. The watersheds are human-dominated with row-crop agriculture and managed forestlands being the major land uses. However, one watershed (Chickasawhatchee Creek) had 10 to 13% less agriculture and greater wetland area, especially along the stream. Suspended particles, dissolved organic carbon, NH4-N, and soluble reactive phosphorus concentrations were greater during wet and flood periods compared with dry and drought periods for each stream. Regional hydrologic conditions had little effect on NO3-N or dissolved inorganic carbon. Chickasawhatchee Creek had significantly lower suspended sediment and NO3-N concentrations and greater organic and inorganic carbon concentrations, reflecting greater wetland area and stronger connection to a regional aquifer system. Even though substantial human land use occurred within all watersheds, water quality was generally good and can be attributed to low stream drainage density and relatively intact floodplain forests. Low drainage density minimizes surface run-off into streams. Floodplain forests reduce nonpoint-source pollutants through biological and physical absorption. In addition to preserving water quality, floodplain forests provide important ecological functions through the export of nutrients and organic carbon to streams. Extreme low flows may be disruptive to aquatic life due to both the lack of water and to the scarcity of biologically important materials originating from floodplain forests.  相似文献   

13.
The optimum conditions for the recovery of copper from a contaminated soil by using the soil flushing technique are evaluated. Tests on a soil artificially contaminated with copper chloride were carried out in order to evaluate the influence of the speed of percolation and of the chelating agent concentration (aqueous solution of an ethylendiaminotetraacetic acid di-sodium salt Na2-EDTA). At pH=7.3 an efficiency up to 93.9% for copper extraction was achieved by flushing 500 ml of Na2-EDTA 0.05 M solution and 100 ml of pure water at 0.792 cm/h. At these operating conditions the formation of EDTA complexes with other competitive cations (calcium and iron) was negligible. The experimental results were in agreement with the ones obtained using a model describing the chemistry of metal extraction. This model assessed that above pH=6 the formation of calcium and iron EDTA complexes was excluded and only the chelation of copper was allowed. The recovery of 91.6% of EDTA was also achieved by evaporating and acidifying the extracted solution: after filtration, solid EDTA was obtained, through the addition of sodium hydroxide Na2-EDTA. About 99.5% of the extracted copper was finally precipitated under alkaline conditions from the liquid phase.  相似文献   

14.
In the present study, chemically modified Aleppo pine (Pinus halepensis Miller) sawdust was used for the removal of phosphate from water. Biosorbent preparation process included size fractionation, extraction for surface activation, acid prehydrolysis, and treatment with urea. Sorption of phosphate ions onto biosorbent was studied using the batch technique. The effect of different parameters such as contact time, adsorbate concentration, and temperature was investigated. The adsorption kinetics data were best described by the pseudo-second-order rate equation, and equilibrium was achieved after 40 and 80 min for modified and unmodified sawdust, respectively. The Langmuir and Freundlich equations for describing adsorption equilibrium were applied to data. The constants and correlation coefficients of these isotherm models were calculated and compared. The adsorption isotherms obey the Freundlich equation. The thermodynamic parameters like free energy, enthalpy, and entropy changes for the adsorption of phosphate ions have been evaluated, and it has been found that the reaction was spontaneous and endothermic in nature. The low value of activated energy of adsorption, 3.088–3.540 kJ mol−1, indicates that the phosphate ions are easily adsorbed on the sawdust. Results suggest that the prepared chemically modified Aleppo pine sawdust has potential in remediation of contaminated waters by phosphate.  相似文献   

15.
The widespread construction of levees has reduced river–floodplain connectivity and altered associated fluvial processes in many river systems. Despite the recognition that levees can alter floodplain connectivity, few studies have examined the role of levees in reducing floodplain areas at large watershed scales. This paper explores the application of a hydrogeomorphic floodplain inundation model in the Wabash Basin, located in the Midwestern United States, to assess changes in floodplain area in levee‐protected areas. We evaluate 10‐ and 30‐m topographic resolutions and spatially examine the influence of levees on floodplain area in relation to river network attributes. Generally, floodplains in levee‐protected areas were influenced by topographic resolution, stream order, and elevation details of levees found in topography datasets. We show, when compared to Federal Emergency Management Agency maps, our approach underpredicts floodplain area when using 10‐m resolution topography data but only slightly overpredicts when using 30‐m resolution data. After removing details of levees from topography data, we found changes in floodplain area varied spatially, but basin‐aggregate results changed little compared to topography datasets that contain levees, though larger floodplain areas were produced in some regions where levees were removed. This work contributes to a growing research emphasis on using hydrogeomorphic floodplain models to understand floodplain disconnectivity.  相似文献   

16.
The harvested mycelial waste of Trichoderma harzianum was used as an adsorbent for the removal of rhodamine 6G and was studied in batch mode. The effects of agitation time and initial dye concentration, adsorbent dosage and pH were examined. The study revealed that the amount of dye adsorbed (mgg(-1)) increased with increase in agitation time and reached equilibrium after 120 min, for dye concentrations of 10-50 mg L(-1). The adsorbent dosage of 1.0 g/50 mL and pH of 8.0 were found to be optimum for maximum dye removal. The batch mode adsorption data followed both the Langmuir and Freundlich isotherms. The pseudo first- and second-order rate kinetics were applied to the adsorbent system. The adsorption kinetics of rhodamine 6G showed that the pseudo-second-order kinetic model provided the best correlation of the equilibrium data. The study implies that it is possible to develop a dye removal system by using T. harzianum biomass, which occurs as sludge in waste stream of fermentation industries.  相似文献   

17.
ABSTRACT: The environment surrounding urban streams imposes constraints upon stream enhancement projects. Constraints include bridges, culverts, highways, sewer and water lines, lack of easements, and other floodplain structures. The consequences of failure of these infrastructure constraints can be significant and should be considered in the design process. Fault tree analysis provides a systematic technique for analyzing the interactions of events that could lead to infrastructure failure. A case study of a stream in Pittsburgh, Pennsylvania, shows that fault tree analysis can effectively model the interactions between the stream system and the infrastructure constraints and predict the most likely modes of failure. In addition, the relative success of alternative designs and failure mitigation techniques can be assessed using this analysis tool, lending insight into the urban stream enhancement design process. The method could also provide justification in the design permitting process and input for risk assessment.  相似文献   

18.
Floodplains and streambanks can positively and negatively influence downstream water quality through interacting geomorphic and biogeochemical processes. Few studies have measured those processes in agricultural watersheds. We measured inputs (floodplain sedimentation and dissolved inorganic loading), cycling (floodplain soil nitrogen [N] and phosphorus [P] mineralization), and losses (bank erosion) of sediment, N, and P longitudinally in stream reaches of Smith Creek, an agricultural watershed in the Valley and Ridge physiographic province. All study reaches were net depositional (floodplain deposition > bank erosion), had high N and P sedimentation and loading rates to the floodplain, high soil concentrations of N and P, and high rates of floodplain soil N and P mineralization. High sediment, N, and P inputs to floodplains are attributed to agricultural activity in the region. Rates of P mineralization were much greater than those measured in other studies of nontidal floodplains that used the same method. Floodplain connectivity and sediment deposition decreased longitudinally, contrary to patterns in most watersheds. The net trapping function of Smith Creek floodplains indicates a benefit to water quality. Further research is needed to determine if future decreases in floodplain deposition, continued bank erosion, and the potential for nitrate leaching from nutrient‐enriched floodplain soils could pose a long‐term source of sediment and nutrients to downstream rivers.  相似文献   

19.
Given the unique biogeochemical, physical, and hydrologic services provided by floodplain wetlands, proper management of river systems should include an understanding of how floodplain modifications influence wetland ecosystems. The construction of levees can reduce river–floodplain connectivity, yet it is unclear how levees affect wetlands within floodplains, let alone the cumulative impacts within an entire watershed. This paper explores spatial relationships between levee and floodplain wetland systems in the Wabash Basin, United States. We used a hydrogeomorphic floodplain delineation technique to map floodplain extents and identify wetlands that may be hydrologically connected to river networks. We then spatially examined the relationship between levee presence, wetland area, and other river network attributes within discrete subbasins. Our results show that cumulative wetland area is relatively constant in subbasins that contain levees, regardless of maximum stream order within the subbasin. In subbasins that do not contain levees, cumulative wetland area increases with maximum stream order. However, we found that wetland distributions around levees can be complex, and further studies on the influence of levees on wetland habitat may need to consider finer resolution spatial scales.  相似文献   

20.
Densmore, Roseann V. and Kenneth F. Karle, 2009. Flood Effects on an Alaskan Stream Restoration Project: The Value of Long‐Term Monitoring. Journal of the American Water Resources Association (JAWRA) 45(6):1424‐1433. Abstract: On a nationwide basis, few stream restoration projects have long‐term programs in place to monitor the effects of floods on channel and floodplain configuration and floodplain vegetation, but long‐term and event‐based monitoring is required to measure the effects of these stochastic events and to use the knowledge for adaptive management and the design of future projects. This paper describes a long‐term monitoring effort (15 years) on a stream restoration project in Glen Creek in Denali National Park and Preserve in Alaska. The stream channel and floodplain of Glen Creek had been severely degraded over a period of 80 years by placer mining for gold, which left many reaches with unstable and incised streambeds without functioning vegetated floodplains. The objectives of the original project, initiated in 1991, were to develop and test methods for the hydraulic design of channel and floodplain morphology and for floodplain stabilization and riparian habitat recovery, and to conduct research and monitoring to provide information for future projects in similar degraded watersheds. Monitoring methods included surveyed stream cross‐sections, vegetation plots, and aerial, ground, and satellite photos. In this paper we address the immediate and outlying effects of a 25‐year flood on the stream and floodplain geometry and riparian vegetation. The long‐term monitoring revealed that significant channel widening occurred following the flood, likely caused by excessive upstream sediment loading and the fairly slow development of floodplain vegetation in this climate. Our results illustrated design flaws, particularly in regard to identification and analysis of sediment sources and the dominant processes of channel adjustment.  相似文献   

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